ES401194A1 - Procedimiento para la obtencion de copolimeros de poli ( fosfazeno) de elevado peso molecular. - Google Patents
Procedimiento para la obtencion de copolimeros de poli ( fosfazeno) de elevado peso molecular.Info
- Publication number
- ES401194A1 ES401194A1 ES401194A ES401194A ES401194A1 ES 401194 A1 ES401194 A1 ES 401194A1 ES 401194 A ES401194 A ES 401194A ES 401194 A ES401194 A ES 401194A ES 401194 A1 ES401194 A1 ES 401194A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- monovalent radical
- chosen
- pch20
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ZSTLPJLUQNQBDQ-UHFFFAOYSA-N azanylidyne(dihydroxy)-$l^{5}-phosphane Chemical compound OP(O)#N ZSTLPJLUQNQBDQ-UHFFFAOYSA-N 0.000 title 1
- 229920001971 elastomer Polymers 0.000 title 1
- 239000000806 elastomer Substances 0.000 title 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- -1 alkali metal salt Chemical class 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920002632 poly(dichlorophosphazene) polymer Polymers 0.000 abstract 1
- 229920002627 poly(phosphazenes) Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/025—Polyphosphazenes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Polyethers (AREA)
- Paints Or Removers (AREA)
Abstract
Procedimiento para la obtención de copolímuros de poli(fosfazeno) de elevado peso molecular, que poseen unidades distribuidas al azar, de fórmula en las que A representa un radical monovalente elegido del grupo consistente en F(CH2)pCH20- y H(CF2)pCH20- y p es un entero de 1 a 9; B representa un radical monovalente elegido del grupo consistente en RC6H40- y RZC6H40- en donde R se elige del grupo consistente en H(CH2)q y F(CF2)q, en donde q es 0-5 y Z representa un miembro divalente del grupo consistente en -CH2-, -0-, -NH-, y -NR''-, en donde R'' es un radical monovalente seleccionado del grupo consistente en H(CH2)q- y F(CF2)q-, en donde q es 0-5 y la relación de A:B está comprendida entre 1:9 y 3:1; caracterizado porque se hace reaccionar una sal de metal alcalino de un flúor-alcóxido y uua sal de metal alcalino de un arilóxido, con poli(diclorofosfazeno) en solución; y a continuación se recupera el copolímero resultante.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12849671A | 1971-03-26 | 1971-03-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES401194A1 true ES401194A1 (es) | 1975-04-16 |
Family
ID=22435621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES401194A Expired ES401194A1 (es) | 1971-03-26 | 1972-03-25 | Procedimiento para la obtencion de copolimeros de poli ( fosfazeno) de elevado peso molecular. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US3700629A (es) |
| JP (1) | JPS546600B1 (es) |
| AU (1) | AU459198B2 (es) |
| BE (1) | BE781226A (es) |
| BR (1) | BR7201733D0 (es) |
| CA (1) | CA951847A (es) |
| ES (1) | ES401194A1 (es) |
| FR (1) | FR2130701B1 (es) |
| GB (1) | GB1355239A (es) |
| IT (1) | IT959575B (es) |
| NL (2) | NL169888B (es) |
| SE (1) | SE408902B (es) |
| ZA (1) | ZA721850B (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3755537A (en) * | 1971-10-29 | 1973-08-28 | Firestone Tire & Rubber Co | Process for separating oligomers from (npci2) rubber |
| US3867341A (en) * | 1973-09-28 | 1975-02-18 | Firestone Tire & Rubber Co | Metal 8-hydroxyquinolate complexes as stabilizers for poly(phosphazenes) to inhibit thermal degradation at elevated temperatures |
| US4005171A (en) * | 1974-05-28 | 1977-01-25 | Horizons Incorporated, A Division Of Horizons Research Incorporated | Catalytic preparation of soluble poly(dichlorophosphazenes) |
| US3972841A (en) * | 1975-01-29 | 1976-08-03 | The Firestone Tire & Rubber Company | Polyphosphazene elastomer with up to 35 mole per cent non-fluorinated alkoxy groups having improved low temperature flexibility |
| US4017458A (en) * | 1976-02-26 | 1977-04-12 | The Firestone Tire & Rubber Company | Stabilization of poly(phosphazenes) |
| US4053456A (en) * | 1976-02-27 | 1977-10-11 | Armstrong Cork Company | Poly(aryloxyphosphazene) copolymers |
| DE3584107D1 (de) * | 1984-04-18 | 1991-10-24 | Ethyl Corp | Polyphosphazen-verfahren. |
| US4593129A (en) * | 1984-04-18 | 1986-06-03 | Ethyl Corporation | Polyphosphazene process |
| US4567229A (en) * | 1984-12-18 | 1986-01-28 | Ethyl Corporation | Aryloxy-alkoxy substituted polyphosphazenes |
| US4870113A (en) * | 1988-12-23 | 1989-09-26 | Ethyl Corporation | Rigid polyphosphazene foam and process for making same |
| US5101002A (en) * | 1989-11-06 | 1992-03-31 | Ethyl Corporation | Cured phosphonitrilic elastomers having alkyl-substituted aryl units |
| KR100594705B1 (ko) * | 1998-12-09 | 2006-07-03 | 다우 코닝 코포레이션 | 촉매 조성물의 제조 방법 |
-
0
- NL NLAANVRAGE7203858,A patent/NL169888C/xx active
-
1971
- 1971-03-26 US US128496A patent/US3700629A/en not_active Expired - Lifetime
-
1972
- 1972-03-17 ZA ZA721850A patent/ZA721850B/xx unknown
- 1972-03-22 IT IT22300/72A patent/IT959575B/it active
- 1972-03-23 CA CA137,955,A patent/CA951847A/en not_active Expired
- 1972-03-23 NL NLAANVRAGE7203858,A patent/NL169888B/xx not_active IP Right Cessation
- 1972-03-23 AU AU40340/72A patent/AU459198B2/en not_active Expired
- 1972-03-24 SE SE7203878A patent/SE408902B/xx unknown
- 1972-03-24 FR FR7210515A patent/FR2130701B1/fr not_active Expired
- 1972-03-24 BR BR721733A patent/BR7201733D0/pt unknown
- 1972-03-24 BE BE781226A patent/BE781226A/xx not_active IP Right Cessation
- 1972-03-24 GB GB1384472A patent/GB1355239A/en not_active Expired
- 1972-03-25 JP JP3024772A patent/JPS546600B1/ja active Pending
- 1972-03-25 ES ES401194A patent/ES401194A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2130701B1 (es) | 1976-08-06 |
| NL169888B (nl) | 1982-04-01 |
| ZA721850B (en) | 1972-12-27 |
| JPS546600B1 (es) | 1979-03-29 |
| SE408902B (sv) | 1979-07-16 |
| BR7201733D0 (pt) | 1973-05-31 |
| GB1355239A (en) | 1974-06-05 |
| NL7203858A (es) | 1972-09-28 |
| CA951847A (en) | 1974-07-23 |
| US3700629A (en) | 1972-10-24 |
| DE2214923B2 (de) | 1975-08-21 |
| AU4034072A (en) | 1973-09-27 |
| DE2214923A1 (de) | 1972-11-23 |
| NL169888C (nl) | |
| IT959575B (it) | 1973-11-10 |
| BE781226A (fr) | 1972-09-25 |
| FR2130701A1 (es) | 1972-11-03 |
| AU459198B2 (en) | 1975-03-03 |
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