ES472082A1 - Un procedimiento perfeccionado para la preparacion de alde- hidos y acidos insaturados. - Google Patents

Un procedimiento perfeccionado para la preparacion de alde- hidos y acidos insaturados.

Info

Publication number
ES472082A1
ES472082A1 ES472082A ES472082A ES472082A1 ES 472082 A1 ES472082 A1 ES 472082A1 ES 472082 A ES472082 A ES 472082A ES 472082 A ES472082 A ES 472082A ES 472082 A1 ES472082 A1 ES 472082A1
Authority
ES
Spain
Prior art keywords
olefins
promoter elements
oxidation
various promoter
molybdenum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES472082A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ES472082A1 publication Critical patent/ES472082A1/es
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un procedimiento perfeccionado para la preparación de aldehídos y ácidos insaturados a partir de propileno o isobutileno mediante la oxidación en fase vapor de propileno o isobuliteno con oxígeno molecular a una temperatura de aproximadamente 200º a 600º C, en presencia de un catalizador, que comprende usar como catalizador un catalizador de la fórmula AaBbFecXdMeMo12Ox en la que A es metal alcalino, talio, plata o mezclas de los mismos; B es cobalto, níquel, zinc, cadmio, berilio, calcio, estroncio, bario, radio o mezclas de los mismo; X es bismuto, teluro o mezclas de los mismos.
ES472082A 1977-07-28 1978-07-27 Un procedimiento perfeccionado para la preparacion de alde- hidos y acidos insaturados. Expired ES472082A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81973377A 1977-07-28 1977-07-28

Publications (1)

Publication Number Publication Date
ES472082A1 true ES472082A1 (es) 1979-04-16

Family

ID=25228904

Family Applications (1)

Application Number Title Priority Date Filing Date
ES472082A Expired ES472082A1 (es) 1977-07-28 1978-07-27 Un procedimiento perfeccionado para la preparacion de alde- hidos y acidos insaturados.

Country Status (13)

Country Link
EP (1) EP0000663B1 (es)
AT (1) AT359055B (es)
BR (1) BR7804848A (es)
CA (1) CA1133505A (es)
DD (1) DD140034A5 (es)
DE (1) DE2861192D1 (es)
ES (1) ES472082A1 (es)
IN (1) IN148201B (es)
IT (1) IT1118241B (es)
NO (1) NO151083C (es)
PT (1) PT68313A (es)
RO (1) RO75319A (es)
YU (1) YU182978A (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1127137A (en) * 1977-12-20 1982-07-06 Dev D. Suresh Ammoxidation of olefins with novel antimonate catalysts
GB2077257B (en) * 1980-05-19 1984-06-27 Asahi Chemical Ind Process for producing methacrolein
US4532365A (en) * 1982-09-20 1985-07-30 The Halcon Sd Group, Inc. Conversion of alkanes to unsaturated aldehydes
EP0279374B1 (en) * 1987-02-17 1992-01-02 Nippon Shokubai Kagaku Kogyo Co., Ltd Catalyst for oxidation of olefin or tertiary alcohol and process for production thereof
US5162578A (en) * 1987-06-12 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Acetic acid from ethane, ethylene and oxygen

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5112603B1 (es) * 1971-05-26 1976-04-21
CA1049553A (en) * 1973-04-30 1979-02-27 The Standard Oil Company Preparation of acrylic acid and methacrylic acid from propylene or isobutylene in a one-reactor, fluid-bed system
GB1456752A (en) * 1973-05-10 1976-11-24 Japan Synthetic Rubber Co Ltd Catalyst and process for the production of unsaturated carbonyl compounds
US3972920A (en) * 1973-06-11 1976-08-03 Mitsubishi Rayon Co., Ltd. Process for producing unsaturated aldehydes, unsaturated fatty acids or conjugated dienes
US4001317A (en) * 1974-07-22 1977-01-04 Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
GB1523772A (en) * 1974-07-22 1978-09-06 Standard Oil Co Oxidation catalysts
GB1489559A (en) * 1975-03-03 1977-10-19 Mitsubishi Rayon Co Catalytic process for the preparation of acrylic acid or methacrylic acid
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
IN142430B (es) * 1975-04-21 1977-07-09 Standard Oil Co
US4118419A (en) * 1975-12-03 1978-10-03 Mitsubishi Rayon Company, Ltd. Catalytic process for the preparation of an unsaturated carboxylic acid
DE2626887B2 (de) * 1976-06-16 1978-06-29 Basf Ag, 6700 Ludwigshafen Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure
US4065507A (en) * 1976-08-02 1977-12-27 Standard Oil Company Preparation of methacrylic derivatives from tertiary butyl-containing compounds

Also Published As

Publication number Publication date
BR7804848A (pt) 1979-04-10
IN148201B (es) 1980-11-29
IT1118241B (it) 1986-02-24
CA1133505A (en) 1982-10-12
DE2861192D1 (en) 1981-12-24
PT68313A (en) 1978-08-01
ATA551778A (de) 1980-03-15
DD140034A5 (de) 1980-02-06
RO75319A (ro) 1980-11-30
NO782583L (no) 1979-01-30
YU182978A (en) 1982-08-31
IT7826141A0 (it) 1978-07-26
AT359055B (de) 1980-10-27
NO151083C (no) 1985-02-06
NO151083B (no) 1984-10-29
EP0000663B1 (en) 1981-10-21
EP0000663A1 (en) 1979-02-07

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19971103