ES2736129T3 - Pila de flujo redox para el almacenaje de energía eléctrica y su empleo - Google Patents

Pila de flujo redox para el almacenaje de energía eléctrica y su empleo Download PDF

Info

Publication number: ES2736129T3
Authority: ES; Spain
Prior art keywords: group; moiety; alkyl; substituted; carboxylic acid
Prior art date: 2015-08-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES16747731T

Other languages

English (en)

Spanish (es)

Inventor

Ulrich Sigmar Schubert

Tobias Janoschka

Norbert Martin

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Jenabatteries GmbH

Original Assignee

Jenabatteries GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2015-08-07

Filing date

2016-08-03

Publication date

2019-12-26

2016-08-03 Application filed by Jenabatteries GmbH filed Critical Jenabatteries GmbH

2019-12-26 Application granted granted Critical

2019-12-26 Publication of ES2736129T3 publication Critical patent/ES2736129T3/es

Status Active legal-status Critical Current

2036-08-03 Anticipated expiration legal-status Critical

Links

238000003860 storage Methods 0.000 title claims abstract description 11
-1 hydroxy, amino Chemical group 0.000 claims abstract description 127
230000000694 effects Effects 0.000 claims abstract description 85
125000000217 alkyl group Chemical group 0.000 claims abstract description 67
125000000623 heterocyclic group Chemical group 0.000 claims abstract description 48
125000003118 aryl group Chemical group 0.000 claims abstract description 41
239000012528 membrane Substances 0.000 claims abstract description 29
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 29
125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 28
125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 25
150000001450 anions Chemical class 0.000 claims abstract description 21
239000000203 mixture Substances 0.000 claims abstract description 17
150000003839 salts Chemical class 0.000 claims abstract description 16
125000003545 alkoxy group Chemical group 0.000 claims abstract description 13
239000008151 electrolyte solution Substances 0.000 claims abstract description 13
238000006243 chemical reaction Methods 0.000 claims abstract description 10
159000000014 iron salts Chemical class 0.000 claims abstract description 9
239000002904 solvent Substances 0.000 claims abstract description 9
239000000654 additive Substances 0.000 claims abstract description 8
239000007788 liquid Substances 0.000 claims abstract description 8
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims abstract description 8
229910052736 halogen Inorganic materials 0.000 claims abstract description 6
150000002367 halogens Chemical class 0.000 claims abstract description 6
125000004093 cyano group Chemical group *C#N 0.000 claims abstract description 5
238000004891 communication Methods 0.000 claims abstract description 4
150000001875 compounds Chemical class 0.000 claims description 55
125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 53
150000007942 carboxylates Chemical group 0.000 claims description 39
125000002947 alkylene group Chemical group 0.000 claims description 34
125000000542 sulfonic acid group Chemical group 0.000 claims description 31
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 29
150000001735 carboxylic acids Chemical class 0.000 claims description 26
239000001257 hydrogen Substances 0.000 claims description 26
229910052739 hydrogen Inorganic materials 0.000 claims description 26
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
150000001768 cations Chemical class 0.000 claims description 22
125000004433 nitrogen atom Chemical group N* 0.000 claims description 21
150000002500 ions Chemical class 0.000 claims description 20
150000002431 hydrogen Chemical class 0.000 claims description 19
125000003277 amino group Chemical group 0.000 claims description 18
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 15
150000001721 carbon Chemical group 0.000 claims description 14
229910052799 carbon Inorganic materials 0.000 claims description 14
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 14
ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 13
239000005977 Ethylene Substances 0.000 claims description 13
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 13
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 12
125000005496 phosphonium group Chemical group 0.000 claims description 12
125000002843 carboxylic acid group Chemical group 0.000 claims description 11
150000001413 amino acids Chemical group 0.000 claims description 10
150000002892 organic cations Chemical class 0.000 claims description 10
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 9
150000001767 cationic compounds Chemical class 0.000 claims description 8
125000001453 quaternary ammonium group Chemical group 0.000 claims description 8
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
239000000460 chlorine Substances 0.000 claims description 7
229910052801 chlorine Inorganic materials 0.000 claims description 7
229910052731 fluorine Inorganic materials 0.000 claims description 7
239000011737 fluorine Substances 0.000 claims description 7
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Chemical compound [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical group S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims description 5
125000003368 amide group Chemical group 0.000 claims description 4
150000001449 anionic compounds Chemical class 0.000 claims description 4
150000002891 organic anions Chemical class 0.000 claims description 4
229910052783 alkali metal Inorganic materials 0.000 claims description 3
150000001340 alkali metals Chemical class 0.000 claims description 3
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
239000007789 gas Substances 0.000 claims description 3
125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims description 2
239000002028 Biomass Substances 0.000 claims description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
244000297179 Syringa vulgaris Species 0.000 claims description 2
235000004338 Syringa vulgaris Nutrition 0.000 claims description 2
239000003245 coal Substances 0.000 claims description 2
239000000945 filler Substances 0.000 claims description 2
238000012432 intermediate storage Methods 0.000 claims description 2
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 17
LFMFPKKYRXFHHZ-UHFFFAOYSA-N R24 Chemical compound C1=C(Cl)C(C)=CC=C1NC1=NC(N)=C(C=CC=C2)C2=N1 LFMFPKKYRXFHHZ-UHFFFAOYSA-N 0.000 claims 1
SYGWYBOJXOGMRU-UHFFFAOYSA-N chembl233051 Chemical group C1=CC=C2C3=CC(C(N(CCN(C)C)C4=O)=O)=C5C4=CC=CC5=C3SC2=C1 SYGWYBOJXOGMRU-UHFFFAOYSA-N 0.000 claims 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 8
239000000243 solution Substances 0.000 description 30
150000001732 carboxylic acid derivatives Chemical class 0.000 description 27
125000004432 carbon atom Chemical group C* 0.000 description 25
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 21
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 20
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 19
125000000732 arylene group Chemical group 0.000 description 19
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 18
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 16
239000000463 material Substances 0.000 description 16
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 14
125000005237 alkyleneamino group Chemical group 0.000 description 14
125000005843 halogen group Chemical group 0.000 description 13
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 12
239000003792 electrolyte Substances 0.000 description 12
125000005529 alkyleneoxy group Chemical group 0.000 description 11
229910052751 metal Inorganic materials 0.000 description 11
239000002184 metal Substances 0.000 description 11
150000003254 radicals Chemical class 0.000 description 11
239000000126 substance Substances 0.000 description 11
239000011780 sodium chloride Substances 0.000 description 10
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 9
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
125000002993 cycloalkylene group Chemical group 0.000 description 9
125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
238000000034 method Methods 0.000 description 9
GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 9
239000000047 product Substances 0.000 description 9
125000001424 substituent group Chemical group 0.000 description 9
229910002804 graphite Inorganic materials 0.000 description 8
239000010439 graphite Substances 0.000 description 8
125000005842 heteroatom Chemical group 0.000 description 8
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 8
RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 7
NQRYJNQNLNOLGT-UHFFFAOYSA-O Piperidinium(1+) Chemical compound C1CC[NH2+]CC1 NQRYJNQNLNOLGT-UHFFFAOYSA-O 0.000 description 7
ZRALSGWEFCBTJO-UHFFFAOYSA-O guanidinium Chemical compound NC(N)=[NH2+] ZRALSGWEFCBTJO-UHFFFAOYSA-O 0.000 description 7
230000003647 oxidation Effects 0.000 description 7
238000007254 oxidation reaction Methods 0.000 description 7
239000002244 precipitate Substances 0.000 description 7
125000005500 uronium group Chemical group 0.000 description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000000872 buffer Substances 0.000 description 6
239000012043 crude product Substances 0.000 description 6
238000000151 deposition Methods 0.000 description 6
230000008021 deposition Effects 0.000 description 6
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
239000000843 powder Substances 0.000 description 6
JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 6
230000009467 reduction Effects 0.000 description 6
238000006722 reduction reaction Methods 0.000 description 6
229910052709 silver Inorganic materials 0.000 description 6
239000004332 silver Substances 0.000 description 6
238000003786 synthesis reaction Methods 0.000 description 6
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 5
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 5
229910021607 Silver chloride Inorganic materials 0.000 description 5
239000002253 acid Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
239000003638 chemical reducing agent Substances 0.000 description 5
125000004122 cyclic group Chemical group 0.000 description 5
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 5
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 5
125000005515 organic divalent group Chemical group 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 5
238000003756 stirring Methods 0.000 description 5
229910052721 tungsten Inorganic materials 0.000 description 5
238000005160 1H NMR spectroscopy Methods 0.000 description 4
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239000007864 aqueous solution Substances 0.000 description 4
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238000005229 chemical vapour deposition Methods 0.000 description 4
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NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000003951 lactams Chemical class 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
150000002605 large molecules Chemical class 0.000 description 1
229910001416 lithium ion Inorganic materials 0.000 description 1
229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000005259 measurement Methods 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
239000011259 mixed solution Substances 0.000 description 1
125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000002828 nitro derivatives Chemical class 0.000 description 1
LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
229920000847 nonoxynol Polymers 0.000 description 1
229920002113 octoxynol Polymers 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
230000005298 paramagnetic effect Effects 0.000 description 1
INFDPOAKFNIJBF-UHFFFAOYSA-N paraquat Chemical compound C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 INFDPOAKFNIJBF-UHFFFAOYSA-N 0.000 description 1
125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
230000035699 permeability Effects 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 1
229940067157 phenylhydrazine Drugs 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000008363 phosphate buffer Substances 0.000 description 1
150000003904 phospholipids Chemical class 0.000 description 1
238000007540 photo-reduction reaction Methods 0.000 description 1
229910003446 platinum oxide Inorganic materials 0.000 description 1
229920002492 poly(sulfone) Polymers 0.000 description 1
229920002239 polyacrylonitrile Polymers 0.000 description 1
229920001521 polyalkylene glycol ether Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920006393 polyether sulfone Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
229920006380 polyphenylene oxide Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920000128 polypyrrole Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229920002981 polyvinylidene fluoride Polymers 0.000 description 1
WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Inorganic materials [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
229910001414 potassium ion Inorganic materials 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
125000000168 pyrrolyl group Chemical group 0.000 description 1
150000004053 quinones Chemical class 0.000 description 1
238000006479 redox reaction Methods 0.000 description 1
229930182490 saponin Natural products 0.000 description 1
235000017709 saponins Nutrition 0.000 description 1
150000007949 saponins Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
238000000926 separation method Methods 0.000 description 1
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
229910010271 silicon carbide Inorganic materials 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
229910001488 sodium perchlorate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
229910001495 sodium tetrafluoroborate Inorganic materials 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000002130 sulfonic acid ester group Chemical group 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
DPKBAXPHAYBPRL-UHFFFAOYSA-M tetrabutylazanium;iodide Chemical compound [I-].CCCC[N+](CCCC)(CCCC)CCCC DPKBAXPHAYBPRL-UHFFFAOYSA-M 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
239000004753 textile Substances 0.000 description 1
125000001544 thienyl group Chemical group 0.000 description 1
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
229910001887 tin oxide Inorganic materials 0.000 description 1
239000002341 toxic gas Substances 0.000 description 1
125000004954 trialkylamino group Chemical group 0.000 description 1
125000005271 tributylamino group Chemical group 0.000 description 1
ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
DTQVDTLACAAQTR-UHFFFAOYSA-N trifluoroacetic acid Substances OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 1
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
235000019798 tripotassium phosphate Nutrition 0.000 description 1
LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
229910000406 trisodium phosphate Inorganic materials 0.000 description 1
235000019801 trisodium phosphate Nutrition 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
238000000108 ultra-filtration Methods 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000004034 viscosity adjusting agent Substances 0.000 description 1
238000004832 voltammetry Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/10—Fuel cells in stationary systems, e.g. emergency power source in plant
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Manufacturing & Machinery (AREA)
Sustainable Development (AREA)
Sustainable Energy (AREA)
Engineering & Computer Science (AREA)
Life Sciences & Earth Sciences (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Fuel Cell (AREA)
Inert Electrodes (AREA)
Pyridine Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

ES16747731T 2015-08-07 2016-08-03 Pila de flujo redox para el almacenaje de energía eléctrica y su empleo Active ES2736129T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE102015010083.1A DE102015010083A1 (de)	2015-08-07	2015-08-07	Redox-Flow-Zelle zur Speicherung elektrischer Energie und deren Verwendung
PCT/EP2016/001338 WO2017025177A1 (fr)	2015-08-07	2016-08-03	Cellule d'oxydoréduction pour le stockage d'énergie électrique et emploi de ladite cellule

Publications (1)

Publication Number	Publication Date
ES2736129T3 true ES2736129T3 (es)	2019-12-26

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ES16747731T Active ES2736129T3 (es)	2015-08-07	2016-08-03	Pila de flujo redox para el almacenaje de energía eléctrica y su empleo

Country Status (26)

Country	Link
US (2)	US11515557B2 (fr)
EP (1)	EP3332438B8 (fr)
JP (1)	JP6814366B2 (fr)
KR (1)	KR102661988B1 (fr)
CN (1)	CN108140864B (fr)
AU (1)	AU2016305138B2 (fr)
BR (1)	BR112018002468B1 (fr)
CA (1)	CA2993464C (fr)
CY (1)	CY1121797T1 (fr)
DE (1)	DE102015010083A1 (fr)
DK (1)	DK3332438T3 (fr)
ES (1)	ES2736129T3 (fr)
HR (1)	HRP20191286T1 (fr)
HU (1)	HUE044843T2 (fr)
IL (1)	IL257325B (fr)
MA (1)	MA43560B1 (fr)
MX (1)	MX384581B (fr)
PL (1)	PL3332438T3 (fr)
PT (1)	PT3332438T (fr)
RU (1)	RU2722695C2 (fr)
SA (1)	SA518390879B1 (fr)
SG (1)	SG11201800805QA (fr)
SI (1)	SI3332438T1 (fr)
TR (1)	TR201910276T4 (fr)
WO (1)	WO2017025177A1 (fr)
ZA (1)	ZA201800437B (fr)

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CN111266086B (zh) *	2020-01-22	2022-05-17	青岛农业大学	一种利用餐厨垃圾制取磁性生物炭的方法
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JP7766613B2 (ja)	2020-04-01	2025-11-10	ビーエーエスエフソシエタス・ヨーロピア	レドックスフローセルにおける電解質としての使用のためのｔｅｍｐｏ誘導体溶液
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CN111624153B (zh) *	2020-07-09	2020-12-15	西南石油大学	一种山地湿气管道气液两相流腐蚀试验装置
CN112103546B (zh) *	2020-09-16	2021-09-03	中盐金坛盐化有限责任公司	不对称型双电子紫精化合物的制备方法
DE102020133090A1 (de)	2020-12-11	2022-06-15	Schaeffler Technologies AG & Co. KG	Elektrodenblech für eine Redox-Flow-Zelle und Redox-Flow-Zelle
US11837767B2 (en) *	2020-12-23	2023-12-05	Uop Llc	Electrolyte compositions for redox flow batteries
CN117121243A (zh) *	2021-04-07	2023-11-24	巴斯夫欧洲公司	用于生产在氧化还原液流电池中用作电解液的tempo衍生物的提纯溶液的烷基化哌啶胺-和哌啶铵衍生物溶液
EP4288415A4 (fr)	2021-05-03	2024-08-07	Wisconsin Alumni Research Foundation	Dérivés de pyridinium obtenus par synthèse hydrothermale pour utilisation en tant qu'anolytes dans des cellules électrochimiques
US12551879B2 (en)	2021-05-19	2026-02-17	Uop Llc	Sandwich-structured thin film composite anion exchange membrane for redox flow battery applications
AU2022280937A1 (en)	2021-05-28	2023-10-19	Wisconsin Alumni Research Foundation	Ionic cyclic nitroxyl radical oligomers
CN113666864A (zh) *	2021-09-15	2021-11-19	宿迁时代储能科技有限公司	一种tempo-4-氯化铵的制备方法
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CN114122414B (zh) *	2021-11-05	2024-07-16	西安交通大学	一种哌啶氮氧自由基/锌复合氧化还原液流电池及其制备方法
CN115732731A (zh) *	2022-11-02	2023-03-03	宿迁时代储能科技有限公司	一种水相-有机氧化还原液流电池
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2015
- 2015-08-07 DE DE102015010083.1A patent/DE102015010083A1/de not_active Withdrawn
2016
- 2016-08-03 US US15/750,766 patent/US11515557B2/en active Active
- 2016-08-03 HU HUE16747731 patent/HUE044843T2/hu unknown
- 2016-08-03 WO PCT/EP2016/001338 patent/WO2017025177A1/fr not_active Ceased
- 2016-08-03 MX MX2018001565A patent/MX384581B/es unknown
- 2016-08-03 CN CN201680053440.0A patent/CN108140864B/zh active Active
- 2016-08-03 RU RU2018108046A patent/RU2722695C2/ru active
- 2016-08-03 BR BR112018002468-6A patent/BR112018002468B1/pt active IP Right Grant
- 2016-08-03 HR HRP20191286TT patent/HRP20191286T1/hr unknown
- 2016-08-03 TR TR2019/10276T patent/TR201910276T4/tr unknown
- 2016-08-03 JP JP2018526295A patent/JP6814366B2/ja active Active
- 2016-08-03 PL PL16747731T patent/PL3332438T3/pl unknown
- 2016-08-03 SG SG11201800805QA patent/SG11201800805QA/en unknown
- 2016-08-03 AU AU2016305138A patent/AU2016305138B2/en active Active
- 2016-08-03 DK DK16747731.4T patent/DK3332438T3/da active
- 2016-08-03 CA CA2993464A patent/CA2993464C/fr active Active
- 2016-08-03 EP EP16747731.4A patent/EP3332438B8/fr active Active
- 2016-08-03 ES ES16747731T patent/ES2736129T3/es active Active
- 2016-08-03 KR KR1020187006471A patent/KR102661988B1/ko active Active
- 2016-08-03 PT PT16747731T patent/PT3332438T/pt unknown
- 2016-08-03 MA MA43560A patent/MA43560B1/fr unknown
- 2016-08-03 SI SI201630310T patent/SI3332438T1/sl unknown
2018
- 2018-01-22 ZA ZA2018/00437A patent/ZA201800437B/en unknown
- 2018-02-04 IL IL257325A patent/IL257325B/en active IP Right Grant
- 2018-02-05 SA SA518390879A patent/SA518390879B1/ar unknown
2019
- 2019-07-10 CY CY20191100723T patent/CY1121797T1/el unknown
2022
- 2022-07-22 US US17/871,467 patent/US20220384834A1/en not_active Abandoned

Also Published As

Publication number	Publication date
HRP20191286T1 (hr)	2019-10-18
BR112018002468A2 (pt)	2018-09-18
PL3332438T3 (pl)	2019-11-29
WO2017025177A1 (fr)	2017-02-16
MX384581B (es)	2025-03-14
DK3332438T3 (da)	2019-08-05
US11515557B2 (en)	2022-11-29
DE102015010083A1 (de)	2017-02-09
SI3332438T1 (sl)	2019-08-30
CA2993464A1 (fr)	2017-02-16
SG11201800805QA (en)	2018-02-27
RU2722695C2 (ru)	2020-06-03
CN108140864B (zh)	2021-09-17
HK1255214A1 (zh)	2019-08-09
HUE044843T2 (hu)	2019-11-28
CY1121797T1 (el)	2020-07-31
JP2018529211A (ja)	2018-10-04
PT3332438T (pt)	2019-07-08
TR201910276T4 (tr)	2019-07-22
JP6814366B2 (ja)	2021-01-20
KR102661988B1 (ko)	2024-05-02
CN108140864A (zh)	2018-06-08
ZA201800437B (en)	2018-12-19
MX2018001565A (es)	2018-09-26
US20180241065A1 (en)	2018-08-23
AU2016305138B2 (en)	2021-07-29
EP3332438B8 (fr)	2019-07-03
EP3332438B1 (fr)	2019-05-01
IL257325A (en)	2018-03-29
SA518390879B1 (ar)	2022-05-08
EP3332438A1 (fr)	2018-06-13
BR112018002468B1 (pt)	2021-07-06
MA43560B1 (fr)	2019-05-31
MA43560A (fr)	2019-05-01
KR20180051518A (ko)	2018-05-16
CA2993464C (fr)	2023-06-20
AU2016305138A1 (en)	2018-03-01
RU2018108046A (ru)	2019-09-09
US20220384834A1 (en)	2022-12-01
IL257325B (en)	2021-01-31
RU2018108046A3 (fr)	2019-10-03

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ES2758306T3 (es)	2020-05-05	Batería de flujo híbrida para la acumulación de energía eléctrica y su uso
ES3055660T3 (en)	2026-02-13	Redox flow battery electrolytes
ES2657763T3 (es)	2018-03-06	Pila de flujo redox para el almacenaje de energía eléctrica y su empleo
WO2020204830A1 (fr)	2020-10-08	Batterie redox
CN113261135B (zh)	2025-01-21	水性电解液、氧化还原液流电池组及其用途
WO2022236241A1 (fr)	2022-11-10	Dérivés de pyridinium obtenus par synthèse hydrothermale pour utilisation en tant qu'anolytes dans des cellules électrochimiques
KR101456249B1 (ko)	2014-11-19	레독스 흐름전지용 유기 전해질, 이의 제조방법 및 이를 포함하는 레독스 흐름전지
US12489120B2 (en)	2025-12-02	Redox flow battery
KR20160008089A (ko)	2016-01-21	레독스 흐름전지용 유기 전해질, 이의 제조방법 및 이를 포함하는 레독스 흐름전지
CA3197808A1 (fr)	2022-06-02	Batteries a flux redox non aqueux
HK1255214B (zh)	2022-04-14	用於储存电能的氧化还原液流电池及其用途
WO2026024708A1 (fr)	2026-01-29	Matériaux redox de pyridinium à substitution c et procédés
JP2023133170A (ja)	2023-09-22	規則構造を有するビオローゲン誘導体及びそれを用いたレドックスフロー電池
HK1255337B (en)	2023-03-24	Hybrid flow battery for storing electrical energy and use thereof