ES2196821T3 - Procedimiento para la obtencion de polisobutenos altamente reactivos. - Google Patents
Procedimiento para la obtencion de polisobutenos altamente reactivos.Info
- Publication number
- ES2196821T3 ES2196821T3 ES99929127T ES99929127T ES2196821T3 ES 2196821 T3 ES2196821 T3 ES 2196821T3 ES 99929127 T ES99929127 T ES 99929127T ES 99929127 T ES99929127 T ES 99929127T ES 2196821 T3 ES2196821 T3 ES 2196821T3
- Authority
- ES
- Spain
- Prior art keywords
- highly reactive
- obtaining highly
- polisobutens
- procedure
- boron trifluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910015900 BF3 Inorganic materials 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920002367 Polyisobutene Polymers 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000010538 cationic polymerization reaction Methods 0.000 abstract 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000003138 primary alcohols Chemical class 0.000 abstract 1
- 150000003333 secondary alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
- C08F110/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
- C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Abstract
Procedimiento para la obtención de poliisobutenos altamente reactivos con un contenido de agrupaciones de vinilideno dispuestas en los extremos de más de un 80 % en mol y con un peso molecular medio de 500 hasta 5000 Dalton mediante polimerización catiónica de isobuteno en fase líquida en presencia de un complejo de trifluoruro de boro, a temperaturas desde +40°C hasta -60°C, caracterizado porque se polimeriza en presencia de un complejo de trifluoruro de boro y a) un alcohol primario con 1 a 20 átomos de carbono o un alcohol secundario con 3 a 20 átomos de carbono o una mezcla, constituida por estos alcoholes, y b) un éter exento de grupos alquilo terciarios de la fórmula I R1-O-R2, en la cual significan Rl y R2 grupos alquilo primarios o secundarios con 3 a 10 átomos de carbono, con la condición, que al menos uno de los grupos Rl y R2 es un grupo alquilo secundario.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19825334A DE19825334A1 (de) | 1998-06-05 | 1998-06-05 | Verfahren zur Herstellung hochreaktiver Polyisobutene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2196821T3 true ES2196821T3 (es) | 2003-12-16 |
Family
ID=7870130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99929127T Expired - Lifetime ES2196821T3 (es) | 1998-06-05 | 1999-06-02 | Procedimiento para la obtencion de polisobutenos altamente reactivos. |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1095070B1 (es) |
| JP (1) | JP2002517575A (es) |
| KR (1) | KR100575510B1 (es) |
| CN (1) | CN1139607C (es) |
| AU (1) | AU4604899A (es) |
| CA (1) | CA2334263A1 (es) |
| DE (2) | DE19825334A1 (es) |
| ES (1) | ES2196821T3 (es) |
| MY (1) | MY122369A (es) |
| WO (1) | WO1999064482A1 (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6562913B1 (en) * | 1999-09-16 | 2003-05-13 | Texas Petrochemicals Lp | Process for producing high vinylidene polyisobutylene |
| US6884858B2 (en) | 1999-10-19 | 2005-04-26 | Texas Petrochemicals Lp | Process for preparing polyolefin products |
| ATE507247T1 (de) * | 1999-09-16 | 2011-05-15 | Tpc Group Llc | Verfahren zur herstellung von polyolefinprodukten |
| US6992152B2 (en) | 1999-10-19 | 2006-01-31 | Texas Petrochemicals Lp | Apparatus and method for controlling olefin polymerization process |
| US7037999B2 (en) * | 2001-03-28 | 2006-05-02 | Texas Petrochemicals Lp | Mid-range vinylidene content polyisobutylene polymer product and process for producing the same |
| JP3808758B2 (ja) * | 2001-03-22 | 2006-08-16 | 株式会社カネカ | イソブチレン系重合体の製造方法 |
| DE10211418A1 (de) | 2002-03-15 | 2003-09-25 | Bayer Ag | Verfahren zur Herstellung hochreaktiver Polyisobutene |
| DE10243576A1 (de) | 2002-09-19 | 2004-04-01 | Basf Ag | Verfahren zur Herstellung von Polyisobuten |
| CA2413611C (en) * | 2002-12-05 | 2012-11-13 | Bayer Inc. | Process for production of high-isoprene butyl rubber |
| DE102009001700A1 (de) | 2008-03-25 | 2009-12-03 | Basf Se | Verfahren zur mikrowellen-unterstützten Polymerisation von ethylenisch ungesättigten Monomeren |
| CN101781377B (zh) * | 2009-01-16 | 2011-07-20 | 北京化工大学 | 用于制备高反应活性聚异丁烯的引发体系 |
| US20100298507A1 (en) | 2009-05-19 | 2010-11-25 | Menschig Klaus R | Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby |
| EP2496613B1 (de) | 2009-11-04 | 2015-07-01 | Basf Se | Verfahren zur herstellung von homo- oder copolymeren |
| DE102010062374A1 (de) | 2009-12-04 | 2011-06-09 | Basf Se | Verfahren zur Herstellung von Homo- oder Copolymeren |
| US8349977B2 (en) * | 2010-02-17 | 2013-01-08 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| SG182759A1 (en) * | 2010-02-17 | 2012-09-27 | Basf Se | Method for producing highly reactive isobutene homo or copolymers |
| CN101921352B (zh) * | 2010-09-28 | 2011-10-26 | 潍坊滨海石油化工有限公司 | 一种低分子量高活性聚异丁烯的生产方法 |
| AR084033A1 (es) | 2010-11-30 | 2013-04-17 | Basf Se | Preparacion de derivados de homo- o copolimeros de isobuteno |
| WO2012072536A2 (de) | 2010-11-30 | 2012-06-07 | Basf Se | Herstellung von derivaten von isobutencopolymerisaten |
| US9562117B2 (en) | 2010-11-30 | 2017-02-07 | Basf Se | Preparation of derivatives of isobutene copolymers |
| US9296841B2 (en) | 2010-11-30 | 2016-03-29 | Basf Se | Preparation of isobutene homo- or copolymer derivatives |
| US8697820B2 (en) | 2011-08-11 | 2014-04-15 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| EP2742073A1 (de) * | 2011-08-11 | 2014-06-18 | Basf Se | Verfahren zur herstellung von hochreaktiven isobutenhomo- oder -copolymeren |
| EP2814852B1 (de) * | 2012-02-17 | 2019-01-23 | Basf Se | Bortrifluorid-katalysatorkomplex und verfahren zur herstellung von hochreaktiven isobutenho-mopolymeren |
| US8853336B2 (en) | 2012-02-17 | 2014-10-07 | Basf Se | Boron trifluoride-catalyst complex and process for preparing high-reactivity isobutene homopolymers |
| CN103724465B (zh) * | 2012-10-16 | 2016-05-25 | 中国石油化工股份有限公司 | 一种烯烃聚合物组合物及其制备方法 |
| US9156924B2 (en) * | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| KR101523568B1 (ko) * | 2013-05-16 | 2015-05-28 | 대림산업 주식회사 | 반응성 폴리부텐 및 비반응성 폴리부텐의 선택적 제조장치 및 방법 |
| MY178969A (en) * | 2013-06-05 | 2020-10-26 | Daelim Ind Co Ltd | Apparatus and method for preparing polybutene having various molecular weights |
| DK3016976T3 (da) | 2013-07-01 | 2020-12-07 | Csl Behring Ag | Proces |
| KR101628897B1 (ko) * | 2014-06-18 | 2016-06-09 | 대림산업 주식회사 | 노르말 프로판올을 포함한 촉매를 이용한 폴리부텐의 제조방법 |
| CN104945545A (zh) * | 2015-06-30 | 2015-09-30 | 清华大学 | 一种高反应活性聚异丁烯的制备方法 |
| BR112018016567B1 (pt) | 2016-02-16 | 2022-07-05 | Basf Se | Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade |
| BR112018015440B1 (pt) | 2016-02-16 | 2022-07-05 | Basf Se | Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade |
| KR102421836B1 (ko) | 2016-07-22 | 2022-07-15 | 바스프 에스이 | 고반응성 이소부텐 단독- 또는 공중합체의 제조 방법 |
| EP3444283B1 (en) | 2017-08-17 | 2020-02-26 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| KR102203006B1 (ko) * | 2019-04-24 | 2021-01-13 | 대림산업 주식회사 | 고반응성 폴리부텐의 제조 방법 |
| US12221458B2 (en) | 2019-08-19 | 2025-02-11 | Lg Chem, Ltd. | Organic borate-based catalyst, method for preparing isobutene oligomer using the same and isobutene oligomer prepared thereby |
| EP4001321A1 (en) | 2020-11-17 | 2022-05-25 | Basf Se | Process for preparation of polyisobutene derivatives |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2702604C2 (de) * | 1977-01-22 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | Polyisobutene |
| GB8329082D0 (en) * | 1983-11-01 | 1983-12-07 | Bp Chem Int Ltd | Low molecular weight polymers of 1-olefins |
| BE1006694A5 (fr) * | 1991-06-22 | 1994-11-22 | Basf Ag | Procede de preparation de polyisobutenes extremement reactifs. |
| JP3119452B2 (ja) * | 1991-11-18 | 2000-12-18 | アモコ・コーポレーション | イソブチレン重合のためのｂｆ▲下３▼・第三エーテレート錯体 |
| DE19520078A1 (de) * | 1995-06-07 | 1996-12-12 | Basf Ag | Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten |
-
1998
- 1998-06-05 DE DE19825334A patent/DE19825334A1/de not_active Withdrawn
-
1999
- 1999-06-02 JP JP2000553486A patent/JP2002517575A/ja not_active Withdrawn
- 1999-06-02 CN CNB998070661A patent/CN1139607C/zh not_active Expired - Lifetime
- 1999-06-02 EP EP99929127A patent/EP1095070B1/de not_active Expired - Lifetime
- 1999-06-02 WO PCT/EP1999/003829 patent/WO1999064482A1/de not_active Ceased
- 1999-06-02 AU AU46048/99A patent/AU4604899A/en not_active Abandoned
- 1999-06-02 KR KR1020007013688A patent/KR100575510B1/ko not_active Expired - Lifetime
- 1999-06-02 DE DE59904860T patent/DE59904860D1/de not_active Expired - Lifetime
- 1999-06-02 ES ES99929127T patent/ES2196821T3/es not_active Expired - Lifetime
- 1999-06-02 CA CA002334263A patent/CA2334263A1/en not_active Abandoned
- 1999-06-07 MY MYPI99002311A patent/MY122369A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR100575510B1 (ko) | 2006-05-03 |
| CN1139607C (zh) | 2004-02-25 |
| MY122369A (en) | 2006-04-29 |
| WO1999064482A1 (de) | 1999-12-16 |
| EP1095070B1 (de) | 2003-04-02 |
| AU4604899A (en) | 1999-12-30 |
| KR20010052539A (ko) | 2001-06-25 |
| CA2334263A1 (en) | 1999-12-16 |
| DE59904860D1 (de) | 2003-05-08 |
| EP1095070A1 (de) | 2001-05-02 |
| CN1304418A (zh) | 2001-07-18 |
| JP2002517575A (ja) | 2002-06-18 |
| DE19825334A1 (de) | 1999-12-09 |
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