ES2928748T3 - Proceso para la preparación de una composición de grasa hidrogenada - Google Patents

Proceso para la preparación de una composición de grasa hidrogenada Download PDF

Info

Publication number: ES2928748T3
Authority: ES; Spain
Prior art keywords: fat composition; unsaturated; unsaturated fat; amount; process according
Prior art date: 2017-07-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES18734246T

Other languages

English (en)

Spanish (es)

Inventor

Bastiaan Jeroen Victor Verkuijl

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bunge Loders Croklaan BV

Original Assignee

Bunge Loders Croklaan BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2017-07-07

Filing date

2018-07-02

Publication date

2022-11-22

2018-07-02 Application filed by Bunge Loders Croklaan BV filed Critical Bunge Loders Croklaan BV

2022-11-22 Application granted granted Critical

2022-11-22 Publication of ES2928748T3 publication Critical patent/ES2928748T3/es

Status Active legal-status Critical Current

2038-07-02 Anticipated expiration legal-status Critical

Links

239000000203 mixture Substances 0.000 title claims abstract description 202
238000000034 method Methods 0.000 title claims abstract description 51
238000002360 preparation method Methods 0.000 title claims abstract description 6
235000021081 unsaturated fats Nutrition 0.000 claims abstract description 98
235000019197 fats Nutrition 0.000 claims abstract description 70
FOIBFBMSLDGNHL-UHFFFAOYSA-N 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin Chemical compound ClC1=C(Cl)C(Cl)=C2OC3=C(Cl)C(Cl)=C(Cl)C(Cl)=C3OC2=C1Cl FOIBFBMSLDGNHL-UHFFFAOYSA-N 0.000 claims abstract description 43
239000003054 catalyst Substances 0.000 claims abstract description 22
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 19
239000001257 hydrogen Substances 0.000 claims abstract description 17
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 17
150000004670 unsaturated fatty acids Chemical class 0.000 claims abstract description 16
235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 10
231100000770 Toxic Equivalency Factor Toxicity 0.000 claims description 38
150000004665 fatty acids Chemical class 0.000 claims description 36
235000014113 dietary fatty acids Nutrition 0.000 claims description 34
239000000194 fatty acid Substances 0.000 claims description 34
229930195729 fatty acid Natural products 0.000 claims description 34
HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 claims description 28
238000005984 hydrogenation reaction Methods 0.000 claims description 23
239000003921 oil Substances 0.000 claims description 16
235000019198 oils Nutrition 0.000 claims description 16
238000006298 dechlorination reaction Methods 0.000 claims description 9
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 8
235000021588 free fatty acids Nutrition 0.000 claims description 8
229910052740 iodine Inorganic materials 0.000 claims description 8
239000011630 iodine Substances 0.000 claims description 8
235000015112 vegetable and seed oil Nutrition 0.000 claims description 8
239000008158 vegetable oil Substances 0.000 claims description 8
150000003626 triacylglycerols Chemical class 0.000 claims description 5
FSPZPQQWDODWAU-UHFFFAOYSA-N 1,2,3,7,8-Pentachlorodibenzodioxin Chemical compound O1C2=CC(Cl)=C(Cl)C(Cl)=C2OC2=C1C=C(Cl)C(Cl)=C2 FSPZPQQWDODWAU-UHFFFAOYSA-N 0.000 claims description 4
238000004904 shortening Methods 0.000 claims description 4
240000002791 Brassica napus Species 0.000 claims description 3
235000004977 Brassica sinapistrum Nutrition 0.000 claims description 3
244000060011 Cocos nucifera Species 0.000 claims description 3
235000013162 Cocos nucifera Nutrition 0.000 claims description 3
244000068988 Glycine max Species 0.000 claims description 3
235000010469 Glycine max Nutrition 0.000 claims description 3
235000018936 Vitellaria paradoxa Nutrition 0.000 claims description 3
241001135917 Vitellaria paradoxa Species 0.000 claims description 3
244000020551 Helianthus annuus Species 0.000 claims 1
235000003222 Helianthus annuus Nutrition 0.000 claims 1
239000003925 fat Substances 0.000 description 61
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 30
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 16
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 11
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 8
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 8
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 8
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 8
239000005642 Oleic acid Substances 0.000 description 8
235000019482 Palm oil Nutrition 0.000 description 8
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 8
239000002540 palm oil Substances 0.000 description 8
238000004061 bleaching Methods 0.000 description 7
150000004671 saturated fatty acids Chemical class 0.000 description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 6
239000007858 starting material Substances 0.000 description 6
208000016444 Benign adult familial myoclonic epilepsy Diseases 0.000 description 5
235000021314 Palmitic acid Nutrition 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
150000002013 dioxins Chemical class 0.000 description 5
208000016427 familial adult myoclonic epilepsy Diseases 0.000 description 5
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 5
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
235000020777 polyunsaturated fatty acids Nutrition 0.000 description 5
125000005456 glyceride group Chemical group 0.000 description 4
235000020778 linoleic acid Nutrition 0.000 description 4
OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 4
150000003071 polychlorinated biphenyls Chemical class 0.000 description 4
239000000047 product Substances 0.000 description 4
238000000746 purification Methods 0.000 description 4
231100000331 toxic Toxicity 0.000 description 4
230000002588 toxic effect Effects 0.000 description 4
235000021355 Stearic acid Nutrition 0.000 description 3
239000003463 adsorbent Substances 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
235000013305 food Nutrition 0.000 description 3
239000000463 material Substances 0.000 description 3
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
238000012545 processing Methods 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
239000008117 stearic acid Substances 0.000 description 3
WCLNVRQZUKYVAI-UHFFFAOYSA-N 1,2,3,4,6,7,8-Heptachlorodibenzodioxin Chemical compound O1C2=C(Cl)C(Cl)=C(Cl)C(Cl)=C2OC2=C1C=C(Cl)C(Cl)=C2Cl WCLNVRQZUKYVAI-UHFFFAOYSA-N 0.000 description 2
WCYYQNSQJHPVMG-UHFFFAOYSA-N 1,2,3,4,7,8-Hexachlorodibenzodioxin Chemical compound O1C2=C(Cl)C(Cl)=C(Cl)C(Cl)=C2OC2=C1C=C(Cl)C(Cl)=C2 WCYYQNSQJHPVMG-UHFFFAOYSA-N 0.000 description 2
YCLUIPQDHHPDJJ-UHFFFAOYSA-N 1,2,3,6,7,8-Hexachlorodibenzodioxin Chemical compound O1C2=C(Cl)C(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2Cl YCLUIPQDHHPDJJ-UHFFFAOYSA-N 0.000 description 2
LGIRBUBHIWTVCK-UHFFFAOYSA-N 1,2,3,7,8,9-Hexachlorodibenzodioxin Chemical compound O1C2=CC(Cl)=C(Cl)C(Cl)=C2OC2=C1C=C(Cl)C(Cl)=C2Cl LGIRBUBHIWTVCK-UHFFFAOYSA-N 0.000 description 2
-1 C 15 fatty acids Chemical class 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
235000019486 Sunflower oil Nutrition 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
AHDXQBPYBBWTEQ-UHFFFAOYSA-N dibenzo-p-dioxin hexahydrochloride Chemical compound C(C=C1)=CC2=C1OC(C=CC=C1)=C1O2.Cl.Cl.Cl.Cl.Cl.Cl AHDXQBPYBBWTEQ-UHFFFAOYSA-N 0.000 description 2
239000012535 impurity Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
235000021281 monounsaturated fatty acids Nutrition 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
230000003389 potentiating effect Effects 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000002600 sunflower oil Substances 0.000 description 2
239000003440 toxic substance Substances 0.000 description 2
231100000419 toxicity Toxicity 0.000 description 2
230000001988 toxicity Effects 0.000 description 2
DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
LNWDBNKKBLRAMH-UHFFFAOYSA-N 1,2,3,4,6-pentachlorodibenzo-p-dioxin Chemical compound O1C2=C(Cl)C(Cl)=C(Cl)C(Cl)=C2OC2=C1C=CC=C2Cl LNWDBNKKBLRAMH-UHFFFAOYSA-N 0.000 description 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
240000003133 Elaeis guineensis Species 0.000 description 1
235000001950 Elaeis guineensis Nutrition 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
206010033546 Pallor Diseases 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000002252 acyl group Chemical group 0.000 description 1
231100000693 bioaccumulation Toxicity 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
150000004827 dibenzo-1,4-dioxins Chemical class 0.000 description 1
150000004826 dibenzofurans Chemical class 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
230000000185 dioxinlike effect Effects 0.000 description 1
235000013399 edible fruits Nutrition 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
235000021323 fish oil Nutrition 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
238000011010 flushing procedure Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
230000008520 organization Effects 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
241000894007 species Species 0.000 description 1
231100000167 toxic agent Toxicity 0.000 description 1
235000010692 trans-unsaturated fatty acids Nutrition 0.000 description 1
PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
- C11C3/123—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation using catalysts based principally on nickel or derivates

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Microbiology (AREA)
Fats And Perfumes (AREA)

ES18734246T 2017-07-07 2018-07-02 Proceso para la preparación de una composición de grasa hidrogenada Active ES2928748T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP17180365		2017-07-07
PCT/EP2018/067852 WO2019007918A1 (en)	2017-07-07	2018-07-02	PROCESS FOR THE PREPARATION OF A HYDROGENIC GREASE COMPOSITION

Publications (1)

Publication Number	Publication Date
ES2928748T3 true ES2928748T3 (es)	2022-11-22

Family

ID=59313069

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES18734246T Active ES2928748T3 (es)	2017-07-07	2018-07-02	Proceso para la preparación de una composición de grasa hidrogenada

Country Status (6)

Country	Link
EP (1)	EP3649219B1 (pl)
CN (1)	CN110914395B (pl)
DK (1)	DK3649219T3 (pl)
ES (1)	ES2928748T3 (pl)
PL (1)	PL3649219T3 (pl)
WO (1)	WO2019007918A1 (pl)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4169844A (en) *	1976-10-18	1979-10-02	Scm Corporation	Hydrogenation of unrefined glyceride oils
US4133822A (en) *	1977-07-13	1979-01-09	Scm Corporation	Hydrogenation of unsaturated fatty acid
US7585990B2 (en) *	2003-07-31	2009-09-08	Cargill, Incorporated	Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
WO2005012471A2 (en) *	2003-07-31	2005-02-10	Cargill, Incorporated	Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
CN1872408A (zh) *	2005-06-01	2006-12-06	中国科学院大连化学物理研究所	一种降低和消除二噁英毒性的方法
JP2008061571A (ja) *	2006-09-07	2008-03-21	Toyomac Ltd	飼料用液状油脂の製造方法および配合飼料
CA2739311A1 (en) *	2008-10-03	2010-04-08	Dag Arntsen	Process for removal of contaminations from organic oils
GB201019639D0 (en)	2010-11-19	2010-12-29	Loders Croklaan Bv	Method
US9540306B2 (en) *	2012-05-14	2017-01-10	Nippon Suisan Kaisha, Ltd.	Highly unsaturated fatty acid or highly unsaturated fatty acid ethyl ester with reduced environmental pollutants, and method for producing same

2018
- 2018-07-02 PL PL18734246.4T patent/PL3649219T3/pl unknown
- 2018-07-02 DK DK18734246.4T patent/DK3649219T3/da active
- 2018-07-02 ES ES18734246T patent/ES2928748T3/es active Active
- 2018-07-02 EP EP18734246.4A patent/EP3649219B1/en active Active
- 2018-07-02 CN CN201880045413.8A patent/CN110914395B/zh active Active
- 2018-07-02 WO PCT/EP2018/067852 patent/WO2019007918A1/en not_active Ceased

Also Published As

Publication number	Publication date
CN110914395B (zh)	2023-07-07
DK3649219T3 (en)	2022-10-24
EP3649219A1 (en)	2020-05-13
EP3649219B1 (en)	2022-10-05
WO2019007918A1 (en)	2019-01-10
PL3649219T3 (pl)	2023-02-06
CN110914395A (zh)	2020-03-24

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