ES2292803T3 - Procedimiento y aparato para la gasificacion de combustibles en un reactor de lecho fluidizado. - Google Patents

Procedimiento y aparato para la gasificacion de combustibles en un reactor de lecho fluidizado. Download PDF

Info

Publication number: ES2292803T3
Authority: ES; Spain
Prior art keywords: reactor; particles; bed; gas; fluidized
Prior art date: 2001-10-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES02764902T

Other languages

English (en)

Spanish (es)

Inventor

Esa Kurkela

Matti Nieminen

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

VTT Technical Research Centre of Finland Ltd

Original Assignee

VTT Technical Research Centre of Finland Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-10-02

Filing date

2002-10-01

Publication date

2008-03-16

2002-10-01 Application filed by VTT Technical Research Centre of Finland Ltd filed Critical VTT Technical Research Centre of Finland Ltd

2008-03-16 Application granted granted Critical

2008-03-16 Publication of ES2292803T3 publication Critical patent/ES2292803T3/es

2022-10-01 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000446 fuel Substances 0.000 title claims abstract description 57
238000000034 method Methods 0.000 title claims abstract description 37
238000002309 gasification Methods 0.000 title claims description 32
239000008267 milk Substances 0.000 title 1
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239000007787 solid Substances 0.000 claims abstract description 33
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229910052801 chlorine Inorganic materials 0.000 claims description 24
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 21
235000008733 Citrus aurantifolia Nutrition 0.000 claims description 11
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OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 12
239000011575 calcium Substances 0.000 description 12
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XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
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238000001704 evaporation Methods 0.000 description 2
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238000000605 extraction Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
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230000000717 retained effect Effects 0.000 description 2
239000000243 solution Substances 0.000 description 2
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239000005995 Aluminium silicate Substances 0.000 description 1
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235000012211 aluminium silicate Nutrition 0.000 description 1
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QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000003637 basic solution Substances 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
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239000003795 chemical substances by application Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
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238000013461 design Methods 0.000 description 1
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239000010881 fly ash Substances 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000002440 industrial waste Substances 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
239000003921 oil Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000005022 packaging material Substances 0.000 description 1
238000012856 packing Methods 0.000 description 1
150000003112 potassium compounds Chemical class 0.000 description 1
239000012264 purified product Substances 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000005057 refrigeration Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C10J3/56—Apparatus; Plants
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1838—Autothermal gasification by injection of oxygen or steam
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Combustion & Propulsion (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
Processing Of Solid Wastes (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Gasification And Melting Of Waste (AREA)
Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Fluidized-Bed Combustion And Resonant Combustion (AREA)

ES02764902T 2001-10-02 2002-10-01 Procedimiento y aparato para la gasificacion de combustibles en un reactor de lecho fluidizado. Expired - Lifetime ES2292803T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FI20011925A FI120770B (fi)	2001-10-02	2001-10-02	Menetelmä ja laitteisto polttoaineen kaasuttamiseksi leijukerrosreaktorissa
FI20011925		2001-10-02

Publications (1)

Publication Number	Publication Date
ES2292803T3 true ES2292803T3 (es)	2008-03-16

Family

ID=8561987

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES02764902T Expired - Lifetime ES2292803T3 (es)	2001-10-02	2002-10-01	Procedimiento y aparato para la gasificacion de combustibles en un reactor de lecho fluidizado.

Country Status (9)

Country	Link
EP (1)	EP1432779B1 (de)
JP (1)	JP4445261B2 (de)
AT (1)	ATE368719T1 (de)
DE (1)	DE60221549T2 (de)
DK (1)	DK1432779T3 (de)
ES (1)	ES2292803T3 (de)
FI (1)	FI120770B (de)
PT (1)	PT1432779E (de)
WO (1)	WO2003029389A1 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN101294092B (zh) *	2007-04-25	2012-07-25	中国科学院过程工程研究所	固体燃料联合热转化方法及转化装置
CN101245264B (zh) *	2008-03-25	2011-02-16	东南大学	单床自热式热解气化燃烧反应器及热解气化燃烧方法
GB0820403D0 (en) *	2008-11-07	2008-12-17	Carson John W	Improved cement
DE102010006192A1 (de)	2010-01-29	2011-08-04	Uhde GmbH, 44141	Verfahren zur Biomasse-Vergasung in einer Wirbelschicht
US8580019B2 (en) *	2010-05-14	2013-11-12	Frontline Bioenergy, Llc	Apparatus and method of optimized acid gas and toxic metal control in gasifier produced gases
IT1400716B1 (it) *	2010-07-06	2013-06-28	Eni Spa	Procedimento per la produzione di gas di sintesi tramite un reattore di gassificazione a letto fluido alimentato con materiale carbonioso e dispositivo adatto allo scopo.
WO2012059016A1 (zh) *	2010-11-01	2012-05-10	广州迪森热能技术股份有限公司	生物质气化工艺
CN102002399A (zh) *	2010-11-15	2011-04-06	国电长源电力股份有限公司	一种采用打包燃料的流化床气化反应方法及反应器
DE102011100490A1 (de) *	2011-05-04	2012-11-08	Outotec Oyj	Verfahren und Anlage zur Erzeugung und Weiterbehandlung von Brenngas
DE102011114171A1 (de) *	2011-09-19	2013-03-21	Thyssenkrupp Uhde Gmbh	Verfahren zur Herstellung von Synthesegas durch Vergasung einer Biomasse in einer Wirbelschicht
CN102784792B (zh) *	2012-07-28	2014-08-20	北京化工大学	多层鼓泡式城市生活垃圾分选装置及方法
ES2436844B1 (es)	2013-09-23	2014-07-07	Eqtec Iberia, S.L.	Procedimiento para la gasificaci�n de materiales sólidos orgánicos y reactor empleado
EP2884170A1 (de) *	2013-12-16	2015-06-17	Doosan Lentjes GmbH	Wirbelbettvorrichtung
CN104593088B (zh) *	2015-01-23	2018-05-25	新奥科技发展有限公司	一种煤气化反应装置及方法
JP6388555B2 (ja) *	2015-03-13	2018-09-12	三菱日立パワーシステムズ株式会社	バイオマスガス化システム及びこれを用いるボイラ設備
WO2020012221A1 (en) *	2018-07-11	2020-01-16	Arcelormittal	Method of heat transfer and associated device
ES2915695B2 (es) *	2020-12-24	2023-01-13	Waste To Energy Advanced Solutions S L	Instalacion y procedimiento de conversion termoquimica de un combustible solido en un gas de sintesis
SE545010C2 (en) *	2021-02-23	2023-02-28	Phoenix Biopower Ip Services Ab	An apparatus and a method for gasification of a solid fuel in a fluidized bed gasifier comprising means for re-introducing solid particles into a fluidized bed
EP4209710A1 (de)	2022-01-10	2023-07-12	ICMEA Srl leader of temporary association of companies ICMEA Srl - Tecnomec Engineering Srl - CNR IRSA	Wirbelbetteinheit
WO2025168667A1 (en) *	2024-02-06	2025-08-14	Borealis Gmbh	Integrated reactor system and process for simultaneously producing a mixture of hydrocarbons from a carbonaceous feedstock and recovering heat

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3617802A1 (de) *	1986-05-27	1987-12-03	Rheinische Braunkohlenw Ag	Verfahren zur herstellung von wasserstoff und kohlenmonoxid enthaltenen gasen aus festen brennstoffen
FI96321C (fi) *	1993-06-11	1996-06-10	Enviropower Oy	Menetelmä ja reaktori prosessikaasun käsittelemiseksi
EP2284245A1 (de) *	1997-12-09	2011-02-16	DONG Energy Power A/S	Wirbelbettreaktor mit Partikelnabscheider und Reaktionskammer

2001
- 2001-10-02 FI FI20011925A patent/FI120770B/fi not_active IP Right Cessation
2002
- 2002-10-01 DE DE60221549T patent/DE60221549T2/de not_active Expired - Lifetime
- 2002-10-01 DK DK02764902T patent/DK1432779T3/da active
- 2002-10-01 AT AT02764902T patent/ATE368719T1/de active
- 2002-10-01 EP EP02764902A patent/EP1432779B1/de not_active Expired - Lifetime
- 2002-10-01 JP JP2003532613A patent/JP4445261B2/ja not_active Expired - Fee Related
- 2002-10-01 WO PCT/FI2002/000775 patent/WO2003029389A1/en not_active Ceased
- 2002-10-01 PT PT02764902T patent/PT1432779E/pt unknown
- 2002-10-01 ES ES02764902T patent/ES2292803T3/es not_active Expired - Lifetime

Also Published As

Publication number	Publication date
PT1432779E (pt)	2007-11-09
FI120770B (fi)	2010-02-26
FI20011925A0 (fi)	2001-10-02
JP4445261B2 (ja)	2010-04-07
JP2005504167A (ja)	2005-02-10
ATE368719T1 (de)	2007-08-15
WO2003029389A1 (en)	2003-04-10
EP1432779A1 (de)	2004-06-30
EP1432779B1 (de)	2007-08-01
FI20011925L (fi)	2003-04-03
DK1432779T3 (da)	2007-12-10
DE60221549D1 (de)	2007-09-13
DE60221549T2 (de)	2008-04-24

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