ES2223598T3 - Procedimiento para la aplicacion de capas de fosfato de manganeso. - Google Patents

Procedimiento para la aplicacion de capas de fosfato de manganeso.

Info

Publication number: ES2223598T3
Authority: ES; Spain
Prior art keywords: ions; manganese; phosphate; work pieces; phosphating
Prior art date: 1999-09-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES00972661T

Other languages

English (en)

Spanish (es)

Inventor

Klaus-Dieter Nittel

Detlev Seifert

Ralf Stickler

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Chemetall GmbH

Original Assignee

Chemetall GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-09-30

Filing date

2000-09-20

Publication date

2005-03-01

2000-09-20 Application filed by Chemetall GmbH filed Critical Chemetall GmbH

2005-03-01 Application granted granted Critical

2005-03-01 Publication of ES2223598T3 publication Critical patent/ES2223598T3/es

2020-09-20 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 title claims abstract description 20
238000000034 method Methods 0.000 title claims abstract description 20
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 23
239000002253 acid Substances 0.000 claims abstract description 15
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims abstract description 14
IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 claims abstract description 12
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 10
229910002651 NO3 Inorganic materials 0.000 claims abstract description 9
229910000831 Steel Inorganic materials 0.000 claims abstract description 9
239000010959 steel Substances 0.000 claims abstract description 9
229910052742 iron Inorganic materials 0.000 claims abstract description 6
-1 nitrate ions Chemical class 0.000 claims abstract description 6
229910001437 manganese ion Inorganic materials 0.000 claims abstract description 5
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims abstract description 4
229910001425 magnesium ion Inorganic materials 0.000 claims abstract description 4
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims abstract description 3
238000001035 drying Methods 0.000 claims abstract description 3
229910001453 nickel ion Inorganic materials 0.000 claims abstract description 3
229910019142 PO4 Inorganic materials 0.000 claims description 21
239000010452 phosphate Substances 0.000 claims description 20
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
230000015572 biosynthetic process Effects 0.000 claims description 7
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
229910045601 alloy Inorganic materials 0.000 claims description 3
239000000956 alloy Substances 0.000 claims description 3
229940093474 manganese carbonate Drugs 0.000 claims description 2
235000006748 manganese carbonate Nutrition 0.000 claims description 2
239000011656 manganese carbonate Substances 0.000 claims description 2
229910000016 manganese(II) carbonate Inorganic materials 0.000 claims description 2
XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims description 2
229910001448 ferrous ion Inorganic materials 0.000 abstract 2
230000003746 surface roughness Effects 0.000 abstract 1
235000021317 phosphate Nutrition 0.000 description 20
229910052751 metal Inorganic materials 0.000 description 8
239000002184 metal Substances 0.000 description 8
239000007789 gas Substances 0.000 description 7
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
230000008569 process Effects 0.000 description 4
238000007654 immersion Methods 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000003111 delayed effect Effects 0.000 description 2
239000011572 manganese Substances 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
238000005554 pickling Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000008901 benefit Effects 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
239000013043 chemical agent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
SZAVHWMCBDFDCM-KTTJZPQESA-N cobalt-60(3+);hexacyanide Chemical compound [60Co+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] SZAVHWMCBDFDCM-KTTJZPQESA-N 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
238000007865 diluting Methods 0.000 description 1
125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
AWKHTBXFNVGFRX-UHFFFAOYSA-K iron(2+);manganese(2+);phosphate Chemical compound [Mn+2].[Fe+2].[O-]P([O-])([O-])=O AWKHTBXFNVGFRX-UHFFFAOYSA-K 0.000 description 1
239000000463 material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
239000003921 oil Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000002161 passivation Methods 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000012286 potassium permanganate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000001012 protector Effects 0.000 description 1
239000010802 sludge Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
239000002966 varnish Substances 0.000 description 1
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
229910000165 zinc phosphate Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/18—Orthophosphates containing manganese cations
- C23C22/188—Orthophosphates containing manganese cations containing also magnesium cations

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Chemical Treatment Of Metals (AREA)
Materials For Medical Uses (AREA)
Diaphragms For Electromechanical Transducers (AREA)

ES00972661T 1999-09-30 2000-09-20 Procedimiento para la aplicacion de capas de fosfato de manganeso. Expired - Lifetime ES2223598T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19947232		1999-09-30
DE19947232A DE19947232A1 (de)	1999-09-30	1999-09-30	Verfahren zum Aufbringen von Manganphosphatschichten

Publications (1)

Publication Number	Publication Date
ES2223598T3 true ES2223598T3 (es)	2005-03-01

Family

ID=7924098

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES00972661T Expired - Lifetime ES2223598T3 (es)	1999-09-30	2000-09-20	Procedimiento para la aplicacion de capas de fosfato de manganeso.

Country Status (6)

Country	Link
EP (1)	EP1230423B1 (pl)
AT (1)	ATE273404T1 (pl)
DE (2)	DE19947232A1 (pl)
ES (1)	ES2223598T3 (pl)
PL (1)	PL196365B1 (pl)
WO (1)	WO2001023638A1 (pl)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2213803C2 (ru) *	2001-07-10	2003-10-10	Закрытое акционерное общество Фирма "Химстар"	Концентрат для получения защитного марганец-фосфатного покрытия и корректирующий состав для него
DE102017207594A1 (de)	2017-05-05	2018-11-08	Federal-Mogul Nürnberg GmbH	Thermische Isolierung eines Stahlkolbens mittels einer Mangan-Phosphat- und einer Polysilazan-Schicht
CN115698380A (zh) *	2020-07-01	2023-02-03	凯密特尔有限责任公司	用于磷酸锰处理方法的改进活化剂

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2375468A (en) *	1938-02-04	1945-05-08	Parker Rust Proof Co	Phosphate coating of metals
DE1246356B (de) *	1963-07-30	1967-08-03	Metallgesellschaft Ag	Verfahren zur Erzeugung von Manganphosphatueberzuegen auf Eisen und Stahl
US3860455A (en) *	1973-03-16	1975-01-14	Oxy Metal Finishing Corp	Method for phosphatizing ferrous surfaces
DE3023479A1 (de) *	1980-06-24	1982-01-14	Metallgesellschaft Ag, 6000 Frankfurt	Phosphatierverfahren
DE4440300A1 (de) *	1994-11-11	1996-05-15	Metallgesellschaft Ag	Verfahren zum Aufbringen von Phosphatüberzügen

1999
- 1999-09-30 DE DE19947232A patent/DE19947232A1/de not_active Withdrawn
2000
- 2000-09-20 PL PL354447A patent/PL196365B1/pl unknown
- 2000-09-20 ES ES00972661T patent/ES2223598T3/es not_active Expired - Lifetime
- 2000-09-20 DE DE50007405T patent/DE50007405D1/de not_active Expired - Lifetime
- 2000-09-20 AT AT00972661T patent/ATE273404T1/de active
- 2000-09-20 WO PCT/EP2000/009193 patent/WO2001023638A1/de not_active Ceased
- 2000-09-20 EP EP00972661A patent/EP1230423B1/de not_active Expired - Lifetime

Also Published As

Publication number	Publication date
WO2001023638A1 (de)	2001-04-05
ATE273404T1 (de)	2004-08-15
EP1230423B1 (de)	2004-08-11
PL196365B1 (pl)	2007-12-31
DE19947232A1 (de)	2001-04-05
DE50007405D1 (de)	2004-09-16
EP1230423A1 (de)	2002-08-14
PL354447A1 (pl)	2004-01-12

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