ES462835A1 - Procedimiento para preparar estere de m-fenoxibencilo de acido 2-haloalquil (oxi-, tio-, sulfinil- o sulfonil) feni- lalcanoicos - Google Patents
Procedimiento para preparar estere de m-fenoxibencilo de acido 2-haloalquil (oxi-, tio-, sulfinil- o sulfonil) feni- lalcanoicosInfo
- Publication number
- ES462835A1 ES462835A1 ES462835A ES462835A ES462835A1 ES 462835 A1 ES462835 A1 ES 462835A1 ES 462835 A ES462835 A ES 462835A ES 462835 A ES462835 A ES 462835A ES 462835 A1 ES462835 A1 ES 462835A1
- Authority
- ES
- Spain
- Prior art keywords
- sulphinyl
- thio
- metal
- alkanoic acid
- animal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 241001465754 Metazoa Species 0.000 title abstract 4
- -1 sulphinyl-phenyl Chemical group 0.000 title abstract 4
- 239000002253 acid Substances 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title abstract 2
- 239000002917 insecticide Substances 0.000 title abstract 2
- 125000000446 sulfanediyl group Chemical group *S* 0.000 title abstract 2
- 230000000895 acaricidal effect Effects 0.000 title 1
- 239000000642 acaricide Substances 0.000 title 1
- 230000009885 systemic effect Effects 0.000 title 1
- 241000196324 Embryophyta Species 0.000 abstract 3
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 abstract 2
- VWCFQNQVNVMFGV-UHFFFAOYSA-N 1-octylsulfinyloctane Chemical compound CCCCCCCCS(=O)CCCCCCCC VWCFQNQVNVMFGV-UHFFFAOYSA-N 0.000 abstract 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 abstract 1
- 241000254173 Coleoptera Species 0.000 abstract 1
- 241000255925 Diptera Species 0.000 abstract 1
- JNCMHMUGTWEVOZ-UHFFFAOYSA-N F[CH]F Chemical compound F[CH]F JNCMHMUGTWEVOZ-UHFFFAOYSA-N 0.000 abstract 1
- PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical class NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 abstract 1
- 108010081348 HRT1 protein Hairy Proteins 0.000 abstract 1
- 102100021881 Hairy/enhancer-of-split related with YRPW motif protein 1 Human genes 0.000 abstract 1
- 241000256244 Heliothis virescens Species 0.000 abstract 1
- 241000255777 Lepidoptera Species 0.000 abstract 1
- 241000208125 Nicotiana Species 0.000 abstract 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- WABPPBHOPMUJHV-UHFFFAOYSA-N Sesamex Chemical compound CCOCCOCCOC(C)OC1=CC=C2OCOC2=C1 WABPPBHOPMUJHV-UHFFFAOYSA-N 0.000 abstract 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 229960005235 piperonyl butoxide Drugs 0.000 abstract 1
- 239000002728 pyrethroid Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
- 230000000699 topical effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
- C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procedimiento para preparar ésteres de m-fenoxi bencilo de ácidos 2-haloalquil (oxi- ,tio.,sulfinil o sulfonil) fenilalcanóicos, de fórmula**fórmula** en la que el sustituyente RCF2X- se encuentra en posición m o p con respecto al carbono al cual está unido el grupo éster de ácido alcanóico y X es S, O , SO o SO2; R es H, F, Cl, CHF2 o CF3, R2 es etilo, n-propilo, isopropilo, t-butilo o isopropenilo, R3 es hidrógeno o ciano, y sus isómeros ópticos, caracterizado porque comprende reaccionar un compuesto de fórmula **fórmula** en la que A es halógeno y R y R2 se definen como anteriormente, con un alcohol m- fenoxibencílico de fórmula **fórmula** en la que R3 se define como anteriormente, en presencia de un aceptor de ácido, consistente en una mina orgánica terciaría, y de un disolvente orgánico inerte, a una temperatura de 10 a 30ºC.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72881776A | 1976-10-01 | 1976-10-01 | |
| US72881876A | 1976-10-01 | 1976-10-01 | |
| US81460077A | 1977-07-11 | 1977-07-11 | |
| US83051577A | 1977-09-06 | 1977-09-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES462835A1 true ES462835A1 (es) | 1979-06-01 |
Family
ID=27505582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES462835A Expired ES462835A1 (es) | 1976-10-01 | 1977-09-30 | Procedimiento para preparar estere de m-fenoxibencilo de acido 2-haloalquil (oxi-, tio-, sulfinil- o sulfonil) feni- lalcanoicos |
Country Status (3)
| Country | Link |
|---|---|
| ES (1) | ES462835A1 (es) |
| FR (3) | FR2411176A2 (es) |
| NZ (1) | NZ185213A (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL61348A (en) * | 1979-11-28 | 1984-05-31 | American Cyanamid Co | (-)-alpha-cyano-m-phenoxybenzyl(+)alpha-isopropyl-4-difluoromethoxy-phenylacetate,its preparation and its use as an insecticide |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1559799A (en) * | 1975-11-12 | 1980-01-30 | Shell Int Research | Process for preparing substituted benzylesters |
| US4242357A (en) * | 1976-04-09 | 1980-12-30 | Bayer Aktiengesellschaft | Carboxylic acid esters for combating pests |
-
1977
- 1977-09-20 NZ NZ18521377A patent/NZ185213A/xx unknown
- 1977-09-30 ES ES462835A patent/ES462835A1/es not_active Expired
-
1978
- 1978-03-13 FR FR7807153A patent/FR2411176A2/fr active Pending
- 1978-12-08 FR FR7834674A patent/FR2411177A1/fr active Granted
- 1978-12-08 FR FR7834673A patent/FR2424900A2/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2411176A2 (fr) | 1979-07-06 |
| FR2411177A1 (fr) | 1979-07-06 |
| FR2411177B2 (es) | 1984-06-01 |
| FR2424900B2 (es) | 1982-04-09 |
| NZ185213A (en) | 1981-03-16 |
| FR2424900A2 (fr) | 1979-11-30 |
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