ES2389185T3 - Composiciones de emulsión explosiva y métodos de preparación de las mismas - Google Patents

Composiciones de emulsión explosiva y métodos de preparación de las mismas Download PDF

Info

Publication number: ES2389185T3
Authority: ES; Spain
Prior art keywords: reactor; emulsion; phase; crystallization temperature; agent
Prior art date: 2007-06-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES08774442T

Other languages

English (en)

Spanish (es)

Inventor

Carl Lubbe

Joseph Oliphant

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

MaxamCorp Holding SL

Original Assignee

MaxamCorp Holding SL

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2007-06-28

Filing date

2008-06-27

Publication date

2012-10-24

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40039821&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2389185(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2008-06-27 Application filed by MaxamCorp Holding SL filed Critical MaxamCorp Holding SL

2012-10-24 Application granted granted Critical

2012-10-24 Publication of ES2389185T3 publication Critical patent/ES2389185T3/es

Status Active legal-status Critical Current

2028-06-27 Anticipated expiration legal-status Critical

Links

239000000839 emulsion Substances 0.000 title claims abstract description 175
239000000203 mixture Substances 0.000 title claims abstract description 118
239000002360 explosive Substances 0.000 title claims abstract description 114
238000000034 method Methods 0.000 title claims description 74
238000002360 preparation method Methods 0.000 title description 2
238000002425 crystallisation Methods 0.000 claims abstract description 116
230000008025 crystallization Effects 0.000 claims abstract description 116
239000003795 chemical substances by application Substances 0.000 claims abstract description 111
230000007423 decrease Effects 0.000 claims abstract description 82
230000001590 oxidative effect Effects 0.000 claims abstract description 81
229910002651 NO3 Inorganic materials 0.000 claims abstract description 57
239000004312 hexamethylene tetramine Substances 0.000 claims abstract description 52
235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 52
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 52
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 49
239000000446 fuel Substances 0.000 claims abstract description 49
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 48
239000003995 emulsifying agent Substances 0.000 claims abstract description 22
239000006185 dispersion Substances 0.000 claims abstract description 5
230000003247 decreasing effect Effects 0.000 claims description 38
230000008569 process Effects 0.000 claims description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
239000003921 oil Substances 0.000 claims description 18
238000010924 continuous production Methods 0.000 claims description 13
239000003431 cross linking reagent Substances 0.000 claims description 10
239000002480 mineral oil Substances 0.000 claims description 7
235000010446 mineral oil Nutrition 0.000 claims description 7
238000002156 mixing Methods 0.000 claims description 5
239000000243 solution Substances 0.000 claims 9
239000007864 aqueous solution Substances 0.000 claims 1
238000010923 batch production Methods 0.000 claims 1
239000007800 oxidant agent Substances 0.000 abstract description 66
BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 21
229910001488 sodium perchlorate Inorganic materials 0.000 description 21
238000001816 cooling Methods 0.000 description 18
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 18
238000005474 detonation Methods 0.000 description 17
230000000295 complement effect Effects 0.000 description 15
235000019198 oils Nutrition 0.000 description 15
238000003860 storage Methods 0.000 description 15
239000003638 chemical reducing agent Substances 0.000 description 14
239000007789 gas Substances 0.000 description 10
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
229910052782 aluminium Inorganic materials 0.000 description 9
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
150000001412 amines Chemical class 0.000 description 9
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
238000000354 decomposition reaction Methods 0.000 description 9
PTIUDKQYXMFYAI-UHFFFAOYSA-N methylammonium nitrate Chemical compound NC.O[N+]([O-])=O PTIUDKQYXMFYAI-UHFFFAOYSA-N 0.000 description 9
239000001301 oxygen Substances 0.000 description 9
229910052760 oxygen Inorganic materials 0.000 description 9
239000004317 sodium nitrate Substances 0.000 description 9
235000010344 sodium nitrate Nutrition 0.000 description 9
239000001993 wax Substances 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
-1 amine nitrate Chemical class 0.000 description 8
230000008901 benefit Effects 0.000 description 8
239000000047 product Substances 0.000 description 8
230000035945 sensitivity Effects 0.000 description 8
239000004034 viscosity adjusting agent Substances 0.000 description 7
239000011324 bead Substances 0.000 description 6
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 5
230000035939 shock Effects 0.000 description 5
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
229910017604 nitric acid Inorganic materials 0.000 description 4
238000004806 packaging method and process Methods 0.000 description 4
239000007762 w/o emulsion Substances 0.000 description 4
229910021529 ammonia Inorganic materials 0.000 description 3
238000010586 diagram Methods 0.000 description 3
230000007613 environmental effect Effects 0.000 description 3
239000000499 gel Substances 0.000 description 3
238000012544 monitoring process Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
235000015112 vegetable and seed oil Nutrition 0.000 description 3
239000008158 vegetable oil Substances 0.000 description 3
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
238000011109 contamination Methods 0.000 description 2
239000013078 crystal Substances 0.000 description 2
230000003467 diminishing effect Effects 0.000 description 2
239000003673 groundwater Substances 0.000 description 2
229910052500 inorganic mineral Inorganic materials 0.000 description 2
239000000463 material Substances 0.000 description 2
239000008041 oiling agent Substances 0.000 description 2
239000011049 pearl Substances 0.000 description 2
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
238000012545 processing Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000004781 supercooling Methods 0.000 description 2
238000012360 testing method Methods 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
KZTZJUQNSSLNAG-UHFFFAOYSA-N aminoethyl nitrate Chemical class NCCO[N+]([O-])=O KZTZJUQNSSLNAG-UHFFFAOYSA-N 0.000 description 1
230000000712 assembly Effects 0.000 description 1
238000000429 assembly Methods 0.000 description 1
238000005422 blasting Methods 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000000593 degrading effect Effects 0.000 description 1
238000000586 desensitisation Methods 0.000 description 1
238000013461 design Methods 0.000 description 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000004880 explosion Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QHDUJTCUPWHNPK-UHFFFAOYSA-N methyl 7-methoxy-2h-indazole-3-carboxylate Chemical compound COC1=CC=CC2=C(C(=O)OC)NN=C21 QHDUJTCUPWHNPK-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
238000012856 packing Methods 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
230000002028 premature Effects 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
230000004044 response Effects 0.000 description 1
238000000518 rheometry Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B23/00—Compositions characterised by non-explosive or non-thermic constituents
- C06B23/006—Stabilisers (e.g. thermal stabilisers)

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Colloid Chemistry (AREA)
Liquid Carbonaceous Fuels (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Inorganic Compounds Of Heavy Metals (AREA)

ES08774442T 2007-06-28 2008-06-27 Composiciones de emulsión explosiva y métodos de preparación de las mismas Active ES2389185T3 (es)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US770378		1991-10-03
US11/770,378 US20120180915A1 (en)	2007-06-28	2007-06-28	Explosive emulsion compositions and methods of making the same
PCT/EP2008/058277 WO2009000915A2 (en)	2007-06-28	2008-06-27	Explosive emulsion compositions and methods of making the same

Publications (1)

Publication Number	Publication Date
ES2389185T3 true ES2389185T3 (es)	2012-10-24

Family

ID=40039821

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES08774442T Active ES2389185T3 (es)	2007-06-28	2008-06-27	Composiciones de emulsión explosiva y métodos de preparación de las mismas

Country Status (12)

Country	Link
US (1)	US20120180915A1 (pl)
EP (1)	EP2176197B1 (pl)
CN (1)	CN101801892B (pl)
AU (1)	AU2008267135B2 (pl)
BR (1)	BRPI0813219B1 (pl)
CA (1)	CA2700683C (pl)
CL (1)	CL2008001909A1 (pl)
ES (1)	ES2389185T3 (pl)
PE (1)	PE20090532A1 (pl)
PL (1)	PL2176197T3 (pl)
RU (1)	RU2469013C2 (pl)
WO (1)	WO2009000915A2 (pl)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR101143853B1 (ko) *	2009-09-23	2012-05-23	신경민	생체세포의 임피던스 변화에 따라 ｒｆ 출력을 제어하는 방법 및 시스템
GB201202402D0 (en) *	2012-02-10	2012-03-28	Maxam Dantex South Africa Proprietary Ltd	Oxidizer solution
CN103848704A (zh) *	2012-11-30	2014-06-11	陕西省汉阴华能新材料研究有限公司	回收油的应用
CN103553850B (zh) *	2013-10-11	2016-01-20	葛洲坝易普力股份有限公司	一种现场向上进行深孔填装制备乳化炸药的工艺方法
CN104515843B (zh) *	2014-12-23	2016-04-13	中煤科工集团淮北爆破技术研究院有限公司	乳化炸药产品质量在线监测方法
CN205738207U (zh)	2015-11-10	2016-11-30	迪博泰有限公司	用于低温爆炸物乳剂的包装系统及适于该系统的角形组件
CN111272971A (zh) *	2020-03-10	2020-06-12	鞍钢矿业爆破有限公司	一种现场混装乳化炸药水相性能自动检测系统及方法
CN112939710B (zh) *	2021-03-24	2022-04-22	葛洲坝易普力湖北昌泰民爆有限公司	一种用煤制油中间产品制备现场混装铵油炸药用油相及其制备方法
KR102744525B1 (ko) *	2021-12-29	2024-12-18	주식회사 한화	저비중 에멀젼 폭약 조성물
AU2022448528A1 (en) *	2022-03-25	2024-10-03	Enaex Sa	New technology for manufacturing low viscosity emulsions

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2126921C3 (de) *	1971-05-29	1981-07-16	Dynamit Nobel Ag, 5210 Troisdorf	Energielieferndes, zur Herstellung von Sprengstoffen geeignetes eutektisches Gemisch mit niedrigem Erstarrungspunkt und seine Verwendung
JPS608998B2 (ja) *	1980-03-12	1985-03-07	日本化薬株式会社	油中水滴型エマルジヨン爆薬
NZ206983A (en) *	1983-02-15	1988-02-29	Ici Australia Ltd	Dynamite explosive composition
IE59303B1 (en) *	1985-08-21	1994-02-09	Ici Australia Ltd	Composition
JPH0637344B2 (ja) *	1986-03-10	1994-05-18	日本油脂株式会社	油中水型エマルシヨン爆薬組成物
JPH0684273B2 (ja) *	1987-08-25	1994-10-26	日本油脂株式会社	油中水型エマルション爆薬組成物
SE8800593L (sv) *	1988-02-22	1989-08-23	Nitro Nobel Ab	Spraengaemneskomposition
US5099763A (en) *	1990-05-16	1992-03-31	Eti Explosive Technologies International	Method of blasting
US5071496A (en) *	1990-05-16	1991-12-10	Eti Explosive Technologies International (Canada)	Low level blasting composition
US5159153A (en) *	1990-06-07	1992-10-27	Cranney Don H	Emulsion that is compatible with reactive sulfide/pyrite ores
CA2049628C (en) *	1991-08-21	2002-02-26	Clare T. Aitken	Vegetable oil emulsion explosive
ES2081744B1 (es) *	1993-04-20	1997-01-16	Espanola Explosivos	Composicion explosiva encartuchable en papel y su procedimiento de fabricacion.
US5608185A (en) *	1995-01-31	1997-03-04	Dyno Nobel Inc.	Method of reducing nitrogen oxide fumes in blasting
US6051086A (en) *	1998-06-08	2000-04-18	Orica Explosives Technology Pty Ltd.	Buffered emulsion blasting agent
AUPP600098A0 (en) *	1998-09-17	1998-10-08	Dyno Nobel Asia Pacific Limited	Explosive emulsion composition
DE19847868C2 (de) *	1998-10-16	2003-09-25	Clariant Gmbh	Sprengstoffe, enthaltend modifizierte Copolymere aus Polyisobutylen und Maleinsäureanhydrid als Emulgatoren
US6214140B1 (en) *	1999-09-22	2001-04-10	Universal Tech Corporation	Development of new high energy blasting products using demilitarized ammonium picrate
RU2277523C2 (ru) *	2004-04-28	2006-06-10	Открытое акционерное общество "Промсинтез"	Эмульсионный взрывчатый состав и способ его получения
US20060243362A1 (en) *	2005-02-01	2006-11-02	Houston Donald J	Explosive compositions

2007
- 2007-06-28 US US11/770,378 patent/US20120180915A1/en not_active Abandoned
2008
- 2008-06-25 PE PE2008001083A patent/PE20090532A1/es active IP Right Grant
- 2008-06-27 EP EP08774442A patent/EP2176197B1/en not_active Not-in-force
- 2008-06-27 CA CA2700683A patent/CA2700683C/en not_active Expired - Fee Related
- 2008-06-27 CN CN2008801033950A patent/CN101801892B/zh not_active Expired - Fee Related
- 2008-06-27 BR BRPI0813219-4A patent/BRPI0813219B1/pt not_active IP Right Cessation
- 2008-06-27 RU RU2010102772/05A patent/RU2469013C2/ru active
- 2008-06-27 CL CL2008001909A patent/CL2008001909A1/es unknown
- 2008-06-27 PL PL08774442T patent/PL2176197T3/pl unknown
- 2008-06-27 WO PCT/EP2008/058277 patent/WO2009000915A2/en not_active Ceased
- 2008-06-27 AU AU2008267135A patent/AU2008267135B2/en not_active Ceased
- 2008-06-27 ES ES08774442T patent/ES2389185T3/es active Active

Also Published As

Publication number	Publication date
WO2009000915A3 (en)	2009-05-28
BRPI0813219B1 (pt)	2019-04-24
CN101801892A (zh)	2010-08-11
CA2700683A1 (en)	2008-12-31
AU2008267135A1 (en)	2008-12-31
EP2176197B1 (en)	2012-06-06
RU2469013C2 (ru)	2012-12-10
EP2176197A2 (en)	2010-04-21
CN101801892B (zh)	2012-11-14
PE20090532A1 (es)	2009-05-29
AU2008267135B2 (en)	2011-12-08
RU2010102772A (ru)	2011-08-10
BRPI0813219A2 (pt)	2014-12-23
CL2008001909A1 (es)	2009-01-02
PL2176197T3 (pl)	2012-11-30
WO2009000915A2 (en)	2008-12-31
CA2700683C (en)	2014-11-18
US20120180915A1 (en)	2012-07-19

Publication	Publication Date	Title
ES2389185T3 (es)	2012-10-24	Composiciones de emulsión explosiva y métodos de preparación de las mismas
JPS5938182B2 (ja)	1984-09-14	乳化爆発組成物
US2455205A (en)	1948-11-30	Compositions suitable for use as gas and power producing liquids
JPS62119187A (ja)	1987-05-30	マイクロセルコンポジツト高エネルギ−材料及びその製造方法
NO146631B (no)	1982-08-02	Vandig inertfasesprengstoff
US2220891A (en)	1940-11-12	Ammonium nitrate explosive composition
JPS6366799B2 (pl)	1988-12-22
US3996078A (en)	1976-12-07	Explosive composition and eutectic mixture therefor
CN107001170A (zh)	2017-08-01	炸药组合物和输送方法
WO1999000342A1 (es)	1999-01-07	Procedimiento e instalacion para la sensibilizacion in situ de explosivos de base acuosa
US4380482A (en)	1983-04-19	Stabilization of water-bearing explosives having a thickened continuous aqueous phase
US2168562A (en)	1939-08-08	Inorganic nitrate explosive
Badgujar et al.	2018	Influence of guanylurea dinitramide (GUDN) on the thermal behaviour, sensitivity and ballistic properties of the B-KNO3-PEC ignition system
US3449181A (en)	1969-06-10	Aqueous slurry type explosive containing the combination of nitrite and sulfamate and/or sulfamic acid as aeration agent
NO141011B (no)	1979-09-17	Tyktflytende, oppskummet, vannholdig sprengstoffblanding
US3306789A (en)	1967-02-28	Nitric acid explosive composition containing inorganic nitrate oxidizer and nitrated aromatic compound
CA1325724C (en)	1994-01-04	Aromatic hydrocarbon-based emulsion explosive composition
CA1325723C (en)	1994-01-04	Nitroalkane-based emulsion explosive composition
JPH0684273B2 (ja)	1994-10-26	油中水型エマルション爆薬組成物
US4994124A (en)	1991-02-19	Sensitized explosive
EP0011383A1 (en)	1980-05-28	Gelled aqueous slurry explosives containing gas bubbles
JP3984383B2 (ja)	2007-10-03	油中水滴型エマルション爆薬組成物の製造方法
US4221618A (en)	1980-09-09	Slurry explosives
USRE26804E (en)	1970-02-24	Temperature co
US3390031A (en)	1968-06-25	Gelled aqueous slurry explosive composition containing an inorganic nitrite