ES373674A1 - Alkyl-sulfoxide and alkyl-sulfone terminated oligomers of ethylenically unsaturated monomers - Google Patents
Alkyl-sulfoxide and alkyl-sulfone terminated oligomers of ethylenically unsaturated monomersInfo
- Publication number
- ES373674A1 ES373674A1 ES373674A ES373674A ES373674A1 ES 373674 A1 ES373674 A1 ES 373674A1 ES 373674 A ES373674 A ES 373674A ES 373674 A ES373674 A ES 373674A ES 373674 A1 ES373674 A1 ES 373674A1
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- see formula
- formula
- hydrophilic group
- sulfoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000005360 alkyl sulfoxide group Chemical group 0.000 title 1
- 239000000178 monomer Substances 0.000 title 1
- -1 -CONH2 Chemical group 0.000 abstract 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/263—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms
- C07D207/27—2-Pyrrolidones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms with substituted hydrocarbon radicals directly attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C315/00—Preparation of sulfones; Preparation of sulfoxides
- C07C315/02—Preparation of sulfones; Preparation of sulfoxides by formation of sulfone or sulfoxide groups by oxidation of sulfides, or by formation of sulfone groups by oxidation of sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Mutual Connection Of Rods And Tubes (AREA)
- Polymerisation Methods In General (AREA)
- Paper (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Procedure for the preparation of oligomers, which have the formula ** (See formula) ** wherein R is a straight chain primary, branched chain primary, secondary, or tertiary group having 5 to 20 carbon atoms or mixtures thereof; R1 and R3 are hydrogen, methyl, ethyl, or -COOH; R2 and R4 are hydrogen, methyl, ethyl, -COOOH or -CH2COOH; Y is a strongly hydrophilic group and is -COOH, -CONH2, OCH3, (see formula); X is Y or a less hydrophilic group and is -COOC2H4OH, + COOC3H6OH, -CONHCH2OH, -CONHC2H5, -CONHCH3, -CONHC3H7, -COOCH3, -COOC2H5, -CN, -COCCH3, -COCC2H5-, or (see formula); a + e is from 2 to 50; ** (See formula) ** is 0 to 1, unless X is a less hydrophilic group in which case (see formula) is less than 0.6; and Z is oxygen or nothing, characterized by comprising the operation of oxidizing a compound of formula ** (See formula) ** wherein R, R1, R2, R3, R4, X, Y, a and b have the definitions indicated above. (Machine-translation by Google Translate, not legally binding)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77717568A | 1968-11-19 | 1968-11-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES373674A1 true ES373674A1 (en) | 1972-02-01 |
Family
ID=25109499
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES373674A Expired ES373674A1 (en) | 1968-11-19 | 1969-11-19 | Alkyl-sulfoxide and alkyl-sulfone terminated oligomers of ethylenically unsaturated monomers |
| ES376148A Expired ES376148A1 (en) | 1968-11-19 | 1970-02-03 | Alkyl-sulfoxide and alkyl-sulfone terminated oligomers of ethylenically unsaturated monomers |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES376148A Expired ES376148A1 (en) | 1968-11-19 | 1970-02-03 | Alkyl-sulfoxide and alkyl-sulfone terminated oligomers of ethylenically unsaturated monomers |
Country Status (15)
| Country | Link |
|---|---|
| AT (2) | AT304070B (en) |
| BE (1) | BE741797A (en) |
| BR (1) | BR6914155D0 (en) |
| CA (1) | CA923905A (en) |
| CH (1) | CH526591A (en) |
| DE (1) | DE1957384A1 (en) |
| ES (2) | ES373674A1 (en) |
| FI (1) | FI50535C (en) |
| FR (1) | FR2023631A1 (en) |
| GB (1) | GB1283087A (en) |
| IE (1) | IE33366B1 (en) |
| LU (1) | LU59831A1 (en) |
| NL (1) | NL163520C (en) |
| NO (1) | NO133759C (en) |
| SE (2) | SE359826B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1526301A (en) | 1975-07-23 | 1978-09-27 | Ciba Geigy Ag | Compositions of matter for use in the treatment of aqueous systems |
| US4189383A (en) | 1975-07-23 | 1980-02-19 | Ciba-Geigy Corporation | Novel compositions of matter for use in the treatment of aqueous systems |
| US4110429A (en) | 1976-12-30 | 1978-08-29 | Colgate-Palmolive Company | Antibacterial oral composition |
| US5618898A (en) * | 1992-02-10 | 1997-04-08 | Toagosei Chemical Industry Co., Ltd. | Weather-resistant solvent-based coating obtained by polymerization with thioether bond converted to sulfone bond |
| GB2264301B (en) * | 1992-02-10 | 1996-07-31 | Toa Gosei Chem Ind | A process for producing a polymer having excellent weatherability |
| CN110483774B (en) * | 2019-08-06 | 2022-01-28 | 金发科技股份有限公司 | Aromatic sulfone polymer and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3203938A (en) * | 1961-11-10 | 1965-08-31 | American Cyanamid Co | Process for copolymerizing an alkali metal ethylene sulfonate in lower saturated alcohols with free radical polymerization catalysts |
| CH465551A (en) * | 1964-11-13 | 1969-01-15 | Geigy Ag J R | Process for dyeing or printing textile fibers made of linear polyesters, cellulose esters or synthetic polyamides with disperse dyes |
-
1969
- 1969-09-25 CA CA063174A patent/CA923905A/en not_active Expired
- 1969-11-07 GB GB5463669A patent/GB1283087A/en not_active Expired
- 1969-11-10 NL NL6916918A patent/NL163520C/en not_active IP Right Cessation
- 1969-11-13 BR BR21415569A patent/BR6914155D0/en unknown
- 1969-11-13 IE IE154469A patent/IE33366B1/en unknown
- 1969-11-14 DE DE19691957384 patent/DE1957384A1/en not_active Ceased
- 1969-11-17 BE BE741797D patent/BE741797A/en unknown
- 1969-11-17 SE SE1574369A patent/SE359826B/xx unknown
- 1969-11-17 LU LU59831D patent/LU59831A1/xx unknown
- 1969-11-17 SE SE7306620A patent/SE396221B/en unknown
- 1969-11-18 NO NO456969A patent/NO133759C/no unknown
- 1969-11-18 FR FR6939698A patent/FR2023631A1/fr active Pending
- 1969-11-18 FI FI332369A patent/FI50535C/en active
- 1969-11-19 AT AT1081469A patent/AT304070B/en not_active IP Right Cessation
- 1969-11-19 AT AT589271A patent/AT305622B/en not_active IP Right Cessation
- 1969-11-19 ES ES373674A patent/ES373674A1/en not_active Expired
- 1969-11-19 CH CH1721969A patent/CH526591A/en not_active IP Right Cessation
-
1970
- 1970-02-03 ES ES376148A patent/ES376148A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IE33366L (en) | 1970-05-19 |
| BE741797A (en) | 1970-05-19 |
| FI50535C (en) | 1976-04-12 |
| DE1957384A1 (en) | 1970-06-11 |
| LU59831A1 (en) | 1970-01-19 |
| NO133759C (en) | 1976-06-23 |
| AT304070B (en) | 1972-12-27 |
| BR6914155D0 (en) | 1973-01-11 |
| FR2023631A1 (en) | 1970-08-21 |
| SE396221B (en) | 1977-09-12 |
| NL163520B (en) | 1980-04-15 |
| NL163520C (en) | 1980-09-15 |
| FI50535B (en) | 1975-12-31 |
| GB1283087A (en) | 1972-07-26 |
| AT305622B (en) | 1973-03-12 |
| CH526591A (en) | 1972-08-15 |
| CA923905A (en) | 1973-04-03 |
| IE33366B1 (en) | 1974-05-29 |
| NL6916918A (en) | 1970-05-21 |
| NO133759B (en) | 1976-03-15 |
| ES376148A1 (en) | 1972-03-16 |
| SE359826B (en) | 1973-09-10 |
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