ES2571946T3 - Procedimiento para la fabricación de artículos de polímeros de tiol-eno - Google Patents
Procedimiento para la fabricación de artículos de polímeros de tiol-enoInfo
- Publication number
- ES2571946T3 ES2571946T3 ES11766978T ES11766978T ES2571946T3 ES 2571946 T3 ES2571946 T3 ES 2571946T3 ES 11766978 T ES11766978 T ES 11766978T ES 11766978 T ES11766978 T ES 11766978T ES 2571946 T3 ES2571946 T3 ES 2571946T3
- Authority
- ES
- Spain
- Prior art keywords
- article
- thiol
- groups
- carbon
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract 4
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- -1 bromoacetyl Chemical group 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- NQTADLQHYWFPDB-UHFFFAOYSA-N N-Hydroxysuccinimide Chemical compound ON1C(=O)CCC1=O NQTADLQHYWFPDB-UHFFFAOYSA-N 0.000 abstract 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- HAXFWIACAGNFHA-UHFFFAOYSA-N aldrithiol Chemical compound C=1C=CC=NC=1SSC1=CC=CC=N1 HAXFWIACAGNFHA-UHFFFAOYSA-N 0.000 abstract 1
- 150000001345 alkine derivatives Chemical class 0.000 abstract 1
- 125000003636 chemical group Chemical group 0.000 abstract 1
- 230000002950 deficient Effects 0.000 abstract 1
- 230000006735 deficit Effects 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
- C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
- C08G77/392—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B1/00—Devices without movable or flexible elements, e.g. microcapillary devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C1/00—Manufacture or treatment of devices or systems in or on a substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81C—PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
- B81C3/00—Assembling of devices or systems from individually processed components
- B81C3/001—Bonding of two components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/02—Polythioethers
- C08G75/04—Polythioethers from mercapto compounds or metallic derivatives thereof
- C08G75/045—Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/12—Polythioether-ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
- C09D181/02—Polythioethers; Polythioether-ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2201/00—Specific applications of microelectromechanical systems
- B81B2201/05—Microfluidics
- B81B2201/058—Microfluidics not provided for in B81B2201/051 - B81B2201/054
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2201/00—Specific applications of microelectromechanical systems
- B81B2201/06—Bio-MEMS
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Computer Hardware Design (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Micromachines (AREA)
- Graft Or Block Polymers (AREA)
- Laminated Bodies (AREA)
Abstract
Un procedimiento para la fabricación de un artículo, comprendiendo dicho procedimiento las etapas de: a) hacer reaccionar un compuesto que comprende al menos dos grupos tiol y un compuesto que comprende al menos dos dobles enlaces carbono-carbono, con la condición de que la proporción (r1) en la mezcla de reacción entre el número de grupos tiol y el número de dobles enlaces carbono-carbono cumple una de: 0,5 <= r1 <= 0,9 y 1,1 <= r1 <= 2, para obtener un primer artículo intermedio, donde dicho primer artículo intermedio comprende al menos un grupo sin reaccionar seleccionado de un grupo tiol sin reaccionar y un doble enlace carbono-carbono sin reaccionar, b) poner en contacto dicho primer artículo intermedio con un segundo artículo, donde la superficie de dicho segundo artículo comprende al menos parcialmente al menos un resto químico seleccionado de un tiol, y una olefina con déficit de electrones para 0,5 <= r1 <= 0,9 y al menos un resto químico seleccionado de vinilo, norborneno, alilo, alqueno, alquino, acetato de vinilo, vinil naftaleno, vinil benceno, compuestos etilénicamente insaturados, epoxi, isocianato, grupos N-hidroxisuccinimida, bromoacetilo, yodoacetilo, piridildisulfuro, oro, platino y plata para 1,1 <= r1 <= 2 y hacer reaccionar al menos una parte de dichos grupos sin reaccionar en dicho primer artículo intermedio con grupos químicos en dicho segundo artículo para obtener uniones covalentes y formar un artículo final, donde dicha olefina con déficit de electrones es al menos una seleccionada de acrilato, metacrilato, maleato, fumarato y maleimida.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE1000972 | 2010-10-01 | ||
| PCT/EP2011/067228 WO2012042059A1 (en) | 2010-10-01 | 2011-10-03 | Method for the manufacture of articles of thiol-ene polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2571946T3 true ES2571946T3 (es) | 2016-05-27 |
Family
ID=44764146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES11766978T Active ES2571946T3 (es) | 2010-10-01 | 2011-10-03 | Procedimiento para la fabricación de artículos de polímeros de tiol-eno |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8927664B2 (es) |
| EP (1) | EP2622002B1 (es) |
| JP (1) | JP5940070B2 (es) |
| KR (1) | KR101844103B1 (es) |
| CN (1) | CN103221458B (es) |
| DK (1) | DK2622002T3 (es) |
| ES (1) | ES2571946T3 (es) |
| PL (1) | PL2622002T3 (es) |
| WO (1) | WO2012042059A1 (es) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11013835B2 (en) * | 2012-02-03 | 2021-05-25 | Board Of Regents, The University Of Texas System | Processability of polymeric substrates and related methods |
| EP2847245B1 (en) | 2012-05-07 | 2019-01-02 | Mercene Labs AB | Method for the manufacture of coated articles and coated articles |
| JP6023001B2 (ja) | 2013-05-22 | 2016-11-09 | ヘンケルジャパン株式会社 | ホットメルト接着剤 |
| WO2015087714A1 (ja) * | 2013-12-09 | 2015-06-18 | 積水化学工業株式会社 | 表示素子用封止剤 |
| US10137673B2 (en) * | 2013-12-31 | 2018-11-27 | Canon U.S. Life Sciences, Inc. | Methods and systems for continuous flow cell lysis in a microfluidic device |
| JPWO2015156191A1 (ja) * | 2014-04-07 | 2017-04-13 | 株式会社ブリヂストン | 接着シート、その製造方法及び積層体 |
| CN103936962B (zh) * | 2014-04-11 | 2016-10-05 | 烟台大学 | 巯基乙烯基加成合成的环氧固化剂 |
| CN106538086B (zh) * | 2014-04-18 | 2019-12-03 | 汉高股份有限及两合公司 | 电磁干扰屏蔽组合物及其应用方法 |
| JP6466935B2 (ja) * | 2014-07-01 | 2019-02-06 | 株式会社ブリヂストン | 重ね合わせ体、積層体の製造方法、積層体、及び接着組成物膜 |
| JP2017528577A (ja) * | 2014-09-22 | 2017-09-28 | スリーエム イノベイティブ プロパティズ カンパニー | シルセスキオキサンポリマーコア、シルセスキオキサンポリマー外層、及び反応性基を含む硬化性ポリマー |
| WO2016081219A1 (en) * | 2014-11-17 | 2016-05-26 | 3M Innovative Properties Company | Quantum dot article with thiol-alkene matrix |
| ES2811137T3 (es) * | 2015-02-20 | 2021-03-10 | Merck Millipore Ltd | Membranas para cromatografía formadas por reacciones de polimerización clic de tiol-eno o tiol-ino |
| JP6544942B2 (ja) | 2015-02-20 | 2019-07-17 | ヘンケルジャパン株式会社 | ホットメルト接着剤及び使い捨て製品 |
| US10492888B2 (en) * | 2015-07-07 | 2019-12-03 | Align Technology, Inc. | Dental materials using thermoset polymers |
| WO2017117160A1 (en) | 2015-12-31 | 2017-07-06 | 3M Innovative Properties Company | Article comprising particles with quantum dots |
| CN108473861A (zh) | 2015-12-31 | 2018-08-31 | 3M创新有限公司 | 可固化量子点组合物和制品 |
| EP3239197B1 (en) | 2016-04-28 | 2019-01-23 | Samsung Electronics Co., Ltd | Layered structures and quantum dot sheets and electronic devices including the same |
| US20190185629A1 (en) * | 2016-08-05 | 2019-06-20 | Microoptx Inc. | Polymeric devices and methods of making |
| EP3504285A1 (en) | 2016-08-25 | 2019-07-03 | Mercene Labs AB | A method for making three dimensional structures using photolithography and an adhesively bondable material |
| WO2019038324A1 (en) | 2017-08-23 | 2019-02-28 | Mercene Labs Ab | PRIMER OR ADHESIVE COATING COMPOSITION |
| WO2019068127A1 (en) * | 2017-10-06 | 2019-04-11 | Saico Biosystems Kg | METHOD FOR CREATING HYPOXIC CONDITIONS WITHIN A MICROFLUIDIC DEVICE |
| US10975246B2 (en) * | 2018-03-27 | 2021-04-13 | Mercene Coatings Ab | Coating and primer |
| AU2019262641B2 (en) | 2018-05-04 | 2025-02-06 | Align Technology, Inc. | Curable composition for use in a high temperature lithography-based photopolymerization process and method of producing crosslinked polymers therefrom |
| WO2020016332A1 (en) * | 2018-07-18 | 2020-01-23 | Københavns Universitet | Methods for the treatment of thermoset polymers |
| CN109735210A (zh) * | 2018-11-29 | 2019-05-10 | 安徽开林新材料股份有限公司 | 一种含改性碳纳米管的紫外光固化涂料 |
| CN110218323A (zh) * | 2019-06-06 | 2019-09-10 | 南京恒桥化学技术材料有限公司 | 一种含降冰片烯结构单体光固化型组合物及光固化型封装材料 |
| FR3098219B1 (fr) * | 2019-07-05 | 2022-06-03 | Socomore | Prépolymères polythioéthers et leurs utilisations dans des compositions durcissables en particulier dans des mastics |
| CN116323768B (zh) | 2020-10-30 | 2026-03-27 | 莫赛纳涂层公司 | 涂层和底漆 |
| KR20230022644A (ko) * | 2021-08-09 | 2023-02-16 | 삼성에스디아이 주식회사 | 유기발광소자 봉지용 조성물 및 이로부터 제조된 유기층을 포함하는 유기발광소자 표시장치 |
| CN113910505A (zh) * | 2021-09-08 | 2022-01-11 | 汕头大学 | 一种聚合物微柱阵列的加工方法 |
| CN114434709B (zh) * | 2021-12-28 | 2024-04-30 | 汕头大学 | 一种凹形微井和微通道的快速制作方法 |
| CN114345273B (zh) * | 2021-12-30 | 2024-03-08 | 南京恒桥化学技术材料有限公司 | 一种光固化组合物的制备方法 |
| CN114736373B (zh) * | 2022-04-28 | 2023-09-19 | 武汉纺织大学 | 一种梯状聚苯硫醚及其制备方法与应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3697396A (en) | 1971-06-25 | 1972-10-10 | Grace W R & Co | Photocurable liquid polyene-polythiol polymer composition |
| US6669873B1 (en) * | 1999-04-22 | 2003-12-30 | Ppc Industries Ohio, Inc. | Optical resin composition comprising thiol-ene prepolymer |
| US6778753B2 (en) * | 2001-07-25 | 2004-08-17 | E. I. Du Pont De Nemours And Company | Halogenated optical polymer composition |
| JP2003238904A (ja) * | 2002-02-21 | 2003-08-27 | Ricoh Co Ltd | 光硬化型光学用接着剤組成物 |
| WO2004009489A2 (en) * | 2002-07-19 | 2004-01-29 | The Regents Of The University Of Colorado | Fabrication of 3d photopolymeric devices |
| US20080274335A1 (en) * | 2004-12-16 | 2008-11-06 | Regents Of The University Of Colorado | Photolytic Polymer Surface Modification |
| US7521015B2 (en) * | 2005-07-22 | 2009-04-21 | 3M Innovative Properties Company | Curable thiol-ene compositions for optical articles |
| US20090096136A1 (en) * | 2007-10-12 | 2009-04-16 | The Regents Of The University Of California | Thiol-ene based poly(alkylsiloxane) materials |
-
2011
- 2011-10-03 ES ES11766978T patent/ES2571946T3/es active Active
- 2011-10-03 JP JP2013530764A patent/JP5940070B2/ja not_active Expired - Fee Related
- 2011-10-03 KR KR1020137011153A patent/KR101844103B1/ko not_active Expired - Fee Related
- 2011-10-03 DK DK11766978.8T patent/DK2622002T3/en active
- 2011-10-03 PL PL11766978.8T patent/PL2622002T3/pl unknown
- 2011-10-03 US US13/876,583 patent/US8927664B2/en active Active
- 2011-10-03 WO PCT/EP2011/067228 patent/WO2012042059A1/en not_active Ceased
- 2011-10-03 EP EP11766978.8A patent/EP2622002B1/en active Active
- 2011-10-03 CN CN201180047630.9A patent/CN103221458B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP2622002A1 (en) | 2013-08-07 |
| PL2622002T3 (pl) | 2016-10-31 |
| KR101844103B1 (ko) | 2018-03-30 |
| JP5940070B2 (ja) | 2016-06-29 |
| US8927664B2 (en) | 2015-01-06 |
| DK2622002T3 (en) | 2016-05-23 |
| CN103221458A (zh) | 2013-07-24 |
| CN103221458B (zh) | 2015-05-27 |
| KR20140031164A (ko) | 2014-03-12 |
| EP2622002B1 (en) | 2016-02-24 |
| JP2013544903A (ja) | 2013-12-19 |
| WO2012042059A1 (en) | 2012-04-05 |
| US20130331528A1 (en) | 2013-12-12 |
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