ES2552753T3 - Composiciones activadas para la eliminación del oxígeno en envases plásticos - Google Patents

Composiciones activadas para la eliminación del oxígeno en envases plásticos Download PDF

Info

Publication number: ES2552753T3
Authority: ES; Spain
Prior art keywords: composition; compound; oxygen; weight; alkyl
Prior art date: 2011-05-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES12719165.8T

Other languages

English (en)

Spanish (es)

Inventor

Murali K. Akkapeddi

Brian A. Lynch

Yang Zhong

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Graham Packaging Co LP

Original Assignee

Graham Packaging Co LP

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-05-06

Filing date

2012-04-19

Publication date

2015-12-02

2012-04-19 Application filed by Graham Packaging Co LP filed Critical Graham Packaging Co LP

2015-12-02 Application granted granted Critical

2015-12-02 Publication of ES2552753T3 publication Critical patent/ES2552753T3/es

Status Active legal-status Critical Current

2032-04-19 Anticipated expiration legal-status Critical

Links

239000000203 mixture Substances 0.000 title claims abstract description 153
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title description 140
239000001301 oxygen Substances 0.000 title description 140
229910052760 oxygen Inorganic materials 0.000 title description 140
238000003379 elimination reaction Methods 0.000 title description 17
230000008030 elimination Effects 0.000 title description 15
229920003023 plastic Polymers 0.000 title description 6
239000004033 plastic Substances 0.000 title description 6
150000001875 compounds Chemical class 0.000 claims abstract description 63
229920000728 polyester Polymers 0.000 claims abstract description 54
150000002894 organic compounds Chemical class 0.000 claims abstract description 39
125000003118 aryl group Chemical group 0.000 claims abstract description 36
125000000217 alkyl group Chemical group 0.000 claims abstract description 35
229910052723 transition metal Inorganic materials 0.000 claims abstract description 35
150000003624 transition metals Chemical class 0.000 claims abstract description 31
229920005601 base polymer Polymers 0.000 claims abstract description 29
239000002184 metal Substances 0.000 claims abstract description 25
239000012190 activator Substances 0.000 claims abstract description 24
229910052751 metal Inorganic materials 0.000 claims abstract description 23
125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 15
230000003647 oxidation Effects 0.000 claims abstract description 15
238000007254 oxidation reaction Methods 0.000 claims abstract description 15
YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical group OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 claims abstract description 12
125000001989 1,3-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([H])C([*:2])=C1[H] 0.000 claims abstract description 11
125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 11
230000003213 activating effect Effects 0.000 claims abstract description 10
125000001072 heteroaryl group Chemical group 0.000 claims abstract description 10
229920000554 ionomer Polymers 0.000 claims abstract description 10
229920005862 polyol Polymers 0.000 claims abstract description 10
150000003077 polyols Chemical class 0.000 claims abstract description 10
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 8
125000003342 alkenyl group Chemical group 0.000 claims abstract description 7
125000002947 alkylene group Chemical group 0.000 claims abstract description 6
239000001257 hydrogen Substances 0.000 claims abstract description 6
125000002030 1,2-phenylene group Chemical group [H]C1=C([H])C([*:1])=C([*:2])C([H])=C1[H] 0.000 claims abstract description 5
125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims abstract description 5
125000000732 arylene group Chemical group 0.000 claims abstract description 5
125000002993 cycloalkylene group Chemical group 0.000 claims abstract description 5
125000001624 naphthyl group Chemical group 0.000 claims abstract description 5
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims abstract description 5
229920000139 polyethylene terephthalate Polymers 0.000 claims description 67
239000005020 polyethylene terephthalate Substances 0.000 claims description 67
239000010410 layer Substances 0.000 claims description 66
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150000002148 esters Chemical class 0.000 claims description 17
239000002356 single layer Substances 0.000 claims description 16
125000004432 carbon atom Chemical group C* 0.000 claims description 14
CFMZSMGAMPBRBE-UHFFFAOYSA-N 2-hydroxyisoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(O)C(=O)C2=C1 CFMZSMGAMPBRBE-UHFFFAOYSA-N 0.000 claims description 13
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229910052757 nitrogen Inorganic materials 0.000 claims description 12
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 10
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DPKHPTVBFHJMBL-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-hydroxyisoindole-1,3-dione Chemical compound BrC1=C(Br)C(Br)=C(Br)C2=C1C(=O)N(O)C2=O DPKHPTVBFHJMBL-UHFFFAOYSA-N 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 4
239000010941 cobalt Substances 0.000 claims description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
150000001983 dialkylethers Chemical class 0.000 claims description 4
RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 claims description 4
229910000071 diazene Inorganic materials 0.000 claims description 4
229920001281 polyalkylene Polymers 0.000 claims description 4
UTRBHXSKVVPTLY-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-hydroxyisoindole-1,3-dione Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C2=C1C(=O)N(O)C2=O UTRBHXSKVVPTLY-UHFFFAOYSA-N 0.000 claims description 3
NQTADLQHYWFPDB-UHFFFAOYSA-N N-Hydroxysuccinimide Chemical compound ON1C(=O)CCC1=O NQTADLQHYWFPDB-UHFFFAOYSA-N 0.000 claims description 3
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HAVQODIOLGTTLU-UHFFFAOYSA-N 2-hydroxy-4-methylisoindole-1,3-dione Chemical compound CC1=CC=CC2=C1C(=O)N(O)C2=O HAVQODIOLGTTLU-UHFFFAOYSA-N 0.000 claims description 2
VJVPGXXYLJECOC-UHFFFAOYSA-N 2-hydroxy-5-methoxyisoindole-1,3-dione Chemical compound COC1=CC=C2C(=O)N(O)C(=O)C2=C1 VJVPGXXYLJECOC-UHFFFAOYSA-N 0.000 claims description 2
JYUWTWHINADSOY-UHFFFAOYSA-N 2-hydroxy-5-methyl-3a,4,5,6,7,7a-hexahydroisoindole-1,3-dione Chemical compound C1C(C)CCC2C(=O)N(O)C(=O)C12 JYUWTWHINADSOY-UHFFFAOYSA-N 0.000 claims description 2
MKACMVMZUIQKNY-UHFFFAOYSA-N 2-hydroxy-5-nitroisoindole-1,3-dione Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(=O)C2=C1 MKACMVMZUIQKNY-UHFFFAOYSA-N 0.000 claims description 2
AVEDGBJBUHVIPC-UHFFFAOYSA-N 3-[2-[3-[2-(2,5-dioxopyrrol-3-yl)ethyl]phenyl]ethyl]pyrrole-2,5-dione Chemical compound O=C1NC(=O)C(CCC=2C=C(CCC=3C(NC(=O)C=3)=O)C=CC=2)=C1 AVEDGBJBUHVIPC-UHFFFAOYSA-N 0.000 claims description 2
AGKFAESBAMSZTB-UHFFFAOYSA-N 4-methylidene-5,7a-dihydro-3aH-isoindole-1,3-dione Chemical compound C=C1CC=CC2C(=O)NC(=O)C12 AGKFAESBAMSZTB-UHFFFAOYSA-N 0.000 claims description 2
VRJMGPJWXCMAOB-UHFFFAOYSA-N 5-(dimethylamino)-2-hydroxyisoindole-1,3-dione Chemical compound CN(C)C1=CC=C2C(=O)N(O)C(=O)C2=C1 VRJMGPJWXCMAOB-UHFFFAOYSA-N 0.000 claims description 2
OUZLROHALHKYIY-UHFFFAOYSA-N 5-chloro-2-hydroxyisoindole-1,3-dione Chemical compound C1=C(Cl)C=C2C(=O)N(O)C(=O)C2=C1 OUZLROHALHKYIY-UHFFFAOYSA-N 0.000 claims description 2
239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 2
JPXQQJRFHFCBDT-UHFFFAOYSA-N methyl 2-hydroxy-1,3-dioxoisoindole-4-carboxylate Chemical compound COC(=O)C1=CC=CC2=C1C(=O)N(O)C2=O JPXQQJRFHFCBDT-UHFFFAOYSA-N 0.000 claims description 2
125000000962 organic group Chemical group 0.000 claims description 2
CIFFBTOJCKSRJY-UHFFFAOYSA-N 3α,4,7,7α-tetrahydro-1h-isoindole-1,3(2h)-dione Chemical compound C1C=CCC2C(=O)NC(=O)C21 CIFFBTOJCKSRJY-UHFFFAOYSA-N 0.000 claims 2
XXYNZSATHOXXBJ-UHFFFAOYSA-N 4-hydroxyisoindole-1,3-dione Chemical compound OC1=CC=CC2=C1C(=O)NC2=O XXYNZSATHOXXBJ-UHFFFAOYSA-N 0.000 claims 1
CARJPEPCULYFFP-UHFFFAOYSA-N 5-Sulfo-1,3-benzenedicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(S(O)(=O)=O)=C1 CARJPEPCULYFFP-UHFFFAOYSA-N 0.000 claims 1
159000000000 sodium salts Chemical group 0.000 claims 1
229920000642 polymer Polymers 0.000 description 40
238000000034 method Methods 0.000 description 23
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 21
230000000052 comparative effect Effects 0.000 description 21
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238000001746 injection moulding Methods 0.000 description 16
238000002156 mixing Methods 0.000 description 16
KDMCQAXHWIEEDE-UHFFFAOYSA-L cobalt(2+);7,7-dimethyloctanoate Chemical compound [Co+2].CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O KDMCQAXHWIEEDE-UHFFFAOYSA-L 0.000 description 15
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229910052719 titanium Inorganic materials 0.000 description 1
230000007704 transition Effects 0.000 description 1
SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
NUBZKXFFIDEZKG-UHFFFAOYSA-K trisodium;5-sulfonatobenzene-1,3-dicarboxylate Chemical group [Na+].[Na+].[Na+].[O-]C(=O)C1=CC(C([O-])=O)=CC(S([O-])(=O)=O)=C1 NUBZKXFFIDEZKG-UHFFFAOYSA-K 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
235000013343 vitamin Nutrition 0.000 description 1
239000011782 vitamin Substances 0.000 description 1
229940088594 vitamin Drugs 0.000 description 1
229930003231 vitamin Natural products 0.000 description 1
239000000811 xylitol Substances 0.000 description 1
HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
235000010447 xylitol Nutrition 0.000 description 1
229960002675 xylitol Drugs 0.000 description 1
150000003752 zinc compounds Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/012—Additives improving oxygen scavenging properties
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
- C08K5/3417—Five-membered rings condensed with carbocyclic rings

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Wrappers (AREA)
Packages (AREA)
Nitrogen Condensed Heterocyclic Rings (AREA)
Pyrrole Compounds (AREA)
Indole Compounds (AREA)

ES12719165.8T 2011-05-06 2012-04-19 Composiciones activadas para la eliminación del oxígeno en envases plásticos Active ES2552753T3 (es)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US201113102747		2011-05-06
US13/102,747 US20120283366A1 (en)	2011-05-06	2011-05-06	Activated oxygen scavenging compositions for plastic containers
PCT/US2012/034235 WO2012154379A1 (en)	2011-05-06	2012-04-19	Activated oxygen scavenging compositions for plastic containers

Publications (1)

Publication Number	Publication Date
ES2552753T3 true ES2552753T3 (es)	2015-12-02

Family

ID=46028177

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES12719165.8T Active ES2552753T3 (es)	2011-05-06	2012-04-19	Composiciones activadas para la eliminación del oxígeno en envases plásticos

Country Status (9)

Country	Link
US (1)	US20120283366A1 (pl)
EP (1)	EP2705081B1 (pl)
JP (1)	JP5954598B2 (pl)
CN (1)	CN103502341B (pl)
CA (1)	CA2834261A1 (pl)
ES (1)	ES2552753T3 (pl)
MX (1)	MX342242B (pl)
PL (1)	PL2705081T3 (pl)
WO (1)	WO2012154379A1 (pl)

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EP2754690B1 (en)	2007-05-10	2017-12-13	Plastipak Packaging, Inc.	Oxygen scavenging molecules, articles containing same, and methods of their use
WO2011060297A2 (en)	2009-11-13	2011-05-19	Constar International, Inc.	Oxygen scavengers, composition comprising the scavengers, and articles made from the compositions
AU2010319298B2 (en)	2009-11-13	2015-11-05	Plastipak Packaging, Inc.	Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions
US20130285277A1 (en) *	2012-04-30	2013-10-31	Constar International, Inc.	Oxygen Scavenging Compositions, Articles Containing Same, and Methods of Their Use
AU2013263416B2 (en) *	2012-05-16	2016-04-14	Graham Packaging Company, L.P.	Low phosphorous oxygen scavenging compositions requiring no induction period
US8962740B2 (en) *	2012-09-10	2015-02-24	Kraft Foods Group Brands Llc	Oxygen scavenger system in a polyolefin matrix
US9447321B2 (en) *	2014-01-16	2016-09-20	Graham Packaging Company, L.P.	Oxygen scavenging compositions for plastic containers
US11338983B2 (en) *	2014-08-22	2022-05-24	Plastipak Packaging, Inc.	Oxygen scavenging compositions, articles containing same, and methods of their use
US10351692B2 (en)	2014-10-17	2019-07-16	Plastipak Packaging, Inc.	Oxygen scavengers, compositions comprising the scavengers, and articles made from the compositions
US20160130434A1 (en) *	2014-11-07	2016-05-12	Graham Packaging Company, L.P.	Oxygen scavenging compositions requiring no induction period
US20160222205A1 (en) *	2015-01-30	2016-08-04	Graham Packaging Company, L.P.	Durable oxygen scavenging plastic containers
JP2018051902A (ja) *	2016-09-28	2018-04-05	東洋製罐グループホールディングス株式会社	多層構造成形体
US10208200B2 (en)	2017-03-30	2019-02-19	Graham Packaging Company, L.P.	Dual oxygen-scavenging compositions requiring no induction period
AU2019374904A1 (en) *	2018-11-08	2021-06-03	Bedford Systems Llc	Multi-use beverage system
CA3121202A1 (en)	2018-11-30	2020-06-04	Nuvation Bio Inc.	Pyrrole and pyrazole compounds and methods of use thereof
WO2021156908A1 (ja) *	2020-02-03	2021-08-12	東洋製罐グループホールディングス株式会社	二重構造体

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US4536409A (en)	1981-01-23	1985-08-20	American Can Company	Oxygen scavenger
DE301719T1 (de)	1987-07-27	1990-12-20	MB Group plc, Reading, Berkshire	Verpackungsmittel.
GB2207439B (en)	1987-07-27	1992-02-12	Metal Box Plc	Improvements in and relating to packaging
GB8803062D0 (en)	1988-02-10	1988-03-09	Grace W R & Co	Sealed containers & sealing compositions for them
GB2216462B (en)	1988-03-12	1992-01-22	Mb Group Plc	Oxygen-scavenging packaging material.
US5211875A (en)	1991-06-27	1993-05-18	W. R. Grace & Co.-Conn.	Methods and compositions for oxygen scavenging
NZ334569A (en)	1996-09-23	2000-08-25	Bp Amoco Corp	Multilayered plastic containers that are resistant to oxygen permeation
US6083585A (en)	1996-09-23	2000-07-04	Bp Amoco Corporation	Oxygen scavenging condensation copolymers for bottles and packaging articles
US6254803B1 (en)	1998-03-25	2001-07-03	Cryovac, Inc.	Oxygen scavengers with reduced oxidation products for use in plastic films
JP2001010675A (ja) *	1999-06-29	2001-01-16	Tsutsumi Yotaro	酸素吸収性包装体
US6423776B1 (en)	2000-05-02	2002-07-23	Honeywell International Inc.	Oxygen scavenging high barrier polyamide compositions for packaging applications
US20030146536A1 (en) *	2001-12-07	2003-08-07	General Electric Company	Color enhancement for resin blends
US20040013833A1 (en) *	2002-03-21	2004-01-22	Lee Robert A.	Compatibilized polyester/polyamide blends
CN100584890C (zh) *	2003-07-24	2010-01-27	可乐丽股份有限公司	氧吸收体及其制造方法以及使用该吸收体的包装材料
AU2005314117A1 (en) *	2004-12-06	2006-06-15	Constar International Inc.	Blends of oxygen scavenging polyamides with polyesters which contain zinc and cobalt
MX2007009868A (es) *	2005-02-15	2007-11-06	Constar Int Inc	"composiciones depuradoras de ox??geno y envase que comprende dichas composiciones".
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2011
- 2011-05-06 US US13/102,747 patent/US20120283366A1/en not_active Abandoned
2012
- 2012-04-19 MX MX2013012764A patent/MX342242B/es active IP Right Grant
- 2012-04-19 PL PL12719165T patent/PL2705081T3/pl unknown
- 2012-04-19 WO PCT/US2012/034235 patent/WO2012154379A1/en not_active Ceased
- 2012-04-19 CN CN201280022075.9A patent/CN103502341B/zh not_active Expired - Fee Related
- 2012-04-19 EP EP12719165.8A patent/EP2705081B1/en not_active Not-in-force
- 2012-04-19 CA CA2834261A patent/CA2834261A1/en not_active Abandoned
- 2012-04-19 ES ES12719165.8T patent/ES2552753T3/es active Active
- 2012-04-19 JP JP2014509304A patent/JP5954598B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
JP2014514421A (ja)	2014-06-19
MX2013012764A (es)	2013-11-21
PL2705081T3 (pl)	2016-01-29
JP5954598B2 (ja)	2016-07-20
WO2012154379A1 (en)	2012-11-15
EP2705081A1 (en)	2014-03-12
EP2705081B1 (en)	2015-08-19
US20120283366A1 (en)	2012-11-08
CN103502341B (zh)	2015-11-25
CN103502341A (zh)	2014-01-08
CA2834261A1 (en)	2012-11-15
MX342242B (es)	2016-09-21

Publication	Publication Date	Title
ES2552753T3 (es)	2015-12-02	Composiciones activadas para la eliminación del oxígeno en envases plásticos
ES2542405T3 (es)	2015-08-05	Aditivos para la eliminación de oxígeno en envases plásticos
ES2688146T3 (es)	2018-10-31	Composiciones de captación de oxígeno para contenedores de plástico
US20260042913A1 (en)	2026-02-12	Oxygen scavenging compositions requiring no induction period
ES2690738T3 (es)	2018-11-22	Composiciones captadoras de oxígeno bajas en fósforo que no requieren período de inducción
ES2668080T3 (es)	2018-05-16	Depuradores de oxígeno, composición que comprende los depuradores y artículos producidos a partir de las composiciones
US20160130433A1 (en)	2016-05-12	Oxygen scavenging compositions requiring no induction period
US10208200B2 (en)	2019-02-19	Dual oxygen-scavenging compositions requiring no induction period