ES2359293T3 - Instalación y procedimiento para el estañado electrolítico de bandas de acero usando un ánodo insoluble. - Google Patents
Instalación y procedimiento para el estañado electrolítico de bandas de acero usando un ánodo insoluble. Download PDFInfo
- Publication number
- ES2359293T3 ES2359293T3 ES08827122T ES08827122T ES2359293T3 ES 2359293 T3 ES2359293 T3 ES 2359293T3 ES 08827122 T ES08827122 T ES 08827122T ES 08827122 T ES08827122 T ES 08827122T ES 2359293 T3 ES2359293 T3 ES 2359293T3
- Authority
- ES
- Spain
- Prior art keywords
- acid
- compartment
- tin
- electrodialysis
- zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000009434 installation Methods 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims description 33
- 239000002253 acid Substances 0.000 claims abstract description 103
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 80
- 238000000909 electrodialysis Methods 0.000 claims abstract description 72
- 239000012528 membrane Substances 0.000 claims abstract description 72
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 47
- 238000004090 dissolution Methods 0.000 claims abstract description 45
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 41
- 125000002091 cationic group Chemical group 0.000 claims abstract description 35
- 238000004070 electrodeposition Methods 0.000 claims abstract description 32
- 125000000129 anionic group Chemical group 0.000 claims abstract description 27
- 150000002500 ions Chemical class 0.000 claims abstract description 24
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 17
- 239000010959 steel Substances 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 238000000926 separation method Methods 0.000 claims abstract description 12
- 150000001450 anions Chemical class 0.000 claims abstract description 10
- 238000006073 displacement reaction Methods 0.000 claims abstract description 6
- 238000010790 dilution Methods 0.000 claims abstract 2
- 239000012895 dilution Substances 0.000 claims abstract 2
- 239000003792 electrolyte Substances 0.000 claims description 29
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- 238000007872 degassing Methods 0.000 claims description 14
- 239000008187 granular material Substances 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 238000007747 plating Methods 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 230000005611 electricity Effects 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 238000011084 recovery Methods 0.000 claims description 5
- 239000012811 non-conductive material Substances 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 1
- 230000009089 cytolysis Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 8
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 229910001432 tin ion Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 230000001174 ascending effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000000502 dialysis Methods 0.000 description 3
- 229940098779 methanesulfonic acid Drugs 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000005097 cold rolling Methods 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011034 membrane dialysis Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- AICMYQIGFPHNCY-UHFFFAOYSA-J methanesulfonate;tin(4+) Chemical compound [Sn+4].CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O AICMYQIGFPHNCY-UHFFFAOYSA-J 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- HXTSPGYEPSIZKP-UHFFFAOYSA-N phenol;tin Chemical compound [Sn].OC1=CC=CC=C1 HXTSPGYEPSIZKP-UHFFFAOYSA-N 0.000 description 1
- 229940044652 phenolsulfonate Drugs 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/002—Cell separation, e.g. membranes, diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/18—Regeneration of process solutions of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/30—Electroplating: Baths therefor from solutions of tin
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/06—Wires; Strips; Foils
- C25D7/0614—Strips or foils
- C25D7/0628—In vertical cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5563 | 2001-12-05 | ||
| FR0705563A FR2919619B1 (fr) | 2007-07-30 | 2007-07-30 | Installation et procede pour l'etamage electrolytique de bandes d'acier,mettant en oeuvre une anode insoluble |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2359293T3 true ES2359293T3 (es) | 2011-05-20 |
Family
ID=39253879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES08827122T Active ES2359293T3 (es) | 2007-07-30 | 2008-06-09 | Instalación y procedimiento para el estañado electrolítico de bandas de acero usando un ánodo insoluble. |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2173928B1 (fr) |
| ES (1) | ES2359293T3 (fr) |
| FR (1) | FR2919619B1 (fr) |
| WO (1) | WO2009019333A1 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10011919B2 (en) * | 2015-05-29 | 2018-07-03 | Lam Research Corporation | Electrolyte delivery and generation equipment |
| CN105908247A (zh) * | 2016-05-16 | 2016-08-31 | 中国钢研科技集团有限公司 | 补充电镀锡液二价锡离子的电解溶锡装置及其系统和方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5318168B2 (fr) * | 1973-11-28 | 1978-06-13 | ||
| US4181580A (en) * | 1973-11-28 | 1980-01-01 | Nippon Steel Corporation | Process for electro-tin plating |
| JP2559935B2 (ja) * | 1991-12-20 | 1996-12-04 | 日本リーロナール株式会社 | 不溶性陽極を用いた錫又は錫ー鉛合金電気めっきの方法及び装置 |
| US5312539A (en) * | 1993-06-15 | 1994-05-17 | Learonal Inc. | Electrolytic tin plating method |
-
2007
- 2007-07-30 FR FR0705563A patent/FR2919619B1/fr not_active Expired - Fee Related
-
2008
- 2008-06-09 EP EP08827122A patent/EP2173928B1/fr not_active Not-in-force
- 2008-06-09 WO PCT/FR2008/000791 patent/WO2009019333A1/fr not_active Ceased
- 2008-06-09 ES ES08827122T patent/ES2359293T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| FR2919619A1 (fr) | 2009-02-06 |
| EP2173928A1 (fr) | 2010-04-14 |
| FR2919619B1 (fr) | 2009-10-09 |
| EP2173928B1 (fr) | 2011-01-12 |
| WO2009019333A1 (fr) | 2009-02-12 |
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