ES474699A1 - Un procedimiento continuo para hidroformilar propileno. - Google Patents
Un procedimiento continuo para hidroformilar propileno.Info
- Publication number
- ES474699A1 ES474699A1 ES474699A ES474699A ES474699A1 ES 474699 A1 ES474699 A1 ES 474699A1 ES 474699 A ES474699 A ES 474699A ES 474699 A ES474699 A ES 474699A ES 474699 A1 ES474699 A1 ES 474699A1
- Authority
- ES
- Spain
- Prior art keywords
- propylene
- carbon monoxide
- hydrogen
- liquid body
- butyraldehydes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007037 hydroformylation reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000007788 liquid Substances 0.000 abstract 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical class CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000000536 complexating effect Effects 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 239000008240 homogeneous mixture Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento continuo para hidroformilar propileno para producir butiraldehidoss, que incluye los pasos de: establecer un cuerpo líquido de una mezcla homogénea que contiene propileno, hidrógeno, monóxido de carbono, dichos productos de buteraldehido, productos de condensación líquidos de alto punto de ebullición de dichos butiraldehidos, un catalizador de complejo de rodio soluble que consiste esencialmente en rodio formando complejo con monóxido de carbono y trifenilfosfina, y trifenilfosfina libre; alimentar al cuerpo líquido una corriente de reciclado gaseosa que contiene por lo menos hidrógeno y propileno no reaccionado; alimentar cantidades de reposición de monóxido de carbono, hidrógeno y propileno al cuerpo líquido.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76233677A | 1977-01-25 | 1977-01-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES474699A1 true ES474699A1 (es) | 1979-04-01 |
Family
ID=25064757
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES466292A Expired ES466292A1 (es) | 1977-01-25 | 1978-01-24 | Mejora en un procedimiento para hidroformilar una alfa-ole- fina |
| ES474698A Expired ES474698A1 (es) | 1977-01-25 | 1978-10-31 | Un procedimiento continuo para hidroformilar una alfa-olefi-na. |
| ES474699A Expired ES474699A1 (es) | 1977-01-25 | 1978-10-31 | Un procedimiento continuo para hidroformilar propileno. |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES466292A Expired ES466292A1 (es) | 1977-01-25 | 1978-01-24 | Mejora en un procedimiento para hidroformilar una alfa-ole- fina |
| ES474698A Expired ES474698A1 (es) | 1977-01-25 | 1978-10-31 | Un procedimiento continuo para hidroformilar una alfa-olefi-na. |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS5857413B2 (es) |
| AT (1) | AT368122B (es) |
| AU (1) | AU522597B2 (es) |
| BE (1) | BE863268R (es) |
| BR (1) | BR7800396A (es) |
| CA (1) | CA1105946A (es) |
| DE (1) | DE2802923C2 (es) |
| ES (3) | ES466292A1 (es) |
| FR (1) | FR2377992A2 (es) |
| GB (1) | GB1599922A (es) |
| IT (1) | IT1093322B (es) |
| MX (1) | MX148047A (es) |
| NL (1) | NL186444C (es) |
| SE (1) | SE444311B (es) |
| ZA (1) | ZA78147B (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE16286T1 (de) * | 1979-03-21 | 1983-05-11 | Davy Mckee (London) Ltd., London | Hydroformylierungsverfahren. |
| DE2965157D1 (en) * | 1979-03-21 | 1983-05-11 | Davy Mckee London | Process for the production of aldehydes by hydroformylation of alkenes |
| FR2459683A1 (fr) | 1979-06-22 | 1981-01-16 | Ugine Kuhlmann | Procede de stabilisation et de regeneration du catalyseur d'hydroformylation du propene |
| JPS606630A (ja) * | 1983-06-24 | 1985-01-14 | Kuraray Co Ltd | アリルアルコ−ルの連続ヒドロホルミル化方法 |
| JPS60174723U (ja) * | 1984-04-27 | 1985-11-19 | 安本 重一 | タイトフレ−ム |
| EP0350922B1 (en) * | 1988-07-14 | 1994-09-21 | UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation) | Process for catalyst-aldehyde product separation |
| DE102005046250B4 (de) * | 2005-09-27 | 2020-10-08 | Evonik Operations Gmbh | Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren |
| JP2013181004A (ja) * | 2012-03-02 | 2013-09-12 | Jnc Corp | オキソ反応触媒寿命改良法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3487112A (en) * | 1967-04-27 | 1969-12-30 | Monsanto Co | Vapor phase hydroformylation process |
| US3527809A (en) * | 1967-08-03 | 1970-09-08 | Union Carbide Corp | Hydroformylation process |
| US3555098A (en) * | 1967-12-13 | 1971-01-12 | Union Oil Co | Hydroformylation |
| GB1338237A (en) * | 1969-12-22 | 1973-11-21 | Union Carbide Corp | Hydroformylation process |
| JPS50123611A (es) * | 1974-03-12 | 1975-09-29 | ||
| JPS511687A (en) * | 1974-06-27 | 1976-01-08 | Sadao Ukita | Tenpura hanbaagunadono nenseizairyono katakeiseinisaishiteno atsumichoseisochi |
| JPS516124A (en) * | 1974-07-05 | 1976-01-19 | Hitachi Chemical Co Ltd | Kikinzoku oyobi ryusandono kaishuhoho |
-
1978
- 1978-01-10 ZA ZA00780147A patent/ZA78147B/xx unknown
- 1978-01-19 CA CA295,310A patent/CA1105946A/en not_active Expired
- 1978-01-23 AU AU32629/78A patent/AU522597B2/en not_active Expired
- 1978-01-24 JP JP53005880A patent/JPS5857413B2/ja not_active Expired
- 1978-01-24 AT AT0049178A patent/AT368122B/de not_active IP Right Cessation
- 1978-01-24 DE DE2802923A patent/DE2802923C2/de not_active Expired
- 1978-01-24 BE BE184600A patent/BE863268R/xx active
- 1978-01-24 SE SE7800872A patent/SE444311B/sv not_active IP Right Cessation
- 1978-01-24 MX MX172157A patent/MX148047A/es unknown
- 1978-01-24 IT IT19576/78A patent/IT1093322B/it active
- 1978-01-24 ES ES466292A patent/ES466292A1/es not_active Expired
- 1978-01-24 FR FR7801867A patent/FR2377992A2/fr active Granted
- 1978-01-24 NL NLAANVRAGE7800856,A patent/NL186444C/xx not_active IP Right Cessation
- 1978-01-24 BR BR7800396A patent/BR7800396A/pt unknown
- 1978-01-24 GB GB2907/78A patent/GB1599922A/en not_active Expired
- 1978-10-31 ES ES474698A patent/ES474698A1/es not_active Expired
- 1978-10-31 ES ES474699A patent/ES474699A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE7800872L (sv) | 1978-09-15 |
| BR7800396A (pt) | 1978-08-22 |
| ATA49178A (de) | 1982-01-15 |
| JPS5392706A (en) | 1978-08-15 |
| ZA78147B (en) | 1978-11-29 |
| SE444311B (sv) | 1986-04-07 |
| DE2802923A1 (de) | 1978-07-27 |
| IT1093322B (it) | 1985-07-19 |
| CA1105946A (en) | 1981-07-28 |
| FR2377992B2 (es) | 1984-02-03 |
| NL7800856A (nl) | 1978-07-27 |
| MX148047A (es) | 1983-03-09 |
| AU522597B2 (en) | 1982-06-17 |
| ES474698A1 (es) | 1979-04-01 |
| BE863268R (fr) | 1978-07-24 |
| AU3262978A (en) | 1979-08-02 |
| GB1599922A (en) | 1981-10-07 |
| IT7819576A0 (it) | 1978-01-24 |
| FR2377992A2 (fr) | 1978-08-18 |
| AT368122B (de) | 1982-09-10 |
| ES466292A1 (es) | 1979-01-16 |
| NL186444C (nl) | 1990-12-03 |
| DE2802923C2 (de) | 1986-03-13 |
| JPS5857413B2 (ja) | 1983-12-20 |
| NL186444B (nl) | 1990-07-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19971103 |