ES2421584T3 - Un proceso para la preparación de un copolímero de etileno en un reactor tubular - Google Patents
Un proceso para la preparación de un copolímero de etileno en un reactor tubularInfo
- Publication number
- ES2421584T3 ES2421584T3 ES06707405T ES06707405T ES2421584T3 ES 2421584 T3 ES2421584 T3 ES 2421584T3 ES 06707405 T ES06707405 T ES 06707405T ES 06707405 T ES06707405 T ES 06707405T ES 2421584 T3 ES2421584 T3 ES 2421584T3
- Authority
- ES
- Spain
- Prior art keywords
- ethylene copolymer
- preparation
- tubular reactor
- comonomer
- mol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Un proceso para la preparación de un copolímero de etileno y un monómero copolimerizable con el mismo, caracterizado porque la polimerización tiene lugar en un reactor tubular a una temperatura máxima de entre 290 y 350ºC, el comonómero es un (met)acrilato difuncional o de funcionalidad superior y el comonómero se aplica en una cantidad de entre 0,008% en moles y 0,200% en moles respecto a la cantidad de copolímero de etileno.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05075571 | 2005-03-09 | ||
| PCT/EP2006/001974 WO2006094723A1 (en) | 2005-03-09 | 2006-02-27 | A process for the preparation of an ethylene copolymer in a tubular reactor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2421584T3 true ES2421584T3 (es) | 2013-09-04 |
Family
ID=34938089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06707405T Expired - Lifetime ES2421584T3 (es) | 2005-03-09 | 2006-02-27 | Un proceso para la preparación de un copolímero de etileno en un reactor tubular |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7820776B2 (es) |
| EP (1) | EP1861434B1 (es) |
| JP (1) | JP2008533223A (es) |
| KR (2) | KR101391511B1 (es) |
| CN (1) | CN101137681B (es) |
| BR (1) | BRPI0608302B1 (es) |
| CA (1) | CA2599636C (es) |
| DK (1) | DK1861434T3 (es) |
| EA (1) | EA015960B1 (es) |
| ES (1) | ES2421584T3 (es) |
| MX (1) | MX2007011007A (es) |
| NO (1) | NO20075055L (es) |
| PL (1) | PL1861434T3 (es) |
| PT (1) | PT1861434E (es) |
| WO (1) | WO2006094723A1 (es) |
| ZA (1) | ZA200707776B (es) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101432322B (zh) * | 2006-03-24 | 2011-01-26 | 沙特基础工业公司 | 挤出涂布组合物 |
| EP2069145A2 (en) | 2006-09-11 | 2009-06-17 | Saudi Basic Industries Corporation | Food packaging |
| SG190030A1 (en) | 2010-10-29 | 2013-06-28 | Dow Global Technologies Llc | Ethylene-based polymers and processes for the same |
| BR112013016031B1 (pt) | 2010-12-22 | 2020-04-07 | Basell Polyolefine Gmbh | processo para preparar copolímero de etileno na presença de iniciador da polimerização por radicais livres por copolimerização de etileno, copolímero de etileno obtido por tal processo e seu uso, bem como processo para revestimento por extrusão de um substrato |
| CN103403040B (zh) * | 2011-03-03 | 2015-11-25 | 巴塞尔聚烯烃股份有限公司 | 在具有至少两个具有不同链转移剂浓度的反应区的管式反应器中制备乙烯均聚物或共聚物的方法 |
| WO2013078018A2 (en) | 2011-11-23 | 2013-05-30 | Dow Global Technologies Llc | Low density ethylene-based polymers with broad molecular weight distributions and low extractables |
| WO2013078224A1 (en) | 2011-11-23 | 2013-05-30 | Dow Global Technologies Llc | Low density ethylene-based polymers with extracts at lower molecular weights |
| WO2013095969A1 (en) | 2011-12-22 | 2013-06-27 | Dow Global Technologies Llc | Ethylene-based polymers with improved melt strength and processes for the same |
| EP2636691A1 (en) | 2012-03-07 | 2013-09-11 | Borealis AG | Process and plant for manufacturing polyethylene-diene-copolymers |
| KR20140117524A (ko) | 2012-04-02 | 2014-10-07 | 보레알리스 아게 | 억제제를 사용하는 에틸렌 중합 공정 |
| JP6339565B2 (ja) | 2012-06-27 | 2018-06-06 | ダウ グローバル テクノロジーズ エルエルシー | エチレン系ポリマーおよびそのプロセス |
| KR102067312B1 (ko) | 2012-11-20 | 2020-01-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 높은 용융 강도를 갖는 저밀도 에틸렌-기재 중합체 |
| EP2999742B1 (en) | 2013-05-22 | 2024-02-14 | Dow Global Technologies LLC | Compositions containing low density ethylene-based polymers with high melt strength and films formed from the same |
| US10011697B2 (en) | 2013-06-20 | 2018-07-03 | Saudi Basic Industries Corporation | Foamed film comprising polyethylene foam |
| EP3027682B1 (en) | 2013-07-31 | 2018-03-14 | Saudi Basic Industries Corporation | Foamed caps and closure seal comprising polyethylene foam |
| ES2667625T3 (es) | 2013-12-19 | 2018-05-11 | Borealis Ag | Recubrimiento de extrusión de polietileno de baja densidad y artículo sellado por calor fabricado a partir de éste |
| EP3626752B1 (en) | 2013-12-26 | 2021-04-21 | Dow Global Technologies LLC | Ethylene-based polymers formed using asymmetrical polyenes |
| JP6609254B2 (ja) * | 2013-12-26 | 2019-11-20 | ダウ グローバル テクノロジーズ エルエルシー | 非対称ポリエンを使用して、エチレン系ポリマーの調製のための反応器の安定性を改善する方法 |
| CN105829362B (zh) | 2013-12-26 | 2019-06-07 | 陶氏环球技术有限责任公司 | 使用不对称多烯形成基于乙烯的聚合物的方法 |
| EP3126412B1 (en) * | 2014-03-31 | 2018-09-12 | Saudi Basic Industries Corporation | Process for the preparation of an ethylene copolymer in a tubular reactor |
| WO2015166297A1 (en) | 2014-04-30 | 2015-11-05 | Exxonmobil Chemical Patents Inc. | Process for manufacturing ethylene polymers and copolymers |
| KR102359175B1 (ko) | 2014-06-27 | 2022-02-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 일산화탄소 및 레올로지 개질제로부터 유도된 단위를 포함하는 에틸렌계 폴리머 |
| US9856338B2 (en) * | 2014-06-27 | 2018-01-02 | Dow Global Technologies Llc | Processes to prepare ethylene-based polymers using a distribution of carbon monoxide |
| US10150826B2 (en) | 2014-07-24 | 2018-12-11 | Sabic Global Technologies B.V. | Method for preparing ethylene copolymer |
| US10273318B2 (en) | 2014-12-30 | 2019-04-30 | Dow Global Technologies Llc | Process to control output and quality of ethylene-based polymer formed by high pressure free radical polymerization |
| WO2016150657A1 (en) | 2015-03-24 | 2016-09-29 | Sabic Global Technologies B.V. | Packaging material comprising polyethylene foam |
| WO2016150726A1 (en) | 2015-03-26 | 2016-09-29 | Sabic Global Technologies B.V. | High-pressure polymerisation process for the preparation of polyethylene |
| EP3985060B8 (en) | 2015-06-17 | 2025-08-20 | Dow Global Technologies LLC | Process for making crosslinked cable insulation using high melt strength ethylene-based polymer made in a tubular reactor and optionally modified with a branching agent |
| WO2016209381A1 (en) | 2015-06-24 | 2016-12-29 | Dow Global Technologies Llc | Processes to prepare ethylene-based polymers with improved melt-strength |
| CN107750259B (zh) | 2015-06-25 | 2021-04-09 | 陶氏环球技术有限责任公司 | 具有低己烷可萃取率和低密度的乙烯基聚合物 |
| US10465024B2 (en) | 2015-06-25 | 2019-11-05 | Dow Global Technologies Llc | Process to make tubular ethylene based polymers with high melt strength |
| BR112017027866B1 (pt) | 2015-06-25 | 2022-05-24 | Dow Global Technologies Llc | Processo para produzir um homopolímero de etileno, formado de um radical livre |
| WO2016210160A1 (en) | 2015-06-25 | 2016-12-29 | Dow Global Technologies Llc | Improved process to make tubular ethylene based polymers with high g' and broad mwd |
| US10400046B2 (en) | 2015-06-25 | 2019-09-03 | Joseph J. Matsko | Portable powered paint system |
| EP3121199B1 (en) | 2015-07-23 | 2017-04-26 | Basell Polyolefine GmbH | High-pressure polymerization process of ethylenically unsaturated monomers in a tubular reactor |
| EP3341418B1 (en) * | 2015-08-26 | 2019-07-03 | SABIC Global Technologies B.V. | Process for the production of ethylene polymers |
| US10889042B2 (en) | 2015-09-07 | 2021-01-12 | Sabic Global Technologies B.V. | Process for the production of stretch film |
| EP3168238A1 (en) | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | Ethylene-based polymers formed by high pressure free radical polymerizations |
| EP3168237A1 (en) | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
| EP3168239A1 (en) | 2015-11-10 | 2017-05-17 | Dow Global Technologies LLC | High pressure free radical polymerizations |
| US10858462B2 (en) | 2015-12-17 | 2020-12-08 | Sabic Global Technologies B.V. | Ethylene copolymers and process for the production thereof |
| CN106928536A (zh) * | 2015-12-31 | 2017-07-07 | Sabic环球技术有限责任公司 | 适用于挤出涂覆的基于乙烯的聚合物组合物 |
| EP3400255B1 (en) | 2016-01-05 | 2022-04-20 | SABIC Global Technologies B.V. | Process for preparing graft copolymer comprising polyethylene |
| US10975186B2 (en) | 2016-01-05 | 2021-04-13 | Sabic Global Technologies B.V. | Process for preparing graft copolymer comprising polyethylene |
| CN105912272B (zh) | 2016-04-14 | 2019-03-01 | 华为技术有限公司 | 一种控制多个安全应用软件的运行的装置和方法 |
| JP6946331B2 (ja) | 2016-04-22 | 2021-10-06 | ダウ グローバル テクノロジーズ エルエルシー | 清浄な押出コーティング処理のための低揮発性管状低密度エチレン系ポリマーを製造する方法 |
| EP3260472A1 (en) | 2016-06-24 | 2017-12-27 | Dow Global Technologies LLC | Ethylene-based polymers formed by high pressure free radical polymerizations |
| EP3260473A1 (en) | 2016-06-24 | 2017-12-27 | Dow Global Technologies LLC | High pressure, free radical polymerizations to produce ethylene-based polymers |
| EP3630853B1 (en) | 2017-06-02 | 2021-03-17 | Dow Global Technologies LLC | Ethylene-based polymers and processes for the same |
| KR102695668B1 (ko) | 2017-10-31 | 2024-08-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/co 혼성중합체 및 이를 제조하는 방법 |
| EP3814389B1 (en) | 2018-06-28 | 2025-11-19 | Dow Global Technologies LLC | Ethylene-based polymers with improved melt strength and thermal stability |
| WO2020183248A1 (en) | 2019-03-14 | 2020-09-17 | Braskem S.A. | Extrusion coating resin from tubular reactor |
| WO2021021709A1 (en) | 2019-07-31 | 2021-02-04 | Dow Global Technologies Llc | Ethylene-based polymer composition with branching |
| AR119441A1 (es) | 2019-07-31 | 2021-12-15 | Dow Global Technologies Llc | Polietileno de baja densidad con resistencia de adhesión en caliente y adhesión al metal mejoradas mediante la adición de ionómeros |
| AR119432A1 (es) * | 2019-07-31 | 2021-12-15 | Dow Global Technologies Llc | Supresión de estrechamiento para polímeros tubulares a base de ldpe para recubrimiento por extrusión a velocidad de línea media y alta |
| AR119443A1 (es) | 2019-07-31 | 2021-12-15 | Dow Global Technologies Llc | Polietileno de baja densidad con papel adhesivo de aluminio mejorado mediante la mezcla de resinas de copolímero ácido |
| US11680117B2 (en) | 2020-04-16 | 2023-06-20 | Exxonmobil Chemical Patents Inc. | Polyethylenes and processes for producing polyethylenes |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2403516C2 (de) * | 1974-01-25 | 1983-02-17 | VEB Leuna-Werke "Walter Ulbricht", DDR 4220 Leuna | Verfahren zur Herstellung von Homo-, Co- und Terpolymerisaten sowie Polymerlegierungen des Äthylens |
| FR2583759B1 (fr) * | 1985-06-20 | 1988-01-15 | Atochem | Films de polyolefines photoreticulables et leur procede de fabrication |
| DE3615562A1 (de) * | 1986-05-09 | 1987-11-12 | Basf Ag | Verfahren zur herstellung von copolymerisaten des ethylens mit acrylsaeureestern in einem roehrenreaktor bei druecken oberhalb 500 bar |
| FR2621920B1 (fr) * | 1987-10-14 | 1990-01-26 | Charbonnages Ste Chimique | Polymeres fonctionnalises de l'ethylene applicables a l'enduction d'un metal et un procede pour leur preparation |
| US5191050A (en) * | 1987-10-14 | 1993-03-02 | Norsolor | Functionalized ethylene polymers useful for metal coating, and process for their preparation |
| FR2660660B1 (fr) * | 1990-04-09 | 1993-05-21 | Norsolor Sa | Perfectionnement au procede de fabrication de polymeres radicalaires de l'ethylene utilisables pour l'enduction d'un metal. |
| JPH0641238A (ja) * | 1992-07-21 | 1994-02-15 | Tosoh Corp | 押出コ−ティング用エチレン重合体の製造方法 |
| GB9216392D0 (en) | 1992-07-31 | 1992-09-16 | Univ Waterloo | Surface roughness characterization of extruded plastic products |
| DE69415317T2 (de) | 1993-05-13 | 1999-06-02 | Exxon Chemical Patents, Inc., Baytown, Tex. | Ethylen-copolymere mit enger zusammensetzungsverteilung, ihre herstellung und ihre verwendung |
-
2006
- 2006-02-27 CA CA2599636A patent/CA2599636C/en not_active Expired - Lifetime
- 2006-02-27 EP EP06707405.4A patent/EP1861434B1/en not_active Expired - Lifetime
- 2006-02-27 DK DK06707405.4T patent/DK1861434T3/da active
- 2006-02-27 PT PT67074054T patent/PT1861434E/pt unknown
- 2006-02-27 CN CN200680007374XA patent/CN101137681B/zh not_active Expired - Lifetime
- 2006-02-27 MX MX2007011007A patent/MX2007011007A/es active IP Right Grant
- 2006-02-27 BR BRPI0608302-1A patent/BRPI0608302B1/pt not_active IP Right Cessation
- 2006-02-27 KR KR1020137019806A patent/KR101391511B1/ko not_active Expired - Fee Related
- 2006-02-27 ES ES06707405T patent/ES2421584T3/es not_active Expired - Lifetime
- 2006-02-27 US US11/885,793 patent/US7820776B2/en not_active Expired - Lifetime
- 2006-02-27 KR KR1020077022791A patent/KR101321177B1/ko not_active Expired - Fee Related
- 2006-02-27 PL PL06707405T patent/PL1861434T3/pl unknown
- 2006-02-27 WO PCT/EP2006/001974 patent/WO2006094723A1/en not_active Ceased
- 2006-02-27 JP JP2008500099A patent/JP2008533223A/ja active Pending
- 2006-02-27 EA EA200701924A patent/EA015960B1/ru not_active IP Right Cessation
-
2007
- 2007-09-11 ZA ZA200707776A patent/ZA200707776B/xx unknown
- 2007-10-08 NO NO20075055A patent/NO20075055L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2599636A1 (en) | 2006-09-14 |
| US7820776B2 (en) | 2010-10-26 |
| CN101137681B (zh) | 2011-04-13 |
| ZA200707776B (en) | 2008-06-25 |
| KR20130090931A (ko) | 2013-08-14 |
| CN101137681A (zh) | 2008-03-05 |
| EA015960B1 (ru) | 2012-01-30 |
| EA200701924A1 (ru) | 2008-02-28 |
| KR20070117649A (ko) | 2007-12-12 |
| KR101321177B1 (ko) | 2013-10-22 |
| PT1861434E (pt) | 2013-07-09 |
| BRPI0608302B1 (pt) | 2017-07-18 |
| PL1861434T3 (pl) | 2013-09-30 |
| US20080242809A1 (en) | 2008-10-02 |
| NO20075055L (no) | 2007-12-03 |
| EP1861434A1 (en) | 2007-12-05 |
| DK1861434T3 (da) | 2013-07-08 |
| KR101391511B1 (ko) | 2014-05-07 |
| JP2008533223A (ja) | 2008-08-21 |
| EP1861434B1 (en) | 2013-04-24 |
| WO2006094723A1 (en) | 2006-09-14 |
| BRPI0608302A2 (pt) | 2009-12-08 |
| CA2599636C (en) | 2012-03-27 |
| MX2007011007A (es) | 2007-11-08 |
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