ES2543361T3 - Una composición que contiene lecitina apropiada para la producción de unas espumas duras de poliuretanos - Google Patents
Una composición que contiene lecitina apropiada para la producción de unas espumas duras de poliuretanos Download PDFInfo
- Publication number
- ES2543361T3 ES2543361T3 ES10170391.6T ES10170391T ES2543361T3 ES 2543361 T3 ES2543361 T3 ES 2543361T3 ES 10170391 T ES10170391 T ES 10170391T ES 2543361 T3 ES2543361 T3 ES 2543361T3
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- polyurethane foams
- hard polyurethane
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- 239000000203 mixture Substances 0.000 title abstract description 17
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 title abstract description 5
- 229940067606 lecithin Drugs 0.000 title abstract description 5
- 235000010445 lecithin Nutrition 0.000 title abstract description 5
- 239000000787 lecithin Substances 0.000 title abstract description 5
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 2
- 239000011496 polyurethane foam Substances 0.000 title abstract 2
- 229920005862 polyol Polymers 0.000 abstract description 9
- 150000003077 polyols Chemical class 0.000 abstract description 9
- 239000012948 isocyanate Substances 0.000 abstract description 2
- 150000002513 isocyanates Chemical class 0.000 abstract description 2
- 239000004604 Blowing Agent Substances 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 1
- 238000009472 formulation Methods 0.000 description 10
- 239000006260 foam Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- -1 1-chloro-2 -propyl Chemical group 0.000 description 4
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000013038 hand mixing Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- JLEXUIVKURIPFI-UHFFFAOYSA-N tris phosphate Chemical compound OP(O)(O)=O.OCC(N)(CO)CO JLEXUIVKURIPFI-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1816—Catalysts containing secondary or tertiary amines or salts thereof having carbocyclic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
- C08G18/3889—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having nitrogen in addition to phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2489/00—Characterised by the use of proteins; Derivatives thereof
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Una composición que es apropiada para la producción de unas espumas duras de poliuretanos y que contiene por lo menos una lecitina, por lo menos un catalizador del tipo de un uretano y/o de un isocianurato, por lo menos un agente de expansión, por lo menos un componente del tipo de un isocianato y por lo menos un componente del tipo de un poliol, caracterizada por que la relación de la masa de la lecitina a la del componente del tipo de un poliol es más pequeña que 2,5 por 100 y como agente de expansión ella contiene unos hidrocarburos con 3 hasta 5 átomos de carbono.
Description
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E10170391
22-07-2015
En los Ejemplos seguidamente expuestos se describe a modo de ejemplo el presente invento, sin que el invento, cuya amplitud de uso se establece a partir de toda la descripción y de las reivindicaciones tenga que estar restringido a las formas de realización que se mencionan en estos Ejemplos.
Ejemplos: Ejemplos de espumación
Para la comprobación técnica del uso de las formulaciones conformes al invento se utilizó la siguiente formulación de espuma:
Tabla 2: Formulaciones para usos de espumas duras (panel de espuma dura / plancha de aislamiento) en partes en masa
- Formulación
- A: Formulación de PUR B: formulación de PUR C: formulación de PIR
- Poliol
- Mezcla con un poliéter-poliol 100 partes Mezcla con un poliéter-poliol 100 partes Stepanpol® PS 2352* 100 partes
- TCPP
- 15 partes
- PMDETA
- 0,2 partes
- DMCHA
- 1,5 -
- Kosmos 75 DEG
- 4,0 partes
- Agua
- 2 0,5 0,25 partes
- Ciclopentano
- 12 -
- HFC-245fa
- - 18
- n-Pentano
- 16 partes
- Lecitina
- Variable variable variable
- Siloxano
- Variable variable Variable
- MDI **
- 145 partes 150 partes 172 partes
* Poliésterpoliol de la entidad Stepan ** Desmodur 44V20L: MDI polimérico de la entidad Bayer, 200 mPa*s; 31,5 % de NCO; funcionalidad 2,7
PMDETA: N,N,N',N",N"-pentametildietilentriamina Kosmos 75 DEG: octoato de potasio (al 75 % en peso en dietilenglicol) DMCHA: N,N-dimetilciclohexilamina TCPP: fosfato de tris(1-cloro-2-propilo).
La realización de las espumaciones se efectuó según el procedimiento de mezcladura a mano. Para ello, se produjeron las formulaciones A, B y C descritas en la Tabla 3 con diferentes siloxanos y se pesaron inicialmente en un vaso de boca ancha. .A continuación, se añadió el MDI, la mezcla de reacción se reunió agitando con un agitador de platos que tenía un diámetro de 6 cm durante 5 segundos a 3.000 rpm (revoluciones por minuto) y se transfirió inmediatamente a un molde de aluminio con un tamaño de 50 cm x 25 cm x 5 cm que estaba regulado termostáticamente a 50 ºC, y que había sido revestido con una lámina de polietileno. La cantidad empleada de la formulación de espuma se había de dimensionar en tal caso de tal manera que ella se encontrase un 10 % por encima de la proporción necesaria para el llenado mínimo del molde. Después de un período de tiempo de endurecimiento de 10 minutos, las espumas se retiraron desde el molde.
En el caso de las formulaciones A y B, se investigó adicionalmente el comportamiento de solubilidad del componente del tipo de un poliol, es decir de la mezcla sin ningún isocianato. En muchos casos es importante que el componente del tipo de un poliol sea estable en almacenamiento durante largo tiempo, es decir que no presente ninguna separación de fases o, todavía, mejor, constituya una mezcla transparente.
En la Tabla 3 recopilan los resultados de los ensayos de espumación. Se indican allí los agentes tensioactivos (Surf.), los sistemas (Syst.), la dosificación (Dos.) de los agentes tensioactivos en partes en masa por 100 partes de poliol, el comportamiento de solubilidad (Solub.) de la mezcla de polioles, la densidad de las espumas en kg / m3 y el valor de λ en mW/m·K, que se utilizaron en cada caso. En los Ejemplos comparativos, que no son conforme al invento, se utilizaron los siloxanos TEGOSTAB B 8462, B 8481 y B 8871 o se trabajó sin ningún agente tensioactivo. Como una lecitina se empleo la LECICO F 100 de la entidad Lecico GmbH.
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Claims (1)
-
imagen1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009029363A DE102009029363A1 (de) | 2009-09-11 | 2009-09-11 | Lecithin enthaltende Zusammensetzung geeignet zur Herstellung von Polyurethanhartschäumen |
| DE102009029363 | 2009-09-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2543361T3 true ES2543361T3 (es) | 2015-08-18 |
Family
ID=42942237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES10170391.6T Active ES2543361T3 (es) | 2009-09-11 | 2010-07-22 | Una composición que contiene lecitina apropiada para la producción de unas espumas duras de poliuretanos |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20110062370A1 (es) |
| EP (1) | EP2295485B1 (es) |
| JP (1) | JP2011057983A (es) |
| CN (1) | CN102020840B (es) |
| BR (1) | BRPI1003538A2 (es) |
| DE (1) | DE102009029363A1 (es) |
| ES (1) | ES2543361T3 (es) |
| PL (1) | PL2295485T3 (es) |
| RU (1) | RU2010137630A (es) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009028061A1 (de) | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
| DE102011007479A1 (de) | 2011-04-15 | 2012-10-18 | Evonik Goldschmidt Gmbh | Zusammensetzung, enthaltend spezielle Amide und organomodifizierte Siloxane, geeignet zur Herstellung von Polyurethanschäumen |
| DE102011083017A1 (de) | 2011-09-20 | 2013-03-21 | Evonik Industries Ag | Verbundwerkstoffe umfassend eine offenzellige Polymermatrix und darin eingebettete Granulate |
| EP2849715B1 (en) * | 2012-05-16 | 2019-07-17 | Archer Daniels Midland Co. | Emulsifier for solubilizing polar solvents in oils and polyols |
| CN102719086A (zh) * | 2012-07-02 | 2012-10-10 | 江苏科泰绝热新材料有限公司 | 一种阻燃聚氨酯泡沫及其制备方法 |
| DE102013226575B4 (de) | 2013-12-19 | 2021-06-24 | Evonik Operations Gmbh | Zusammensetzung, geeignet zur Herstellung von Polyurethanschäumen, enthaltend mindestens einen ungesättigten Fluorkohlenwasserstoff oder ungesättigten Fluorkohlenwasserstoff als Treibmittel, Polyurethanschäume, Verfahren zu deren Herstellung und deren Verwendung |
| DE102014215388A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215382A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215384A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| ES2793850T3 (es) | 2015-07-07 | 2020-11-17 | Evonik Degussa Gmbh | Producción de espuma de poliuretano |
| MX2019000424A (es) | 2016-07-19 | 2019-03-28 | Evonik Degussa Gmbh | Uso de poliolesteres para la produccion de revestimientos plasticos porosos. |
| CN107163219A (zh) * | 2017-05-19 | 2017-09-15 | 美的集团股份有限公司 | 聚氨酯泡沫的发泡配方、制备方法和聚氨酯泡沫保温材料 |
| CN107903366B (zh) * | 2017-11-14 | 2019-08-30 | 美的集团股份有限公司 | 用于聚氨酯发泡的催化剂、聚氨酯发泡组合物及其发泡方法与应用 |
| US12534564B2 (en) | 2019-01-07 | 2026-01-27 | Evonik Operations Gmbh | Production of rigid polyurethane foam |
| US12122890B2 (en) | 2020-08-20 | 2024-10-22 | Evonik Operations Gmbh | Production of polyurethane foam |
| CN112375195B (zh) * | 2020-11-13 | 2022-07-08 | 南京红宝丽新材料有限公司 | 用于与异氰酸酯反应的组合物、硬质聚氨酯板材及其制备方法 |
| CN119213063A (zh) | 2022-05-17 | 2024-12-27 | 赢创运营有限公司 | 聚氨酯泡沫的生产 |
| EP4282890A1 (de) | 2022-05-25 | 2023-11-29 | Evonik Operations GmbH | Herstellung von polyurethanschaum unter verwendung von ionischen flüssigkeiten |
| EP4282892A1 (de) | 2022-05-25 | 2023-11-29 | Evonik Operations GmbH | Herstellung von polyurethanschaum unter verwendung von katalysatoren auf basis ionischer flüssigkeiten |
| CA3251080A1 (en) | 2022-06-08 | 2025-03-17 | Evonik Operations Gmbh | Polyether-siloxane block copolymers for producing polyurethane foams |
| JP2025518384A (ja) | 2022-06-08 | 2025-06-12 | エボニック オペレーションズ ゲーエムベーハー | 難燃性ポリウレタンフォームの製造 |
| EP4299656A1 (de) | 2022-07-01 | 2024-01-03 | Evonik Operations GmbH | Herstellung von propoxylierten benzoldicarbonsäureamiden und dem entsprechenden polyurethanschaum |
| CN114974707A (zh) * | 2022-07-05 | 2022-08-30 | 贵阳中安科技集团有限公司 | 一种自灭火电缆 |
| JP2025528473A (ja) | 2022-08-31 | 2025-08-28 | エボニック オペレーションズ ゲーエムベーハー | ポリウレタンフォームの製造 |
| CN119998362A (zh) | 2022-09-28 | 2025-05-13 | 赢创运营有限公司 | 制备SiOC-连接的线性聚二烷基硅氧烷-聚醚嵌段共聚物的方法及其用途 |
| EP4372036A1 (en) | 2022-11-15 | 2024-05-22 | Evonik Operations GmbH | Depolymerization of polyisocyanurate with organic amine bases |
| EP4372024A1 (en) | 2022-11-15 | 2024-05-22 | Evonik Operations GmbH | New method for recycling of polyisocyanurates |
| JP2026504596A (ja) | 2023-02-17 | 2026-02-05 | エボニック オペレーションズ ゲーエムベーハー | 固形物を含有するポリウレタンフォーム材のための安定剤 |
| JP2026504595A (ja) | 2023-02-17 | 2026-02-05 | エボニック オペレーションズ ゲーエムベーハー | 再生ポリオールを含有するポリウレタンフォーム材のための安定剤 |
| WO2025082815A1 (de) | 2023-10-19 | 2025-04-24 | Evonik Operations Gmbh | Stabilisatoren für polyurethanschaumstoffe |
| EP4606832A1 (de) | 2024-02-22 | 2025-08-27 | Evonik Operations GmbH | Stabilisatoren für polyurethanschaumstoffe enthaltend recycling-polyol |
| US20260015475A1 (en) | 2024-07-12 | 2026-01-15 | Evonik Operations Gmbh | Production of polyurethane foam |
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| US3007883A (en) * | 1956-10-25 | 1961-11-07 | Bayer Ag | Cellular polyurethanes resembling natural sponge and method of preparing same |
| NL284810A (es) | 1962-01-25 | |||
| NL290776A (es) * | 1962-11-03 | |||
| US3650880A (en) * | 1968-11-20 | 1972-03-21 | Hooker Chemical Corp | Porous polyurethanes and method of manufacture |
| DE2015159A1 (de) * | 1970-03-28 | 1971-10-21 | Bayer | Verfahren zur Herstellung von flammwidrigen Polyurethanschaumstoffen |
| US3746663A (en) | 1971-09-13 | 1973-07-17 | Air Prod & Chem | Process for preparation of a polyurethane foam using a polymeric liquid foam stabilizer |
| US3788975A (en) * | 1971-09-30 | 1974-01-29 | Universal Oil Prod Co | Simultaneous production of aromatic hydrocarbons and isobutane |
| US4024088A (en) * | 1974-12-23 | 1977-05-17 | Union Carbide Corporation | Compositions and methods useful in forming polyether polyurethanes having release properties |
| US4451425A (en) * | 1983-01-28 | 1984-05-29 | The Dow Chemical Company | Method for injection molding polyurethane using internal release agents |
| US4500442A (en) * | 1983-01-28 | 1985-02-19 | The Dow Chemical Company | Compositions containing mold release agents |
| US4596665A (en) * | 1984-11-23 | 1986-06-24 | The Dow Chemical Company | Flexible polymer foams prepared with C4 or higher polyethers as cell openers |
| JPH03200847A (ja) * | 1989-12-28 | 1991-09-02 | Asahi Glass Co Ltd | 発泡合成樹脂の製造方法 |
| CA2078580A1 (en) | 1991-09-20 | 1993-03-21 | Kenrick M. Lewis | Use of capped surfactants for production of rigid polyurethane foams blown with hydrochlorofluorocarbons |
| US5169872A (en) | 1992-05-11 | 1992-12-08 | Dow Corning Corporation | Process for preparing rigid polyurethane and polyisocyanurate foams having enhanced benefits |
| US5600019A (en) | 1993-12-17 | 1997-02-04 | The Dow Chemical Company | Polyisocyanate based polymers perpared from formulations including non-silicone surfactants and method for the preparation thereof |
| US5470501A (en) * | 1995-05-08 | 1995-11-28 | Basf Corporation | Processability of hydrocarbon blown, polyisocyanate based foams through use of a compatibilizing agent |
| JP3826469B2 (ja) * | 1997-02-03 | 2006-09-27 | 東ソー株式会社 | 硬質イソシアヌレートフォームの製造法 |
| US6822012B1 (en) * | 2000-03-23 | 2004-11-23 | Ashland Inc | Peelable polymeric coating composition |
| US7183330B2 (en) | 2003-12-15 | 2007-02-27 | Air Products And Chemicals, Inc. | Silicone surfactants for rigid polyurethane foam made with hydrocarbon blowing agents |
| DE102005034052A1 (de) * | 2005-07-21 | 2007-01-25 | Goldschmidt Gmbh | Trimerisierungskatalysatoren |
| JP4699834B2 (ja) * | 2005-08-02 | 2011-06-15 | 旭ファイバーグラス株式会社 | ポリイソシアヌレート発泡体の製造方法 |
| DE102005050473A1 (de) * | 2005-10-21 | 2007-04-26 | Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethan-Kaltschäumen |
| DE102006042338A1 (de) * | 2006-09-08 | 2008-03-27 | Evonik Goldschmidt Gmbh | Verwendung von Urethan- oder Harnstoffgruppen enthaltenden Polyethern zur Stabilisierung von Polyurethanschäumen |
| US8303843B2 (en) * | 2006-12-15 | 2012-11-06 | Evonik Goldschmidt Gmbh | Aqueous cold-cure flexible stabilizer formulations |
| DE102006060115A1 (de) * | 2006-12-20 | 2008-06-26 | Evonik Goldschmidt Gmbh | Cyclische Siloxane und deren Verwendung |
| JP5360520B2 (ja) * | 2007-07-04 | 2013-12-04 | 川崎化成工業株式会社 | ポリウレタンフォーム用組成物及びポリウレタンフォーム |
| DE102007046736A1 (de) * | 2007-09-28 | 2009-04-02 | Evonik Goldschmidt Gmbh | Verwendung linearer Siloxane und Verfahren zu deren Herstellung |
| DE102008000243A1 (de) * | 2008-02-06 | 2009-08-13 | Evonik Goldschmidt Gmbh | Neuartige Kompatibilisierungsmittel zur Verbesserung der Lagerstabilität von Polyolmischungen |
| DE102008043218A1 (de) * | 2008-09-24 | 2010-04-01 | Evonik Goldschmidt Gmbh | Polymere Werkstoffe sowie daraus bestehende Kleber- und Beschichtungsmittel auf Basis multialkoxysilylfunktioneller Präpolymerer |
| DE102008043343A1 (de) * | 2008-10-31 | 2010-05-06 | Evonik Goldschmidt Gmbh | Silikonpolyetherblock-Copolymere mit definierter Polydispersität im Polyoxyalkylenteil und deren Verwendung als Stabilisatoren zur Herstellung von Polyurethanschäumen |
-
2009
- 2009-09-11 DE DE102009029363A patent/DE102009029363A1/de not_active Withdrawn
-
2010
- 2010-07-22 EP EP20100170391 patent/EP2295485B1/de not_active Not-in-force
- 2010-07-22 ES ES10170391.6T patent/ES2543361T3/es active Active
- 2010-07-22 PL PL10170391T patent/PL2295485T3/pl unknown
- 2010-08-30 US US12/871,464 patent/US20110062370A1/en not_active Abandoned
- 2010-09-08 BR BRPI1003538-9A patent/BRPI1003538A2/pt not_active Application Discontinuation
- 2010-09-10 CN CN201010283617.0A patent/CN102020840B/zh not_active Expired - Fee Related
- 2010-09-10 RU RU2010137630/04A patent/RU2010137630A/ru not_active Application Discontinuation
- 2010-09-10 JP JP2010202556A patent/JP2011057983A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| RU2010137630A (ru) | 2012-03-20 |
| PL2295485T3 (pl) | 2015-10-30 |
| EP2295485A1 (de) | 2011-03-16 |
| CN102020840B (zh) | 2014-04-30 |
| CN102020840A (zh) | 2011-04-20 |
| DE102009029363A1 (de) | 2011-03-24 |
| EP2295485B1 (de) | 2015-05-20 |
| JP2011057983A (ja) | 2011-03-24 |
| US20110062370A1 (en) | 2011-03-17 |
| BRPI1003538A2 (pt) | 2012-05-29 |
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