ES2740982T3 - Lavado de suelos contaminados - Google Patents
Lavado de suelos contaminados Download PDFInfo
- Publication number
- ES2740982T3 ES2740982T3 ES12783688T ES12783688T ES2740982T3 ES 2740982 T3 ES2740982 T3 ES 2740982T3 ES 12783688 T ES12783688 T ES 12783688T ES 12783688 T ES12783688 T ES 12783688T ES 2740982 T3 ES2740982 T3 ES 2740982T3
- Authority
- ES
- Spain
- Prior art keywords
- batch
- process water
- washing
- solution
- chelating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005406 washing Methods 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 claims abstract description 178
- 239000002689 soil Substances 0.000 claims abstract description 92
- 229910052751 metal Inorganic materials 0.000 claims abstract description 85
- 239000002184 metal Substances 0.000 claims abstract description 85
- 239000000243 solution Substances 0.000 claims abstract description 80
- 150000002739 metals Chemical class 0.000 claims abstract description 77
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 76
- 239000002738 chelating agent Substances 0.000 claims abstract description 69
- 231100000331 toxic Toxicity 0.000 claims abstract description 49
- 230000002588 toxic effect Effects 0.000 claims abstract description 49
- 239000007790 solid phase Substances 0.000 claims abstract description 22
- 238000011084 recovery Methods 0.000 claims abstract description 21
- 239000002957 persistent organic pollutant Substances 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims abstract description 10
- 238000000926 separation method Methods 0.000 claims abstract description 10
- 229910000000 metal hydroxide Inorganic materials 0.000 claims abstract description 9
- 150000004692 metal hydroxides Chemical class 0.000 claims abstract description 9
- 230000003647 oxidation Effects 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 230000020477 pH reduction Effects 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- 239000003599 detergent Substances 0.000 claims abstract description 4
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 4
- 238000010525 oxidative degradation reaction Methods 0.000 claims abstract description 3
- 239000012487 rinsing solution Substances 0.000 claims abstract description 3
- 238000010923 batch production Methods 0.000 claims abstract 9
- 230000001376 precipitating effect Effects 0.000 claims abstract 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 59
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 13
- 235000011149 sulphuric acid Nutrition 0.000 claims description 9
- 229910052793 cadmium Inorganic materials 0.000 claims description 7
- 239000000356 contaminant Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 229910052745 lead Inorganic materials 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 239000013049 sediment Substances 0.000 description 65
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 53
- 239000011575 calcium Substances 0.000 description 14
- 238000001556 precipitation Methods 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
- 239000012071 phase Substances 0.000 description 13
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 10
- 235000011941 Tilia x europaea Nutrition 0.000 description 10
- 239000004571 lime Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 238000004064 recycling Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 238000003916 acid precipitation Methods 0.000 description 7
- 150000004679 hydroxides Chemical class 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 238000005119 centrifugation Methods 0.000 description 6
- 238000010908 decantation Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000003643 water by type Substances 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000003337 fertilizer Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 238000005188 flotation Methods 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005067 remediation Methods 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- -1 saline ions Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920004890 Triton X-100 Polymers 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 238000009297 electrocoagulation Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910000457 iridium oxide Inorganic materials 0.000 description 1
- HTXDPTMKBJXEOW-UHFFFAOYSA-N iridium(IV) oxide Inorganic materials O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000000590 phytopharmaceutical Substances 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910001952 rubidium oxide Inorganic materials 0.000 description 1
- CWBWCLMMHLCMAM-UHFFFAOYSA-M rubidium(1+);hydroxide Chemical compound [OH-].[Rb+].[Rb+] CWBWCLMMHLCMAM-UHFFFAOYSA-M 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/02—Extraction using liquids, e.g. washing, leaching, flotation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI201100216A SI23762A (sl) | 2011-06-17 | 2011-06-17 | Ponovna uporaba edta po pranju onesnaĺ˝enih tal |
| PCT/SI2012/000039 WO2012173576A2 (fr) | 2011-06-17 | 2012-06-15 | Lavage de sols contaminés |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2740982T3 true ES2740982T3 (es) | 2020-02-07 |
Family
ID=47146631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12783688T Active ES2740982T3 (es) | 2011-06-17 | 2012-06-15 | Lavado de suelos contaminados |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9108233B2 (fr) |
| EP (1) | EP2720812B1 (fr) |
| CA (1) | CA2871879C (fr) |
| ES (1) | ES2740982T3 (fr) |
| PL (1) | PL2720812T3 (fr) |
| SI (1) | SI23762A (fr) |
| WO (1) | WO2012173576A2 (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2951096B1 (fr) * | 2009-10-09 | 2013-03-15 | Total Sa | Procede d'oxydation de composes organiques |
| SI23762A (sl) | 2011-06-17 | 2012-12-31 | Envit D.O.O. | Ponovna uporaba edta po pranju onesnaĺ˝enih tal |
| GB2543076A (en) * | 2015-10-07 | 2017-04-12 | Envit Env Tech And Eng Ltd | Soil and sediment remediation |
| JP6052942B1 (ja) * | 2016-10-19 | 2016-12-27 | 公信 山▲崎▼ | 土壌浄化施設における雨水を利用するキレート剤回収方法 |
| JP6052943B1 (ja) * | 2016-10-20 | 2016-12-27 | 公信 山▲崎▼ | キレート剤を用いる土壌浄化施設における土壌浄化方法 |
| JP6052944B1 (ja) * | 2016-10-20 | 2016-12-27 | 公信 山▲崎▼ | キレート剤を用いる土壌浄化施設のための土壌浄化方法 |
| JP6052946B1 (ja) * | 2016-10-25 | 2016-12-27 | 公信 山▲崎▼ | キレート剤を含む洗浄水を用いる土壌浄化施設における土壌浄化方法 |
| JP6052945B1 (ja) * | 2016-10-25 | 2016-12-27 | 公信 山▲崎▼ | キレート剤を用いる土壌浄化施設における土壌浄化方法 |
| JP6052947B1 (ja) * | 2016-10-25 | 2016-12-27 | 公信 山▲崎▼ | キレート剤を含む洗浄水を用いる土壌浄化施設のための土壌浄化方法 |
| GB2568955A (en) * | 2017-12-04 | 2019-06-05 | Envit Environmental Tech And Engineering Ltd | Curbing toxic emissions from remediated substrate |
| CN110484263B (zh) * | 2019-07-02 | 2021-11-23 | 广东省生态环境技术研究所 | 一种复合淋滤剂及其应用 |
| CN112718838A (zh) * | 2020-11-20 | 2021-04-30 | 上海胜丰环境能源科技有限公司 | 一种高浓度铜污染土壤的淋洗系统及工艺 |
| EP4301529B1 (fr) | 2021-03-05 | 2025-03-26 | ENVIT, Environmental Technologies and Engineering Ltd. | Élimination de l'arsenic, de l'antimoine et de métaux toxiques d'un substrat contaminé |
| US11613496B2 (en) * | 2021-05-26 | 2023-03-28 | Halliburton Energy Services, Inc. | Removal of sand impurities in wet processing |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4629509A (en) | 1985-06-24 | 1986-12-16 | Allied Corporation | Immobilization of lead and cadmium in fly ash |
| DE3929137C1 (fr) | 1989-09-01 | 1991-02-28 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De | |
| US5225087A (en) | 1991-05-10 | 1993-07-06 | Westinghouse Electric Corp. | Recovery of EDTA from steam generator cleaning solutions |
| US5202033A (en) | 1991-09-30 | 1993-04-13 | Rmt, Inc. | In situ method for decreasing heavy metal leaching from soil or waste |
| US5494649A (en) | 1991-10-03 | 1996-02-27 | Cognis, Inc. | Process for removing heavy metals from paint chips |
| US5849567A (en) | 1995-03-31 | 1998-12-15 | Gsf-Forschungszentrum Fur Umwelt Und Gesundheit Gmbh | Method of decontaminating solid materials contaminated with heavy metals |
| US5599137A (en) * | 1995-09-13 | 1997-02-04 | Chemtech Analysis Inc. | Mobile soil treatment apparatus and method |
| US5917117A (en) | 1996-03-21 | 1999-06-29 | Phytotech, Inc. | Inducing hyperaccumulation of metals in plant shoots |
| US5919001A (en) | 1996-06-21 | 1999-07-06 | Lin; Hsing Kuang | Process for simultaneously removing lead, copper and mercury from contaminated soils |
| CA2308445A1 (fr) | 1997-11-04 | 1999-05-14 | University Of Guelph | Mode d'emploi d'especes de pelargonium en tant qu'hyperaccumulateur pour remedier a un sol contamine |
| US6204430B1 (en) | 1998-02-18 | 2001-03-20 | Rocky Mountain Remediation Services Llc | Hexametaphosphate as an agent for treating wastes, preparing construction materials and stabilizing soils |
| JP4263874B2 (ja) | 2002-04-22 | 2009-05-13 | 株式会社平和 | 遊技機 |
| CA2605053A1 (fr) * | 2007-10-02 | 2009-04-02 | Institut National De La Recherche Scientifique (Inrs) | Traitement de milieux contamines par des composes organiques hydrophobes et des metaux |
| US8115046B2 (en) * | 2008-01-18 | 2012-02-14 | Rta Systems, Inc. | Micro encapsulation composition for hydrocarbons and detoxification of highly hazardous chemicals and substances |
| MX2012009164A (es) * | 2010-02-10 | 2013-05-20 | M I Drilling Fluids Uk Ltd | Metodo y sistema para descontaminar arena. |
| SI23762A (sl) | 2011-06-17 | 2012-12-31 | Envit D.O.O. | Ponovna uporaba edta po pranju onesnaĺ˝enih tal |
-
2011
- 2011-06-17 SI SI201100216A patent/SI23762A/sl not_active IP Right Cessation
-
2012
- 2012-06-15 PL PL12783688T patent/PL2720812T3/pl unknown
- 2012-06-15 CA CA2871879A patent/CA2871879C/fr active Active
- 2012-06-15 EP EP12783688.0A patent/EP2720812B1/fr active Active
- 2012-06-15 WO PCT/SI2012/000039 patent/WO2012173576A2/fr not_active Ceased
- 2012-06-15 ES ES12783688T patent/ES2740982T3/es active Active
- 2012-06-15 US US14/125,094 patent/US9108233B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| SI23762A (sl) | 2012-12-31 |
| US9108233B2 (en) | 2015-08-18 |
| WO2012173576A2 (fr) | 2012-12-20 |
| EP2720812B1 (fr) | 2019-05-22 |
| EP2720812A2 (fr) | 2014-04-23 |
| CA2871879C (fr) | 2019-02-12 |
| PL2720812T3 (pl) | 2020-01-31 |
| CA2871879A1 (fr) | 2012-12-20 |
| WO2012173576A3 (fr) | 2013-03-14 |
| US20140126965A1 (en) | 2014-05-08 |
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