ES2485498T3 - Formulaciones de curado doble con unos componentes que contienen grupos uretdiona - Google Patents
Formulaciones de curado doble con unos componentes que contienen grupos uretdiona Download PDFInfo
- Publication number
- ES2485498T3 ES2485498T3 ES08862265.9T ES08862265T ES2485498T3 ES 2485498 T3 ES2485498 T3 ES 2485498T3 ES 08862265 T ES08862265 T ES 08862265T ES 2485498 T3 ES2485498 T3 ES 2485498T3
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- groups
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- radiation
- containing uretdione
- uretdione groups
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
- C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/798—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/243—Two or more independent types of crosslinking for one or more polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
- C09D167/07—Unsaturated polyesters having carbon-to-carbon unsaturation having terminal carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, e.g. by ultrasonic waves, corona discharge, irradiation, electric currents or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
- D06M10/10—Macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
- D06M15/51—Unsaturated polymerisable polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/568—Reaction products of isocyanates with polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/572—Reaction products of isocyanates with polyesters or polyesteramides
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Formulaciones endurecibles térmicamente y por radiaciones constituidas a base de A) por lo menos 5 % en peso de por lo menos un componente endurecible por radiaciones, pudiendo éste contener también grupos OH, B) de 10 a 90 % en peso de por lo menos un componente que contiene grupos uretdiona, conteniendo éste también grupos OH y/o unos grupos endurecibles por radiaciones, C) de 0,1 a 5 % en peso de por lo menos una sal de tetraalquil-amonio y/o una sal de fosfonio con halógenos, hidróxidos, alcoholatos o aniones de ácidos orgánicos o inorgánicos como ion de signo contrario, y de 0,1 a 5 % en peso de por lo menos un catalizador concomitante, escogido entre C1) por lo menos un epóxido y/o C2) por lo menos un acetilacetonato metálico.
Description
Claims (1)
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imagen1 imagen2 imagen3 imagen4
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007061012A DE102007061012A1 (de) | 2007-12-18 | 2007-12-18 | Dual Cure Formulierungen mit Uretdiongruppen haltigen Komponenten |
| DE102007061012 | 2007-12-18 | ||
| PCT/EP2008/063846 WO2009077222A1 (de) | 2007-12-18 | 2008-10-15 | Dual cure formulierungen mit uretdiongruppen haltigen komponenten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2485498T3 true ES2485498T3 (es) | 2014-08-13 |
Family
ID=40229759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES08862265.9T Active ES2485498T3 (es) | 2007-12-18 | 2008-10-15 | Formulaciones de curado doble con unos componentes que contienen grupos uretdiona |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20100227942A1 (es) |
| EP (1) | EP2188320B1 (es) |
| JP (1) | JP2011506714A (es) |
| CN (1) | CN101463221A (es) |
| DE (1) | DE102007061012A1 (es) |
| ES (1) | ES2485498T3 (es) |
| WO (1) | WO2009077222A1 (es) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007062316A1 (de) * | 2007-12-21 | 2009-06-25 | Evonik Degussa Gmbh | Reaktive Isocyanatzusammensetzungen |
| TWI357922B (en) | 2007-12-24 | 2012-02-11 | Eternal Chemical Co Ltd | Coating compositions and curing method thereof |
| DE102010034039A1 (de) | 2010-08-11 | 2012-02-16 | Bundesdruckerei Gmbh | Verfahren zur Herstellung einer Folie für ein Sicherheits- und/oder Wertdokument |
| DE102010041247A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Degussa Gmbh | Verfahren zur Herstellung von lagerstabilen Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung in Lösung |
| WO2012043333A1 (ja) * | 2010-09-29 | 2012-04-05 | Dic株式会社 | 活性エネルギー線硬化型樹脂組成物、偏光板用接着剤及び偏光板 |
| DE102011006163A1 (de) | 2011-03-25 | 2012-09-27 | Evonik Degussa Gmbh | Lagerstabile Polyurethan-Prepregs und daraus hergestellte Formkörper aus Polyurethanzusammensetzung mit flüssigen Harzkomponenten |
| DE102012205951B4 (de) | 2012-04-12 | 2016-09-01 | Chemetall Gmbh | Dichtmassen-System, ungehärtete Grundmasse und Mischung, Härter, Verfahren zum Beschichten eines Substrates und Verwendung eines Dichtmassen-Systems |
| CN102675590B (zh) * | 2012-05-25 | 2014-04-02 | 深圳职业技术学院 | 一种含脂环族环氧和双键的双重固化树脂的制备方法及应用 |
| KR101965988B1 (ko) * | 2012-06-18 | 2019-04-04 | 피피지 인더스트리즈 오하이오 인코포레이티드 | 금속 기재 코팅에 유용한 이중-경화 조성물 및 이 조성물을 사용하는 방법 |
| DE102012219324A1 (de) | 2012-10-23 | 2014-04-24 | Evonik Industries Ag | Zusammensetzungen umfassend alkoxysilanhaltige Isocyanateund saure Stabilisatoren |
| US9175117B2 (en) | 2013-03-15 | 2015-11-03 | Covestro Llc | Dual cure composite resins containing uretdione and unsaturated sites |
| CN105745511B (zh) * | 2013-11-18 | 2018-04-06 | 纳幕尔杜邦公司 | 复合材料和包含所述复合材料的防弹护甲制品 |
| EP3034569B1 (de) * | 2014-12-19 | 2016-11-30 | Evonik Degussa GmbH | Thermisch nachhärtende mit aktinischer Strahlung vernetzende Systeme |
| JP6529594B2 (ja) * | 2015-01-22 | 2019-06-12 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 低い酸価のポリオールを主体としたコーティング材料系 |
| CN106397740A (zh) * | 2015-07-30 | 2017-02-15 | 肯特催化材料股份有限公司 | 环氧树脂固化促进剂及其制备方法 |
| JP2017082076A (ja) * | 2015-10-27 | 2017-05-18 | 旭化成株式会社 | ポリイソシアネート組成物、塗料組成物及び塗装方法 |
| CN108698081A (zh) * | 2016-02-19 | 2018-10-23 | 巴斯夫涂料有限公司 | 制备多层涂层的方法 |
| EP3263616B8 (de) | 2016-06-27 | 2020-01-15 | Evonik Operations GmbH | Alkoxysilan-funktionalisierte allophanat-haltige beschichtungsmittel |
| EP3375827A1 (de) | 2017-03-17 | 2018-09-19 | TIGER Coatings GmbH & Co. KG | Laminat-tinte |
| EP3401344B1 (de) | 2017-05-09 | 2020-04-08 | Evonik Operations GmbH | Verfahren zur herstellung von trimeren und/oder oligomeren von diisocyanaten |
| CN109666127B (zh) * | 2018-12-05 | 2021-09-10 | 上海华峰新材料研发科技有限公司 | 合成革用自流平光固化聚氨酯树脂及其制备方法 |
| CN109868110A (zh) * | 2019-02-25 | 2019-06-11 | 江苏大学 | 一种薄木皮用涂覆型柔性胶水及其制备方法与实施工艺 |
| CN110655855B (zh) * | 2019-10-08 | 2021-08-24 | 中国石油天然气集团公司 | 一种工业重防腐长效耐候水性丙烯酸聚氨酯防腐蚀涂料及其制备方法 |
| CN110746572A (zh) * | 2019-10-15 | 2020-02-04 | 浙江禾欣科技有限公司 | 一种双重固化型汽车内饰革用无溶剂聚氨酯树脂及其制备方法 |
| CN110885663A (zh) * | 2019-11-26 | 2020-03-17 | 塔威新材料科技(上海)有限公司 | 一种uv湿气双重固化反应型聚氨酯热熔胶组合物 |
| CN112552862A (zh) * | 2020-11-19 | 2021-03-26 | 东莞市聚龙高科电子技术有限公司 | 双重固化胶水、智能终端壳体及制造方法 |
| CN112625590B (zh) * | 2020-12-23 | 2021-10-29 | 江南大学 | 一种uv固化的含羟基铵盐的氨基甲酸酯丙烯酸酯防雾涂层的制备方法 |
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| DE19961926A1 (de) | 1999-12-22 | 2001-07-05 | Basf Coatings Ag | Thermisch mit aktinischer Strahlung härtbare Stoffgemische und ihre Verwendung |
| DE10016194A1 (de) | 2000-03-31 | 2001-10-04 | Bayer Ag | Beschichtungssystem enthaltend UV-härtbare, Isocyanatgruppen aufweisende Urethan(meth)acrylate und Hydroxylgruppen aufweisende Urethan(meth)acrylate |
| US6458874B1 (en) | 2000-06-22 | 2002-10-01 | Basf Corporation | Coating compositions having improved direct to metal adhesion |
| DE10032136A1 (de) * | 2000-07-01 | 2002-01-17 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbares Mehrkomponentensystem, Verfahren zu seiner Herstellung und seine Verwendung |
| DE10140156A1 (de) | 2001-08-16 | 2003-03-20 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbare Beschichtungsstoffe und ihre Verwendung |
| DE10144531B4 (de) | 2001-09-11 | 2006-01-19 | Henkel Kgaa | UV-härtende anti-fingerprint Beschichtungen, Verfahren zum Beschichten und Verwendung eines lösmittelfreien Überzugsmittels |
| DE10347901A1 (de) * | 2003-10-15 | 2005-05-19 | Degussa Ag | Polyurethan-Pulverlackbeschichtungen, welche feste uretdiongruppenhaltige Polyadditionsverbindungen enthalten, und ein Verfahren zu ihrer Herstellung |
| DE102004011004A1 (de) * | 2004-03-06 | 2005-09-22 | Degussa Ag | Verfahren zur Herstellung fester, hochreaktiver Uretdiongruppen haltiger Polyurethanzusammensetzungen |
| US20090012202A1 (en) * | 2007-07-03 | 2009-01-08 | Henkel Corporation | Acrylated Urethanes, Processes for Making the Same and Curable Compositions Including the Same |
-
2007
- 2007-10-15 US US12/682,993 patent/US20100227942A1/en not_active Abandoned
- 2007-12-18 DE DE102007061012A patent/DE102007061012A1/de not_active Withdrawn
-
2008
- 2008-10-15 EP EP08862265.9A patent/EP2188320B1/de not_active Not-in-force
- 2008-10-15 ES ES08862265.9T patent/ES2485498T3/es active Active
- 2008-10-15 WO PCT/EP2008/063846 patent/WO2009077222A1/de not_active Ceased
- 2008-10-15 JP JP2010538507A patent/JP2011506714A/ja active Pending
- 2008-12-17 CN CNA200810185568XA patent/CN101463221A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP2188320A1 (de) | 2010-05-26 |
| US20100227942A1 (en) | 2010-09-09 |
| JP2011506714A (ja) | 2011-03-03 |
| DE102007061012A1 (de) | 2009-06-25 |
| EP2188320B1 (de) | 2014-05-14 |
| WO2009077222A1 (de) | 2009-06-25 |
| CN101463221A (zh) | 2009-06-24 |
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