ES2527626T3 - Componente de catalizador para la polimerización de olefinas y método de preparación del mismo - Google Patents

Componente de catalizador para la polimerización de olefinas y método de preparación del mismo Download PDF

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Publication number
ES2527626T3
ES2527626T3 ES10824363.5T ES10824363T ES2527626T3 ES 2527626 T3 ES2527626 T3 ES 2527626T3 ES 10824363 T ES10824363 T ES 10824363T ES 2527626 T3 ES2527626 T3 ES 2527626T3
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Prior art keywords
general formula
alkyl
aryl
represented
halogen
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ES10824363.5T
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Inventor
Xianzhi Xia
Jin Zhao
Yuexiang Liu
Jigui Zhang
Weili Li
Yang Tan
Suzhen Qiao
Renqi Peng
Ping Gao
Maoping Yin
Tianyi Zhang
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Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
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Sinopec Beijing Research Institute of Chemical Industry
China Petroleum and Chemical Corp
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Componente de catalizador para la polimerización de olefinas, que comprende un producto de reacción de: (1) un aducto representado por la fórmula general (I): MgX2·m(R'OH)·nE·qH2O; (2) al menos un compuesto de titanio representado por la fórmula general (II): Ti(OR)4-kXk; y (3) al menos un compuesto a donador de electrones y al menos un compuesto b donador de electrones; en el que, en la fórmula general (I), **Fórmula** X es Cl o Br; R' es un alquilo C1-C4; E es al menos un o-alcoxibenzoato representado por la fórmula general (III): en la que R1 y R2 se eligen independientemente de alquilo C1-C12 lineal o ramificado, cicloalquilo C3-C10, cicloalquilalquilo C4-C10, arilo C6-C10, alcarilo C7-C10 y aralquilo C7-C10; m oscila entre 1,0 y 5,0; n oscila entre 0 y 0,5; y q oscila entre 0 y 0,8; en la fórmula general (II), **Fórmula** R es un alquilo C1-C20, X es un halógeno y k es 0, 1, 2, 3 ó 4; el al menos un compuesto a donador de electrones se elige de ésteres de diol representados por la fórmula general (IV): en la que R1 y R2 se eligen independientemente de alquilo C1-C10 lineal o ramificado, cicloalquilo C3-C20, cicloalquilalquilo C4-C20, arilo C6-C20 y aralquilo C7-C20, cuyo anillo de arilo o anillo de cicloalquilo está opcionalmente sustituido adicionalmente por un sustituyente elegido de halógeno, alquilo C1-C6 y alcoxilo C1-C6; R3-R6 y R1-R2n se eligen independientemente de hidrógeno, halógeno, alquilo C1-C20 sustituido o no sustituido, lineal o ramificado, cicloalquilo C3-C20, cicloalquilalquilo C4-C20, arilo C6-C20, alcarilo C7-C20, aralquilo C7-C20, alquenilo C2-C10, arilo C10-C20 condensado y grupo éster, cada uno de R3-R6 y R1-R2n comprende opcionalmente uno o más heteroátomos como sustitución de un átomo de carbono o un átomo de hidrógeno o ambos, eligiéndose dicho heteroátomo de N, O, S, Si, P y halógeno, y uno o más de R3-R6 y R1-R2n se unen opcionalmente para formar un anillo; y n es un número entero que oscila entre 0 y 10; el al menos un compuesto b donador de electrones se elige de compuestos de diéter representados por la fórmula general (V): **Fórmula**
ES10824363.5T 2009-10-20 2010-04-19 Componente de catalizador para la polimerización de olefinas y método de preparación del mismo Active ES2527626T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN200910236103 2009-10-20
CN2009102361037A CN102040690A (zh) 2009-10-20 2009-10-20 一种低灰分聚丙烯的制备方法
PCT/CN2010/000534 WO2011047522A1 (zh) 2009-10-20 2010-04-19 用于烯烃聚合的催化剂组分及其制备方法

Publications (1)

Publication Number Publication Date
ES2527626T3 true ES2527626T3 (es) 2015-01-27

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ES10824363.5T Active ES2527626T3 (es) 2009-10-20 2010-04-19 Componente de catalizador para la polimerización de olefinas y método de preparación del mismo

Country Status (12)

Country Link
US (1) US9353197B2 (es)
EP (1) EP2492290B1 (es)
JP (1) JP5603946B2 (es)
KR (1) KR101419757B1 (es)
CN (2) CN102040690A (es)
BR (1) BR112012009247B1 (es)
ES (1) ES2527626T3 (es)
IN (1) IN2012DN03425A (es)
MY (1) MY163365A (es)
PT (1) PT2492290E (es)
SA (1) SA110310320B1 (es)
WO (1) WO2011047522A1 (es)

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US9499569B2 (en) * 2009-07-15 2016-11-22 China Petroleum & Chemical Corporation Spherical magnesium halide adduct, a catalyst component and a catalyst for olefin polymerization prepared therefrom
CN102796213B (zh) * 2011-05-27 2014-05-28 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分和催化剂体系及其应用和烯烃聚合方法
CN102796211B (zh) * 2011-05-27 2014-03-12 中国石油化工股份有限公司 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂以及烯烃聚合方法
US9481741B2 (en) * 2012-11-26 2016-11-01 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof
US9522968B2 (en) 2012-11-26 2016-12-20 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof
CN104981487B (zh) * 2013-01-31 2017-03-08 沙特基础工业公司 用于烯烃聚合的催化剂组合物
CN104250317B (zh) * 2013-06-28 2016-12-28 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂
CN104250319B (zh) * 2013-06-28 2017-02-15 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂体系
CN104250320B (zh) * 2013-06-28 2016-12-28 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂体系
CN104250883B (zh) * 2013-06-28 2017-03-29 中国石油化工股份有限公司 一种聚丙烯无纺布及其制备方法
CN104558298B (zh) * 2013-10-17 2018-04-10 中国石油化工股份有限公司 一种电工膜用聚丙烯树脂及其制备方法
CN104558297A (zh) * 2013-10-17 2015-04-29 中国石油化工股份有限公司 一种双向拉伸薄膜用聚丙烯树脂及其制备方法
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CN105440181B (zh) * 2014-08-15 2017-12-19 中国石油化工股份有限公司 一种丙烯聚合物及其制备方法
CN105566524B (zh) * 2014-10-10 2018-01-23 中国石油化工股份有限公司 一种用于乙烯聚合反应的催化剂组分及其催化剂
CN105566522B (zh) * 2014-10-10 2018-01-23 中国石油化工股份有限公司 用于乙烯聚合反应的催化剂组分及其催化剂
CN107522803A (zh) * 2016-06-20 2017-12-29 中国石油化工股份有限公司 球形载体和烯烃聚合催化剂及其制备方法和应用以及烯烃聚合的方法
WO2018067367A1 (en) * 2016-10-06 2018-04-12 W.R. Grace & Co.-Conn. Procatalyst composition made with a combination of internal electron donors
CN109096425A (zh) * 2017-06-21 2018-12-28 中国石油化工股份有限公司 一种用于烯烃聚合的催化剂和烯烃聚合方法
CN109694429B (zh) * 2017-10-20 2022-01-04 中国石油化工股份有限公司 一种聚丙烯及其制备方法和应用
CN109694420B (zh) * 2017-10-24 2021-08-03 中国石油化工股份有限公司 用于烯烃聚合的催化剂体系和预聚合催化剂以及烯烃聚合方法
MY207750A (en) * 2018-05-21 2025-03-17 China Petroleum & Chem Corp Catalyst component for olefin polymerization, preparation method thereof, and catalyst including same
JP7479361B2 (ja) * 2018-10-19 2024-05-08 中国石油化工股▲ふん▼有限公司 オレフィン重合用触媒成分、触媒及びその応用
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US9499569B2 (en) * 2009-07-15 2016-11-22 China Petroleum & Chemical Corporation Spherical magnesium halide adduct, a catalyst component and a catalyst for olefin polymerization prepared therefrom

Also Published As

Publication number Publication date
JP5603946B2 (ja) 2014-10-08
MY163365A (en) 2017-09-15
KR101419757B1 (ko) 2014-07-17
EP2492290B1 (en) 2014-10-15
US20120226004A1 (en) 2012-09-06
EP2492290A1 (en) 2012-08-29
JP2013508477A (ja) 2013-03-07
EP2492290A4 (en) 2013-10-16
SA110310320B1 (ar) 2014-01-26
PT2492290E (pt) 2014-11-20
BR112012009247A2 (pt) 2020-08-25
CN102574939B (zh) 2017-07-14
CN102040690A (zh) 2011-05-04
WO2011047522A1 (zh) 2011-04-28
BR112012009247B1 (pt) 2021-11-09
KR20120086715A (ko) 2012-08-03
IN2012DN03425A (es) 2015-10-23
CN102574939A (zh) 2012-07-11
US9353197B2 (en) 2016-05-31

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