ES2194442T3 - Procedimiento de hidrogenacion con minimo tiempo de residencia para copolimeros de bloques de polisopreno-polibutadieno. - Google Patents

Procedimiento de hidrogenacion con minimo tiempo de residencia para copolimeros de bloques de polisopreno-polibutadieno.

Info

Publication number
ES2194442T3
ES2194442T3 ES99907462T ES99907462T ES2194442T3 ES 2194442 T3 ES2194442 T3 ES 2194442T3 ES 99907462 T ES99907462 T ES 99907462T ES 99907462 T ES99907462 T ES 99907462T ES 2194442 T3 ES2194442 T3 ES 2194442T3
Authority
ES
Spain
Prior art keywords
block
isoprene
butadiene
blocks
polisoprene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99907462T
Other languages
English (en)
Inventor
David Karl Schisla
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kraton Polymers Research BV
Original Assignee
Kraton Polymers Research BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kraton Polymers Research BV filed Critical Kraton Polymers Research BV
Application granted granted Critical
Publication of ES2194442T3 publication Critical patent/ES2194442T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/005—Modified block copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Procedimiento para hidrogenar selectivamente un copolímero de bloques que tenga al menos un bloque de polímero de butadieno y al menos un bloque de polímero de isopreno con un catalizador de hidrogenación que hidrogene los bloques de isopreno y los bloques de butadieno a una velocidad diferente, el cual procedimiento comprende (a) elegir un peso molecular deseado de polímero y un nivel deseado de insaturación residual en el (los) bloque(s) de isopreno y en el (los) bloque(s) de butadieno y determinar los pesos moleculares del (de los) bloque(s) de butadieno y del (de los) bloque(s) de isopreno, de forma que el tiempo requerido para hidrogenar el (los) bloque(s) de butadieno y el (los) bloque(s) de isopreno con el catalizador de hidrogenación hasta los niveles deseados de insaturación residual sea sustancialmente el mismo; (b) polimerizar aniónicamente butadieno e isopreno para formar un copolímero de bloques como se determina en la etapa (a); y (c) hidrogenar selectivamente el copolímero debloques con el catalizador de hidrogenación hasta que el (los) bloque(s) de butadieno y/o el (los) bloque(s) de isopreno hayan alcanzado el nivel deseado de insaturación residual.
ES99907462T 1998-01-30 1999-01-29 Procedimiento de hidrogenacion con minimo tiempo de residencia para copolimeros de bloques de polisopreno-polibutadieno. Expired - Lifetime ES2194442T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US7317898P 1998-01-30 1998-01-30

Publications (1)

Publication Number Publication Date
ES2194442T3 true ES2194442T3 (es) 2003-11-16

Family

ID=22112207

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99907462T Expired - Lifetime ES2194442T3 (es) 1998-01-30 1999-01-29 Procedimiento de hidrogenacion con minimo tiempo de residencia para copolimeros de bloques de polisopreno-polibutadieno.

Country Status (8)

Country Link
US (1) US6184307B1 (es)
EP (1) EP1051435B1 (es)
JP (1) JP4612185B2 (es)
KR (1) KR100607067B1 (es)
DE (1) DE69908300T2 (es)
ES (1) ES2194442T3 (es)
TW (1) TW486490B (es)
WO (1) WO1999038895A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4000874B2 (ja) * 2001-03-16 2007-10-31 日本ゼオン株式会社 油展ゴムおよびゴム組成物
EP1403312B1 (en) * 2001-06-14 2012-04-25 Kuraray Co., Ltd. Rubber composition, crosslinkable rubber composition and crosslinked articles
AU2002354471A1 (en) * 2001-12-20 2003-07-09 Kuraray Co., Ltd. Rubber composition, crosslinkable rubber composition and crosslinked rubber
US7241540B2 (en) * 2004-04-27 2007-07-10 Kraton Polymers U.S. Llc Photocurable compositions and flexographic printing plates comprising the same
EP1856205A1 (en) 2005-03-01 2007-11-21 Firestone Polymers, LLC Oxygen scavenging polyesters with reduced recycle color
ES2370416T5 (es) * 2005-05-20 2016-04-25 Bridgestone Corporation Método para preparar polímeros de bajo peso molecular
CN101679544B (zh) * 2007-04-09 2013-02-13 加利福尼亚大学董事会 得自半结晶-无定形聚烯烃嵌段共聚物的软而强的弹性体组合物
CN110139882A (zh) 2016-11-09 2019-08-16 株式会社普利司通 聚丁二烯和聚异戊二烯的高顺式-1,4嵌段共聚物
WO2020099078A1 (en) 2018-11-13 2020-05-22 Evonik Operations Gmbh Random copolymers for use as base oils or lubricant additives
ES2950909T3 (es) * 2020-05-05 2023-10-16 Evonik Operations Gmbh Copolímeros de polidieno lineales hidrogenados como material base o aditivos lubricantes para composiciones lubricantes

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3465063A (en) * 1965-10-06 1969-09-02 Shell Oil Co Hydrogenated diolefin block copolymers
US4879349A (en) * 1987-11-05 1989-11-07 Shell Oil Company Selective hydrogenation process
US5208296A (en) * 1992-09-02 1993-05-04 Polysar Rubber Corporation Nitrile rubber hydrogenation
JPH06306128A (ja) * 1993-04-23 1994-11-01 Kuraray Co Ltd ブロック共重合体及び組成物
JPH08100023A (ja) * 1994-09-29 1996-04-16 Nippon Zeon Co Ltd ブロック共重合体水素添加物、樹脂組成物、およびブロック共重合体

Also Published As

Publication number Publication date
TW486490B (en) 2002-05-11
EP1051435B1 (en) 2003-05-28
KR100607067B1 (ko) 2006-08-01
JP2002501951A (ja) 2002-01-22
EP1051435A1 (en) 2000-11-15
JP4612185B2 (ja) 2011-01-12
DE69908300D1 (de) 2003-07-03
KR20010034376A (ko) 2001-04-25
WO1999038895A1 (en) 1999-08-05
DE69908300T2 (de) 2003-12-11
US6184307B1 (en) 2001-02-06

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