ES2531411T3 - Procedimiento para la conversión de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno - Google Patents

Procedimiento para la conversión de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno Download PDF

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Publication number
ES2531411T3
ES2531411T3 ES10712056T ES10712056T ES2531411T3 ES 2531411 T3 ES2531411 T3 ES 2531411T3 ES 10712056 T ES10712056 T ES 10712056T ES 10712056 T ES10712056 T ES 10712056T ES 2531411 T3 ES2531411 T3 ES 2531411T3
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membrane
conversion
hydrogen
catalyst
procedure
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Tsou Joana Coelho
Alexander Panchenko
Annebart Engbert Wentink
Sebastian Ahrens
Thomas Heidemann
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion characterised by membranes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles, e.g. fluidised bed technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0656—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/06—Polluted air
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Procedimiento para la conversión de hidrocarburos alifáticos con 1 a 4 átomos de C en hidrocarburos aromáticos, que comprende las etapas: a) convertir un flujo de reactante E que contiene al menos un hidrocarburo alifático con 1 a 4 átomos de C, en presencia de un catalizador en condiciones no oxidativas, en un flujo de producto P que contiene hidrocarburos aromáticos e hidrógeno y b) separar electroquímicamente al menos una parte del hidrógeno producido durante la conversión del flujo de producto P por medio de un conjunto de membrana-electrodos hermético a los gases, que presenta al menos una membrana que conduce protones de manera selectiva y en cada lado de la membrana al menos un catalizador de electrodo, en el que en el lado del material retenido de la membrana se oxida al menos una parte del hidrógeno en el catalizador de ánodo para dar protones y los protones se reducen tras atravesar la membrana en el lado del material permeado en el catalizador de cátodo para dar hidrógeno.
ES10712056T 2009-04-06 2010-03-30 Procedimiento para la conversión de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno Active ES2531411T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09157395 2009-04-06
PCT/EP2010/054140 WO2010115765A1 (de) 2009-04-06 2010-03-30 Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff

Publications (1)

Publication Number Publication Date
ES2531411T3 true ES2531411T3 (es) 2015-03-13

Family

ID=42635072

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10712056T Active ES2531411T3 (es) 2009-04-06 2010-03-30 Procedimiento para la conversión de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno

Country Status (9)

Country Link
US (1) US8609914B2 (es)
EP (1) EP2417059B1 (es)
JP (1) JP5797637B2 (es)
KR (1) KR20120004984A (es)
CN (1) CN102459067B (es)
EA (1) EA020384B1 (es)
ES (1) ES2531411T3 (es)
PL (1) PL2417059T3 (es)
WO (1) WO2010115765A1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2417058T5 (pl) 2009-04-06 2021-12-13 Basf Se Sposób elektrochemicznego oddzielania wodoru z mieszaniny reakcyjnej
PL2417083T3 (pl) * 2009-04-06 2015-05-29 Basf Se Sposób przeprowadzania gazu ziemnego w węglowodory aromatyczne z elektrochemicznym wydzielaniem wodoru i elektrochemicznym przeprowadzaniem wodoru w wodę
ES2529554T3 (es) * 2009-04-06 2015-02-23 Basf Se Procedimiento para la transformación de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno con generación de corriente eléctrica e hidrógeno
CN102548952B (zh) * 2009-07-10 2014-05-14 巴斯夫欧洲公司 在电化学分离氢气的情况下将烃直接胺化成氨基烃的方法
ES2533702T3 (es) 2009-07-10 2015-04-14 Basf Se Procedimiento para la aminación directa de hidrocarburos para dar aminohidrocarburos con separación electroquímica de hidrógeno y conversión electroquímica del hidrógeno en agua
WO2011026744A2 (de) 2009-09-03 2011-03-10 Basf Se Verfahren zur herstellung von benzol aus methan
US20140171708A1 (en) * 2012-11-29 2014-06-19 Ceramatec, Inc. System and process for converting natural gas into benzene
GB201317870D0 (en) * 2013-10-09 2013-11-20 Protia As Process for dehydroaromatization of alkanes with in-situ hydrogen removal
JP6292383B2 (ja) * 2014-02-07 2018-03-14 パナソニックＩｐマネジメント株式会社 脱水素化装置
JP6588090B2 (ja) * 2014-09-29 2019-10-09 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 膜／電極接合体、該膜／電極接合体を含む反応器及び水素を分離する方法
US20160176779A1 (en) * 2014-12-23 2016-06-23 Pioneer Energy Inc. Ethane and Ethylene to Aromatics
US10525407B2 (en) 2015-10-07 2020-01-07 University Of Maryland, College Park Systems, methods, and devices for direct conversion of methane
US10855714B2 (en) 2016-10-31 2020-12-01 KnowBe4, Inc. Systems and methods for an artificial intelligence driven agent
KR101905500B1 (ko) 2016-12-07 2018-10-15 한국에너지기술연구원 산소 분리막을 사용한 메탄 산화 이량화 방법
CN109904469A (zh) * 2019-02-26 2019-06-18 武汉理工大学 一种优化阴极催化层结构的膜电极制备方法
KR102703952B1 (ko) * 2021-09-08 2024-09-06 한국화학연구원 메탄의 비산화 직접전환 반응기 및 이를 이용한 에틸렌 및 방향족 화합물의 제조방법
EP4727682A1 (en) * 2023-06-14 2026-04-22 TotalEnergies OneTech Reactor comprising an extractive membrane, preparation and use

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KR20100129750A (ko) 2008-02-29 2010-12-09 바스프 에스이 이온성 액체를 포함하는 촉매 잉크, 및 전극, ｃｃｍ, ｇｄｅ 및 ｍｅａ의 제조에서의 이의 용도
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CN102076886A (zh) 2008-06-30 2011-05-25 巴斯夫欧洲公司 电化学直接胺化烃类的方法

Also Published As

Publication number Publication date
US8609914B2 (en) 2013-12-17
US20120012467A1 (en) 2012-01-19
WO2010115765A1 (de) 2010-10-14
JP5797637B2 (ja) 2015-10-21
KR20120004984A (ko) 2012-01-13
EA201190239A1 (ru) 2012-04-30
JP2012522899A (ja) 2012-09-27
CN102459067A (zh) 2012-05-16
EP2417059A1 (de) 2012-02-15
EA020384B1 (ru) 2014-10-30
EP2417059B1 (de) 2014-12-10
PL2417059T3 (pl) 2015-05-29
CN102459067B (zh) 2015-08-19

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