ES2188600T3 - Procedimiento de preparacion de polimeros de etileno y productos de esta forma obtenidos. - Google Patents

Procedimiento de preparacion de polimeros de etileno y productos de esta forma obtenidos.

Info

Publication number
ES2188600T3
ES2188600T3 ES94113559T ES94113559T ES2188600T3 ES 2188600 T3 ES2188600 T3 ES 2188600T3 ES 94113559 T ES94113559 T ES 94113559T ES 94113559 T ES94113559 T ES 94113559T ES 2188600 T3 ES2188600 T3 ES 2188600T3
Authority
ES
Spain
Prior art keywords
procedure
products
preparation
ethylene polymers
form obtained
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94113559T
Other languages
English (en)
Inventor
Luigi Resconi
Fabrizio Piemontesi
Maurizio Galimberti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Application granted granted Critical
Publication of ES2188600T3 publication Critical patent/ES2188600T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

HOMORES MUY ALTOS Y DISTRIBUCIONES DE PESO MOLECULAR ESTRECHAS SE OBTIENEN A TRAVES DE LLEVAR A CABO LA REACCION DE POLIMERIZACION EL PRESENCIA DE CATALIZADORES CON BASE DE METALOCENO EN DONDE EL METALOCENO ES ESTEREORIGIDO Y ESTA EN SU FORMA ISOMERICA MESO.
ES94113559T 1993-09-13 1994-08-31 Procedimiento de preparacion de polimeros de etileno y productos de esta forma obtenidos. Expired - Lifetime ES2188600T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI931960A IT1271406B (it) 1993-09-13 1993-09-13 Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti

Publications (1)

Publication Number Publication Date
ES2188600T3 true ES2188600T3 (es) 2003-07-01

Family

ID=11366885

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94113559T Expired - Lifetime ES2188600T3 (es) 1993-09-13 1994-08-31 Procedimiento de preparacion de polimeros de etileno y productos de esta forma obtenidos.

Country Status (15)

Country Link
US (2) US5585448A (es)
EP (1) EP0643078B1 (es)
JP (1) JPH07165813A (es)
KR (2) KR100328099B1 (es)
CN (3) CN1069651C (es)
AU (1) AU690127B2 (es)
BR (1) BR9403069A (es)
CA (1) CA2131940A1 (es)
DE (1) DE69432040T2 (es)
ES (1) ES2188600T3 (es)
FI (1) FI944193L (es)
IL (1) IL110905A (es)
IT (1) IT1271406B (es)
RU (1) RU2161627C2 (es)
TR (1) TR27973A (es)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1271407B (it) * 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti
DE59409642D1 (de) * 1993-11-24 2001-03-01 Targor Gmbh Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
IT1273660B (it) * 1994-07-20 1997-07-09 Spherilene Srl Procedimento per la preparazione di polimeri amorfi del propilene
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine
TW383313B (en) * 1994-12-20 2000-03-01 Mitsui Petrochemical Ind Preparation of ethylene-alpha-olefin-nonconjugate polyene random copolymers, the copolymers obtaining which, and the use of the copolymers
IT1272922B (it) * 1995-01-23 1997-07-01 Spherilene Srl Procedimento per la preparazione di composti metallocenici
WO1996023750A1 (de) * 1995-02-01 1996-08-08 Basf Aktiengesellschaft Verfahren zur herstellung von olefin-oligomeren
IT1275856B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione
IT1275857B1 (it) * 1995-03-03 1997-10-24 Spherilene Srl Copolimeri atattici del propilene con l'etilene
IT1274469B (it) * 1995-05-11 1997-07-17 Spherilene Spa Composizioni poliolefiniche vulcanizzabili dinamicamente
ES2182950T3 (es) * 1995-05-16 2003-03-16 Univation Tech Llc Produccion de polietileno utilizando metalocenos estereosomericos.
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
IT1283630B1 (it) * 1996-05-09 1998-04-23 Enichem Spa Procedimento per la preparazione di copolimeri elastomerici ep(d)m
FR2749018B1 (fr) * 1996-05-21 1998-07-31 Hutchinson Elastomere reticule a transformation thermoplastique, son procede de fabrication et ses utilisations
IT1284097B1 (it) * 1996-07-02 1998-05-08 Montell Tecnology Company Bv Processo in sospensione per la preparazione di copolimeri elastomerici dell'etilene
DE69720609T2 (de) * 1996-07-16 2003-11-13 Basell Polyolefine Gmbh Verfahren zur Modifikation von die Rac/Meso-Verhältnis einer Metallocenverbindung
IL129600A0 (en) * 1996-11-15 2000-02-29 Montell Technology Company Bv Heterocyclic metallocenes and polymerization catalysts
US6177377B1 (en) * 1996-12-18 2001-01-23 Amherst Polymer Technology, Inc. Polymer blends and process for preparation
FI972230A7 (fi) 1997-01-28 1998-07-29 Borealis As Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus
CA2292538A1 (en) * 1997-06-14 1998-12-23 Charles L. Myers Ethylene enhancement of processes for synthesis of high melting thermoplastic elastomeric .alpha.-olefin polymers (pre/epe effects)
NL1006346C2 (nl) * 1997-06-18 1998-12-21 Dsm Nv Werkwijze voor de bereiding van polyolefines bij hoge temperatuur met behulp van Zr-metallocenen.
US7026404B2 (en) * 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6559252B1 (en) * 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
US6518378B2 (en) 1998-01-09 2003-02-11 The Board Of Trustees Of The Leland Stanford Junior University High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis
US6479685B2 (en) 1998-01-09 2002-11-12 The Board Of Trustees Of The Leland Standard Junior University Metallocene catalysts for synthesis of high-melting polyolefin copolymer elastomers
AU2111599A (en) 1998-01-09 1999-07-26 Board Of Trustees Of The Leland Stanford Junior University High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis
US6977283B1 (en) 1998-04-07 2005-12-20 Exxonmobil Chemical Patents Inc. Polymerization process
JP4579413B2 (ja) * 1998-04-07 2010-11-10 エクソンモービル・ケミカル・パテンツ・インク 重合方法
EP0953582A1 (en) * 1998-04-27 1999-11-03 Fina Research S.A. Polyolefin production
EP1098934A1 (en) 1998-07-01 2001-05-16 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
BR9916426A (pt) * 1998-12-21 2001-09-04 Exxonmobil Chem Patents Inc Composições semicristalinas de c3 etileno-propileno superior ramificado
US6818585B2 (en) 1998-12-30 2004-11-16 Univation Technologies, Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US6469188B1 (en) 1999-01-20 2002-10-22 California Institute Of Technology Catalyst system for the polymerization of alkenes to polyolefins
CA2392949A1 (en) * 1999-12-01 2001-06-07 Univation Technologies Llc Catalyst compounds, catalyst systems thereof and their use in a polymerization process
US6534153B1 (en) 1999-12-09 2003-03-18 Exxonmobil Oil Corporation Matte surface film with improved matte appearance
JP5156167B2 (ja) 2001-04-12 2013-03-06 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンポリマー及び製造法
KR100458600B1 (ko) * 2002-02-07 2004-12-03 주식회사 엘지화학 메틸렌 브릿지된 메탈로센 촉매를 이용한 올레핀-시클릭올레핀 공중합체의 제조 방법
US6706828B2 (en) * 2002-06-04 2004-03-16 Crompton Corporation Process for the oligomerization of α-olefins having low unsaturation
WO2004033510A2 (en) * 2002-10-10 2004-04-22 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
SE0300195D0 (sv) * 2003-01-28 2003-01-28 Borealis Tech Oy Coating composition, method of preparation thereofand substrate coated therewith
WO2004094490A1 (en) * 2003-04-15 2004-11-04 Exxonmobil Chemical Patents Inc. Catalysts for propylene copolymers, polymerization process and copolymer of propylene
DE10360060A1 (de) 2003-12-19 2005-07-21 Basell Polyolefine Gmbh Verfahren zur meso-selektiven Synthese von anso-Metallocen
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
US7598329B2 (en) 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
WO2009104783A1 (en) 2008-02-20 2009-08-27 Sumitomo Chemical Company, Limited Catalyst component for polymerization of ethylene and process for producing ethylene polymer (2)
CN101945901B (zh) * 2008-02-20 2012-09-26 住友化学株式会社 乙烯均聚物
EA024402B1 (ru) * 2010-07-01 2016-09-30 Тотал Ресерч Энд Текнолоджи Фелюи Применение каталитической системы на носителе для получения полиолефинов
EP2591017B1 (en) 2010-07-06 2015-09-09 Ticona GmbH Process for producing high molecular weight polyethylene
CN102959144A (zh) 2010-07-06 2013-03-06 提克纳有限公司 高分子量聚乙烯纤维和膜、它们的生产和用途
JP2013529718A (ja) 2010-07-06 2013-07-22 ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング 高分子量ポリエチレンの製造方法
WO2012004680A2 (en) 2010-07-06 2012-01-12 Ticona Gmbh Process for producing high molecular weight polyethylene
BR112012032745A2 (pt) 2010-07-06 2016-11-08 Ticona Gmbh processo para produção de polietileno de alto peso molecular
WO2013093540A1 (en) 2011-12-19 2013-06-27 Ticona Gmbh Process for producing high molecular weight polyethylene
KR101457120B1 (ko) * 2012-08-03 2014-10-31 주식회사 엘지화학 전이 금속 화합물을 포함하는 전이 금속 촉매 조성물 및 상기 촉매 조성물을 이용한 폴리 올레핀의 제조 방법
CN110922516B (zh) * 2018-09-20 2022-12-30 中国石油化工股份有限公司 一种乙烯共聚物及其制备方法
CN114716599B (zh) * 2021-01-05 2024-02-13 中国石油化工股份有限公司 一种烯烃共聚物及其制备方法与应用

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3288768A (en) * 1962-04-19 1966-11-29 Chisso Corp Method for manufacturing amorphous linear copolymers
DE1720720C3 (de) * 1967-10-05 1979-08-02 Bunawerke Huels Gmbh, 4370 Marl Verfahren zur Herstellung von amorphen Copolymeren aus Äthylen und höheren a -Olefinen mit modifizierten metallorganischen Mischkatalysatoren
US3957743A (en) * 1971-07-09 1976-05-18 Montecatini Edison S.P.A. Process for producing elastomers and intermediates for synthetic rubbers
US4013823A (en) * 1972-06-09 1977-03-22 The B. F. Goodrich Company Process for preparing elastomeric copolymers of ethylene and higher alpha-olefins
FR2460964A1 (fr) * 1979-07-06 1981-01-30 Naphtachimie Sa Copolymeres elastomeres d'ethylene et de propylene, leur fabrication et leurs applications
DZ520A1 (fr) * 1982-03-24 2004-09-13 Union Carbide Corp Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé.
FR2597487B1 (fr) * 1986-04-17 1989-09-29 Bp Chimie Sa Copolymeres amorphes de masse moleculaire elevee d'ethylene et d'alpha-olefines.
EP0275925B1 (en) * 1987-01-19 1995-04-05 Sumitomo Chemical Company, Limited Rubbery copolymers of ethylene, propylene and a nonconjugated polyene and their use
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5229478A (en) * 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
CA1327673C (en) * 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3836059A1 (de) * 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
PL286365A1 (en) * 1989-08-03 1991-04-22 Exxon Chemical Patents Inc Method of polymerizing especially ethylene any polymerization catalyst and method of obtaining same
EP0672689A1 (en) * 1990-06-22 1995-09-20 Exxon Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
DE59104869D1 (de) * 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
US5134209A (en) * 1990-12-26 1992-07-28 Shell Oil Company Process of producing ethylene-propylene rubbery copolymer
DE59209568D1 (de) * 1991-02-27 1999-01-07 Ticona Gmbh Verfahren zur Herstellung von Cycloolefin(co)polymeren mit enger Molekulargewichtsverteilung
ATE223440T1 (de) * 1991-03-09 2002-09-15 Basell Polyolefine Gmbh Metallocen und katalysator
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
TW300901B (es) * 1991-08-26 1997-03-21 Hoechst Ag
DE59210001D1 (de) * 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
TW318184B (es) * 1991-11-30 1997-10-21 Hoechst Ag
DE69310390T2 (de) * 1992-01-23 1997-10-23 Mitsui Petrochemical Ind Verfahren zur Herstellung eines Polyolefins
US5620760A (en) * 1992-06-30 1997-04-15 Montell Technology Company Bv Shaped articles for biomedical use
ATE177436T1 (de) * 1992-08-15 1999-03-15 Targor Gmbh Verfahren zur herstellung von polyolefinen
IT1264680B1 (it) * 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system

Also Published As

Publication number Publication date
DE69432040T2 (de) 2003-08-14
AU690127B2 (en) 1998-04-23
AU7286994A (en) 1995-03-23
FI944193A0 (fi) 1994-09-12
KR950008543A (ko) 1995-04-19
IL110905A0 (en) 1994-11-28
DE69432040D1 (de) 2003-02-27
US5585448A (en) 1996-12-17
RU94033101A (ru) 1996-07-20
RU2161627C2 (ru) 2001-01-10
CN1069651C (zh) 2001-08-15
KR100328114B1 (ko) 2002-03-09
ITMI931960A0 (it) 1993-09-13
EP0643078A2 (en) 1995-03-15
IL110905A (en) 2001-08-08
EP0643078B1 (en) 2003-01-22
TR27973A (tr) 1995-11-07
US5886123A (en) 1999-03-23
IT1271406B (it) 1997-05-28
JPH07165813A (ja) 1995-06-27
CN1105674A (zh) 1995-07-26
CN1308090A (zh) 2001-08-15
FI944193A7 (fi) 1995-03-14
ITMI931960A1 (it) 1995-03-13
KR100328099B1 (ko) 2002-06-22
BR9403069A (pt) 1995-05-02
EP0643078A3 (en) 1995-04-26
CN1149586A (zh) 1997-05-14
CA2131940A1 (en) 1995-03-14
FI944193L (fi) 1995-03-14

Similar Documents

Publication Publication Date Title
RU94033101A (ru) Способ получения полимеров этилена и продукты, полученные из них
ES2171668T3 (es) Catalizador en soporte de polimero para la polimerizacion de olefinas.
ES2167488T3 (es) Catalizadores ziegler-natta con metalocenos para la polimerizacion de olefinas.
DE69532461D1 (de) Katalysatorsysteme und Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtverteilung
MX9604229A (es) Compuesto de metaloceno, procedimiento para su preparacion y su uso en catalizadores para la polimerizacion de olefinas.
DE69823031D1 (de) Olefin polymerisationsverfahren
MX9206587A (es) Proceso para la preparacion de un catalizador prepolimerizado.
AR009035A1 (es) Complejos de metales que contienen ciclopentadienilo sustituido por un heteroatomo en posicion 3; sistemas catalizadores para la polimerizacion deolefinas que incluyen dichos complejos, procedimiento para polimerizar olefinas con dichos sistemas, productos de poliolefinas obtenidos con dicho
BR9814410A (pt) Sistema catalisador suportado, uso do mesmo, e, processos para preparar um polìmero de olefina e, um sistema catalisador suportado.
AR016279A1 (es) Procedimiento de sintesis de polimeros en bloque, polimeros en bloque obtenidos y compuesto precursor para obtenerlos
ATE132507T1 (de) Trägerkatalysator für olefinpolymerisation mit monozyklopentadienylkomplexen von übergangsmetallen
ES2196395T3 (es) Copolimeros cicloolefinicos, su empleo y articulos moldeados preparados a partir de ellos.
ES2176180T3 (es) Uso de compuestos organometalicos de fluorenilo.
BR9506041A (pt) Copolímeros de etileno e processo para a preparação de polímeros à base de etileno
AR027124A1 (es) Proceso para la preparacion de polimeros de etileno y compuesto de metaloceno
MY112105A (en) Process for the preparation of ethylene polymers and products obtained therefrom.
NO933577D0 (no) Kromkatalysatorblandinger
ES2165637T3 (es) Proceso para la preparacion de un polimero cicloolefinico.
ES2196606T3 (es) Articulos de moldeo por inyeccion hechos a partir de metaloceno-popipropileno.
ES2079213T3 (es) Catalizador para la polimerizacion de olefinas, procedimiento para su produccion y su empleo.
ATE269366T1 (de) Ethylenpolymerisation
BR9914828B1 (pt) processo para a polimerizaÇço de pelo menos uma ou mais olefinas.
BR9917391A (pt) Processo para a polimerização de pelo menos uma ou mais olefinas, filme, e, artigo
FI891669A7 (fi) Katalyytti etyleenipolymeerien molekyylipainojakautuman säätämiseksi
ES2156362T3 (es) Procedimiento para la obtencion de polimeros de alquenos mediante polimerizacion en fase gaseosa.