ES456928A1 - Procedimiento para la obtencion de butenodiol-diesteres. - Google Patents
Procedimiento para la obtencion de butenodiol-diesteres.Info
- Publication number
- ES456928A1 ES456928A1 ES456928A ES456928A ES456928A1 ES 456928 A1 ES456928 A1 ES 456928A1 ES 456928 A ES456928 A ES 456928A ES 456928 A ES456928 A ES 456928A ES 456928 A1 ES456928 A1 ES 456928A1
- Authority
- ES
- Spain
- Prior art keywords
- butenediol
- carboxylic acid
- manufacture
- carried out
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- -1 butenediol diesters Chemical class 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 230000007062 hydrolysis Effects 0.000 abstract 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- ORTVZLZNOYNASJ-UPHRSURJSA-N (z)-but-2-ene-1,4-diol Chemical class OC\C=C/CO ORTVZLZNOYNASJ-UPHRSURJSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/06—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to ring carbon atoms
- C07D307/08—Preparation of tetrahydrofuran
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/283—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la obtención de butenodiol-diésteres, caracterizado porque comprende hacer reaccionar butadieno, oxígeno molecular y un ácido carboxílico en presencia de un catalizador de metal noble, empleando un éster del ácido carboxílico con un alcohol alifático de cadena corta en lugar del ácido carboxílico, y realizándose la reacción en presencia de un catalizador de saponificación y, como mínimo, 1 mol de agua por mol de butadieno a transformar, o saponificándose el éster antes de la reacción.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19762611423 DE2611423A1 (de) | 1976-03-18 | 1976-03-18 | Verfahren zur herstellung von butendiol-diestern und deren folgeprodukte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES456928A1 true ES456928A1 (es) | 1978-01-16 |
Family
ID=5972783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES456928A Expired ES456928A1 (es) | 1976-03-18 | 1977-03-17 | Procedimiento para la obtencion de butenodiol-diesteres. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4239910A (es) |
| JP (1) | JPS52113912A (es) |
| BE (1) | BE852425A (es) |
| CA (1) | CA1095074A (es) |
| DE (1) | DE2611423A1 (es) |
| ES (1) | ES456928A1 (es) |
| FR (1) | FR2344520A1 (es) |
| GB (1) | GB1570405A (es) |
| IE (1) | IE44251B1 (es) |
| IT (1) | IT1075571B (es) |
| NL (1) | NL7702615A (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5432409A (en) * | 1977-08-03 | 1979-03-09 | Mitsubishi Chem Ind Ltd | Preparation of ciol and cyclic ether |
| DE2847068A1 (de) * | 1978-10-28 | 1980-05-08 | Basf Ag | Verfahren zur herstellung von butendioldiacetaten und von butandiol |
| JPS5845410B2 (ja) * | 1978-12-12 | 1983-10-08 | ジェイエスアール株式会社 | テトラヒドロフラン及び１，４↓−ブタンジオ−ルの製造方法 |
| JP7062783B2 (ja) * | 2018-09-27 | 2022-05-06 | 富士フイルム株式会社 | ジカルボン酸モノエステルの製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2217452C3 (de) * | 1971-04-17 | 1978-03-16 | Mitsubishi Chemical Industries, Ltd., Tokio | Verfahren zur Herstellung von 1,4-Diacyloxybuten-(2) |
| US3872163A (en) * | 1972-01-19 | 1975-03-18 | Kuraray Co | Method of preparing 1,4-diacyloxy-2-butenes |
| US3965156A (en) * | 1974-02-04 | 1976-06-22 | General Electric Company | Process for preparing vinyl esters of carboxylic acids |
| US3965152A (en) * | 1974-02-04 | 1976-06-22 | General Electric Company | Process for preparing allylic esters of carboxylic acids |
-
1976
- 1976-03-18 DE DE19762611423 patent/DE2611423A1/de not_active Withdrawn
-
1977
- 1977-02-14 IT IT20272/77A patent/IT1075571B/it active
- 1977-03-10 NL NL7702615A patent/NL7702615A/xx not_active Application Discontinuation
- 1977-03-10 FR FR7707073A patent/FR2344520A1/fr active Granted
- 1977-03-11 GB GB10353/77A patent/GB1570405A/en not_active Expired
- 1977-03-14 BE BE175756A patent/BE852425A/xx unknown
- 1977-03-14 JP JP2713377A patent/JPS52113912A/ja active Pending
- 1977-03-16 CA CA274,099A patent/CA1095074A/en not_active Expired
- 1977-03-17 ES ES456928A patent/ES456928A1/es not_active Expired
- 1977-03-18 US US05/779,284 patent/US4239910A/en not_active Expired - Lifetime
- 1977-03-18 IE IE585/77A patent/IE44251B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IT1075571B (it) | 1985-04-22 |
| FR2344520B1 (es) | 1980-08-01 |
| GB1570405A (en) | 1980-07-02 |
| DE2611423A1 (de) | 1977-10-06 |
| JPS52113912A (en) | 1977-09-24 |
| BE852425A (fr) | 1977-09-14 |
| FR2344520A1 (fr) | 1977-10-14 |
| IE44251L (en) | 1977-09-18 |
| CA1095074A (en) | 1981-02-03 |
| IE44251B1 (en) | 1981-09-23 |
| NL7702615A (nl) | 1977-09-20 |
| US4239910A (en) | 1980-12-16 |
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