ES2531163T3 - Procedimiento y electrolito para la deposición galvánica de bronces - Google Patents
Procedimiento y electrolito para la deposición galvánica de bronces Download PDFInfo
- Publication number
- ES2531163T3 ES2531163T3 ES02022718T ES02022718T ES2531163T3 ES 2531163 T3 ES2531163 T3 ES 2531163T3 ES 02022718 T ES02022718 T ES 02022718T ES 02022718 T ES02022718 T ES 02022718T ES 2531163 T3 ES2531163 T3 ES 2531163T3
- Authority
- ES
- Spain
- Prior art keywords
- electrolyte
- bronzes
- procedure
- galvanic deposition
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003792 electrolyte Substances 0.000 title abstract 5
- 230000008021 deposition Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 abstract 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract 2
- 229910001431 copper ion Inorganic materials 0.000 abstract 2
- 229940098779 methanesulfonic acid Drugs 0.000 abstract 2
- 229910001432 tin ion Inorganic materials 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/58—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/60—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of tin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
- Chemically Coating (AREA)
Abstract
Procedimiento para la deposición galvánica de bronces con una proporción de cobre de > 10 % en peso, donde un sustrato a recubrir se metaliza en un electrolito ácido con una densidad de corriente ajustada a entre 0,1 y 120 A/dm2, donde el electrolito presenta al menos iones de estaño y de cobre, un medio humectante aromático no iónico, así como ácido metanosulfónico, caracterizado por que en el electrolito se ajusta una concentración de iones de estaño de 2 a 75 g/l, una concentración de iones de cobre de 2 a 70 g/l y una concentración de ácido metanosulfónico de al menos 238 g/l y se añaden al electrolito bismuto y/o cinc.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02022718.7A EP1408141B1 (de) | 2002-10-11 | 2002-10-11 | Verfahren und Elektrolyt zur galvanischen Abscheidung von Bronzen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2531163T3 true ES2531163T3 (es) | 2015-03-11 |
Family
ID=32010957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02022718T Expired - Lifetime ES2531163T3 (es) | 2002-10-11 | 2002-10-11 | Procedimiento y electrolito para la deposición galvánica de bronces |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20060137991A1 (es) |
| EP (1) | EP1408141B1 (es) |
| JP (1) | JP4675626B2 (es) |
| KR (1) | KR100684818B1 (es) |
| CN (1) | CN1703540B (es) |
| ES (1) | ES2531163T3 (es) |
| WO (1) | WO2004035875A2 (es) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004041701A1 (de) * | 2004-08-28 | 2006-03-02 | Enthone Inc., West Haven | Verfahren zur elektrolytischen Abscheidung von Metallen |
| EP1791693B1 (en) * | 2004-09-24 | 2012-06-27 | Jarden Zinc Products, LLC | Electroplated metals with silvery-white appearance and method of making |
| US7296370B2 (en) * | 2004-09-24 | 2007-11-20 | Jarden Zinc Products, Inc. | Electroplated metals with silvery-white appearance and method of making |
| US20060260948A2 (en) * | 2005-04-14 | 2006-11-23 | Enthone Inc. | Method for electrodeposition of bronzes |
| CN100368924C (zh) * | 2005-05-31 | 2008-02-13 | 西北工业大学 | 一种非周期性红外波段负磁导率材料 |
| ES2698205T5 (en) | 2005-11-25 | 2025-02-27 | Macdermid Enthone Inc | Process for cleaning of processing solutions |
| CN101522954B (zh) * | 2006-05-24 | 2011-11-16 | 埃托特克德国有限公司 | 金属电镀组合物和用于沉积适合于生产薄膜太阳能电池的铜-锌-锡的方法 |
| DE502007002479D1 (de) | 2007-02-14 | 2010-02-11 | Umicore Galvanotechnik Gmbh | Kupfer-Zinn-Elektrolyt und Verfahren zur Abscheidung von Bronzeschichten |
| JP5642928B2 (ja) | 2007-12-12 | 2014-12-17 | ローム・アンド・ハース・エレクトロニック・マテリアルズ,エル.エル.シー. | 青銅の電気めっき |
| PL2116634T3 (pl) | 2008-05-08 | 2011-04-29 | Umicore Galvanotechnik Gmbh | Zmodyfikowany elektrolit miedziowo-cynowy i sposób osadzania warstw brązu |
| DE102008032398A1 (de) * | 2008-07-10 | 2010-01-14 | Umicore Galvanotechnik Gmbh | Verbesserter Kupfer-Zinn-Elektrolyt und Verfahren zur Abscheidung von Bronzeschichten |
| DE102011008836B4 (de) | 2010-08-17 | 2013-01-10 | Umicore Galvanotechnik Gmbh | Elektrolyt und Verfahren zur Abscheidung von Kupfer-Zinn-Legierungsschichten |
| US8426241B2 (en) | 2010-09-09 | 2013-04-23 | International Business Machines Corporation | Structure and method of fabricating a CZTS photovoltaic device by electrodeposition |
| EP2565297A3 (en) | 2011-08-30 | 2013-04-24 | Rohm and Haas Electronic Materials LLC | Adhesion promotion of cyanide-free white bronze |
| CN102605394B (zh) * | 2012-03-07 | 2015-02-18 | 深圳市华傲创表面技术有限公司 | 一种无氰酸性白铜锡电镀液 |
| JP6101510B2 (ja) * | 2013-02-18 | 2017-03-22 | 株式会社シミズ | 非シアン銅−錫合金めっき浴 |
| US20170204528A1 (en) * | 2014-08-08 | 2017-07-20 | Okuno Chemical Industries Co., Ltd. | Copper-tin alloy plating bath |
| US11597637B2 (en) | 2018-02-22 | 2023-03-07 | Vis, Llc | Under hoist support stand |
| EP3540097A1 (en) | 2018-03-13 | 2019-09-18 | COVENTYA S.p.A. | Electroplated products and electroplating bath for providing such products |
| US10906789B2 (en) * | 2018-09-05 | 2021-02-02 | Vis, Llc | Power unit for a floor jack |
| CN117845047A (zh) * | 2022-09-30 | 2024-04-09 | 苏州宇邦新型材料股份有限公司 | 一种锡渣的回收方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2854388A (en) * | 1955-03-14 | 1958-09-30 | City Auto Stamping Co | Electrodeposition of copper-tin alloys |
| JPS5672196A (en) * | 1979-11-19 | 1981-06-16 | Shimizu Shoji Kk | Bright plating bath for copper-tin alloy |
| DE3339541C2 (de) * | 1983-11-02 | 1986-08-07 | Degussa Ag, 6000 Frankfurt | Alkalisch-cyanidisches Bad zur galvanischen Abscheidung von Kupfer-Zinn-Legierungsüberzügen |
| JPS63206494A (ja) * | 1987-02-20 | 1988-08-25 | Yutaka Fujiwara | シアン化合物を含まない光沢銅−亜鉛−錫合金電気めつき浴 |
| JPH02107795A (ja) * | 1988-10-14 | 1990-04-19 | Tohoku Ricoh Co Ltd | 銅一スズ合金メツキ浴 |
| DE3934866A1 (de) * | 1989-10-19 | 1991-04-25 | Blasberg Oberflaechentech | Verfahren zur abscheidung von blei- und bleihaltigen schichten, elektrolyte zur durchfuehrung des verfahrens sowie verwendung von tensiden in sauren blei-elektrolyten |
| JP2901292B2 (ja) * | 1989-12-05 | 1999-06-07 | 住友ゴム工業 株式会社 | ゴムコーティングタイヤ用ビードワイヤおよびそれを用いたタイヤ |
| DE4336664A1 (de) * | 1993-10-27 | 1995-05-04 | Demetron Gmbh | Werkstücke aus nichtkorrosionsbeständigen Metallen mit nach dem PVD-Verfahren aufgebrachten Überzügen |
| JPH0711477A (ja) * | 1993-06-28 | 1995-01-13 | Electroplating Eng Of Japan Co | 貴金属めっき品 |
| US5385661A (en) * | 1993-09-17 | 1995-01-31 | International Business Machines Corporation | Acid electrolyte solution and process for the electrodeposition of copper-rich alloys exploiting the phenomenon of underpotential deposition |
| JP3274766B2 (ja) * | 1994-06-28 | 2002-04-15 | 荏原ユージライト株式会社 | 低融点錫合金めっき浴 |
| JPH0827590A (ja) * | 1994-07-13 | 1996-01-30 | Okuno Chem Ind Co Ltd | 光沢銅−錫合金めっき浴 |
| US6176996B1 (en) * | 1997-10-30 | 2001-01-23 | Sungsoo Moon | Tin alloy plating compositions |
| JP3366851B2 (ja) * | 1997-12-18 | 2003-01-14 | 株式会社ジャパンエナジー | 錫合金電気めっき液およびめっき方法 |
| TW577938B (en) * | 1998-11-05 | 2004-03-01 | Uyemura C & Co Ltd | Tin-copper alloy electroplating bath and plating process therewith |
| JP2001060672A (ja) * | 1999-08-20 | 2001-03-06 | Mitsubishi Electric Corp | エッチング方法およびエッチングマスク |
| JP3433291B2 (ja) * | 1999-09-27 | 2003-08-04 | 石原薬品株式会社 | スズ−銅含有合金メッキ浴、スズ−銅含有合金メッキ方法及びスズ−銅含有合金メッキ皮膜が形成された物品 |
| JP2001107287A (ja) * | 1999-10-07 | 2001-04-17 | Ebara Udylite Kk | Sn−Cu合金めっき浴 |
| EP1091023A3 (en) * | 1999-10-08 | 2003-05-14 | Shipley Company LLC | Alloy composition and plating method |
| JP2001181889A (ja) * | 1999-12-22 | 2001-07-03 | Nippon Macdermid Kk | 光沢錫−銅合金電気めっき浴 |
| DE10046600C2 (de) * | 2000-09-20 | 2003-02-20 | Schloetter Fa Dr Ing Max | Elektrolyt und Verfahren zur Abscheidung von Zinn-Kupfer-Legierungsschichten und Verwendung des Elektrolyten |
| JP2004510053A (ja) * | 2000-09-20 | 2004-04-02 | デーエル.−イーエヌゲー.マックス シュレッター ゲーエムベーハー ウント ツェーオー.カーゲー | 錫−銅合金層を析出させるための電解質及び方法 |
| US20020187364A1 (en) * | 2001-03-16 | 2002-12-12 | Shipley Company, L.L.C. | Tin plating |
| DE60226196T2 (de) * | 2001-05-24 | 2009-05-14 | Shipley Co., L.L.C., Marlborough | Zinn-Plattieren |
| US20060260948A2 (en) * | 2005-04-14 | 2006-11-23 | Enthone Inc. | Method for electrodeposition of bronzes |
-
2002
- 2002-10-11 ES ES02022718T patent/ES2531163T3/es not_active Expired - Lifetime
- 2002-10-11 EP EP02022718.7A patent/EP1408141B1/de not_active Revoked
-
2003
- 2003-10-10 KR KR1020057004846A patent/KR100684818B1/ko not_active Expired - Lifetime
- 2003-10-10 JP JP2004544134A patent/JP4675626B2/ja not_active Expired - Lifetime
- 2003-10-10 WO PCT/EP2003/011229 patent/WO2004035875A2/de not_active Ceased
- 2003-10-10 CN CN2003801012538A patent/CN1703540B/zh not_active Expired - Lifetime
- 2003-10-10 US US10/531,142 patent/US20060137991A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20060137991A1 (en) | 2006-06-29 |
| JP2005537394A (ja) | 2005-12-08 |
| WO2004035875A3 (de) | 2005-04-14 |
| KR20050059174A (ko) | 2005-06-17 |
| KR100684818B1 (ko) | 2007-02-22 |
| CN1703540B (zh) | 2010-10-06 |
| EP1408141A1 (de) | 2004-04-14 |
| JP4675626B2 (ja) | 2011-04-27 |
| EP1408141B1 (de) | 2014-12-17 |
| CN1703540A (zh) | 2005-11-30 |
| WO2004035875A2 (de) | 2004-04-29 |
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