ES2533079T3 - Isomerización de 1-cloro-3,3,3-trifIuoropropeno - Google Patents

Isomerización de 1-cloro-3,3,3-trifIuoropropeno Download PDF

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Publication number
ES2533079T3
ES2533079T3 ES09832509.5T ES09832509T ES2533079T3 ES 2533079 T3 ES2533079 T3 ES 2533079T3 ES 09832509 T ES09832509 T ES 09832509T ES 2533079 T3 ES2533079 T3 ES 2533079T3
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Spain
Prior art keywords
chloro
trifluoropropene
mixture
metal oxide
packing material
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ES09832509.5T
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Inventor
Ryan Hulse
Rajiv R. Singh
Konstantin Pokrovski
Hsueh Sung Tung
Daniel Merkel
Haiyou Wang
Michael Van Der Puy
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Honeywell International Inc
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Honeywell International Inc
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Application filed by Honeywell International Inc filed Critical Honeywell International Inc
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/35Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C07C17/358Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction by isomerisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00Purification; Separation; Stabilisation; Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/10Alkenes with five carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/12Alkadienes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/12Alkadienes
    • C07C11/16Alkadienes with four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/21Alkatrienes; Alkatetraenes; Other alkapolyenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/22Aliphatic unsaturated hydrocarbons containing carbon-to-carbon triple bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/28Aliphatic unsaturated hydrocarbons containing carbon-to-carbon double bonds and carbon-to-carbon triple bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/38Separation; Purification; Stabilisation; Use of additives
    • C07C17/383Separation; Purification; Stabilisation; Use of additives by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Un método para convertir (E)-1-cloro-3,3,3-trifluoropropeno en (Z)-1-cloro-3,3,3-trifluoropropeno, que comprende: proporcionar una corriente de alimentación que consiste esencialmente en (E)-1-cloro-3,3,3-trifluoropropeno o una mezcla de (E)-1-cloro-3,3,3-trifluoropropeno y (Z)-1-cloro-3,3,3-trifluoropropeno con menos de 5% en peso de (Z)-1- cloro-3,3,3-trifluoropropeno; poner en contacto la corriente de alimentación con una superficie calentada que se mantiene entre 150°C y 400°C durante un periodo de tiempo suficiente para convertir al menos una porción del (E)-1- cloro-3,3,3-trifluoropropeno en (Z)-1-cloro-3,3,3-trifluoropropeno para producir una corriente de producto y destilar la corriente de producto para separar los isómeros (E) y (Z) entre sí, en la que la superficie calentada incluye la superficie exterior de un material de empaquetamiento y el material de empaquetamiento es acero inoxidable o un material catalítico que comprende: un óxido de metal, óxido de metal halogenado, un haluro de metal de ácido de Lewis o un metal de valencia cero o una mezcla o aleación de los mismos.

Description

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Claims (1)

  1. imagen1
ES09832509.5T 2008-12-12 2009-12-10 Isomerización de 1-cloro-3,3,3-trifIuoropropeno Active ES2533079T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US12221808P 2008-12-12 2008-12-12
US122218P 2008-12-12
US12/633,420 US8217208B2 (en) 2008-12-12 2009-12-08 Isomerization of 1-chloro-3,3,3-trifluoropropene
US633420 2009-12-08
PCT/US2009/067420 WO2010068715A2 (en) 2008-12-12 2009-12-10 Isomerization of 1-chloro-3,3,3-trifluoropropene

Publications (1)

Publication Number Publication Date
ES2533079T3 true ES2533079T3 (es) 2015-04-07

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
ES09832509.5T Active ES2533079T3 (es) 2008-12-12 2009-12-10 Isomerización de 1-cloro-3,3,3-trifIuoropropeno

Country Status (9)

Country Link
US (1) US8217208B2 (es)
EP (1) EP2379474B1 (es)
JP (3) JP5745425B2 (es)
KR (2) KR101698482B1 (es)
CN (1) CN102245548B (es)
CA (1) CA2746089C (es)
ES (1) ES2533079T3 (es)
MX (1) MX2011006010A (es)
WO (1) WO2010068715A2 (es)

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FR2962442B1 (fr) 2010-07-09 2016-02-26 Arkema France Composition stable de 2,3,3,3-tetrafluoropropene
US8704017B2 (en) * 2010-09-03 2014-04-22 Honeywell International Inc. Continuous low-temperature process to produce trans-1-chloro-3,3,3-trifluoropropene
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US8404907B2 (en) * 2011-02-18 2013-03-26 Honeywell International Inc. Process for cis-1-chloro-3,3,3-trifluoropropene
US8653309B2 (en) * 2011-04-20 2014-02-18 Honeywell International Inc. Process for producing trans-1233zd
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US9000239B2 (en) * 2012-05-15 2015-04-07 Honeywell International Inc. Methods for producing 1-chloro-3,3,3-trifluoropropene from 2-chloro-3,3,3-trifluoropropene
JP6156374B2 (ja) * 2012-06-13 2017-07-05 セントラル硝子株式会社 1−クロロ−3,3,3−トリフルオロ−1−プロペン及び1,3,3,3−テトラフルオロプロペンの製造方法
US20140275644A1 (en) * 2013-03-14 2014-09-18 Honeywell International Inc. Method to produce cis-1-chloro-3,3,3-trifluoropropene
US9162947B2 (en) * 2013-03-15 2015-10-20 Honeywell International Inc. High temperature isomerization of (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene
JP6381890B2 (ja) * 2013-10-25 2018-08-29 三菱重工サーマルシステムズ株式会社 冷媒循環装置、冷媒循環方法および異性化抑制方法
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FR3033791B1 (fr) 2015-03-18 2017-04-14 Arkema France Stabilisation du 1-chloro-3,3,3-trifluoropropene
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JP6753434B2 (ja) 2018-06-13 2020-09-09 ダイキン工業株式会社 ジフルオロエチレンの製造方法
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Also Published As

Publication number Publication date
EP2379474B1 (en) 2015-01-14
KR20170007862A (ko) 2017-01-20
EP2379474A2 (en) 2011-10-26
WO2010068715A3 (en) 2010-09-16
CN102245548B (zh) 2015-02-04
KR20110106363A (ko) 2011-09-28
MX2011006010A (es) 2011-07-13
EP2379474A4 (en) 2012-07-25
KR101839442B1 (ko) 2018-03-16
JP2015110648A (ja) 2015-06-18
CA2746089C (en) 2019-11-26
US20100152504A1 (en) 2010-06-17
CN102245548A (zh) 2011-11-16
JP6082765B2 (ja) 2017-02-15
WO2010068715A2 (en) 2010-06-17
JP2017110020A (ja) 2017-06-22
JP2012512160A (ja) 2012-05-31
CA2746089A1 (en) 2010-06-17
JP5745425B2 (ja) 2015-07-08
WO2010068715A4 (en) 2010-11-04
KR101698482B1 (ko) 2017-01-20
US8217208B2 (en) 2012-07-10

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