ES2286159T3 - Metodo para la hidrogenacion de poli-o momometilalcanales. - Google Patents

Metodo para la hidrogenacion de poli-o momometilalcanales. Download PDF

Info

Publication number: ES2286159T3
Authority: ES; Spain
Prior art keywords: copper; process according; hydrogenation; alkanal; polymethyl
Prior art date: 2000-11-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES01993593T

Other languages

English (en)

Spanish (es)

Inventor

Matthias Dernbach

Michael Koch

Gerhard Schulz

Hagen Weigl

Steffen Maas

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-11-08

Filing date

2001-11-02

Publication date

2007-12-01

2001-11-02 Application filed by BASF SE filed Critical BASF SE

2007-12-01 Application granted granted Critical

2007-12-01 Publication of ES2286159T3 publication Critical patent/ES2286159T3/es

2021-11-02 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 43
238000000034 method Methods 0.000 title claims abstract description 42
239000003054 catalyst Substances 0.000 claims abstract description 46
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 31
239000010949 copper Substances 0.000 claims abstract description 29
229910052802 copper Inorganic materials 0.000 claims abstract description 27
229910021645 metal ion Inorganic materials 0.000 claims abstract description 20
-1 methylol group Chemical group 0.000 claims abstract description 11
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 6
230000000737 periodic effect Effects 0.000 claims abstract description 6
238000009903 catalytic hydrogenation reaction Methods 0.000 claims abstract description 5
150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 3
125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 3
125000003118 aryl group Chemical group 0.000 claims abstract description 3
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 28
239000003463 adsorbent Substances 0.000 claims description 19
239000000203 mixture Substances 0.000 claims description 19
150000002500 ions Chemical class 0.000 claims description 16
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
238000006243 chemical reaction Methods 0.000 claims description 13
238000002360 preparation method Methods 0.000 claims description 10
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 9
239000000463 material Substances 0.000 claims description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
239000002253 acid Substances 0.000 claims description 7
239000012528 membrane Substances 0.000 claims description 7
239000007858 starting material Substances 0.000 claims description 7
229910052751 metal Inorganic materials 0.000 claims description 6
239000002184 metal Substances 0.000 claims description 6
238000010668 complexation reaction Methods 0.000 claims description 4
229910044991 metal oxide Inorganic materials 0.000 claims description 4
150000004706 metal oxides Chemical class 0.000 claims description 4
239000002808 molecular sieve Substances 0.000 claims description 4
238000000926 separation method Methods 0.000 claims description 4
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
229910052593 corundum Inorganic materials 0.000 claims description 3
229910000510 noble metal Inorganic materials 0.000 claims description 3
229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
229910052725 zinc Inorganic materials 0.000 claims description 3
239000011701 zinc Substances 0.000 claims description 3
229910052684 Cerium Inorganic materials 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
150000002739 metals Chemical class 0.000 claims 1
238000007493 shaping process Methods 0.000 claims 1
230000007704 transition Effects 0.000 claims 1
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 46
239000000047 product Substances 0.000 description 18
235000019256 formaldehyde Nutrition 0.000 description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 8
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 7
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
239000000243 solution Substances 0.000 description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
238000009835 boiling Methods 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
229920005862 polyol Polymers 0.000 description 6
150000003077 polyols Chemical class 0.000 description 6
239000002904 solvent Substances 0.000 description 6
YYKMQUOJKCKTSD-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butanal Chemical compound CCC(CO)(CO)C=O YYKMQUOJKCKTSD-UHFFFAOYSA-N 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
239000011651 chromium Substances 0.000 description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000004821 distillation Methods 0.000 description 4
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
235000012239 silicon dioxide Nutrition 0.000 description 4
FJJYHTVHBVXEEQ-UHFFFAOYSA-N 2,2-dimethylpropanal Chemical compound CC(C)(C)C=O FJJYHTVHBVXEEQ-UHFFFAOYSA-N 0.000 description 3
JJMOMMLADQPZNY-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanal Chemical compound OCC(C)(C)C=O JJMOMMLADQPZNY-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
241000196324 Embryophyta Species 0.000 description 3
AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
238000005575 aldol reaction Methods 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
229910052681 coesite Inorganic materials 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000008139 complexing agent Substances 0.000 description 3
229910052906 cristobalite Inorganic materials 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052759 nickel Inorganic materials 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
239000011148 porous material Substances 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
229910052682 stishovite Inorganic materials 0.000 description 3
229910052905 tridymite Inorganic materials 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
XIKVGYYSAJEFFR-UHFFFAOYSA-N 2-(hydroxymethyl)butanal Chemical compound CCC(CO)C=O XIKVGYYSAJEFFR-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
HNRMPXKDFBEGFZ-UHFFFAOYSA-N ethyl trimethyl methane Natural products CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910052742 iron Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
239000000843 powder Substances 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 1
QYPLKDUOPJZROX-UHFFFAOYSA-N 2,2-dimethylbutanal Chemical compound CCC(C)(C)C=O QYPLKDUOPJZROX-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
ZZBAGJPKGRJIJH-UHFFFAOYSA-N 7h-purine-2-carbaldehyde Chemical compound O=CC1=NC=C2NC=NC2=N1 ZZBAGJPKGRJIJH-UHFFFAOYSA-N 0.000 description 1
241000640882 Condea Species 0.000 description 1
239000005749 Copper compound Substances 0.000 description 1
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
206010065042 Immune reconstitution inflammatory syndrome Diseases 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 1
BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
239000007832 Na2SO4 Substances 0.000 description 1
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
238000000184 acid digestion Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000000956 alloy Substances 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
238000001636 atomic emission spectroscopy Methods 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
210000000601 blood cell Anatomy 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000001354 calcination Methods 0.000 description 1
239000011575 calcium Substances 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
150000001728 carbonyl compounds Chemical class 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
229920001429 chelating resin Polymers 0.000 description 1
UUMMHAPECIIHJR-UHFFFAOYSA-N chromium(4+) Chemical compound [Cr+4] UUMMHAPECIIHJR-UHFFFAOYSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
150000001880 copper compounds Chemical class 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000037213 diet Effects 0.000 description 1
235000005911 diet Nutrition 0.000 description 1
238000001035 drying Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
239000002360 explosive Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000004186 food analysis Methods 0.000 description 1
239000008098 formaldehyde solution Substances 0.000 description 1
REHUGJYJIZPQAV-UHFFFAOYSA-N formaldehyde;methanol Chemical compound OC.O=C REHUGJYJIZPQAV-UHFFFAOYSA-N 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
239000011344 liquid material Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
125000000896 monocarboxylic acid group Chemical group 0.000 description 1
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000006187 pill Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229910021426 porous silicon Inorganic materials 0.000 description 1
238000000746 purification Methods 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
150000004072 triols Chemical class 0.000 description 1
ZISSAWUMDACLOM-UHFFFAOYSA-N triptane Chemical compound CC(C)C(C)(C)C ZISSAWUMDACLOM-UHFFFAOYSA-N 0.000 description 1
150000003673 urethanes Chemical class 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)
Polyethers (AREA)

ES01993593T 2000-11-08 2001-11-02 Metodo para la hidrogenacion de poli-o momometilalcanales. Expired - Lifetime ES2286159T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE10055180A DE10055180A1 (de)	2000-11-08	2000-11-08	Verfahren zur Hydrierung von Poly- oder Monomethylolalkanalen
DE10055180		2000-11-08

Publications (1)

Publication Number	Publication Date
ES2286159T3 true ES2286159T3 (es)	2007-12-01

Family

ID=7662456

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES01993593T Expired - Lifetime ES2286159T3 (es)	2000-11-08	2001-11-02	Metodo para la hidrogenacion de poli-o momometilalcanales.

Country Status (12)

Country	Link
US (1)	US7060861B2 (de)
EP (1)	EP1335891B1 (de)
JP (1)	JP3881958B2 (de)
KR (1)	KR100785983B1 (de)
CN (1)	CN1191219C (de)
AT (1)	ATE364587T1 (de)
AU (1)	AU2002216990A1 (de)
BR (1)	BR0115199B1 (de)
DE (2)	DE10055180A1 (de)
ES (1)	ES2286159T3 (de)
MX (1)	MXPA03003325A (de)
WO (1)	WO2002038525A2 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2008107333A1 (de) *	2007-03-02	2008-09-12	Basf Se	Verfahren zur herstellung von hydroxypivalinaldehyd und neopentylglykol
US9056824B2 (en)	2013-01-31	2015-06-16	Eastman Chemical Company	Preparation of hydroxy aldehydes
US8710278B1 (en)	2013-01-31	2014-04-29	Eastman Chemical Company	Process for producing polyols
KR102359896B1 (ko) *	2017-10-12	2022-02-07	주식회사 엘지화학	디메틸올부탄알의 제조방법 및 이를 이용한 트리메틸올프로판의 제조방법
KR102245932B1 (ko) *	2017-10-23	2021-04-28	주식회사 엘지화학	트리메틸올프로판의 제조방법
CN108314617B (zh) *	2018-01-13	2020-10-09	安徽金禾实业股份有限公司	一种季戊四醇生产中乙醛的回收方法及装置
CN114315659B (zh) *	2022-01-12	2023-03-24	西南石油大学	一种含油钻屑清洗剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1100029C (zh) *	1994-05-19	2003-01-29	巴福斯股份公司	催化剂、其制备方法和应用
DE19653093A1 (de) *	1996-12-20	1998-06-25	Basf Ag	Verfahren zur Herstellung von Polyalkoholen
DE19730939A1 (de) *	1997-07-18	1999-01-21	Basf Ag	Verfahren zur Hydrierung von Carbonylverbindungen
DE19809418A1 (de) *	1998-03-05	1999-09-09	Basf Ag	Verfahren zur Hydrierung von Carbonylverbindungen

2000
- 2000-11-08 DE DE10055180A patent/DE10055180A1/de not_active Withdrawn
2001
- 2001-11-02 ES ES01993593T patent/ES2286159T3/es not_active Expired - Lifetime
- 2001-11-02 DE DE50112632T patent/DE50112632D1/de not_active Expired - Lifetime
- 2001-11-02 BR BRPI0115199-1A patent/BR0115199B1/pt not_active IP Right Cessation
- 2001-11-02 KR KR1020037006255A patent/KR100785983B1/ko not_active Expired - Fee Related
- 2001-11-02 AT AT01993593T patent/ATE364587T1/de not_active IP Right Cessation
- 2001-11-02 EP EP01993593A patent/EP1335891B1/de not_active Expired - Lifetime
- 2001-11-02 CN CNB01818362XA patent/CN1191219C/zh not_active Expired - Lifetime
- 2001-11-02 US US10/399,502 patent/US7060861B2/en not_active Expired - Lifetime
- 2001-11-02 AU AU2002216990A patent/AU2002216990A1/en not_active Abandoned
- 2001-11-02 WO PCT/EP2001/012681 patent/WO2002038525A2/de not_active Ceased
- 2001-11-02 MX MXPA03003325A patent/MXPA03003325A/es active IP Right Grant
- 2001-11-02 JP JP2002541064A patent/JP3881958B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
AU2002216990A1 (en)	2002-05-21
US20040044256A1 (en)	2004-03-04
CN1191219C (zh)	2005-03-02
MXPA03003325A (es)	2003-06-19
JP3881958B2 (ja)	2007-02-14
CN1473141A (zh)	2004-02-04
DE50112632D1 (de)	2007-07-26
WO2002038525A2 (de)	2002-05-16
EP1335891B1 (de)	2007-06-13
BR0115199A (pt)	2004-02-17
KR20030048463A (ko)	2003-06-19
JP2004513156A (ja)	2004-04-30
DE10055180A1 (de)	2002-05-29
WO2002038525A3 (de)	2002-08-01
EP1335891A2 (de)	2003-08-20
KR100785983B1 (ko)	2007-12-14
BR0115199B1 (pt)	2011-08-09
US7060861B2 (en)	2006-06-13
ATE364587T1 (de)	2007-07-15

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