ES2595491T3 - Un biocida sinérgico y proceso para controlar el crecimiento de microorganismos - Google Patents

Un biocida sinérgico y proceso para controlar el crecimiento de microorganismos Download PDF

Info

Publication number: ES2595491T3
Authority: ES; Spain
Prior art keywords: ammonium; methylamine; monohaloamine; dihaloamine; monochloramine
Prior art date: 2005-08-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES06802295.3T

Other languages

English (en)

Spanish (es)

Inventor

Michael J. Mayer

Freddie L. Singleton

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Solenis Technologies Cayman LP

Original Assignee

Solenis Technologies Cayman LP

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2005-08-26

Filing date

2006-08-24

Publication date

2016-12-30

2006-08-24 Application filed by Solenis Technologies Cayman LP filed Critical Solenis Technologies Cayman LP

2006-08-24 Priority claimed from PCT/US2006/033155 external-priority patent/WO2007025087A2/en

2016-12-30 Application granted granted Critical

2016-12-30 Publication of ES2595491T3 publication Critical patent/ES2595491T3/es

Status Active legal-status Critical Current

2026-08-24 Anticipated expiration legal-status Critical

Links

238000000034 method Methods 0.000 title claims abstract description 68
244000005700 microbiome Species 0.000 title claims abstract description 37
230000002195 synergetic effect Effects 0.000 title claims abstract description 26
230000012010 growth Effects 0.000 title claims abstract description 22
239000003139 biocide Substances 0.000 title description 37
230000008569 process Effects 0.000 title description 26
230000003115 biocidal effect Effects 0.000 title description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
229910001868 water Inorganic materials 0.000 claims abstract description 38
QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical compound ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 claims description 137
239000000460 chlorine Substances 0.000 claims description 56
229910052801 chlorine Inorganic materials 0.000 claims description 52
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 51
239000007800 oxidant agent Substances 0.000 claims description 36
230000001590 oxidative effect Effects 0.000 claims description 35
150000001412 amines Chemical class 0.000 claims description 32
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 17
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
229910052736 halogen Inorganic materials 0.000 claims description 15
150000002367 halogens Chemical class 0.000 claims description 15
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 13
239000000908 ammonium hydroxide Substances 0.000 claims description 13
-1 aliphatic amines Chemical class 0.000 claims description 11
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 10
229910052757 nitrogen Inorganic materials 0.000 claims description 9
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 8
229910021529 ammonia Inorganic materials 0.000 claims description 8
150000003863 ammonium salts Chemical class 0.000 claims description 8
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 8
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
229910052921 ammonium sulfate Inorganic materials 0.000 claims description 6
235000011130 ammonium sulphate Nutrition 0.000 claims description 6
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
229910052794 bromium Inorganic materials 0.000 claims description 6
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 5
239000001099 ammonium carbonate Substances 0.000 claims description 5
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 4
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 claims description 4
235000019270 ammonium chloride Nutrition 0.000 claims description 4
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 4
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 4
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 claims description 4
CUILPNURFADTPE-UHFFFAOYSA-N hypobromous acid Chemical compound BrO CUILPNURFADTPE-UHFFFAOYSA-N 0.000 claims description 4
239000004254 Ammonium phosphate Substances 0.000 claims description 3
235000012501 ammonium carbonate Nutrition 0.000 claims description 3
229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
235000019289 ammonium phosphates Nutrition 0.000 claims description 3
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
150000003141 primary amines Chemical class 0.000 claims description 3
150000003335 secondary amines Chemical class 0.000 claims description 3
YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims description 3
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 2
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 claims description 2
USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims description 2
239000005695 Ammonium acetate Substances 0.000 claims description 2
229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 claims description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 2
ZDXPYRJPNDTMRX-VKHMYHEASA-N L-glutamine Chemical compound OC(=O)[C@@H](N)CCC(N)=O ZDXPYRJPNDTMRX-VKHMYHEASA-N 0.000 claims description 2
OVRNDRQMDRJTHS-UHFFFAOYSA-N N-acelyl-D-glucosamine Natural products CC(=O)NC1C(O)OC(CO)C(O)C1O OVRNDRQMDRJTHS-UHFFFAOYSA-N 0.000 claims description 2
OVRNDRQMDRJTHS-FMDGEEDCSA-N N-acetyl-beta-D-glucosamine Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O OVRNDRQMDRJTHS-FMDGEEDCSA-N 0.000 claims description 2
MBLBDJOUHNCFQT-LXGUWJNJSA-N N-acetylglucosamine Natural products CC(=O)N[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO MBLBDJOUHNCFQT-LXGUWJNJSA-N 0.000 claims description 2
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical group [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
ZGSDJMADBJCNPN-UHFFFAOYSA-N [S-][NH3+] Chemical compound [S-][NH3+] ZGSDJMADBJCNPN-UHFFFAOYSA-N 0.000 claims description 2
229940043376 ammonium acetate Drugs 0.000 claims description 2
235000019257 ammonium acetate Nutrition 0.000 claims description 2
235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
229940107816 ammonium iodide Drugs 0.000 claims description 2
APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 2
239000011609 ammonium molybdate Substances 0.000 claims description 2
235000018660 ammonium molybdate Nutrition 0.000 claims description 2
229940010552 ammonium molybdate Drugs 0.000 claims description 2
VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 claims description 2
229910001870 ammonium persulfate Inorganic materials 0.000 claims description 2
150000004982 aromatic amines Chemical class 0.000 claims description 2
CODNYICXDISAEA-UHFFFAOYSA-N bromine monochloride Chemical compound BrCl CODNYICXDISAEA-UHFFFAOYSA-N 0.000 claims description 2
239000004202 carbamide Substances 0.000 claims description 2
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims description 2
229940043276 diisopropanolamine Drugs 0.000 claims description 2
UESSEMPSSAXQJC-UHFFFAOYSA-N ethanol;methanamine Chemical compound NC.CCO UESSEMPSSAXQJC-UHFFFAOYSA-N 0.000 claims description 2
ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 claims description 2
150000002357 guanidines Chemical class 0.000 claims description 2
229950006780 n-acetylglucosamine Drugs 0.000 claims description 2
VBCHBQPSMZOZAV-UHFFFAOYSA-N n-butyl-n-ethylhexan-1-amine Chemical compound CCCCCCN(CC)CCCC VBCHBQPSMZOZAV-UHFFFAOYSA-N 0.000 claims description 2
MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 claims description 2
GSVWUPPSQAZZTF-UHFFFAOYSA-N n-ethyl-n-methylhexan-1-amine Chemical compound CCCCCCN(C)CC GSVWUPPSQAZZTF-UHFFFAOYSA-N 0.000 claims description 2
RIWRFSMVIUAEBX-UHFFFAOYSA-N n-methyl-1-phenylmethanamine Chemical compound CNCC1=CC=CC=C1 RIWRFSMVIUAEBX-UHFFFAOYSA-N 0.000 claims description 2
VZCDJZXWMNOHNZ-UHFFFAOYSA-N n-methyl-n-propylheptan-1-amine Chemical compound CCCCCCCN(C)CCC VZCDJZXWMNOHNZ-UHFFFAOYSA-N 0.000 claims description 2
IKVDMBQGHZVMRN-UHFFFAOYSA-N n-methyldecan-1-amine Chemical compound CCCCCCCCCCNC IKVDMBQGHZVMRN-UHFFFAOYSA-N 0.000 claims description 2
OMEMQVZNTDHENJ-UHFFFAOYSA-N n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCNC OMEMQVZNTDHENJ-UHFFFAOYSA-N 0.000 claims description 2
XJINZNWPEQMMBV-UHFFFAOYSA-N n-methylhexan-1-amine Chemical compound CCCCCCNC XJINZNWPEQMMBV-UHFFFAOYSA-N 0.000 claims description 2
OZIXTIPURXIEMB-UHFFFAOYSA-N n-methylnonan-1-amine Chemical compound CCCCCCCCCNC OZIXTIPURXIEMB-UHFFFAOYSA-N 0.000 claims description 2
XMRPIOZXPHTSCE-UHFFFAOYSA-N n-methyltridecan-1-amine Chemical compound CCCCCCCCCCCCCNC XMRPIOZXPHTSCE-UHFFFAOYSA-N 0.000 claims description 2
HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 claims description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
229920000768 polyamine Polymers 0.000 claims description 2
229920000642 polymer Polymers 0.000 claims description 2
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
GVERIJPZBUHJMT-UHFFFAOYSA-N 1-aminooctadecan-2-ol Chemical compound CCCCCCCCCCCCCCCCC(O)CN GVERIJPZBUHJMT-UHFFFAOYSA-N 0.000 claims 1
HKGKYUVCADNOOC-UHFFFAOYSA-N 1-aminotetradecan-2-ol Chemical compound CCCCCCCCCCCCC(O)CN HKGKYUVCADNOOC-UHFFFAOYSA-N 0.000 claims 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
239000005642 Oleic acid Substances 0.000 claims 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
JSYGRUBHOCKMGQ-UHFFFAOYSA-N dichloramine Chemical compound ClNCl JSYGRUBHOCKMGQ-UHFFFAOYSA-N 0.000 description 77
239000000243 solution Substances 0.000 description 34
238000004519 manufacturing process Methods 0.000 description 21
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238000012360 testing method Methods 0.000 description 11
238000007792 addition Methods 0.000 description 10
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239000008367 deionised water Substances 0.000 description 5
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239000000725 suspension Substances 0.000 description 5
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ES06802295.3T 2005-08-26 2006-08-24 Un biocida sinérgico y proceso para controlar el crecimiento de microorganismos Active ES2595491T3 (es)

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US71150805P	2005-08-26	2005-08-26
US711508P		2005-08-26
PCT/US2006/033155 WO2007025087A2 (en)	2005-08-26	2006-08-24	A synergistic biocide and process for controlling growth of microorganisms

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Publication number	Priority date	Publication date	Assignee	Title
EP2459492A1 (en) *	2009-07-27	2012-06-06	Lonza Inc.	Stabilized active halogen solutions
CN109769855A (zh) *	2011-10-21	2019-05-21	纳尔科公司	氨基磺酸或其盐，与铵盐和/或胺的组合或其他含卤素的杀生物剂在造纸领域的应用
BR122022000561B1 (pt) *	2012-06-05	2022-05-03	Buckman Laboratories International, Inc	Método para controlar ou impedir a precipitação ou incrustação de cálcio
CN106127264A (zh) *	2016-08-30	2016-11-16	孟玲	一种控制水体系中微生物生长的方法
DE102017007273A1 (de) *	2017-08-01	2019-02-07	Instraction Gmbh	Entfernung von Bakterien aus Trinkwasser über Filtration
BR112020007682B1 (pt) *	2017-10-18	2024-01-23	Solenis Technologies, L.P.	Método para controlar e remover biofilme em contato com sistema aquoso, e, composição
CN111377511B (zh) *	2020-03-18	2022-11-04	中国建筑科学研究院有限公司	一种采用消毒方法提高既有建筑消防水系统用水点流量的方法
KR20230018383A (ko) *	2020-04-29	2023-02-07	솔레니스 테크놀러지스, 엘.피.	할로아민 살생물제의 생산을 제어하기 위한 방법 및 장치

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US1884546A (en) *	1931-11-14	1932-10-25	Paul F Bovard	Paper making technique
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EP0785908B1 (en) *	1994-10-03	2001-01-24	Weinstock, David	Method of treating liquids to inhibit growth of living organisms
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PL1928246T3 (pl)	2017-04-28
ZA200802688B (en)	2009-10-28
CN101296621B (zh)	2012-05-30
CN101296621A (zh)	2008-10-29

Publication	Publication Date	Title
ES2331094T3 (es)	2009-12-21	Metodo y aparato para producir un biocida sinergico.
US8613859B2 (en)	2013-12-24	Synergistic biocide and process for controlling growth of microoganisms
ES2273967T3 (es)	2007-05-16	Proceso para la desinfeccion de aguas.
EP1928246B1 (en)	2016-08-24	A synergistic biocide and process for controlling growth of microorganisms
ES2595491T3 (es)	2016-12-30	Un biocida sinérgico y proceso para controlar el crecimiento de microorganismos
CA2763212C (en)	2020-04-21	Use of monochlorourea to treat industrial waters
CN101296862B (zh)	2011-06-15	用于制备协同杀生物剂的方法
WO2006103314A1 (en)	2006-10-05	Electrochemical method for preparing microbiocidal solutions