ES2194500T3 - Procedimiento para la obtencion de aldehidos y/o alcoholes o aminas. - Google Patents

Procedimiento para la obtencion de aldehidos y/o alcoholes o aminas.

Info

Publication number
ES2194500T3
ES2194500T3 ES99942870T ES99942870T ES2194500T3 ES 2194500 T3 ES2194500 T3 ES 2194500T3 ES 99942870 T ES99942870 T ES 99942870T ES 99942870 T ES99942870 T ES 99942870T ES 2194500 T3 ES2194500 T3 ES 2194500T3
Authority
ES
Spain
Prior art keywords
guide member
reaction liquid
carbonyl
nozzle
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99942870T
Other languages
English (en)
Inventor
Peter Zehner
Armin Ulonska
Rocco Paciello
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2194500T3 publication Critical patent/ES2194500T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/60—Preparation of compounds containing amino groups bound to a carbon skeleton by condensation or addition reactions, e.g. Mannich reaction, addition of ammonia or amines to alkenes or to alkynes or addition of compounds containing an active hydrogen atom to Schiff's bases, quinone imines, or aziranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/006—Baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/246—Stationary reactors without moving elements inside provoking a loop type movement of the reactants internally, i.e. the mixture circulating inside the vessel such that the upward stream is separated physically from the downward stream(s)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00777—Baffles attached to the reactor wall horizontal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

Procedimiento para la obtención de aldehídos y/o alcoholes o aminas mediante la reacción de olefinas en fase líquida con monóxido de carbono y agua, dispersándose una parte de estos gases en el líquido de la reacción en forma de burbujas gaseosas y otra parte está disuelta en el líquido de la reacción, en presencia o en ausencia de una amina primaria o secundaria y en presencia de un complejo homogéneo, disuelto en el líquido de la reacción, de cobalto-, rodio-, paladio- o rutenio-carbonilo con un ligando que contiene fósforo, arsénico, antimonio o nitrógeno, a temperatura elevada y a una presión desde 1 hasta 100 bares, caracterizado porque la reacción se lleva a cabo en un reactor de forma tubular, dispuesto verticalmente, que comprende un cuerpo del reactor y al menos un conducto de inversión, conduciéndose una parte del líquido de la reacción en continuo a través del conducto de inversión al menos hasta una tobera dispuesta en la parte superior del cuerpo del reactor, que está asociadacon un órgano conductor abierto en la parte superior y en la parte inferior, limitado mediante paredes paralelas en el interior del reactor, así como con una placa de rebote que se encuentra por debajo de la abertura inferior del órgano conductor, y genera con esta tobera en este órgano conductor una corriente de líquido dirigida hacia abajo, que contiene burbujas gaseosas dispersadas, que se invierte, tras abandonar el órgano conductor, en una corriente que fluye hacia arriba en el recinto intermedio comprendido entre la pared del órgano conductor y el a pared del cuerpo del reactor, y en el extremo superior del órgano conductor es aspirada en el órgano conductor por el chorro de la tobera dispuesta en el órgano conductor.
ES99942870T 1998-08-14 1999-08-13 Procedimiento para la obtencion de aldehidos y/o alcoholes o aminas. Expired - Lifetime ES2194500T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19836807A DE19836807A1 (de) 1998-08-14 1998-08-14 Verfahren zur Herstellung von Aldehyden und/oder Alkoholen oder Aminen

Publications (1)

Publication Number Publication Date
ES2194500T3 true ES2194500T3 (es) 2003-11-16

Family

ID=7877481

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99942870T Expired - Lifetime ES2194500T3 (es) 1998-08-14 1999-08-13 Procedimiento para la obtencion de aldehidos y/o alcoholes o aminas.

Country Status (11)

Country Link
US (1) US6642420B1 (es)
EP (1) EP1114017B1 (es)
JP (1) JP2002522518A (es)
KR (1) KR100580423B1 (es)
CN (1) CN1165506C (es)
AT (1) ATE234802T1 (es)
DE (2) DE19836807A1 (es)
ES (1) ES2194500T3 (es)
MY (1) MY124357A (es)
TW (1) TW541298B (es)
WO (1) WO2000009467A1 (es)

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DE10008903A1 (de) 2000-02-25 2001-09-06 Degussa Verfahren zur Herstellung von Malonsäurediestern in einem Reaktor mit innen liegenden Wärmeaustauschern
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DE10201676A1 (de) * 2002-01-17 2003-07-31 Basf Ag Verfahren zur Hydroformylierung von Olefinen mit 2 bis 6 Kohlenstoffatomen
US6908601B2 (en) 2002-02-08 2005-06-21 The Boc Group, Inc. Method for the production of nitrogen trifluoride
DE10206132A1 (de) * 2002-02-14 2003-08-21 Basf Ag Reaktorkaskade aus Haupt- und Nachreaktor
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KR101206214B1 (ko) * 2009-01-16 2012-12-03 주식회사 엘지화학 올레핀으로부터의 알코올을 제조하는 시스템
KR101278375B1 (ko) 2010-01-18 2013-07-05 주식회사 엘지화학 올레핀 유래 알데히드로부터 알코올로의 변환방법 및 이에 사용되는 반응 장치
KR101342741B1 (ko) 2010-03-09 2013-12-19 주식회사 엘지화학 반응효율이 뛰어난 올레핀의 하이드로포밀화 방법
KR101298343B1 (ko) * 2010-05-04 2013-08-20 주식회사 엘지화학 올레핀의 하이드로포밀화 반응장치 및 이를 이용하는 하이드로포밀화 방법
KR101411133B1 (ko) * 2010-05-25 2014-06-23 주식회사 엘지화학 반응 선택성이 우수한 올레핀의 하이드로포밀화 방법
CN102826975B (zh) * 2011-06-17 2015-08-19 中国石油化工股份有限公司 一种丙烯氢甲酰化反应制备丁醛的方法
CN102826970B (zh) * 2011-06-17 2015-08-19 中国石油化工股份有限公司 一种低碳烯烃氢甲酰化二段反应方法和装置
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
SG11201405863QA (en) 2012-04-12 2014-11-27 Basf Se Method for replenishing the catalyst in continuous hydroformylation
KR101403823B1 (ko) * 2013-02-13 2014-06-03 주식회사 엘지화학 올레핀으로부터의 알코올을 제조하는 장치
KR101448374B1 (ko) * 2013-02-26 2014-10-07 주식회사 엘지화학 반응 선택성이 우수한 올레핀의 하이드로포밀화 방법
CN104513143A (zh) * 2013-09-26 2015-04-15 陶氏技术投资有限责任公司 加氢甲酰化方法
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TW201726242A (zh) * 2015-12-22 2017-08-01 巴斯夫歐洲公司 圓柱形反應器及其用於連續氫甲醯化反應的用途
CN106118883B (zh) * 2016-06-29 2020-04-21 广西壮族自治区林业科学研究院 一种樟树精油浸提装置及应用
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
US10941092B2 (en) 2017-06-13 2021-03-09 Basf Se Hydroformylation process for producing 1,6-hexanediol derivatives
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
CN107469736A (zh) * 2017-10-12 2017-12-15 重庆农药化工（集团）有限公司 可调节反应压力的反应釜及可调压反应釜系统
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CN110201611B (zh) * 2019-05-30 2021-11-23 河南能源化工集团研究总院有限公司 一种用于烯烃氢甲酰化的三相流反应装置及其操作方法
EP3594498B1 (de) 2019-11-06 2022-01-05 Pfeiffer Vacuum Gmbh System mit einer gasrezirkulationseinrichtung
CN112830870A (zh) * 2019-11-25 2021-05-25 南京延长反应技术研究院有限公司 一种由烯烃羰基化制备异构醛的强化反应系统及工艺
CN112827433A (zh) * 2019-11-25 2021-05-25 南京延长反应技术研究院有限公司 一种由烯烃羰基化制备异构醛的智能强化反应系统及工艺
CN115066429A (zh) 2020-02-11 2022-09-16 巴斯夫欧洲公司 二异丁烯的低压醛化
CN114177876A (zh) * 2020-09-15 2022-03-15 上海睿碳能源科技有限公司 一种喷射环流反应器及其应用
CN114177875A (zh) * 2020-09-15 2022-03-15 上海睿碳能源科技有限公司 一种喷射环流反应器及其应用
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Also Published As

Publication number Publication date
MY124357A (en) 2006-06-30
ATE234802T1 (de) 2003-04-15
CN1312785A (zh) 2001-09-12
US6642420B1 (en) 2003-11-04
EP1114017A1 (de) 2001-07-11
DE19836807A1 (de) 2000-02-17
KR100580423B1 (ko) 2006-05-16
TW541298B (en) 2003-07-11
JP2002522518A (ja) 2002-07-23
DE59904660D1 (de) 2003-04-24
CN1165506C (zh) 2004-09-08
KR20010072453A (ko) 2001-07-31
WO2000009467A1 (de) 2000-02-24
EP1114017B1 (de) 2003-03-19

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