ES2194874T3 - Silice precipitada. - Google Patents
Silice precipitada.Info
- Publication number
- ES2194874T3 ES2194874T3 ES94928934T ES94928934T ES2194874T3 ES 2194874 T3 ES2194874 T3 ES 2194874T3 ES 94928934 T ES94928934 T ES 94928934T ES 94928934 T ES94928934 T ES 94928934T ES 2194874 T3 ES2194874 T3 ES 2194874T3
- Authority
- ES
- Spain
- Prior art keywords
- cuba
- foot
- agent
- silice
- silicate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052914 metal silicate Inorganic materials 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- 238000002604 ultrasonography Methods 0.000 abstract 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- NHLKHSHVLSAUTC-GVCNIIFKSA-N pie2 Chemical compound C([C@H](C(=O)N1CCC[C@@H]1C(=O)N[C@H](CCC(O)=O)C(=O)N[C@H](CC=1C2=CC=CC=C2NC=1)C(=O)N[C@H](CCCNC(N)=N)C(=O)N[C@H](CC=1C2=CC=CC=C2NC=1)C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CS)C(=O)N[C@H](C)C(=O)N[C@H](C)C(O)=O)NC(=O)[C@@H](CC(O)=O)NC(=O)[C@@H](CS)NC(=O)[C@@H](C)NC(=O)CNC(=O)[C@H](N)CCCCN)C1=CC=C(O)C=C1 NHLKHSHVLSAUTC-GVCNIIFKSA-N 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000002787 reinforcement Effects 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
- C01P2006/17—Pore diameter distribution
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Silicon Compounds (AREA)
- Saccharide Compounds (AREA)
- Steroid Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
LA INVENCION SE REFIERE A SILICES QUE SE PRESENTAN EN FORMA DE POLVO, BOLAS SENSIBLEMENTE ESFERICAS O DE GRANULADOS, PRESENTAN UNA SUPERFICIE ESPECIFICA CTAB COMPRENDIDA ENTRE 140 Y 240 M2/G, UN FACTOR DE DESAGLOMERACION CON ULTRASONIDOS ELEVADOS, DIAMETRO MEDIANO, TRAS LA DESAGLOMERACION CON ULTRASONIDOS, PEQUEÑO, Y EVENTUALMENTE UNA DISTRIBUCION POROSA DE MANERA QUE EL VOLUMEN POROSO CONSTITUIDO POR LOS POROS CUYO DIAMETRO ESTA COMPRENDIDO ENTRE 175 Y 275 A REPRESENTA MENOS DE 50% DEL VOLUMEN POROSO CONSTITUIDO POR LOS POROS DE DIAMETROS INFERIORES O IGUALE A 400 A. LA UTILIZAION DE DICHAS SILICE COM O CARGAR DE REFUERZO PARA ELASTOMERO. PROCESOP DE PREPARACION DE SILICE PRECIPITADA DEL TIPO QUE COMPRENDE LA REACCION DE UN SILICATO DE METAL ALCALINO M CON UN AGENTE ACIDIFICANTE, POR LO QUE SE OBTIENE UNA SUSPENSION DE SILICE PRECIPITADA, Y DESPUES LA SEPARACION Y EL SECADO DE ESTA SUSPENSION, EN EL QUE SE REALIZA LA PRECIPITACION DE LA SIGUIENTE MANERA: (I) SE FORMA UN PIE DE CUBA INICIALQUE COMPRENDE UNA PARTE DE LA CANTIDAD TOTAL DEL SILICATO DE METALALCALINO M INTRODUCIDO EN LA REACCION, LA CONCENTRACION DE SILICATO(EXPRESADA EN SIO2) EN DICHO PIE DE CUBA SIENDO INFERIOR A 20G7L, (II) SE AÑADE EL AGENTE ACIDIFICANTE AL PIE DE CUBA HASTA QUE AL MENOS 5% DE LA CANTIDAD DE M2O PRESENTE EN DICHO PIE DE CUBA INICIAL SEAN NEUTRALIZADOS, (III) SE AÑADE AL MEDIO DE REACCION SIMULTANEAMENTE EL AGENTE ACIDIFICANTE Y LA CANTIDAD RESTANTE DE SILICATO DE METAL ALCALINO M DE MANERA QUE LA RELACION CANTIDAD DE SILICATO AÑADIDA (EXPRESADA EN SIO2)/CANTIDAD DE SILICE LA PRESENTA EN PRESENTE EN EL PIE DE CUBA INCIAL (EXPRESADA EN (SIO2) SEA SUPERIOR A 4 Y A LO SUMO 100.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9311553A FR2710629B1 (fr) | 1993-09-29 | 1993-09-29 | Nouveau procédé de préparation de silice précipitée, nouvelles silices précipitées et leur utilisation au renforcement des élastomères. |
| FR9410046A FR2723581B1 (fr) | 1994-08-12 | 1994-08-12 | Nouveau procede de preparation de silice precipitee |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2194874T3 true ES2194874T3 (es) | 2003-12-01 |
Family
ID=26230634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94928934T Expired - Lifetime ES2194874T3 (es) | 1993-09-29 | 1994-09-29 | Silice precipitada. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6335396B1 (es) |
| EP (1) | EP0670813B1 (es) |
| JP (1) | JP2799773B2 (es) |
| KR (2) | KR0158071B1 (es) |
| CN (1) | CN1047149C (es) |
| AT (1) | ATE234264T1 (es) |
| AU (2) | AU686240B2 (es) |
| BR (1) | BR9405616A (es) |
| CA (1) | CA2150369C (es) |
| DE (1) | DE69432248T2 (es) |
| ES (1) | ES2194874T3 (es) |
| FI (1) | FI120581B (es) |
| PT (1) | PT670813E (es) |
| RU (1) | RU2092435C1 (es) |
| WO (1) | WO1995009127A1 (es) |
Families Citing this family (74)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977065B1 (en) * | 1993-10-07 | 2005-12-20 | Degussa Ag | Precipitated silicas |
| FR2732331B1 (fr) * | 1995-03-29 | 1997-06-20 | Rhone Poulenc Chimie | Nouveau procede de preparation de silice precipitee, nouvelles silices precipitees contenant du zinc et leur utilisation au renforcement des elastomeres |
| FR2732329B1 (fr) * | 1995-03-29 | 1997-06-20 | Rhone Poulenc Chimie | Nouveau procede de preparation de silice precipitee, nouvelles silices precipitees contenant de l'aluminium et leur utilisation au renforcement des elastomeres |
| DE19526476A1 (de) * | 1995-07-20 | 1997-01-23 | Degussa | Fällungskieselsäure |
| DE19527278A1 (de) * | 1995-07-26 | 1997-01-30 | Degussa | Fällungskieselsäure |
| GB2308588B (en) | 1995-12-27 | 1999-06-02 | Rhone Poulenc Chemicals | Silica particulates |
| CN1048956C (zh) * | 1996-05-14 | 2000-02-02 | 汪承源 | 二次结晶超细白炭黑的制法 |
| FR2750692B1 (fr) * | 1996-07-05 | 1998-10-16 | Rhone Poulenc Chimie | Nouvelle silice abrasive, utilisable dans les dentifrices, son procede de preparation et compositions dentifrices la contenant |
| US5891949A (en) * | 1997-05-02 | 1999-04-06 | J.M. Huber Corporation | Natural rubber compound |
| US5929156A (en) * | 1997-05-02 | 1999-07-27 | J.M. Huber Corporation | Silica product for use in elastomers |
| FR2763581B1 (fr) | 1997-05-26 | 1999-07-23 | Rhodia Chimie Sa | Silice precipitee utilisable comme charge renforcante pour elastomeres |
| FR2763593B1 (fr) * | 1997-05-26 | 1999-07-09 | Michelin & Cie | Composition de caoutchouc a base de silice destinee a la fabrication d'enveloppes de pneumatiques routiers ayant une resistance au roulement amelioree |
| JP4071343B2 (ja) * | 1998-02-18 | 2008-04-02 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| JPH11236208A (ja) * | 1998-02-25 | 1999-08-31 | Nippon Silica Ind Co Ltd | ゴム補強用含水ケイ酸 |
| DE19840153A1 (de) * | 1998-09-03 | 2000-04-20 | Degussa | Fällungskieselsäure |
| JP3678627B2 (ja) † | 2000-04-11 | 2005-08-03 | 横浜ゴム株式会社 | ゴム組成物 |
| RU2179153C1 (ru) * | 2000-06-07 | 2002-02-10 | Закрытое акционерное общество "Хорс" | Способ получения диоксида кремния |
| PT1419106T (pt) * | 2001-08-13 | 2016-12-27 | Rhodia Chimie Sa | Processo de preparação de sílicas, sílicas com distribuição granulométrica e/ou repartição porosa específicas e suas utilizações, em particular no reforço de polímeros |
| FR2831178B1 (fr) | 2001-10-22 | 2006-04-14 | Rhodia Chimie Sa | Compositions pigmentaires a base de silice |
| FR2833937B1 (fr) * | 2001-12-26 | 2004-11-12 | Rhodia Chimie Sa | Silices a faible reprise en eau |
| US7985392B2 (en) * | 2002-07-10 | 2011-07-26 | Tokuyama Corporation | Cake of easily dispersible precipitated silica |
| FR2843121B3 (fr) | 2002-08-02 | 2004-09-10 | Rhodia Chimie Sa | Agent ignifugeant, procede de preparation et l'utilisation de cet agent |
| FR2856680B1 (fr) | 2003-06-30 | 2005-09-09 | Rhodia Chimie Sa | Materiaux d'isolation thermique et/ou acoustique a base de silice et procedes pour leur obtention |
| CA2542516C (en) * | 2003-10-22 | 2012-09-04 | Comalco Aluminium Limited | Destruction of organics in bayer process streams |
| FR2862978B1 (fr) | 2003-12-01 | 2005-12-30 | Rhodia Chimie Sa | Nouvel agent promoteur d'adherence sur une surface d'isolant thermique et en particulier sur une surface de polystyrene, et son utilisation dans le domaine de la construction et plus particulierement dans les systemes d'isolation |
| FR2864063B1 (fr) * | 2003-12-19 | 2006-04-07 | Rhodia Chimie Sa | Silice de haute structure a faible reprise en eau |
| US7202154B2 (en) * | 2004-01-05 | 2007-04-10 | International Business Machines Corporation | Suspension for filling via holes in silicon and method for making the same |
| CN100341956C (zh) * | 2004-05-28 | 2007-10-10 | 河南大学 | 一种纳米二氧化硅微粒制备方法 |
| FR2886303B1 (fr) | 2005-05-26 | 2007-07-20 | Rhodia Chimie Sa | Utilisation d'une combinaison particuliere d'un agent de couplage et d'un agent de recouvrement, comme systeme de couplage(charge blanche-elastomere) dans les compositions de caoutchouc comprenant une charge inorganique |
| RU2329950C1 (ru) * | 2006-11-07 | 2008-07-27 | Николай Алексеевич Дежов | Способ получения композиции, содержащей соединения осажденного диоксида кремния и алюминия |
| FR2928363B1 (fr) * | 2008-03-10 | 2012-08-31 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, silices precipitees a morphologie, granulometrie et porosite particulieres et leurs utilisations, notamment pour le renforcement de polymeres |
| DE102008017731A1 (de) | 2008-04-07 | 2009-10-08 | Continental Aktiengesellschaft | Kautschukmischung |
| DE102008017747A1 (de) * | 2008-04-07 | 2009-10-08 | Evonik Degussa Gmbh | Gefällte Kieselsäuren als Verstärkerfüllstoff für Elastomermischungen |
| RU2385839C2 (ru) * | 2008-06-30 | 2010-04-10 | Открытое акционерное общество "СОДА" (ОАО "СОДА") | Способ получения высокодисперсной двуокиси кремния |
| DE102008035867A1 (de) * | 2008-08-01 | 2010-02-04 | Evonik Degussa Gmbh | Neuartige Fällungskieselsäuren für Trägeranwendungen |
| DE102008046874A1 (de) | 2008-09-11 | 2010-03-18 | Continental Reifen Deutschland Gmbh | Gummiartikel |
| FR2962996B1 (fr) | 2010-07-23 | 2012-07-27 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
| FR2966830B1 (fr) | 2010-11-03 | 2012-11-16 | Rhodia Operations | Utilisation d'une silice precipitee contenant de l'aluminium, d'une silice precipitee et de 3-acryloxy-propyltriethoxysilane dans une composition d'elastomere(s) isoprenique(s) |
| ES2401813B2 (es) | 2011-10-11 | 2013-08-12 | Industrias Químicas Del Ebro, S.A. | Carga reforzante de caucho. |
| FR2985993B1 (fr) * | 2012-01-25 | 2014-11-28 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
| FR2985992B1 (fr) * | 2012-01-25 | 2015-03-06 | Rhodia Operations | Nouveau procede de preparation de silices precitees |
| FR2985991B1 (fr) * | 2012-01-25 | 2014-11-28 | Rhodia Operations | Nouveau procede de preparation de silices precipitees |
| FR2985990B1 (fr) * | 2012-01-25 | 2014-11-28 | Rhodia Operations | Nouveau procede de preparation de silices precipitees a morphologie, granulometrie et porosite particulieres |
| FR2988386B1 (fr) | 2012-03-22 | 2014-05-09 | Rhodia Operations | Procede de preparation de silice precipitee comprenant une etape de delitage a chaud |
| FR2988383B1 (fr) | 2012-03-22 | 2017-06-09 | Rhodia Operations | Procede de preparation de silice precipitee mettant en oeuvre un malaxeur ou une extrudeuse |
| FR2988385B1 (fr) | 2012-03-22 | 2014-05-09 | Rhodia Operations | Procede de preparation de silice precipitee comprenant une etape de concentration membranaire |
| FR2988384B1 (fr) | 2012-03-22 | 2015-09-11 | Rhodia Operations | Procede de preparation de silice precipitee comprenant une etape de fort compactage |
| FR2997405B1 (fr) | 2012-10-29 | 2015-11-13 | Rhodia Operations | Utilisation d'une silice precipitee contenant du titane et d'un agent de couplage specifique dans une composition d'elastomere(s) |
| JP2015504842A (ja) * | 2013-01-23 | 2015-02-16 | ローディア オペレーションズ | 特有のモルフォロジ、粒度、および気孔率を有する沈澱シリカの製造方法 |
| FR3001971B1 (fr) * | 2013-02-14 | 2016-05-27 | Rhodia Operations | Utilisation d'un acide polycarboxylique lors de la preparation d'une composition d'elastomere(s) |
| CN107921371A (zh) | 2015-07-28 | 2018-04-17 | 罗地亚经营管理公司 | 用于回收硫酸钠的方法 |
| EP3156368A1 (en) | 2015-10-15 | 2017-04-19 | Rhodia Operations | Novel process for the preparation of silicate, novel process for the preparation of precipitated silica |
| CN105460940B (zh) * | 2016-02-22 | 2017-05-31 | 冷水江三A新材料科技有限公司 | 一种介孔药物载体二氧化硅及其制备方法 |
| PL3507850T3 (pl) | 2016-08-30 | 2021-01-25 | Rhodia Operations | Elektrolit stało-ciekły do stosowania w akumulatorze |
| WO2019025410A1 (en) | 2017-08-04 | 2019-02-07 | Rhodia Operations | ELASTOMERIC COMPOSITION COMPRISING PRECIPITATED SILICA AND AROMATIC POLYMER CONTAINING SULFUR |
| US11365306B2 (en) | 2017-11-29 | 2022-06-21 | Pirelli Tyre S.P.A. | Microbeads comprising silicate fibres with needle-shaped morphology of nanometric size, preparation thereof, elastomeric compositions and tyres for vehicles comprising them |
| EP3732131A1 (en) | 2017-12-27 | 2020-11-04 | Rhodia Operations | Silica suspensions |
| PL3746403T3 (pl) | 2018-02-01 | 2024-09-30 | Rhodia Operations | Zawiesina krzemionki w rozpuszczalniku organicznym i sposób jej wytwarzania |
| CN111566844A (zh) | 2018-02-02 | 2020-08-21 | 罗地亚经营管理公司 | 复合电解质 |
| WO2019170694A1 (en) | 2018-03-08 | 2019-09-12 | Solvay Sa | A process for the preparation of a solid polymer electrolyte useful in batteries |
| WO2020070119A1 (en) | 2018-10-04 | 2020-04-09 | Rhodia Operations | Process for the manufacture of precipitated silica |
| WO2020094714A1 (en) * | 2018-11-08 | 2020-05-14 | Rhodia Operations | Precipitated silica and process for its manufacture |
| EP3653673A1 (en) | 2018-11-16 | 2020-05-20 | Rhodia Operations | Organosilane-modified precipitated silica |
| EP3691015A1 (en) | 2019-02-01 | 2020-08-05 | Rhodia Operations | Electrolyte |
| WO2021009550A1 (en) | 2019-07-18 | 2021-01-21 | Rhodia Brasil Ltda | Preparation of immobilized enzymes |
| WO2021069256A1 (en) * | 2019-10-07 | 2021-04-15 | Rhodia Operations | Silica for oral care compositions |
| WO2021074047A1 (en) | 2019-10-15 | 2021-04-22 | Rhodia Operations | Process for the preparation of modified silica, modified silica and its uses |
| EP4125781A1 (en) | 2020-03-24 | 2023-02-08 | Rhodia Operations | Whitening oral care compositions |
| WO2022180133A1 (en) | 2021-02-26 | 2022-09-01 | Solvay Specialty Polymers Italy S.P.A. | Method for sanitizing or sterilizing the surface of an article having a fluoropolymer coating |
| US20240182312A1 (en) | 2021-04-02 | 2024-06-06 | Rhodia Operations | New silica, process for its preparation and its uses |
| US20240158615A1 (en) | 2022-11-02 | 2024-05-16 | The Goodyear Tire & Rubber Company | Precipitated silica pretreated with a coupling agent and polyethylene glycol for a rubber composition |
| EP4619472A1 (en) | 2022-11-14 | 2025-09-24 | Rhodia Operations | Modified precipitated silica, its manufacture and use |
| US20240326361A1 (en) | 2023-03-29 | 2024-10-03 | The Goodyear Tire & Rubber Company | Sealant composition for self-sealing pneumatic tire |
| US20240343892A1 (en) | 2023-04-14 | 2024-10-17 | The Goodyear Tire & Rubber Company | Rubber composition including biodegradable oil |
Family Cites Families (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB710015A (en) | 1950-12-02 | 1954-06-02 | Degussa | An improved process for the production of finely divided silica |
| US2731326A (en) * | 1951-08-31 | 1956-01-17 | Du Pont | Process of preparing dense amorphous silica aggregates and product |
| GB719918A (en) | 1951-12-11 | 1954-12-08 | Wyandotte Chemicals Corp | Production of pigment grade silica |
| US3024199A (en) | 1958-09-02 | 1962-03-06 | Du Pont | Stable aquasols of hydrous rare earth oxides and their preparation |
| US3383172A (en) | 1964-02-04 | 1968-05-14 | Degussa | Process for producing silica in the form of hollow spheres |
| DE1807714C2 (de) | 1968-11-08 | 1971-01-04 | Degussa | Verfahren und Vorrichtung zum kontinuierlichen Vorverdichten sowie gleichzeitigen Formen von feinteiligen Stoffen |
| US3669624A (en) | 1970-07-09 | 1972-06-13 | Grace W R & Co | Process for producing high average pore volume silica |
| US3963512A (en) | 1971-02-10 | 1976-06-15 | Commonwealth Scientific And Industrial Research Organization | Modification of mineral surfaces |
| US3794712A (en) | 1971-10-26 | 1974-02-26 | Nat Petro Chem | Preparation of silica gels |
| US3923533A (en) | 1972-03-02 | 1975-12-02 | Ppg Industries Inc | Thermally stable and crush resistant microporous glass catalyst supports |
| US3800031A (en) | 1972-04-06 | 1974-03-26 | Grace W R & Co | Process for preparing silica hydrogel |
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-
1994
- 1994-09-29 EP EP94928934A patent/EP0670813B1/fr not_active Expired - Lifetime
- 1994-09-29 JP JP7510154A patent/JP2799773B2/ja not_active Expired - Lifetime
- 1994-09-29 DE DE69432248T patent/DE69432248T2/de not_active Expired - Lifetime
- 1994-09-29 AU AU78163/94A patent/AU686240B2/en not_active Expired
- 1994-09-29 CA CA002150369A patent/CA2150369C/fr not_active Expired - Lifetime
- 1994-09-29 RU RU9495112453A patent/RU2092435C1/ru active
- 1994-09-29 KR KR1019950702167A patent/KR0158071B1/ko not_active Expired - Lifetime
- 1994-09-29 ES ES94928934T patent/ES2194874T3/es not_active Expired - Lifetime
- 1994-09-29 AT AT94928934T patent/ATE234264T1/de not_active IP Right Cessation
- 1994-09-29 CN CN94190729A patent/CN1047149C/zh not_active Expired - Lifetime
- 1994-09-29 BR BR9405616-1A patent/BR9405616A/pt not_active IP Right Cessation
- 1994-09-29 WO PCT/FR1994/001143 patent/WO1995009127A1/fr not_active Ceased
- 1994-09-29 PT PT94928934T patent/PT670813E/pt unknown
-
1995
- 1995-05-29 FI FI952605A patent/FI120581B/fi not_active IP Right Cessation
-
1997
- 1997-10-31 AU AU43667/97A patent/AU712323B2/en not_active Expired
-
1998
- 1998-05-29 KR KR1019980704068A patent/KR0158188B1/ko not_active Expired - Lifetime
-
2000
- 2000-04-17 US US09/551,231 patent/US6335396B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0670813A1 (fr) | 1995-09-13 |
| DE69432248D1 (de) | 2003-04-17 |
| KR0158071B1 (ko) | 1998-11-16 |
| AU712323B2 (en) | 1999-11-04 |
| FI952605A0 (fi) | 1995-05-29 |
| US6335396B1 (en) | 2002-01-01 |
| FI120581B (fi) | 2009-12-15 |
| EP0670813B1 (fr) | 2003-03-12 |
| BR9405616A (pt) | 1999-09-08 |
| DE69432248T2 (de) | 2004-08-19 |
| RU2092435C1 (ru) | 1997-10-10 |
| CA2150369C (fr) | 2001-05-01 |
| PT670813E (pt) | 2003-07-31 |
| JP2799773B2 (ja) | 1998-09-21 |
| WO1995009127A1 (fr) | 1995-04-06 |
| JPH08502716A (ja) | 1996-03-26 |
| ATE234264T1 (de) | 2003-03-15 |
| AU686240B2 (en) | 1998-02-05 |
| CN1114832A (zh) | 1996-01-10 |
| FI952605A7 (fi) | 1995-05-29 |
| AU7816394A (en) | 1995-04-18 |
| CA2150369A1 (fr) | 1995-04-06 |
| CN1047149C (zh) | 1999-12-08 |
| KR0158188B1 (en) | 1999-10-15 |
| KR950704193A (ko) | 1995-11-17 |
| AU4366797A (en) | 1998-02-05 |
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