ES2547871T3 - Fluoración catalítica en fase gaseosa de 1230xa para dar 1234yf - Google Patents

Fluoración catalítica en fase gaseosa de 1230xa para dar 1234yf Download PDF

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Publication number
ES2547871T3
ES2547871T3 ES10814773.7T ES10814773T ES2547871T3 ES 2547871 T3 ES2547871 T3 ES 2547871T3 ES 10814773 T ES10814773 T ES 10814773T ES 2547871 T3 ES2547871 T3 ES 2547871T3
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Prior art keywords
gas phase
fluoridation
catalytic
give
stream
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Active
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ES10814773.7T
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English (en)
Inventor
Anne Pigamo
Dominique Deur-Bert
Laurent Wendlinger
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Arkema France SA
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Arkema France SA
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Priority claimed from PCT/IB2009/056054 external-priority patent/WO2011077191A1/en
Application filed by Arkema France SA filed Critical Arkema France SA
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Publication of ES2547871T3 publication Critical patent/ES2547871T3/es
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
    • C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C07C17/42—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procedimiento para preparar 2,3,3,3-tetrafluoropropeno (1234yf), que comprende: (i) poner en contacto 1,1,2,3-tetracloropropeno (1230xa) con fluoruro de hidrógeno HF en fase gaseosa en presencia de un catalizador de fluoración en condiciones suficientes para producir una mezcla de reacción; (ii) separar la mezcla de reacción en una primera corriente que comprende HCl, 2,3,3,3-tetrafluoropropeno (1234yf) y una segunda corriente que comprende HF, 2-cloro-3,3,3-trifluoro-1-propeno (1233xf) y 1,1,1,2,2- pentafluoropropano (245cb); (iii) recircular al menos una parte de la segunda corriente al menos en parte de vuelta a la etapa (i).

Description

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Claims (1)

  1. imagen1
ES10814773.7T 2009-12-23 2010-12-22 Fluoración catalítica en fase gaseosa de 1230xa para dar 1234yf Active ES2547871T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
WOPCT/IB2009/056054 2009-12-23
PCT/IB2009/056054 WO2011077191A1 (en) 2009-12-23 2009-12-23 Catalytic gas phase fluorination of 1230xa to 1234yf
PCT/IB2010/056022 WO2011077394A1 (en) 2009-12-23 2010-12-22 CATALYTIC GAS PHASE FLUORINATION OF 1230xa TO 1234yf

Publications (1)

Publication Number Publication Date
ES2547871T3 true ES2547871T3 (es) 2015-10-09

Family

ID=44583744

Family Applications (1)

Application Number Title Priority Date Filing Date
ES10814773.7T Active ES2547871T3 (es) 2009-12-23 2010-12-22 Fluoración catalítica en fase gaseosa de 1230xa para dar 1234yf

Country Status (5)

Country Link
EP (1) EP2516368B1 (es)
CN (1) CN102686543B (es)
ES (1) ES2547871T3 (es)
HU (1) HUE025486T2 (es)
WO (1) WO2011077394A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013065617A1 (en) * 2011-10-31 2013-05-10 Daikin Industries, Ltd. Process for producing 2-chloro-3,3,3-trifluoropropene
US9353029B2 (en) * 2013-03-14 2016-05-31 Honeywell International, Inc. Fluorination process and reactor
JP5807690B2 (ja) 2013-04-25 2015-11-10 ダイキン工業株式会社 含フッ素オレフィンの製造方法
JP5825299B2 (ja) * 2013-07-12 2015-12-02 ダイキン工業株式会社 ２，３，３，３−テトラフルオロプロペンの製造方法
CN104496747B (zh) * 2014-12-30 2018-12-28 山东东岳化工有限公司 一种2,3,3,3-四氟丙烯的制备方法
GB2559056B (en) * 2015-07-17 2019-09-11 Mexichem Fluor Sa De Cv Process for preparing 245cb and 1234yf from 243db
CN108349755A (zh) * 2015-11-05 2018-07-31 霍尼韦尔国际公司 用于从通过1230xa得到1234yf的方法的无水或含水氢氯酸副产物中去除氟化有机物的方法
CN106349005B (zh) 2016-08-25 2018-08-28 浙江衢州巨新氟化工有限公司 一种联产三氟丙烯类产品和四氟丙烯类产品的方法
SI4219647T1 (sl) 2018-04-30 2025-04-30 The Chemours Company Fc, Llc Vsebnik, ki vsebuje stabilizirane sestavke fluorolefina
CN116143583B (zh) * 2023-04-19 2023-07-07 山东澳帆新材料有限公司 一种2,3,3,3-四氟丙烯和1,3,3,3-四氟丙烯的联产制备方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4902838A (en) 1988-12-28 1990-02-20 E. I. Du Pont De Nemours And Company Isomerization of saturated fluorohydrocarbons
FR2669022B1 (fr) 1990-11-13 1992-12-31 Atochem Procede de fabrication du tetrafluoro-1,1,1,2-ethane.
US5714651A (en) 1995-12-28 1998-02-03 Elf Atochem North America, Inc. Use of polymerization inhibitor to prolong the life of a Lewis acid catalyst
DE69909860T2 (de) 1998-02-26 2004-05-27 Central Glass Co., Ltd., Ube Verfahren zur Herstellung von fluorierten Propanen
US7485598B2 (en) 2006-06-21 2009-02-03 Arkema Inc. High pressure catalyst activation method and catalyst produced thereby
US8084653B2 (en) * 2004-04-29 2011-12-27 Honeywell International, Inc. Method for producing fluorinated organic compounds
US8058486B2 (en) 2004-04-29 2011-11-15 Honeywell International Inc. Integrated process to produce 2,3,3,3-tetrafluoropropene
PL4212499T3 (pl) 2006-01-03 2026-07-13 Honeywell International Inc. Sposób wytwarzania fluorowanych związków organicznych
WO2008002500A1 (en) 2006-06-27 2008-01-03 E. I. Du Pont De Nemours And Company Tetrafluoropropene production processes
CN101522597B (zh) 2006-10-03 2013-05-29 墨西哥化学阿玛科股份有限公司 通过脱卤化氢制备c3-c6(氢)氟烯烃的方法
WO2008054781A1 (en) 2006-10-31 2008-05-08 E. I. Du Pont De Nemours And Company Processes for the production of fluoropropanes and halopropenes and azeotropic compositions of 2-chloro-3,3,3-trifluoro-1-propene with hf and of 1,1,1,2,2-pentafluoropropane with hf
US8063257B2 (en) * 2007-01-03 2011-11-22 Honeywell International Inc. Method for producing 2,3,3,3-tetrafluoropropene
WO2009003084A1 (en) * 2007-06-27 2008-12-31 Arkema Inc. Process for the manufacture of hydrofluoroolefins
US7795480B2 (en) 2007-07-25 2010-09-14 Honeywell International Inc. Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf)
CN101597209A (zh) * 2008-03-20 2009-12-09 霍尼韦尔国际公司 用于制备2,3,3,3-四氟丙烯的一体式方法
FR2929271B1 (fr) 2008-03-28 2010-04-16 Arkema France Procede pour la preparation du 1,2,3,3,3-pentafluoropropene- 1
WO2009158321A1 (en) * 2008-06-26 2009-12-30 Arkema Inc. Catalytic gas phase fluorination of 1230xa to 1234yf

Also Published As

Publication number Publication date
CN102686543A (zh) 2012-09-19
EP2516368A1 (en) 2012-10-31
EP2516368B1 (en) 2015-07-01
WO2011077394A1 (en) 2011-06-30
HUE025486T2 (en) 2016-02-29
CN102686543B (zh) 2015-04-15

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