ES2191500A1 - Nueva polinitramina, su procedimiento de sintesis, nuevas composiciones pirotecnicas. - Google Patents
Nueva polinitramina, su procedimiento de sintesis, nuevas composiciones pirotecnicas.Info
- Publication number
- ES2191500A1 ES2191500A1 ES009501473A ES9501473A ES2191500A1 ES 2191500 A1 ES2191500 A1 ES 2191500A1 ES 009501473 A ES009501473 A ES 009501473A ES 9501473 A ES9501473 A ES 9501473A ES 2191500 A1 ES2191500 A1 ES 2191500A1
- Authority
- ES
- Spain
- Prior art keywords
- dodecane
- hexa
- hexanitro
- new
- polynitramine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 239000002131 composite material Substances 0.000 title 1
- 239000002360 explosive Substances 0.000 title 1
- 239000003721 gunpowder Substances 0.000 title 1
- 239000004449 solid propellant Substances 0.000 title 1
- NINQAYBICGTGQD-UHFFFAOYSA-N 1-(6,8,12-triacetyl-4,10-dibenzyl-2,4,6,8,10,12-hexazatetracyclo[5.5.0.03,11.05,9]dodecan-2-yl)ethanone Chemical compound CC(=O)N1C2C(N3CC=4C=CC=CC=4)N(C(=O)C)C1C(N1C(C)=O)N(C(C)=O)C3C1N2CC1=CC=CC=C1 NINQAYBICGTGQD-UHFFFAOYSA-N 0.000 abstract 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000006396 nitration reaction Methods 0.000 abstract 1
- 230000009935 nitrosation Effects 0.000 abstract 1
- 238000007034 nitrosation reaction Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/22—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains four or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/34—Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
El invento se refiere a una nueva polinitramina, el 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetraciclo-(5.5.0.0 {Sup,5,9}.0{Sup,3,11})-dodecano, también denominado hexanitro- hexaazaisowurtzitano, preparado por nitrosación del 4,10- dibencil-2,6,8,12-tetraacetil-2,4,6,8,10,12-hexaazatetraciclo- (5.5.0.0{Sup,5,9}.0{Sup,3,11})-dodecano, seguido por una nitración del producto obtenido. Esta polinitramina es una sustancia explosiva con mayores prestaciones que el hexógeno o el octógeno, que se puede utilizar como carga explosiva u oxidante en las composiciones pirotécnicas.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9212575A FR2831167B1 (fr) | 1992-10-21 | 1992-10-21 | Nouvelle polynitramine, son procede de synthese, nouvelles compositions pyrotechniques |
| GB9513427A GB2394222B (en) | 1992-10-21 | 1995-06-29 | A method of making a polynitramine |
| IT1995TO000565A IT1316050B1 (it) | 1992-10-21 | 1995-07-06 | Polinitramina, suo procedimento di sintesi e composizionipirotecniche. |
| DE19526503A DE19526503B4 (de) | 1992-10-21 | 1995-07-20 | Verfahren zur Herstellung von Hexanitrohexaazaisowurtzitan |
| ES009501473A ES2191500B1 (es) | 1992-10-21 | 1995-07-21 | Nueva polinitramina, su procedimiento de sintesis, nuevas composiciones pirotecnicas. |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9212575A FR2831167B1 (fr) | 1992-10-21 | 1992-10-21 | Nouvelle polynitramine, son procede de synthese, nouvelles compositions pyrotechniques |
| GB9513427A GB2394222B (en) | 1992-10-21 | 1995-06-29 | A method of making a polynitramine |
| IT1995TO000565A IT1316050B1 (it) | 1992-10-21 | 1995-07-06 | Polinitramina, suo procedimento di sintesi e composizionipirotecniche. |
| DE19526503A DE19526503B4 (de) | 1992-10-21 | 1995-07-20 | Verfahren zur Herstellung von Hexanitrohexaazaisowurtzitan |
| ES009501473A ES2191500B1 (es) | 1992-10-21 | 1995-07-21 | Nueva polinitramina, su procedimiento de sintesis, nuevas composiciones pirotecnicas. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2191500A1 true ES2191500A1 (es) | 2003-09-01 |
| ES2191500B1 ES2191500B1 (es) | 2004-07-01 |
Family
ID=32777251
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES009501473A Expired - Fee Related ES2191500B1 (es) | 1992-10-21 | 1995-07-21 | Nueva polinitramina, su procedimiento de sintesis, nuevas composiciones pirotecnicas. |
Country Status (5)
| Country | Link |
|---|---|
| DE (1) | DE19526503B4 (es) |
| ES (1) | ES2191500B1 (es) |
| FR (1) | FR2831167B1 (es) |
| GB (1) | GB2394222B (es) |
| IT (1) | IT1316050B1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2831167B1 (fr) * | 1992-10-21 | 2004-04-23 | Poudres & Explosifs Ste Nale | Nouvelle polynitramine, son procede de synthese, nouvelles compositions pyrotechniques |
| FR2830532B1 (fr) * | 1996-02-15 | 2005-09-16 | Poudres & Explosifs Ste Nale | Procede de synthese de derives de l'hexaazaisowurtzitane et forme polymorphe alpha d'un derive de l'hexaazaisowurtzitane |
| RU2448110C1 (ru) * | 2010-10-21 | 2012-04-20 | Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) | Способ дебензилирования 2,6,8,12-тетраацетил-2,4,6,8,10,12-гексаазаизовюрцитана |
| CN106946894B (zh) * | 2017-04-10 | 2019-03-15 | 中国科学院上海有机化学研究所 | 钯基双金属催化剂在hbiw催化氢解反应中的应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6147209A (en) * | 1988-12-21 | 2000-11-14 | Cordant Technologies Inc. | Method for making new polycyclic polyamides as precursors for energetic polycyclic polynitramine oxidizers |
| FR2831167A1 (fr) * | 1992-10-21 | 2003-04-25 | Poudres & Explosifs Ste Nale | Nouvelle polynitramine, son procede de synthese, nouvelles compositions pyrotechniques |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0753519B1 (en) * | 1995-02-01 | 2000-05-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Hexaazaisowurtzitane derivatives and process for producing the same |
| US5723604A (en) * | 1995-06-22 | 1998-03-03 | Thiokol Corporation | Synthesis of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo 5.5.0.05,9.03,11!dodecane |
-
1992
- 1992-10-21 FR FR9212575A patent/FR2831167B1/fr not_active Expired - Lifetime
-
1995
- 1995-06-29 GB GB9513427A patent/GB2394222B/en not_active Expired - Fee Related
- 1995-07-06 IT IT1995TO000565A patent/IT1316050B1/it active
- 1995-07-20 DE DE19526503A patent/DE19526503B4/de not_active Expired - Fee Related
- 1995-07-21 ES ES009501473A patent/ES2191500B1/es not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6147209A (en) * | 1988-12-21 | 2000-11-14 | Cordant Technologies Inc. | Method for making new polycyclic polyamides as precursors for energetic polycyclic polynitramine oxidizers |
| FR2831167A1 (fr) * | 1992-10-21 | 2003-04-25 | Poudres & Explosifs Ste Nale | Nouvelle polynitramine, son procede de synthese, nouvelles compositions pyrotechniques |
Non-Patent Citations (1)
| Title |
|---|
| PATIL, D.G. y col. Thermal Decomposition of Energetic Materials 53. Kinetics and Mechanism of Thermolysis of Hexanitrohexazaisowurtzitane. Combustion and Flame. 1991, Vol. 87, Nö 2, páginas 145-151. Resumen. * |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2831167A1 (fr) | 2003-04-25 |
| DE19526503B4 (de) | 2006-06-14 |
| DE19526503A1 (de) | 2003-07-17 |
| IT1316050B1 (it) | 2003-03-28 |
| GB2394222B (en) | 2004-09-29 |
| ITTO950565A0 (es) | 1995-07-06 |
| ES2191500B1 (es) | 2004-07-01 |
| GB2394222A (en) | 2004-04-21 |
| ITTO950565A1 (it) | 1997-01-06 |
| GB9513427D0 (en) | 2003-02-26 |
| FR2831167B1 (fr) | 2004-04-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EC2A | Search report published |
Date of ref document: 20030901 Kind code of ref document: A1 |
|
| PC2A | Transfer of patent |
Free format text: SNPE MATERIAUX ENERGETIQUES |
|
| FG2A | Definitive protection |
Ref document number: 2191500B1 Country of ref document: ES |
|
| PC2A | Transfer of patent | ||
| GD2A | Contractual licences |
Effective date: 20111226 |
|
| PC2A | Transfer of patent |
Owner name: HERAKLES Effective date: 20130708 |
|
| FD2A | Announcement of lapse in spain |
Effective date: 20180806 |