ES2408579T3 - Método para la detección, medida y control de trióxido de azufre y de otros condensables presentes en los gases de combustión - Google Patents

Método para la detección, medida y control de trióxido de azufre y de otros condensables presentes en los gases de combustión Download PDF

Info

Publication number: ES2408579T3
Authority: ES; Spain
Prior art keywords: temperature; probe; gas; identified; species
Prior art date: 2008-08-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES09010525T

Other languages

English (en)

Spanish (es)

Inventor

Chetan Chothani

Charles A. Lockert

Bernhard P. Breen

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BREEN ENERGY SOLUTIONS A PENNSYLVANIA CORP

Original Assignee

BREEN ENERGY SOLUTIONS A PENNSYLVANIA CORP

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2008-08-14

Filing date

2009-08-14

Publication date

2013-06-21

2009-08-14 Application filed by BREEN ENERGY SOLUTIONS A PENNSYLVANIA CORP filed Critical BREEN ENERGY SOLUTIONS A PENNSYLVANIA CORP

2013-06-21 Application granted granted Critical

2013-06-21 Publication of ES2408579T3 publication Critical patent/ES2408579T3/es

Status Active legal-status Critical Current

2029-08-14 Anticipated expiration legal-status Critical

Links

238000000034 method Methods 0.000 title claims abstract description 51
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 title claims description 92
239000003546 flue gas Substances 0.000 title claims description 34
238000005259 measurement Methods 0.000 title description 9
238000001514 detection method Methods 0.000 title description 3
239000000523 sample Substances 0.000 claims abstract description 118
238000010438 heat treatment Methods 0.000 claims abstract description 41
238000001816 cooling Methods 0.000 claims abstract description 40
238000009833 condensation Methods 0.000 claims abstract description 35
230000005494 condensation Effects 0.000 claims abstract description 35
239000000463 material Substances 0.000 claims abstract description 30
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238000001704 evaporation Methods 0.000 claims abstract description 17
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QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 48
239000007789 gas Substances 0.000 claims description 48
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 41
239000000567 combustion gas Substances 0.000 claims description 30
BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 claims description 20
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 19
229910021529 ammonia Inorganic materials 0.000 claims description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
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235000002918 Fraxinus excelsior Nutrition 0.000 description 2
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VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
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AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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235000019738 Limestone Nutrition 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
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235000011941 Tilia x europaea Nutrition 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000809 air pollutant Substances 0.000 description 1
231100001243 air pollutant Toxicity 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
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239000004202 carbamide Substances 0.000 description 1
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238000006555 catalytic reaction Methods 0.000 description 1
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239000006028 limestone Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
230000000873 masking effect Effects 0.000 description 1
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QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
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Classifications

- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/14—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N25/00—Investigating or analyzing materials by the use of thermal means
- G01N25/56—Investigating or analyzing materials by the use of thermal means by investigating moisture content
- G01N25/66—Investigating or analyzing materials by the use of thermal means by investigating moisture content by investigating dew-point
- G01N25/68—Investigating or analyzing materials by the use of thermal means by investigating moisture content by investigating dew-point by varying the temperature of a condensing surface
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/0042—SO2 or SO3

Landscapes

Chemical & Material Sciences (AREA)
General Health & Medical Sciences (AREA)
Immunology (AREA)
Physics & Mathematics (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Analytical Chemistry (AREA)
Electrochemistry (AREA)
Biochemistry (AREA)
General Physics & Mathematics (AREA)
Chemical Kinetics & Catalysis (AREA)
Pathology (AREA)
Sampling And Sample Adjustment (AREA)
Investigating Or Analyzing Materials Using Thermal Means (AREA)
Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Treating Waste Gases (AREA)
Investigating Or Analyzing Materials By The Use Of Fluid Adsorption Or Reactions (AREA)

ES09010525T 2008-08-14 2009-08-14 Método para la detección, medida y control de trióxido de azufre y de otros condensables presentes en los gases de combustión Active ES2408579T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US88923P		1998-06-11
US8892308P	2008-08-14	2008-08-14

Publications (1)

Publication Number	Publication Date
ES2408579T3 true ES2408579T3 (es)	2013-06-21

Family

ID=41465389

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES09010525T Active ES2408579T3 (es)	2008-08-14	2009-08-14	Método para la detección, medida y control de trióxido de azufre y de otros condensables presentes en los gases de combustión

Country Status (5)

Country	Link
US (1)	US8256267B2 (de)
EP (1)	EP2154530B1 (de)
JP (1)	JP5208883B2 (de)
CN (1)	CN101718724B (de)
ES (1)	ES2408579T3 (de)

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WO2016074178A1 (zh) *	2014-11-12	2016-05-19	德梅斯特科技有限公司	一种用于净化火力发电厂尾气的装置
US10088157B2 (en) *	2015-02-24	2018-10-02	General Electric Technology Gmbh	Multi-sensor probe for monitoring combustion in a conduit
WO2016146959A1 (en) *	2015-03-17	2016-09-22	Statoil Petroleum As	Dew point and carry-over monitoring
DE102015204883A1 (de) *	2015-03-18	2016-09-22	Siemens Aktiengesellschaft	Laser-basierte IR-Spektroskopie für die Messung von Schwefeltrioxid im Abgas von Gaskraftwerken
US9919266B2 (en) *	2016-01-14	2018-03-20	Fluor Technologies Corporation	Systems and methods for treatment of flue gas
CN105606683A (zh) *	2016-01-29	2016-05-25	华电电力科学研究院	So3在线连续监测装置及方法
US10557378B2 (en) *	2016-03-07	2020-02-11	General Electric Technology Gmbh	System and method for regulating condensation of flue gas in a steam generator
CN108459134B (zh) *	2018-03-22	2024-03-12	西安交通大学	烟气冷凝除湿脱污环境活性离子取样监测探针、系统及方法
CN109342284B (zh) *	2018-10-22	2025-10-21	北京清新环境技术股份有限公司	一种用于烟气中有害物质的检测系统及检测方法
DK3608667T3 (da) *	2018-11-15	2022-05-02	Holcim Technology Ltd	Fremgangsmåde og indretning til at analysere prøver af en gas i en cementdrejeovn
ES2966787T3 (es) *	2019-07-10	2024-04-24	Basf Se	Procedimiento para reducir la concentración de SO3 en una mezcla de reacción que comprende ácido metano sulfónico y SO3
US20210223132A1 (en) *	2020-01-21	2021-07-22	Breen Energy Solutions	Systems and methods for detecting moisture leaks or moisture ingress
CN111693559B (zh) *	2020-06-22	2022-04-01	中国核动力研究设计院	气相混合物的蒸汽液滴质量流量分离测量装置及测量方法
CN112255056B (zh) *	2020-11-03	2025-07-29	西安热工研究院有限公司	一种燃煤电站烟气中硫酸氢铵的采集装置及方法
CN112834562B (zh) *	2021-01-04	2022-04-12	吉林大学	一种热导式混合气体中氦气浓度检测的装置及其方法
CN113731047A (zh) *	2021-08-16	2021-12-03	中科三清科技有限公司	一种烟气脱硫脱硝除尘一体化装置及其处理工艺
CN116296638B (zh) *	2023-04-10	2025-12-23	中国能源建设集团华中电力试验研究院有限公司	一种便携式烟气三氧化硫、湿度采样箱
CN117890527B (zh) *	2024-03-14	2024-05-24	山西泰瑞祥科技有限公司	一种烟气监测系统

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2009
- 2009-08-12 US US12/540,010 patent/US8256267B2/en not_active Expired - Fee Related
- 2009-08-13 JP JP2009187709A patent/JP5208883B2/ja not_active Expired - Fee Related
- 2009-08-13 CN CN200910211691.9A patent/CN101718724B/zh not_active Expired - Fee Related
- 2009-08-14 EP EP09010525A patent/EP2154530B1/de not_active Not-in-force
- 2009-08-14 ES ES09010525T patent/ES2408579T3/es active Active

Also Published As

Publication number	Publication date
JP5208883B2 (ja)	2013-06-12
JP2010060557A (ja)	2010-03-18
CN101718724B (zh)	2013-08-28
EP2154530B1 (de)	2013-02-13
EP2154530A3 (de)	2011-03-23
EP2154530A2 (de)	2010-02-17
US20100037678A1 (en)	2010-02-18
CN101718724A (zh)	2010-06-02
US8256267B2 (en)	2012-09-04

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