ES2224048T3 - Celda para la fabricacion de aluminio por electrolisis que funciona con anodos de base metalica. - Google Patents
Celda para la fabricacion de aluminio por electrolisis que funciona con anodos de base metalica.Info
- Publication number
- ES2224048T3 ES2224048T3 ES02702627T ES02702627T ES2224048T3 ES 2224048 T3 ES2224048 T3 ES 2224048T3 ES 02702627 T ES02702627 T ES 02702627T ES 02702627 T ES02702627 T ES 02702627T ES 2224048 T3 ES2224048 T3 ES 2224048T3
- Authority
- ES
- Spain
- Prior art keywords
- aluminum
- cell
- electrolyte
- coating
- wettable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 193
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 187
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 238000005868 electrolysis reaction Methods 0.000 title claims description 12
- 238000000576 coating method Methods 0.000 claims abstract description 63
- 239000011248 coating agent Substances 0.000 claims abstract description 60
- 229910052751 metal Inorganic materials 0.000 claims abstract description 24
- 239000002184 metal Substances 0.000 claims abstract description 24
- 239000011148 porous material Substances 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 19
- 210000004027 cell Anatomy 0.000 claims description 83
- 239000003792 electrolyte Substances 0.000 claims description 47
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 42
- 239000010410 layer Substances 0.000 claims description 35
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 24
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 229910001610 cryolite Inorganic materials 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052684 Cerium Inorganic materials 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- 239000002344 surface layer Substances 0.000 claims description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 150000001785 cerium compounds Chemical class 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229910016569 AlF 3 Inorganic materials 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical class [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 210000005056 cell body Anatomy 0.000 claims 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
- 235000013980 iron oxide Nutrition 0.000 claims 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 9
- XVVDIUTUQBXOGG-UHFFFAOYSA-N [Ce].FOF Chemical compound [Ce].FOF XVVDIUTUQBXOGG-UHFFFAOYSA-N 0.000 abstract description 5
- 239000004411 aluminium Substances 0.000 abstract 6
- 238000005363 electrowinning Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 description 19
- 239000002245 particle Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
- 239000000919 ceramic Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 229910010293 ceramic material Inorganic materials 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- -1 neobium Chemical compound 0.000 description 4
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- 229910033181 TiB2 Inorganic materials 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 210000003850 cellular structure Anatomy 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/085—Cell construction, e.g. bottoms, walls, cathodes characterised by its non electrically conducting heat insulating parts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| WOPCT/IB01/00323 | 2001-03-07 | ||
| IB0100323 | 2001-03-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2224048T3 true ES2224048T3 (es) | 2005-03-01 |
Family
ID=11004053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02702627T Expired - Lifetime ES2224048T3 (es) | 2001-03-07 | 2002-03-04 | Celda para la fabricacion de aluminio por electrolisis que funciona con anodos de base metalica. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20040144642A1 (fr) |
| EP (1) | EP1366216B1 (fr) |
| AT (1) | ATE272728T1 (fr) |
| CA (1) | CA2437687A1 (fr) |
| DE (1) | DE60200885T2 (fr) |
| ES (1) | ES2224048T3 (fr) |
| NZ (1) | NZ527308A (fr) |
| RU (1) | RU2283372C2 (fr) |
| WO (1) | WO2002070785A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2401885C1 (ru) * | 2009-03-23 | 2010-10-20 | Федеральное государственное образовательное учреждение высшего профессионального образования "Сибирский федеральный университет" | Способ защиты катодного устройства алюминиевого электролизера |
| RU2502832C1 (ru) * | 2012-10-08 | 2013-12-27 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Способ защиты катодных блоков со смачиваемым покрытием на основе диборида титана при обжиге электролизера |
| WO2014159715A1 (fr) * | 2013-03-13 | 2014-10-02 | Alcoa Inc. | Systèmes et procédés de protection de cellules d'électrolyse |
| RU2763059C1 (ru) * | 2021-01-26 | 2021-12-27 | Сергей Владимирович Кидаков | Производство алюминия с движущимся электролитом в электролизере |
| CN116411317B (zh) * | 2023-04-19 | 2025-09-16 | 昆明理工恒达科技股份有限公司 | 一种电解锌用阴极板 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE549859A (fr) * | 1955-07-28 | |||
| US4396482A (en) * | 1980-07-21 | 1983-08-02 | Aluminum Company Of America | Composite cathode |
| WO1983000171A1 (fr) * | 1981-07-01 | 1983-01-20 | De Nora, Vittorio | Production electrolytique d'aluminium |
| CH648870A5 (de) * | 1981-10-23 | 1985-04-15 | Alusuisse | Kathode fuer eine schmelzflusselektrolysezelle zur herstellung von aluminium. |
| US4560448A (en) * | 1982-05-10 | 1985-12-24 | Eltech Systems Corporation | Aluminum wettable materials for aluminum production |
| CH651855A5 (de) * | 1982-07-09 | 1985-10-15 | Alusuisse | Festkoerperkathode in einer schmelzflusselektrolysezelle. |
| US4600481A (en) * | 1982-12-30 | 1986-07-15 | Eltech Systems Corporation | Aluminum production cell components |
| AU2428988A (en) * | 1987-09-02 | 1989-03-31 | Eltech Systems Corporation | Non-consumable anode for molten salt electrolysis |
| DE69111078T2 (de) * | 1990-11-28 | 1996-01-11 | Moltech Invent S.A., Luxemburg/Luxembourg | Elektrodenzusammenstellung und multimonopolare zellen für die aluminiumelektrogewinnung. |
| US5310476A (en) * | 1992-04-01 | 1994-05-10 | Moltech Invent S.A. | Application of refractory protective coatings, particularly on the surface of electrolytic cell components |
| US5364513A (en) * | 1992-06-12 | 1994-11-15 | Moltech Invent S.A. | Electrochemical cell component or other material having oxidation preventive coating |
| US5472578A (en) * | 1994-09-16 | 1995-12-05 | Moltech Invent S.A. | Aluminium production cell and assembly |
| US5510008A (en) * | 1994-10-21 | 1996-04-23 | Sekhar; Jainagesh A. | Stable anodes for aluminium production cells |
| DE69809202T2 (de) * | 1997-05-23 | 2003-05-28 | Moltech Invent S.A., Luxemburg/Luxembourg | Aluminium-herstellungszelle und kathode |
| DE60005301T2 (de) * | 1999-01-08 | 2004-06-17 | Moltech Invent S.A. | Elektrolytische zelle mit verbesserter tonerde-zufuhr |
-
2002
- 2002-03-04 NZ NZ527308A patent/NZ527308A/en unknown
- 2002-03-04 WO PCT/IB2002/000670 patent/WO2002070785A1/fr not_active Ceased
- 2002-03-04 RU RU2003129655/02A patent/RU2283372C2/ru not_active IP Right Cessation
- 2002-03-04 EP EP02702627A patent/EP1366216B1/fr not_active Expired - Lifetime
- 2002-03-04 AT AT02702627T patent/ATE272728T1/de not_active IP Right Cessation
- 2002-03-04 CA CA002437687A patent/CA2437687A1/fr not_active Abandoned
- 2002-03-04 ES ES02702627T patent/ES2224048T3/es not_active Expired - Lifetime
- 2002-03-04 US US10/469,455 patent/US20040144642A1/en not_active Abandoned
- 2002-03-04 DE DE60200885T patent/DE60200885T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20040144642A1 (en) | 2004-07-29 |
| EP1366216B1 (fr) | 2004-08-04 |
| ATE272728T1 (de) | 2004-08-15 |
| RU2003129655A (ru) | 2005-02-10 |
| RU2283372C2 (ru) | 2006-09-10 |
| DE60200885T2 (de) | 2005-08-04 |
| DE60200885D1 (de) | 2004-09-09 |
| NZ527308A (en) | 2005-03-24 |
| CA2437687A1 (fr) | 2002-09-12 |
| WO2002070785A1 (fr) | 2002-09-12 |
| EP1366216A1 (fr) | 2003-12-03 |
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