ES2556971T3 - Process for the treatment of textile fiber materials - Google Patents
Process for the treatment of textile fiber materials Download PDFInfo
- Publication number
- ES2556971T3 ES2556971T3 ES06118792.8T ES06118792T ES2556971T3 ES 2556971 T3 ES2556971 T3 ES 2556971T3 ES 06118792 T ES06118792 T ES 06118792T ES 2556971 T3 ES2556971 T3 ES 2556971T3
- Authority
- ES
- Spain
- Prior art keywords
- compound
- formula
- treatment
- mixture
- fiber materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 4
- 239000002657 fibrous material Substances 0.000 title 1
- 239000004753 textile Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract description 14
- 239000000203 mixture Substances 0.000 abstract description 10
- 239000003599 detergent Substances 0.000 abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001768 cations Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 108010059892 Cellulase Proteins 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229940106157 cellulase Drugs 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 229960004585 etidronic acid Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
una composición detergente que comprende al menos un compuesto de fórmula**Fórmula** en donde M es hidrógeno o un catión, junto con al menos un compuesto de fórmula**Fórmula** en donde, R6 y R7, independientemente uno de otro, son hidrógeno, alquilo de 1 a 8 átomos de carbono, alcoxi de 1 a 8 átomos de carbono o halógeno, y M es como se definió anteriormente bajo las fórmulas (1) a (4).a detergent composition comprising at least one compound of formula ** Formula ** wherein M is hydrogen or a cation, together with at least one compound of formula ** Formula ** wherein, R6 and R7, independently of each other, they are hydrogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms or halogen, and M is as defined above under formulas (1) to (4).
Description
- A TO
- B B
- Zeolita A Zeolite A
- ---- 20 g ---- 20 g
- Carbonato de sodio Sodium carbonate
- 15 g 15 g 15 g 15 g
- Silicato de sodio Sodium silicate
- 5 g 5 g 5 g 5 g
- Sulfato de sodio Sodium sulfate
- 11 g 17 g 11 g 17 g
- Celulasa Cellulase
- 1,5 g ----- 1.5 g -----
- Proteasa Protease
- ---- 1,5 g ---- 1.5 g
- Policarboxilato (aditivo auxiliar) Polycarboxylate (auxiliary additive)
- ---- 4 g ---- 4 g
- Carboximetilcelulosa Carboxymethyl cellulose
- 2 g 2 g 2 g 2 g
- Perfume Fragrance
- 0,1 g 0,1 g 0.1 g 0.1 g
- Agua Water
- 5 g 5 g 5 g 5 g
- Blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado Fluorescent bleach or mixture of fluorescent bleach used
- X g X g X g X g
Tabla 3b (Polvos de lavado utilizados) Table 3b (Washing powders used)
- Cantidad del blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado Amount of fluorescent bleach or mixture of fluorescent bleach used
- Polvo de lavado Washing powder
- Compuesto del Ejemplo de preparación 1 Compound of Preparation Example 1
- 0,3 g B 0.3 g B
- Mezcla del compuesto del Ejemplo de preparación 2 y el compuesto de la fórmula (8) [relación en peso 1:1] Mixture of the compound of Preparation Example 2 and the compound of the formula (8) [1: 1 weight ratio]
- 0,2 g B 0.2 g B
- Mezcla del compuesto del Ejemplo de preparación 3 y el compuesto de la fórmula (8) [relación en peso 1:2] Mixture of the compound of Preparation Example 3 and the compound of the formula (8) [1: 2 weight ratio]
- 0,5 g B 0.5 g B
Constitución del compuesto de fórmula (8): Constitution of the compound of formula (8):
Los tejidos de algodón lavados con los detergentes dados en la Tabla 3b de acuerdo con el procedimiento general muestran buenas propiedades de blancura. Ejemplo de aplicación 2: Procedimiento general: Cotton fabrics washed with the detergents given in Table 3b according to the general procedure show good whiteness properties. Application example 2: General procedure:
11 eleven
Se prepara un licor de lavado disolviendo 0,8 g de un polvo de lavado en 200 ml de agua del grifo. Se añaden 10 g de una tela de algodón blanqueado al baño y se lava a 30ºC durante 15 minutos y luego se enjuaga, se seca en forma centrífuga y se plancha a 160ºC. A wash liquor is prepared by dissolving 0.8 g of a washing powder in 200 ml of tap water. 10 g of a bleached cotton cloth are added to the bath and washed at 30 ° C for 15 minutes and then rinsed, dried in a centrifugal manner and ironed at 160 ° C.
Se usan los siguientes polvos de lavado (las cantidades dadas en las siguientes Tablas 4a y 4b son en porcentaje en peso, con base en el peso total del detergente): The following washing powders are used (the amounts given in the following Tables 4a and 4b are in percent by weight, based on the total weight of the detergent):
Tabla 4a (Ingredientes de los polvos de lavado C y D) Table 4a (Ingredients of washing powders C and D)
- C C
- D D
- Lauril-benceno-sulfonato de sodio (LAS) Sodium Lauryl Benzene Sulphonate (LAS)
- 8% 8% 8% 8%
- Lauril éter sulfato de sodio (AES) Sodium Lauryl Ether Sulfate (AES)
- 3% 3% 3% 3%
- Dobanol 23-6.5 (alcohol etoxilado no iónico) Dobanol 23-6.5 (non-ionic ethoxylated alcohol)
- 5% 5% 5% 5%
- Zeolita A Zeolite A
- 20% 20% twenty% twenty%
- Policarboxilato (aditivo auxiliar) Polycarboxylate (auxiliary additive)
- 5% 5% 5% 5%
- Sosa bland
- 18% 18% 18% 18%
- Silicato de sodio Sodium silicate
- 4% 4% 4% 4%
- Sulfato de sodio Sodium sulfate
- 5% 5% 5% 5%
- Ácido hidroxi etano difosfónico (agente complejante) Hydroxy ethane diphosphonic acid (complexing agent)
- 0,5% 0,5% 0.5% 0.5%
- Celulasa Cellulase
- 1,5% ----- 1.5% -----
- Proteasa Protease
- ---- 1,5% ---- 1.5%
- Carboximetilcelulosa Carboxymethyl cellulose
- 1% 1% one% one%
- Perborato de sodio monohidratado Sodium perborate monohydrate
- 15% 15% fifteen% fifteen%
- TAED TAED
- 5% 5% 5% 5%
- Jabón Soap
- 2% 2% 2% 2%
- Blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado Fluorescent bleach or mixture of fluorescent bleach used
- X% X% X% X%
- En cada uno de los detergentes anteriores se usa una cantidad suficiente de agua para completar el 100%. In each of the above detergents a sufficient amount of water is used to complete 100%.
Tabla 4b (Polvos de lavado usados) Table 4b (Used washing powders)
- Cantidad del blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado Amount of fluorescent bleach or mixture of fluorescent bleach used
- Polvo de lavado Washing powder
- Compuesto del Ejemplo de preparación 2 Compound of Preparation Example 2
- 0,4% C 0.4% C
- Mezcla del compuesto del Ejemplo de preparación 1 y el compuesto de la fórmula (8) [relación en peso 9:1] Mixture of the compound of Preparation Example 1 and the compound of the formula (8) [9: 1 weight ratio]
- 0,3% D 0.3% D
12 12
- Cantidad del blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado Amount of fluorescent bleach or mixture of fluorescent bleach used
- Polvo de lavado Washing powder
- Mezcla del compuesto del Ejemplo de preparación 4 y el compuesto de la fórmula (8) [relación en peso 1:5] Mixture of the compound of Preparation Example 4 and the compound of the formula (8) [1: 5 weight ratio]
- 0,2% D 0.2% D
En cuanto a la constitución de los compuestos de las fórmulas (8) véase el Ejemplo de aplicación 1. As for the constitution of the compounds of the formulas (8) see Application Example 1.
Las telas de algodón lavadas con los detergentes suministrados en la Tabla 4b de acuerdo con el procedimiento general muestran buenas propiedades de blancura. Cotton fabrics washed with the detergents provided in Table 4b according to the general procedure show good whiteness properties.
13 13
Claims (1)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405136 | 2002-02-25 | ||
| EP02405136 | 2002-02-25 | ||
| EP02405876 | 2002-10-11 | ||
| EP02405876 | 2002-10-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2556971T3 true ES2556971T3 (en) | 2016-01-21 |
Family
ID=27758773
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06118792.8T Expired - Lifetime ES2556971T3 (en) | 2002-02-25 | 2003-02-18 | Process for the treatment of textile fiber materials |
| ES03706527T Expired - Lifetime ES2271534T3 (en) | 2002-02-25 | 2003-02-18 | PROCEDURE FOR THE TREATMENT OF TEXTILE FIBER MATERIALS. |
| ES03702652T Expired - Lifetime ES2271529T3 (en) | 2002-02-25 | 2003-02-18 | PROCEDURE FOR THE TREATMENT OF TEXTILE FIBER MATERIALS. |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03706527T Expired - Lifetime ES2271534T3 (en) | 2002-02-25 | 2003-02-18 | PROCEDURE FOR THE TREATMENT OF TEXTILE FIBER MATERIALS. |
| ES03702652T Expired - Lifetime ES2271529T3 (en) | 2002-02-25 | 2003-02-18 | PROCEDURE FOR THE TREATMENT OF TEXTILE FIBER MATERIALS. |
Country Status (12)
| Country | Link |
|---|---|
| EP (4) | EP1478724B1 (en) |
| JP (2) | JP4567976B2 (en) |
| CN (2) | CN1294247C (en) |
| AR (3) | AR038583A1 (en) |
| AT (2) | ATE340847T1 (en) |
| AU (2) | AU2003205777B2 (en) |
| BR (3) | BR0306184B1 (en) |
| DE (2) | DE60308485T2 (en) |
| ES (3) | ES2556971T3 (en) |
| TW (2) | TWI324177B (en) |
| WO (2) | WO2003070869A1 (en) |
| ZA (2) | ZA200402942B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003070869A1 (en) * | 2002-02-25 | 2003-08-28 | Ciba Specialty Chemicals Holding Inc. | Process for the treatment of textile fibre materials |
| CN1764714B (en) | 2003-03-24 | 2011-01-12 | 西巴特殊化学品控股有限公司 | detergent composition |
| DE602005006751D1 (en) * | 2004-01-20 | 2008-06-26 | Ciba Holding Inc | |
| JP2007533812A (en) * | 2004-04-20 | 2007-11-22 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | Amphoteric fluorescent whitening agents in detergent formulations |
| KR101253657B1 (en) * | 2004-08-30 | 2013-04-10 | 시바 홀딩 인코포레이티드 | Shading Process |
| WO2007135003A1 (en) * | 2006-05-23 | 2007-11-29 | Ciba Holding Inc. | A detergent composition for textile fibre materials |
| CN109158366B (en) * | 2014-01-26 | 2021-08-24 | 艺康美国股份有限公司 | In-situ cleaning process and in-situ cleaning system |
| EP3099831B1 (en) | 2014-01-31 | 2021-04-07 | Goldcorp Inc. | Process for separation of at least one metal sulfide comprising arsenic and/or antimony from a mixed sulfide concentrate |
| CN105001671A (en) * | 2015-06-29 | 2015-10-28 | 纳爱斯丽水日化有限公司 | Compound brightening agent and washing agent composition containing compound brightening agent |
| CN107857738A (en) * | 2017-11-28 | 2018-03-30 | 贺州学院 | The synthesis and application of hexadecylamino pyrrolotriazine derivatives |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1107667B (en) * | 1959-07-30 | 1961-05-31 | Wolfen Filmfab Veb | Process for the preparation of optical brightening agents |
| JPS515308A (en) * | 1974-07-03 | 1976-01-17 | Kao Corp | HAKUSHOKUGOSEISENZAISOSEIBUTSU |
| EP0003568B1 (en) * | 1978-02-14 | 1982-06-02 | Bayer Ag | Composition comprising optical brightening agents for use in the whitening of paper coating compositions |
| US4364845A (en) * | 1978-07-17 | 1982-12-21 | Ciba-Geigy Corporation | Concentrated aqueous solutions of sulfo group-containing fluorescent brighteners which are stable on storage |
| JPS5817199A (en) * | 1981-07-23 | 1983-02-01 | 花王株式会社 | Detergent composition |
| US4460485A (en) * | 1983-07-15 | 1984-07-17 | Lever Brothers Company | Polyester fabric conditioning and whitening composition |
| GB2158454B (en) | 1984-04-06 | 1988-05-18 | Colgate Palmolive Co | Liquid laundry detergent composition |
| GB9108136D0 (en) | 1991-04-17 | 1991-06-05 | Unilever Plc | Concentrated detergent powder compositions |
| US5466802A (en) * | 1993-11-10 | 1995-11-14 | The Procter & Gamble Company | Detergent compositions which provide dye transfer inhibition benefits |
| DE4416438A1 (en) | 1994-05-10 | 1995-11-16 | Basf Ag | Mononuclear or multinuclear metal complexes and their use as bleaching and oxidation catalysts |
| PT682145E (en) * | 1994-05-12 | 2005-01-31 | Ciba Sc Holding Ag | TEXTILE TREATMENT |
| GB9409465D0 (en) * | 1994-05-12 | 1994-06-29 | Ciba Geigy Ag | Protective use |
| DE4443177A1 (en) | 1994-12-05 | 1996-06-13 | Henkel Kgaa | Activator mixtures for inorganic per compounds |
| GB9503474D0 (en) * | 1995-02-22 | 1995-04-12 | Ciba Geigy Ag | Compounds and their use |
| ATE206073T1 (en) | 1995-12-29 | 2001-10-15 | Novozymes As | PARTICLES CONTAINING ENZYME AND LIQUID DETERGENT CONCENTRATE |
| JPH09241693A (en) * | 1996-03-05 | 1997-09-16 | Lion Corp | Method for producing high bulk density granular detergent composition |
| ZA974226B (en) * | 1996-05-17 | 1998-12-28 | Procter & Gamble | Detergent composition |
| GB9610832D0 (en) * | 1996-05-23 | 1996-07-31 | Ciba Geigy Ag | Stilbene compounds and their use |
| GB2318360A (en) * | 1996-10-15 | 1998-04-22 | Ciba Geigy Ag | Fluorescent whitening agent formulation |
| GB9626851D0 (en) * | 1996-12-24 | 1997-02-12 | Ciba Geigy Ag | Compounds |
| ES2255503T3 (en) | 1999-07-14 | 2006-07-01 | Ciba Specialty Chemicals Holding Inc. | METAL COMPLEXES OF TRIPODAL LIGANDS. |
| DE60033522T8 (en) | 1999-07-28 | 2008-03-27 | Ciba Specialty Chemicals Holding Inc. | WATER-SOLUBLE GRANULES OF MANGANIC COMPLEXES FROM THE SALT TYPE |
| US6294047B1 (en) * | 1999-07-30 | 2001-09-25 | Institute Of Paper | Methods for reducing fluorescence in paper-containing samples |
| JP2001342495A (en) * | 2000-06-05 | 2001-12-14 | Kao Corp | Detergent composition |
| ES2320735T3 (en) | 2000-07-04 | 2009-05-28 | Ciba Holding Inc. | METHOD FOR TREATING FIBER MATERIALS. |
| JP4414653B2 (en) | 2001-04-30 | 2010-02-10 | チバ ホールディング インコーポレーテッド | Metal complex compounds and their use as oxidation catalysts |
| WO2003070869A1 (en) * | 2002-02-25 | 2003-08-28 | Ciba Specialty Chemicals Holding Inc. | Process for the treatment of textile fibre materials |
-
2003
- 2003-02-18 WO PCT/EP2003/001618 patent/WO2003070869A1/en not_active Ceased
- 2003-02-18 ES ES06118792.8T patent/ES2556971T3/en not_active Expired - Lifetime
- 2003-02-18 EP EP03706527A patent/EP1478724B1/en not_active Expired - Lifetime
- 2003-02-18 EP EP06118792.8A patent/EP1715029B1/en not_active Expired - Lifetime
- 2003-02-18 AU AU2003205777A patent/AU2003205777B2/en not_active Ceased
- 2003-02-18 DE DE60308485T patent/DE60308485T2/en not_active Expired - Lifetime
- 2003-02-18 ES ES03706527T patent/ES2271534T3/en not_active Expired - Lifetime
- 2003-02-18 JP JP2003569764A patent/JP4567976B2/en not_active Expired - Fee Related
- 2003-02-18 BR BRPI0306184-1B1A patent/BR0306184B1/en active IP Right Grant
- 2003-02-18 WO PCT/EP2003/001619 patent/WO2003070870A1/en not_active Ceased
- 2003-02-18 CN CNB038016044A patent/CN1294247C/en not_active Expired - Lifetime
- 2003-02-18 DE DE60308661T patent/DE60308661T2/en not_active Expired - Lifetime
- 2003-02-18 JP JP2003569763A patent/JP4567975B2/en not_active Expired - Fee Related
- 2003-02-18 EP EP06118810A patent/EP1724333A1/en not_active Withdrawn
- 2003-02-18 AT AT03702652T patent/ATE340847T1/en active
- 2003-02-18 AT AT03706527T patent/ATE340242T1/en active
- 2003-02-18 BR BRPI0306187-6A patent/BRPI0306187B1/en unknown
- 2003-02-18 ES ES03702652T patent/ES2271529T3/en not_active Expired - Lifetime
- 2003-02-18 CN CNB038016168A patent/CN1294248C/en not_active Expired - Lifetime
- 2003-02-18 EP EP03702652A patent/EP1485460B1/en not_active Expired - Lifetime
- 2003-02-18 BR BR0306187-6A patent/BR0306187A/en active IP Right Grant
- 2003-02-18 AU AU2003208870A patent/AU2003208870B2/en not_active Ceased
- 2003-02-21 AR ARP030100573A patent/AR038583A1/en active IP Right Grant
- 2003-02-21 AR ARP030100572A patent/AR038582A1/en active IP Right Grant
- 2003-02-24 TW TW092103773A patent/TWI324177B/en not_active IP Right Cessation
- 2003-02-24 TW TW092103771A patent/TWI332045B/en not_active IP Right Cessation
-
2004
- 2004-04-19 ZA ZA2004/02942A patent/ZA200402942B/en unknown
- 2004-04-19 ZA ZA2004/02941A patent/ZA200402941B/en unknown
-
2007
- 2007-08-14 AR ARP070103604A patent/AR067835A2/en active IP Right Grant
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