ES2556971T3 - Proceso para el tratamiento de materiales de fibras textiles - Google Patents
Proceso para el tratamiento de materiales de fibras textiles Download PDFInfo
- Publication number
- ES2556971T3 ES2556971T3 ES06118792.8T ES06118792T ES2556971T3 ES 2556971 T3 ES2556971 T3 ES 2556971T3 ES 06118792 T ES06118792 T ES 06118792T ES 2556971 T3 ES2556971 T3 ES 2556971T3
- Authority
- ES
- Spain
- Prior art keywords
- compound
- formula
- treatment
- mixture
- fiber materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 4
- 239000002657 fibrous material Substances 0.000 title 1
- 239000004753 textile Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract description 14
- 239000000203 mixture Substances 0.000 abstract description 10
- 239000003599 detergent Substances 0.000 abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001768 cations Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 108010059892 Cellulase Proteins 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 229940106157 cellulase Drugs 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 229960004585 etidronic acid Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
una composición detergente que comprende al menos un compuesto de fórmula**Fórmula** en donde M es hidrógeno o un catión, junto con al menos un compuesto de fórmula**Fórmula** en donde, R6 y R7, independientemente uno de otro, son hidrógeno, alquilo de 1 a 8 átomos de carbono, alcoxi de 1 a 8 átomos de carbono o halógeno, y M es como se definió anteriormente bajo las fórmulas (1) a (4).
Description
- A
- B
- Zeolita A
- ---- 20 g
- Carbonato de sodio
- 15 g 15 g
- Silicato de sodio
- 5 g 5 g
- Sulfato de sodio
- 11 g 17 g
- Celulasa
- 1,5 g -----
- Proteasa
- ---- 1,5 g
- Policarboxilato (aditivo auxiliar)
- ---- 4 g
- Carboximetilcelulosa
- 2 g 2 g
- Perfume
- 0,1 g 0,1 g
- Agua
- 5 g 5 g
- Blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado
- X g X g
Tabla 3b (Polvos de lavado utilizados)
- Cantidad del blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado
- Polvo de lavado
- Compuesto del Ejemplo de preparación 1
- 0,3 g B
- Mezcla del compuesto del Ejemplo de preparación 2 y el compuesto de la fórmula (8) [relación en peso 1:1]
- 0,2 g B
- Mezcla del compuesto del Ejemplo de preparación 3 y el compuesto de la fórmula (8) [relación en peso 1:2]
- 0,5 g B
Constitución del compuesto de fórmula (8):
Los tejidos de algodón lavados con los detergentes dados en la Tabla 3b de acuerdo con el procedimiento general muestran buenas propiedades de blancura. Ejemplo de aplicación 2: Procedimiento general:
11
Se prepara un licor de lavado disolviendo 0,8 g de un polvo de lavado en 200 ml de agua del grifo. Se añaden 10 g de una tela de algodón blanqueado al baño y se lava a 30ºC durante 15 minutos y luego se enjuaga, se seca en forma centrífuga y se plancha a 160ºC.
Se usan los siguientes polvos de lavado (las cantidades dadas en las siguientes Tablas 4a y 4b son en porcentaje en peso, con base en el peso total del detergente):
Tabla 4a (Ingredientes de los polvos de lavado C y D)
- C
- D
- Lauril-benceno-sulfonato de sodio (LAS)
- 8% 8%
- Lauril éter sulfato de sodio (AES)
- 3% 3%
- Dobanol 23-6.5 (alcohol etoxilado no iónico)
- 5% 5%
- Zeolita A
- 20% 20%
- Policarboxilato (aditivo auxiliar)
- 5% 5%
- Sosa
- 18% 18%
- Silicato de sodio
- 4% 4%
- Sulfato de sodio
- 5% 5%
- Ácido hidroxi etano difosfónico (agente complejante)
- 0,5% 0,5%
- Celulasa
- 1,5% -----
- Proteasa
- ---- 1,5%
- Carboximetilcelulosa
- 1% 1%
- Perborato de sodio monohidratado
- 15% 15%
- TAED
- 5% 5%
- Jabón
- 2% 2%
- Blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado
- X% X%
- En cada uno de los detergentes anteriores se usa una cantidad suficiente de agua para completar el 100%.
Tabla 4b (Polvos de lavado usados)
- Cantidad del blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado
- Polvo de lavado
- Compuesto del Ejemplo de preparación 2
- 0,4% C
- Mezcla del compuesto del Ejemplo de preparación 1 y el compuesto de la fórmula (8) [relación en peso 9:1]
- 0,3% D
12
- Cantidad del blanqueador fluorescente o mezcla del blanqueador fluorescente utilizado
- Polvo de lavado
- Mezcla del compuesto del Ejemplo de preparación 4 y el compuesto de la fórmula (8) [relación en peso 1:5]
- 0,2% D
En cuanto a la constitución de los compuestos de las fórmulas (8) véase el Ejemplo de aplicación 1.
Las telas de algodón lavadas con los detergentes suministrados en la Tabla 4b de acuerdo con el procedimiento general muestran buenas propiedades de blancura.
13
Claims (1)
-
imagen1 imagen2 imagen3
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405136 | 2002-02-25 | ||
| EP02405136 | 2002-02-25 | ||
| EP02405876 | 2002-10-11 | ||
| EP02405876 | 2002-10-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2556971T3 true ES2556971T3 (es) | 2016-01-21 |
Family
ID=27758773
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03706527T Expired - Lifetime ES2271534T3 (es) | 2002-02-25 | 2003-02-18 | Procedimiento para el tratamiento de materiales de fibras textiles. |
| ES06118792.8T Expired - Lifetime ES2556971T3 (es) | 2002-02-25 | 2003-02-18 | Proceso para el tratamiento de materiales de fibras textiles |
| ES03702652T Expired - Lifetime ES2271529T3 (es) | 2002-02-25 | 2003-02-18 | Procedimiento para el tratamiento de materiales de fibra textil. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03706527T Expired - Lifetime ES2271534T3 (es) | 2002-02-25 | 2003-02-18 | Procedimiento para el tratamiento de materiales de fibras textiles. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03702652T Expired - Lifetime ES2271529T3 (es) | 2002-02-25 | 2003-02-18 | Procedimiento para el tratamiento de materiales de fibra textil. |
Country Status (12)
| Country | Link |
|---|---|
| EP (4) | EP1715029B1 (es) |
| JP (2) | JP4567975B2 (es) |
| CN (2) | CN1294247C (es) |
| AR (3) | AR038582A1 (es) |
| AT (2) | ATE340242T1 (es) |
| AU (2) | AU2003205777B2 (es) |
| BR (3) | BR0306184B1 (es) |
| DE (2) | DE60308485T2 (es) |
| ES (3) | ES2271534T3 (es) |
| TW (2) | TWI324177B (es) |
| WO (2) | WO2003070870A1 (es) |
| ZA (2) | ZA200402941B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4567975B2 (ja) * | 2002-02-25 | 2010-10-27 | チバ ホールディング インコーポレーテッド | 繊維材料の処理の方法 |
| CN1764714B (zh) | 2003-03-24 | 2011-01-12 | 西巴特殊化学品控股有限公司 | 洗涤剂组合物 |
| ATE395404T1 (de) * | 2004-01-20 | 2008-05-15 | Ciba Holding Inc | Triazinylaminostilbendisulfonsäuremischungen |
| AU2005235734A1 (en) * | 2004-04-20 | 2005-11-03 | Ciba Specialty Chemicals Holding Inc. | Amphoteric fluorescent whitening agents in detergent formulations |
| MX2007002350A (es) * | 2004-08-30 | 2007-04-23 | Ciba Sc Holding Ag | Proceso de matizado. |
| ATE483011T1 (de) * | 2006-05-23 | 2010-10-15 | Basf Se | Waschmittel für textilfaserstoffe |
| CN109158366B (zh) * | 2014-01-26 | 2021-08-24 | 艺康美国股份有限公司 | 原位清洗工艺和原位清洗系统 |
| PE20211337A1 (es) | 2014-01-31 | 2021-07-26 | Goldcorp Inc | Proceso para la separacion y recuperacion de sulfuros de metales de una mena o concentrado de sulfuros mixtos |
| CN105001671A (zh) * | 2015-06-29 | 2015-10-28 | 纳爱斯丽水日化有限公司 | 一种复合型增白剂及含所述增白剂的洗涤剂组合物 |
| CN107857738A (zh) * | 2017-11-28 | 2018-03-30 | 贺州学院 | 十六烷基氨基三嗪衍生物的合成与应用 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1107667B (de) * | 1959-07-30 | 1961-05-31 | Wolfen Filmfab Veb | Verfahren zur Herstellung von optischen Aufhellungsmitteln |
| JPS515308A (ja) * | 1974-07-03 | 1976-01-17 | Kao Corp | Hakushokugoseisenzaisoseibutsu |
| EP0003568B1 (de) * | 1978-02-14 | 1982-06-02 | Bayer Ag | Zubereitung optischer Aufheller zum Weisstönen von Papierstreichmassen |
| US4364845A (en) * | 1978-07-17 | 1982-12-21 | Ciba-Geigy Corporation | Concentrated aqueous solutions of sulfo group-containing fluorescent brighteners which are stable on storage |
| JPS5817199A (ja) * | 1981-07-23 | 1983-02-01 | 花王株式会社 | 洗浄剤組成物 |
| US4460485A (en) | 1983-07-15 | 1984-07-17 | Lever Brothers Company | Polyester fabric conditioning and whitening composition |
| GB2158454B (en) | 1984-04-06 | 1988-05-18 | Colgate Palmolive Co | Liquid laundry detergent composition |
| GB9108136D0 (en) | 1991-04-17 | 1991-06-05 | Unilever Plc | Concentrated detergent powder compositions |
| US5466802A (en) * | 1993-11-10 | 1995-11-14 | The Procter & Gamble Company | Detergent compositions which provide dye transfer inhibition benefits |
| DE4416438A1 (de) | 1994-05-10 | 1995-11-16 | Basf Ag | Ein- oder mehrkernige Metall-Komplexe und ihre Verwendung als Bleich- und Oxidationskatalysatoren |
| GB9409465D0 (en) * | 1994-05-12 | 1994-06-29 | Ciba Geigy Ag | Protective use |
| EP0682145B1 (en) * | 1994-05-12 | 2004-08-25 | Ciba SC Holding AG | Textile treatment |
| DE4443177A1 (de) | 1994-12-05 | 1996-06-13 | Henkel Kgaa | Aktivatormischungen für anorganische Perverbindungen |
| GB9503474D0 (en) * | 1995-02-22 | 1995-04-12 | Ciba Geigy Ag | Compounds and their use |
| PT873183E (pt) | 1995-12-29 | 2002-03-28 | Novozymes As | Particulas que contem enzimas e concentrados de detergente liquido |
| JPH09241693A (ja) * | 1996-03-05 | 1997-09-16 | Lion Corp | 高嵩密度粒状洗剤組成物の製造方法 |
| ZA974226B (en) * | 1996-05-17 | 1998-12-28 | Procter & Gamble | Detergent composition |
| GB9610832D0 (en) * | 1996-05-23 | 1996-07-31 | Ciba Geigy Ag | Stilbene compounds and their use |
| GB2318360A (en) * | 1996-10-15 | 1998-04-22 | Ciba Geigy Ag | Fluorescent whitening agent formulation |
| GB9626851D0 (en) * | 1996-12-24 | 1997-02-12 | Ciba Geigy Ag | Compounds |
| US6800775B1 (en) | 1999-07-14 | 2004-10-05 | Ciba Specialty Chemicals Corporation | Metal complexes of tripodal ligands |
| CN1280394C (zh) | 1999-07-28 | 2006-10-18 | 西巴特殊化学品控股有限公司 | 水杨型锰配合物的水溶性颗粒 |
| US6294047B1 (en) * | 1999-07-30 | 2001-09-25 | Institute Of Paper | Methods for reducing fluorescence in paper-containing samples |
| JP2001342495A (ja) * | 2000-06-05 | 2001-12-14 | Kao Corp | 洗剤組成物 |
| AU2001289609B2 (en) | 2000-07-04 | 2006-10-12 | Ciba Specialty Chemicals Holding Inc. | Method for treating textile fibre materials or leather |
| JP4414653B2 (ja) | 2001-04-30 | 2010-02-10 | チバ ホールディング インコーポレーテッド | 酸化触媒としての金属錯体化合物及びその使用 |
| JP4567975B2 (ja) * | 2002-02-25 | 2010-10-27 | チバ ホールディング インコーポレーテッド | 繊維材料の処理の方法 |
-
2003
- 2003-02-18 JP JP2003569763A patent/JP4567975B2/ja not_active Expired - Fee Related
- 2003-02-18 CN CNB038016044A patent/CN1294247C/zh not_active Expired - Lifetime
- 2003-02-18 AU AU2003205777A patent/AU2003205777B2/en not_active Ceased
- 2003-02-18 ES ES03706527T patent/ES2271534T3/es not_active Expired - Lifetime
- 2003-02-18 WO PCT/EP2003/001619 patent/WO2003070870A1/en not_active Ceased
- 2003-02-18 WO PCT/EP2003/001618 patent/WO2003070869A1/en not_active Ceased
- 2003-02-18 EP EP06118792.8A patent/EP1715029B1/en not_active Expired - Lifetime
- 2003-02-18 DE DE60308485T patent/DE60308485T2/de not_active Expired - Lifetime
- 2003-02-18 EP EP06118810A patent/EP1724333A1/en not_active Withdrawn
- 2003-02-18 EP EP03702652A patent/EP1485460B1/en not_active Expired - Lifetime
- 2003-02-18 AT AT03706527T patent/ATE340242T1/de active
- 2003-02-18 AU AU2003208870A patent/AU2003208870B2/en not_active Ceased
- 2003-02-18 EP EP03706527A patent/EP1478724B1/en not_active Expired - Lifetime
- 2003-02-18 BR BRPI0306184-1B1A patent/BR0306184B1/pt active IP Right Grant
- 2003-02-18 DE DE60308661T patent/DE60308661T2/de not_active Expired - Lifetime
- 2003-02-18 BR BR0306187-6A patent/BR0306187A/pt active IP Right Grant
- 2003-02-18 CN CNB038016168A patent/CN1294248C/zh not_active Expired - Lifetime
- 2003-02-18 BR BRPI0306187-6A patent/BRPI0306187B1/pt unknown
- 2003-02-18 AT AT03702652T patent/ATE340847T1/de active
- 2003-02-18 ES ES06118792.8T patent/ES2556971T3/es not_active Expired - Lifetime
- 2003-02-18 ES ES03702652T patent/ES2271529T3/es not_active Expired - Lifetime
- 2003-02-18 JP JP2003569764A patent/JP4567976B2/ja not_active Expired - Fee Related
- 2003-02-21 AR ARP030100572A patent/AR038582A1/es active IP Right Grant
- 2003-02-21 AR ARP030100573A patent/AR038583A1/es active IP Right Grant
- 2003-02-24 TW TW092103773A patent/TWI324177B/zh not_active IP Right Cessation
- 2003-02-24 TW TW092103771A patent/TWI332045B/zh not_active IP Right Cessation
-
2004
- 2004-04-19 ZA ZA2004/02941A patent/ZA200402941B/en unknown
- 2004-04-19 ZA ZA2004/02942A patent/ZA200402942B/en unknown
-
2007
- 2007-08-14 AR ARP070103604A patent/AR067835A2/es active IP Right Grant
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