ES2191137T3 - Procedimiento para la deshidrogenacion de 1,4-butano-diol para dar gama-butirolactona. - Google Patents

Procedimiento para la deshidrogenacion de 1,4-butano-diol para dar gama-butirolactona.

Info

Publication number
ES2191137T3
ES2191137T3 ES97115339T ES97115339T ES2191137T3 ES 2191137 T3 ES2191137 T3 ES 2191137T3 ES 97115339 T ES97115339 T ES 97115339T ES 97115339 T ES97115339 T ES 97115339T ES 2191137 T3 ES2191137 T3 ES 2191137T3
Authority
ES
Spain
Prior art keywords
dehydrogenation
butirolactone
butane
diol
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97115339T
Other languages
English (en)
Inventor
Hans Jochen Dr Mercker
Frank-Friedrich Dr Pape
Joachim Dr Simon
Andreas Dr Henne
Michael Dr Hesse
Ulrich Dr Kohler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2191137T3 publication Critical patent/ES2191137T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/394—Metal dispersion value, e.g. percentage or fraction

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

METODO PARA LA DESHIDROGENACION DE 1,4 OR QUE CONTIENE COBRE; EN DICHO METODO EL CATALIZADOR CONTIENE 4 A 40 % EN PESO DE COBRE Y 0 A 5 % EN PESO DE NA SUB,2}O, CON RESPECTO AL PESO TOTAL DEL CATALIZADOR, SOBRE UN SOPORTE DE 80 A 100 % EN PESO DE SIO SUB,2} Y 0 A 20 % EN PESO DE CAO.
ES97115339T 1996-09-05 1997-09-04 Procedimiento para la deshidrogenacion de 1,4-butano-diol para dar gama-butirolactona. Expired - Lifetime ES2191137T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19636066A DE19636066A1 (de) 1996-09-05 1996-09-05 Verfahren zur Dehydrierung von 1,4-Butandiol zu gamma-Butyrolacton

Publications (1)

Publication Number Publication Date
ES2191137T3 true ES2191137T3 (es) 2003-09-01

Family

ID=7804722

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97115339T Expired - Lifetime ES2191137T3 (es) 1996-09-05 1997-09-04 Procedimiento para la deshidrogenacion de 1,4-butano-diol para dar gama-butirolactona.

Country Status (7)

Country Link
US (2) US5955620A (es)
EP (1) EP0827956B1 (es)
JP (1) JP4152460B2 (es)
KR (1) KR100456497B1 (es)
DE (2) DE19636066A1 (es)
ES (1) ES2191137T3 (es)
TW (1) TW418199B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100363644B1 (ko) * 2000-07-24 2002-12-05 애경유화 주식회사 무수말레인산으로부터 감마-부티로락톤을 제조하는 기상수소화 촉매, 그 촉매의 제조 방법 및 그 촉매를 사용하여감마-부티로락톤의 제조 방법
DE60004072T2 (de) * 2000-12-14 2004-02-12 Dairen Chemical Corp. Verfahren für die Herstellung von Lacton
RU2217428C2 (ru) * 2002-02-18 2003-11-27 ГУ Институт нефтехимии и катализа АН РБ и УНЦ РАН Способ получения лактонов
CN1301984C (zh) * 2005-04-14 2007-02-28 复旦大学 一种γ－丁内酯的催化合成方法
US8828903B2 (en) * 2008-11-10 2014-09-09 Basf Corporation Copper catalyst for dehydrogenation application
CN102029156B (zh) * 2009-10-07 2013-02-27 Sk新技术株式会社 由1,4-丁二醇制备γ-丁内酯和N-甲基吡咯烷酮的方法
CN102665900B (zh) * 2009-12-25 2015-03-04 东曹株式会社 氢化催化剂和其制造方法、以及其用途
JP5966244B2 (ja) * 2009-12-25 2016-08-10 東ソー株式会社 水素化触媒とその製造方法、及びその用途
CN115367702A (zh) * 2022-07-25 2022-11-22 朱义峰 一种用于氢燃料电池的在线供氢系统及方法
CN115779957B (zh) * 2022-12-10 2024-03-19 南通格瑞凯泰工程技术有限公司 1,4-丁二醇低压脱氢制γ-丁内酯用催化剂及其应用
CN117582993B (zh) * 2023-11-22 2025-12-26 万华化学集团股份有限公司 一种由1,4-丁二醇脱氢制备γ-丁内酯的催化剂、制备方法及其应用
FR3161127A1 (fr) 2024-04-11 2025-10-17 Commissariat A L'energie Atomique Et Aux Energies Alternatives Catalyseur pour l’hydrogénation et la déshydrogénation de vecteurs d’hydrogène liquides organiques
FR3161126A1 (fr) 2024-04-11 2025-10-17 Commissariat A L'energie Atomique Et Aux Energies Alternatives Catalyseur pour l’hydrogénation et la déshydrogénation de vecteurs d’hydrogène liquides organiques

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE699945C (de) * 1938-07-16 1940-12-10 I G Farbenindustrie Akt Ges von Diolen
GB1066979A (en) * 1966-04-06 1967-04-26 Leuna Werke Veb Process for the production of ª†-butyrolactone
DE2845905C3 (de) * 1978-10-21 1983-05-26 Chemische Werke Hüls AG, 4370 Marl Verfahren zur kontinuierlichen Herstellung von Butandiol-1,4
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
EP0304696B1 (de) * 1987-08-08 1992-04-29 BASF Aktiengesellschaft Verfahren zur Herstellung von 1,4-Butandiol und/oder Tetrahydrofuran
JPH02255668A (ja) * 1989-03-28 1990-10-16 Daicel Chem Ind Ltd ラクトン化合物の製造方法
JP3095293B2 (ja) * 1992-08-25 2000-10-03 東燃化学株式会社 γ‐ブチロラクトンの製造方法
DE4339269A1 (de) * 1993-11-18 1995-05-24 Basf Ag Verfahren zur Herstellung von gamma-Butyrolacton
DE4403187C1 (de) * 1994-02-02 1995-09-28 Degussa Geformter Kupfer-Katalysator für die selektive Hydrierung von Furfural zu Furfurylalkohol
FR2729090A1 (fr) * 1995-01-11 1996-07-12 Inst Francais Du Petrole Catalyseurs de reduction selective des oxydes d'azote en azote en milieu oxydant, procede de preparation et utilisation

Also Published As

Publication number Publication date
US5955620A (en) 1999-09-21
EP0827956A1 (de) 1998-03-11
DE59709132D1 (de) 2003-02-20
DE19636066A1 (de) 1998-03-12
US6093677A (en) 2000-07-25
KR19980024362A (ko) 1998-07-06
KR100456497B1 (ko) 2005-11-25
TW418199B (en) 2001-01-11
JPH10152485A (ja) 1998-06-09
EP0827956B1 (de) 2003-01-15
JP4152460B2 (ja) 2008-09-17

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