ES2664726T3 - Sales de aminas anhidras, altamente concentradas, de alcoxisulfatos de hidrocarburo, y uso y procedimiento empleando diluciones acuosas de las mismas - Google Patents
Sales de aminas anhidras, altamente concentradas, de alcoxisulfatos de hidrocarburo, y uso y procedimiento empleando diluciones acuosas de las mismas Download PDFInfo
- Publication number
- ES2664726T3 ES2664726T3 ES14701292.6T ES14701292T ES2664726T3 ES 2664726 T3 ES2664726 T3 ES 2664726T3 ES 14701292 T ES14701292 T ES 14701292T ES 2664726 T3 ES2664726 T3 ES 2664726T3
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- Spain
- Prior art keywords
- weight
- hydrocarbon
- less
- groups
- alkoxy groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 7
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 6
- 229930195733 hydrocarbon Natural products 0.000 title abstract 6
- 150000001412 amines Chemical class 0.000 title description 2
- 150000003839 salts Chemical class 0.000 title description 2
- 239000012895 dilution Substances 0.000 title 1
- 238000010790 dilution Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 7
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 abstract 5
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 abstract 5
- 125000005529 alkyleneoxy group Chemical group 0.000 abstract 4
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- -1 amine salts Chemical class 0.000 abstract 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/584—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific surfactants
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/03—Monoamines
- C07C211/05—Mono-, di- or tri-ethylamine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/03—Monoamines
- C07C211/07—Monoamines containing one, two or three alkyl groups, each having the same number of carbon atoms in excess of three
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
- C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
- C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/334—Polymers modified by chemical after-treatment with organic compounds containing sulfur
- C08G65/3344—Polymers modified by chemical after-treatment with organic compounds containing sulfur containing oxygen in addition to sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/602—Compositions for stimulating production by acting on the underground formation containing surfactants
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- Physics & Mathematics (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Detergent Compositions (AREA)
Abstract
Composición altamente concentrada y fluyente a 25 °C, de sales de aminas de polialcoxisulfatos de hidrocarburo, presentando: (A) más de un 80 % en peso, en particular más de un 90 % en peso, en particular más de un 95 % en peso de sales de aminas de polialcoxisulfatos de hidrocarburo de la fórmula R4-O-[EO, PO, AO]n-SO3-HNR1R2R3+ donde - uno, dos o tres de los restos R1, R2 y R3 están elegidos independientemente entre sí del grupo de: - alquilo con 1 a 14 átomos de carbono, - alquenilo con 3 a 18 átomos de carbono, - hidroxialquilo con 2 a 4 átomos de carbono, - y sus mezclas, estando el hidroxialquilo eventualmente alcoxilado y siendo los restos restantes en cada caso hidrógeno; y - R4 es/son uno o varios hidrocarburo(s) de C6 a C36 diferentes; eventualmente en mezcla con menos del 20 % en peso, en particular menos del 10 % en peso, de las sales de aminas anteriores de polialcoxisulfatos de hidrocarburo, en los cuales los grupos alcoxi son exclusivamente EO; (B) al menos del 0,1 hasta menos del 5 % en peso, en particular del 0,2 al 3 % en peso, del hidrocarburo polialcoxilado no sulfatado R4-O-[EO, PO, AO]n-H o sus mezclas; (C) hasta menos del 5 % en peso del hidroxi-hidrocarburo no sulfatado R4-OH o sus mezclas; siendo (B) y (C) juntos de un 0,1 a un 10 % en peso, en particular de un 0,5 a un 5 % en peso, de la composición; presentando la composición menos de un 2 % en peso de agua y siendo el número n de los grupos alcoxi EO, PO, AO juntos de 2 a 16, preferentemente de 3 a 16 y siendo los grupos alcoxi: - de 1 a 15 grupos propoxi (PO) y - de 1 a 15 grupos etoxi (EO), y eventualmente - de 0 a 10 grupos alquilenoxi de C4 a C12 (AO), y estando distribuidos los grupos alcoxi estadísticamente o presentándose en bloques o ambas cosas.
Description
-medir el valor de pH como indicio para la descomposición del polialcoxisulfato de alquilo / alcoholetersulfato.
Los resultados se reúnen en la tabla 3.
Tabla 3
- Amina y/o sal
- 70 °C Na2CO3 (valor de pH al inicio: 10.0)
- Sulfato de un alcohol Ziegler de C10 lineal con grupo promedio 4 PO y 1 EO
- Na Tras 3 semanas pH 5.7
- MIPA
- Tras 6 meses pH 9.7
- TIPA
- Tras 6 meses pH 9.8
9
Claims (1)
-
imagen1 imagen2 imagen3 imagen4
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013100789.9A DE102013100789A1 (de) | 2013-01-25 | 2013-01-25 | Hochkonzentrierte, wasserfreie Aminsalze von Kohlenwasserstoff-alkoxysulfaten und Verwendung und Verfahren unter Verwendung von wässrigen Verdünnungen derselben |
| DE102013100789 | 2013-01-25 | ||
| PCT/EP2014/000186 WO2014114459A1 (de) | 2013-01-25 | 2014-01-24 | Hochkonzentrierte, wasserfreie aminsalze von kohlenwasserstoff-alkoxysulfaten und verwendung und verfahren unter verwendung von wässrigen verdünnungen derselben |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2664726T3 true ES2664726T3 (es) | 2018-04-23 |
Family
ID=50002680
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES14714923.1T Active ES2672443T3 (es) | 2013-01-25 | 2014-01-24 | Sales de amina anhidras altamente concentradas de alcoxi sulfatos de hidrocarburo y uso y procedimiento mediante el uso de diluciones acuosas de las mismas |
| ES14701292.6T Active ES2664726T3 (es) | 2013-01-25 | 2014-01-24 | Sales de aminas anhidras, altamente concentradas, de alcoxisulfatos de hidrocarburo, y uso y procedimiento empleando diluciones acuosas de las mismas |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES14714923.1T Active ES2672443T3 (es) | 2013-01-25 | 2014-01-24 | Sales de amina anhidras altamente concentradas de alcoxi sulfatos de hidrocarburo y uso y procedimiento mediante el uso de diluciones acuosas de las mismas |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US9758718B2 (es) |
| EP (2) | EP2948522B1 (es) |
| CN (2) | CN104968758B (es) |
| AU (2) | AU2014210175B2 (es) |
| CA (2) | CA2896321C (es) |
| DE (1) | DE102013100789A1 (es) |
| DK (2) | DK2948523T3 (es) |
| ES (2) | ES2672443T3 (es) |
| MX (2) | MX2015009379A (es) |
| NO (1) | NO3062775T3 (es) |
| RU (2) | RU2648771C2 (es) |
| TR (1) | TR201807905T4 (es) |
| WO (2) | WO2014114287A1 (es) |
| ZA (1) | ZA201504631B (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EA039889B1 (ru) * | 2017-10-06 | 2022-03-23 | Дау Глоубл Текнолоджиз Ллк | Композиция, содержащая алканоламин и простой эфир гликоля, предназначенная для улучшенного извлечения битума |
| AR118835A1 (es) * | 2019-05-03 | 2021-11-03 | Sasol Performance Chemicals Gmbh | Fluidos de inyección que comprenden surfactantes aniónicos y alcoholes alcoxilados y el uso de tales fluidos en procesos de recuperación de petróleo mejorada |
| BR112022014559A2 (pt) * | 2020-01-23 | 2022-09-20 | Basf Se | Composição agroquímica, composto de fórmula (i), solução adjuvante e método para controlar vegetação indesejável |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4017405A (en) | 1973-03-26 | 1977-04-12 | Union Oil Company Of California | Soluble oil composition |
| US3990515A (en) * | 1974-12-24 | 1976-11-09 | Sun Oil Co | Waterflooding process with recovery of lost surfactant |
| GB1504789A (en) | 1975-12-02 | 1978-03-22 | British Petroleum Co | Hydrocarbon/water mixtures |
| US4113011A (en) | 1977-03-07 | 1978-09-12 | Union Oil Company Of California | Enhanced oil recovery process |
| US4293428A (en) | 1978-01-18 | 1981-10-06 | Exxon Production Research Company | Propoxylated ethoxylated surfactants and method of recovering oil therewith |
| US4265264A (en) | 1979-04-30 | 1981-05-05 | Conoco, Inc. | Method of transporting viscous hydrocarbons |
| US4477372A (en) * | 1982-05-13 | 1984-10-16 | Henkel Corporation | Anionic nonionic surfactant mixture |
| US4524002A (en) | 1983-02-23 | 1985-06-18 | Gaf Corporation | Foaming agent |
| JPS59185286A (ja) * | 1983-04-04 | 1984-10-20 | ライオン株式会社 | 石油の回収方法 |
| US4703797A (en) * | 1983-12-28 | 1987-11-03 | Cities Service Co. | Sweep improvement in enhanced oil recovery |
| EP0167337A2 (en) | 1984-06-25 | 1986-01-08 | Atlantic Richfield Company | Alkoxylated ether sulfate anionic surfactants |
| FR2574470A1 (fr) | 1984-12-06 | 1986-06-13 | Exxon Production Research Co | Procede de recuperation assistee de petrole dans un intervalle de fortes et faibles salinites, utilisant des surfactants propoxyles |
| US4886120A (en) | 1989-02-01 | 1989-12-12 | Conoco Inc. | Process for secondary oil recovery utilizing propoxylated ethoxylated surfactants in seawater |
| DE4341050A1 (de) | 1993-12-02 | 1995-06-08 | Huels Chemische Werke Ag | Tensidkonzentrate als Basistenside für konzentrierte Flüssigformulierungen |
| USH1818H (en) | 1997-10-17 | 1999-11-02 | Sasol Technology (Proprietary) Limited | Detergent and cleaning compositions derived from new detergent alcohols |
| US6410005B1 (en) * | 2000-06-15 | 2002-06-25 | Pmd Holdings Corp. | Branched/block copolymers for treatment of keratinous substrates |
| US20070125542A1 (en) * | 2005-12-07 | 2007-06-07 | Akzo Nobel N.V. | High temperature gellant in low and high density brines |
| ES2293826B1 (es) * | 2006-06-07 | 2008-12-16 | Kao Corporation S.A. | Composicion detergente. |
| US8664166B2 (en) | 2008-02-07 | 2014-03-04 | Shell Oil Company | Method and composition for enhanced hydrocarbons recovery |
| CA2719153C (en) | 2008-04-10 | 2016-06-21 | Basf Se | Novel surfactants for tertiary mineral oil extraction based on branched alcohols |
| AR078418A1 (es) | 2009-09-10 | 2011-11-09 | Univ Texas | Composiciones y metodos para controlar la estabilidad de surfactantes de etersulfato a temperaturas elevadas |
| EA024664B1 (ru) | 2010-03-10 | 2016-10-31 | Басф Се | Способ добычи нефти с применением поверхностно-активных веществ с основанием алкилпропокси-поверхностно-активных веществ, содержащих cc, водная композиция поверхностно-активных веществ для добычи нефти и поверхностно-активное вещество |
-
2013
- 2013-01-25 DE DE102013100789.9A patent/DE102013100789A1/de not_active Withdrawn
-
2014
- 2014-01-24 EP EP14701292.6A patent/EP2948522B1/de active Active
- 2014-01-24 AU AU2014210175A patent/AU2014210175B2/en active Active
- 2014-01-24 DK DK14714923.1T patent/DK2948523T3/en active
- 2014-01-24 DK DK14701292.6T patent/DK2948522T3/en active
- 2014-01-24 CA CA2896321A patent/CA2896321C/en active Active
- 2014-01-24 WO PCT/DE2014/000026 patent/WO2014114287A1/de not_active Ceased
- 2014-01-24 MX MX2015009379A patent/MX2015009379A/es unknown
- 2014-01-24 ES ES14714923.1T patent/ES2672443T3/es active Active
- 2014-01-24 CA CA2896343A patent/CA2896343C/en active Active
- 2014-01-24 TR TR2018/07905T patent/TR201807905T4/tr unknown
- 2014-01-24 CN CN201480005766.7A patent/CN104968758B/zh active Active
- 2014-01-24 CN CN201480005765.2A patent/CN104981530B/zh active Active
- 2014-01-24 AU AU2014210229A patent/AU2014210229B2/en active Active
- 2014-01-24 US US14/763,416 patent/US9758718B2/en active Active
- 2014-01-24 ES ES14701292.6T patent/ES2664726T3/es active Active
- 2014-01-24 US US14/763,355 patent/US9732270B2/en active Active
- 2014-01-24 EP EP14714923.1A patent/EP2948523B1/de active Active
- 2014-01-24 MX MX2015009378A patent/MX375487B/es active IP Right Grant
- 2014-01-24 WO PCT/EP2014/000186 patent/WO2014114459A1/de not_active Ceased
- 2014-01-24 RU RU2015134764A patent/RU2648771C2/ru active
- 2014-01-24 RU RU2015134762A patent/RU2656322C2/ru active
- 2014-10-31 NO NO14802985A patent/NO3062775T3/no unknown
-
2015
- 2015-06-25 ZA ZA2015/04631A patent/ZA201504631B/en unknown
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