ES2530861T3 - Polímeros basados en etileno y procedimientos para los mismos - Google Patents

Polímeros basados en etileno y procedimientos para los mismos Download PDF

Info

Publication number
ES2530861T3
ES2530861T3 ES11770304T ES11770304T ES2530861T3 ES 2530861 T3 ES2530861 T3 ES 2530861T3 ES 11770304 T ES11770304 T ES 11770304T ES 11770304 T ES11770304 T ES 11770304T ES 2530861 T3 ES2530861 T3 ES 2530861T3
Authority
ES
Spain
Prior art keywords
formula
ch2ch3
ethylene
chain transfer
coch3
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES11770304T
Other languages
English (en)
Inventor
John O Osby
Mehmet Demirors
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Application granted granted Critical
Publication of ES2530861T3 publication Critical patent/ES2530861T3/es
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/50—Nitriles containing four or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F26/08—N-Vinyl-pyrrolidine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C08F28/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur
    • C08F28/04—Thioethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/11—Melt tension or melt strength
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C08F28/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur by a bond to sulfur

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Un polímero basado en etileno, que comprende una cantidad mayoritaria de etileno polimerizado, basada en el peso del polímero, formado de por lo menos los siguientes: etileno y un "agente de transferencia de cadena monomérico (CTA monomérico)", que comprende un "extremo de copolimerización" y un "extremo de transferencia de cadena"; en el que el "extremo de copolimerización" del agente de transferencia de cadena se selecciona del grupo que consiste en los siguientes:**Fórmula** en la que R1 se selecciona de H, CH3, CH2CH3, CN, o COCH3;**Fórmula** en la que R2 se selecciona de H, CH3, CH2CH3, CN, o COCH3;**Fórmula** en la que R3 se selecciona de H, alquilo de C1-C22, cicloalquilo de c3-C8, o fenilo;**Fórmula** en la que R4 se selecciona de H, CH3, CH2CH3, CN, O COCH3, y R5 se selecciona de H, alquilo de C1-C22, cicloalquilo de C3-C8, fenilo, o COCH3;**Fórmula** en la que R9, R10, R11 se seleccionan independientemente cada uno de H, CH3, o CH2CH3;**Fórmula** en la que R12, R13 se seleccionan independientemente cada uno de H, CH3, CH2CH3 o fenilo;**Fórmula** en la que R14 se selecciona de H, CH3, CH2CH3, o CN; y**Fórmula** en la que R15 se selecciona de H, alquilo de C1-C22, cicloalquilo de C3-C8, o fenilo; y el extremo de transferencia de cadena" del agente de transferencia de cadena se selecciona del grupo que consiste en los siguientes:**Fórmula**
ES11770304T 2010-10-29 2011-10-05 Polímeros basados en etileno y procedimientos para los mismos Active ES2530861T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US40812410P 2010-10-29 2010-10-29
PCT/US2011/054843 WO2012057975A1 (en) 2010-10-29 2011-10-05 Ethylene-based polymers and processes for the same

Publications (1)

Publication Number Publication Date
ES2530861T3 true ES2530861T3 (es) 2015-03-06

Family

ID=44801222

Family Applications (1)

Application Number Title Priority Date Filing Date
ES11770304T Active ES2530861T3 (es) 2010-10-29 2011-10-05 Polímeros basados en etileno y procedimientos para los mismos

Country Status (11)

Country Link
US (1) US9150681B2 (es)
EP (1) EP2632961B1 (es)
JP (1) JP5980219B2 (es)
KR (1) KR101844104B1 (es)
CN (1) CN103282391B (es)
AR (1) AR083592A1 (es)
BR (1) BR112013010462B1 (es)
CA (1) CA2816287C (es)
ES (1) ES2530861T3 (es)
SG (1) SG190030A1 (es)
WO (1) WO2012057975A1 (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG190030A1 (en) 2010-10-29 2013-06-28 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
BR112013016031B1 (pt) * 2010-12-22 2020-04-07 Basell Polyolefine Gmbh processo para preparar copolímero de etileno na presença de iniciador da polimerização por radicais livres por copolimerização de etileno, copolímero de etileno obtido por tal processo e seu uso, bem como processo para revestimento por extrusão de um substrato
WO2013095969A1 (en) 2011-12-22 2013-06-27 Dow Global Technologies Llc Ethylene-based polymers with improved melt strength and processes for the same
JP6339565B2 (ja) * 2012-06-27 2018-06-06 ダウ グローバル テクノロジーズ エルエルシー エチレン系ポリマーおよびそのプロセス
KR102067312B1 (ko) 2012-11-20 2020-01-16 다우 글로벌 테크놀로지스 엘엘씨 높은 용융 강도를 갖는 저밀도 에틸렌-기재 중합체
WO2014105110A2 (en) 2012-12-28 2014-07-03 Dow Global Technologies Llc Method to reduce the crystallization temperature of carboxylic acid comonomer at elevated pressures, and to improve the copolymerization of the same
EP2999742B1 (en) * 2013-05-22 2024-02-14 Dow Global Technologies LLC Compositions containing low density ethylene-based polymers with high melt strength and films formed from the same
KR102208726B1 (ko) 2013-05-22 2021-01-29 다우 글로벌 테크놀로지스 엘엘씨 고용융 강도 및 중간-고밀도 조절을 갖는 저밀도 에틸렌-기반 폴리머 조성물
KR20160107181A (ko) 2013-12-26 2016-09-13 다우 글로벌 테크놀로지스 엘엘씨 리튬 염-촉매된 트랜스에스테르화 공정용 억제제 배합물 및 리튬 염의 제거방법
CN105829362B (zh) * 2013-12-26 2019-06-07 陶氏环球技术有限责任公司 使用不对称多烯形成基于乙烯的聚合物的方法
EP3626752B1 (en) * 2013-12-26 2021-04-21 Dow Global Technologies LLC Ethylene-based polymers formed using asymmetrical polyenes
JP6609254B2 (ja) * 2013-12-26 2019-11-20 ダウ グローバル テクノロジーズ エルエルシー 非対称ポリエンを使用して、エチレン系ポリマーの調製のための反応器の安定性を改善する方法
KR102359175B1 (ko) 2014-06-27 2022-02-08 다우 글로벌 테크놀로지스 엘엘씨 일산화탄소 및 레올로지 개질제로부터 유도된 단위를 포함하는 에틸렌계 폴리머
US9856338B2 (en) 2014-06-27 2018-01-02 Dow Global Technologies Llc Processes to prepare ethylene-based polymers using a distribution of carbon monoxide
US10144898B2 (en) 2014-11-13 2018-12-04 Dow Global Technologies Llc Lubricant compositions for improved high pressure free-radical polymerizations
EP3985060B8 (en) 2015-06-17 2025-08-20 Dow Global Technologies LLC Process for making crosslinked cable insulation using high melt strength ethylene-based polymer made in a tubular reactor and optionally modified with a branching agent
WO2016209381A1 (en) 2015-06-24 2016-12-29 Dow Global Technologies Llc Processes to prepare ethylene-based polymers with improved melt-strength
BR112017027866B1 (pt) 2015-06-25 2022-05-24 Dow Global Technologies Llc Processo para produzir um homopolímero de etileno, formado de um radical livre
US10400046B2 (en) 2015-06-25 2019-09-03 Joseph J. Matsko Portable powered paint system
WO2016210160A1 (en) * 2015-06-25 2016-12-29 Dow Global Technologies Llc Improved process to make tubular ethylene based polymers with high g' and broad mwd
US10465024B2 (en) 2015-06-25 2019-11-05 Dow Global Technologies Llc Process to make tubular ethylene based polymers with high melt strength
CN107750259B (zh) 2015-06-25 2021-04-09 陶氏环球技术有限责任公司 具有低己烷可萃取率和低密度的乙烯基聚合物
KR102397059B1 (ko) 2015-06-30 2022-05-12 다우 글로벌 테크놀로지스 엘엘씨 개선된 압출 코팅을 위한 에틸렌계 폴리머 조성물
EP3238938A1 (en) 2016-04-29 2017-11-01 Borealis AG Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers
US11078441B2 (en) 2016-09-28 2021-08-03 Dow Global Technologies Llc Lubricant treatments for free-radical polymerizations
BR112019010616B1 (pt) 2016-12-22 2022-11-29 Dow Global Technologies Llc Processo para produzir uma composição, configuração de polimerização, composição e artigo
EP3630853B1 (en) 2017-06-02 2021-03-17 Dow Global Technologies LLC Ethylene-based polymers and processes for the same
KR102695668B1 (ko) 2017-10-31 2024-08-19 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/co 혼성중합체 및 이를 제조하는 방법
US20210395410A1 (en) * 2018-12-04 2021-12-23 Sabic Global Technologies B.V. Polyolefin terpolymers, vitrimers made therefrom, and method of making the polyolefin terpolymers and vitrimers
WO2020202071A1 (en) * 2019-04-05 2020-10-08 Sabic Global Technologies B.V. Semi-crystalline silyl ether based vitrimers, methods of making and uses thereof
KR20220164756A (ko) * 2020-04-06 2022-12-13 다우 글로벌 테크놀로지스 엘엘씨 필름 또는 블렌드에서 사용하기 위한 향상된 용융 강도 저밀도 폴리에틸렌
JP7514133B2 (ja) * 2020-07-27 2024-07-10 旭化成株式会社 高圧法低密度ポリエチレン樹脂

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3658878A (en) 1965-12-20 1972-04-25 Eastman Kodak Co Ethylenically unsaturated cyano group containing compounds
US3554987A (en) 1965-12-20 1971-01-12 Eastman Kodak Co Novel compounds and photographic materials containing said compounds
DE2722097C3 (de) 1977-05-16 1981-09-17 Basf Ag, 6700 Ludwigshafen (Meth)acryloxy-alkylpropanale, Verfahren zu dessen Herstellung und Verwendung derselben
US4250070A (en) * 1978-01-26 1981-02-10 Basf Aktiengesellschaft Aqueous dispersions, containing hydrazine derivatives, of carbonyl-containing copolymers
US5021511A (en) 1988-12-27 1991-06-04 Rohm And Haas Company Polymer compositions derived from acryloxyalkylcyanoacetamides
SE9103077D0 (sv) 1991-10-22 1991-10-22 Neste Oy Omaettad etensampolymer och saett foer framstaellning daerav
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
JP3157163B2 (ja) 1991-12-30 2001-04-16 ザ・ダウ・ケミカル・カンパニー エチレンインターポリマーの重合
JP3550159B2 (ja) * 1992-04-10 2004-08-04 住友化学工業株式会社 接着剤
RU2113443C1 (ru) 1993-01-29 1998-06-20 Дзе Дау Кемикал Компани Способ получения композиции сополимеров этилена и альфа-олефинов, композиция сополимеров этилена и альфа-олефинов
US6448341B1 (en) 1993-01-29 2002-09-10 The Dow Chemical Company Ethylene interpolymer blend compositions
ATE152138T1 (de) * 1993-10-02 1997-05-15 Basf Ag Copolymerisate auf ethylenbasis und ihre verwendung als fliessverbesserer in erdölmitteldestillaten
US5869575A (en) 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
SE507045C2 (sv) 1996-05-31 1998-03-23 Borealis As Etensampolymer med förhöjd omättnadsgrad och sätt för framställning därav
DE19733104A1 (de) * 1997-07-31 1999-02-04 Wacker Chemie Gmbh Vernetzbare, in Wasser redispergierbare Pulverzusammensetzung
US6117492A (en) * 1999-03-30 2000-09-12 Air Products And Chemicals, Inc. Polymers having dual crosslinkable functionality and process for forming high performance nonwoven webs
US6506696B2 (en) * 2001-03-26 2003-01-14 Air Products Polymers, L.P. High performance synthetic nonwovens using polymers having dual crosslinkable functionality
US7064091B2 (en) * 2003-01-29 2006-06-20 Air Products Polymers, L.P. Incorporation of a self-crosslinking polymer into a nonwoven binder for use in improving the wet strength of pre-moistened wipes
EP1650232A1 (en) 2004-10-25 2006-04-26 Total Petrochemicals Research Feluy LDPE-Like polymers with bisindenyl-based ligands having different rings
CA2599636C (en) 2005-03-09 2012-03-27 Saudi Basic Industries Corporation A process for the preparation of an ethylene copolymer in a tubular reactor
CN101432322B (zh) 2006-03-24 2011-01-26 沙特基础工业公司 挤出涂布组合物
DE102009026819A1 (de) 2008-09-08 2010-03-11 Evonik Röhm Gmbh Monomermischung, Polymer, Beschichtungsmittel und Verfahren zur Herstellung einer Beschichtung
MX2011003550A (es) * 2008-10-07 2011-08-17 Dow Global Technologies Llc Resinas de polietileno de baja densidad, alta presion con propiedades opticas mejoradas producidas a traves del uso de agentes de transferencia de cadena altamente activos.
CN102762609A (zh) 2009-12-18 2012-10-31 陶氏环球技术有限责任公司 生产低密度聚乙烯的聚合方法
JP5216028B2 (ja) 2010-01-18 2013-06-19 住友ゴム工業株式会社 インナーライナー用ゴム組成物及び空気入りタイヤ
WO2012044504A1 (en) 2010-09-30 2012-04-05 Dow Global Technologies Llc Polymerization process to make low density polyethylene
BR112013007508A2 (pt) 2010-09-30 2019-09-24 Dow Global Technologies Llc processo de polimerização em alta pressãp para formar um interpolímero a base de etileno, interpolímero a base de etileno e artigo
SG190030A1 (en) 2010-10-29 2013-06-28 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
CN102002815B (zh) 2010-11-03 2016-01-20 宁波泰力斯高分子科技有限公司 具有双向可伸缩的直立结构纤维棉及生产装置和方法
BR112013016031B1 (pt) 2010-12-22 2020-04-07 Basell Polyolefine Gmbh processo para preparar copolímero de etileno na presença de iniciador da polimerização por radicais livres por copolimerização de etileno, copolímero de etileno obtido por tal processo e seu uso, bem como processo para revestimento por extrusão de um substrato

Also Published As

Publication number Publication date
US20130237678A1 (en) 2013-09-12
WO2012057975A1 (en) 2012-05-03
KR20140000254A (ko) 2014-01-02
BR112013010462A2 (pt) 2016-08-02
EP2632961B1 (en) 2014-12-24
JP2013540877A (ja) 2013-11-07
BR112013010462B1 (pt) 2020-10-27
CN103282391A (zh) 2013-09-04
AR083592A1 (es) 2013-03-06
KR101844104B1 (ko) 2018-03-30
CA2816287C (en) 2019-06-18
SG190030A1 (en) 2013-06-28
EP2632961A1 (en) 2013-09-04
CA2816287A1 (en) 2012-05-03
JP5980219B2 (ja) 2016-08-31
US9150681B2 (en) 2015-10-06
CN103282391B (zh) 2016-12-07

Similar Documents

Publication Publication Date Title
AR089419A1 (es) Polimeros a base de etilo con resistencia a la fusion mejorada y procesos para los mismos
MX377120B (es) Composicion curable fotocromatica, producto curado de la misma y laminado que incluye el producto curado.
AR079232A1 (es) Polimeros multiproposito estables hidroliticamente
ES2524692T3 (es) Polimerización por radicales de etileno cebada por peróxidos orgánicos con alta productividad
MX2008008850A (es) Composiciones para el cuidado personal que contienen copolimeros cationicos sinteticos y un surfactante detergente.
CO6400218A2 (es) Compuestos heterocíclicos antivirales
GT200800095A (es) Nucleosidos antivirales
JP2010506038A5 (es)
CO6561783A2 (es) Inhibidores del virus flaviviridae
AR095078A1 (es) Método para potenciar propiedades de formación de espuma en composiciones de limpieza a través del uso de polímeros anfifílicos, no iónicos y dichas composiciones
CO7240428A2 (es) Derivados de éster del ácido 2-aminonicotínico y bactericida que contiene el mismo como ingrediente activo
AR078163A1 (es) Utilizacion de aminodihidrotiazinas para el tratamiento o prevencion de la diabetes
WO2013076315A3 (en) Substituted n-(tetrazol-5-yl)- and n-(triazol-5-yl)arylcarboxamide compounds and their use as herbicides
JP2012041559A5 (es)
CL2012002808A1 (es) Composición que comprende un polímero derivado de al menos dos monómeros: acrilico-x y una alquilamina, en donde el peso molecular del polimero es de entre 500 a 200.000 y, ademas, el polimero es modificado para contener un grupo funcional capaz de depurar una o mas composiciones que contienen uno o mas metales.
CO6351793A2 (es) \"derivados de indol macrociclicos utiles como inhibidores del virus de la hepatitis
MX336902B (es) Espesador que contiene un polimero cationico y composicion que contiene ese espesador, en particular para textiles.
JP2013540864A5 (es)
SG168462A1 (en) Novel copolymer and photoresist composition comprising the same
BRPI0810766A2 (pt) Polímero de silicone enxertado e produtos feitos com mesmo
IN2014DN09099A (es)
AR083592A1 (es) Polimeros a base de etileno y procesos para dichos polimeros
MX2015008705A (es) Polimeros de estructura de peine novedosos que puedan utilizar en cosmeticos y detergentes.
JP2016536436A5 (es)
BR112013012695A2 (pt) "copolímero, uso de um copolímero, e, formulação detergente para a lavagem de pratos em máquina."