ES478008A1 - Procedimiento para preparar cicloalcanoles y cicloalcanonas. - Google Patents
Procedimiento para preparar cicloalcanoles y cicloalcanonas.Info
- Publication number
- ES478008A1 ES478008A1 ES478008A ES478008A ES478008A1 ES 478008 A1 ES478008 A1 ES 478008A1 ES 478008 A ES478008 A ES 478008A ES 478008 A ES478008 A ES 478008A ES 478008 A1 ES478008 A1 ES 478008A1
- Authority
- ES
- Spain
- Prior art keywords
- oxidation
- cycloalkanones
- metal salt
- cycloalkanols
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 230000003647 oxidation Effects 0.000 abstract 4
- 238000007254 oxidation reaction Methods 0.000 abstract 4
- -1 cycloalkyl hydroperoxide Chemical compound 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001924 cycloalkanes Chemical class 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para preparar cicloalconoles y cicloalcanonas por oxidación, en fase líquida, de un cicloalcano de 5 a 12 átomos de carbono en el anillo, mediante un gas que contiene oxígeno molecular, obteniendo así una mezcla de oxidación que contiene hidroperóxido de cicloalcohilo, la cual mezcla de oxidación, en la etapa b), se trata, en presencia de una solución acuosa de un hidróxido de metal alcalino, con una sal metálica que causa la descomposición del hidroperóxido de cicloalcohilo, caracterizado porque, antes del tratamiento con la sal metálica en la etapa b), los ácidos presentes en la mezcla de oxidación son parcial o totalmente neutralizados en la etapa a).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7802125A NL7802125A (nl) | 1978-02-25 | 1978-02-25 | Werkwijze voor het bereiden van cycloalkanolen en cycloalkanonen. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES478008A1 true ES478008A1 (es) | 1979-07-01 |
Family
ID=19830398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES478008A Expired ES478008A1 (es) | 1978-02-25 | 1979-02-23 | Procedimiento para preparar cicloalcanoles y cicloalcanonas. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4238415A (es) |
| EP (1) | EP0004105B1 (es) |
| JP (1) | JPS54135748A (es) |
| AR (1) | AR219789A1 (es) |
| BR (1) | BR7901214A (es) |
| CA (1) | CA1118453A (es) |
| CS (1) | CS227668B2 (es) |
| DE (1) | DE2960603D1 (es) |
| ES (1) | ES478008A1 (es) |
| IN (1) | IN150726B (es) |
| MX (1) | MX5676E (es) |
| NL (1) | NL7802125A (es) |
| PL (1) | PL114149B1 (es) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57169438A (en) * | 1981-04-14 | 1982-10-19 | Ube Ind Ltd | Preparation of cyclohexanol and cyclohexanone |
| NL8201695A (nl) * | 1982-04-23 | 1983-11-16 | Stamicarbon | Werkwijze voor de bereiding van cyclohexanol en cyclohexanon. |
| DE3403410A1 (de) * | 1984-02-01 | 1985-08-01 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von cyclohexylhydroperoxid sowie cyclohexanol und cyclohexanon enthaltenden gemischen |
| US5206441A (en) * | 1992-04-06 | 1993-04-27 | E. I. Du Pont De Nemours And Company | High rate process for preparation of cyclohexanol and cyclohexanone |
| NL9201269A (nl) * | 1992-07-15 | 1994-02-01 | Dsm Nv | Werkwijze voor de bereiding van cyclohexylhydroperoxide. |
| BE1007904A3 (nl) * | 1993-12-23 | 1995-11-14 | Dsm Nv | Werkwijze voor de bereiding van een alkanol en/of een alkanon. |
| BE1009662A3 (nl) * | 1995-10-13 | 1997-06-03 | Dsm Nv | Werkwijze voor het ontleden van cycloalkylhydroperoxide. |
| US5780683A (en) * | 1996-09-11 | 1998-07-14 | Abb Lummus Global Inc. | Cyclohexane oxidation |
| BE1011041A3 (nl) * | 1997-03-12 | 1999-04-06 | Dsm Nv | Werkwijze voor het ontleden van cycloalkylhydroperoxide. |
| BR9913474A (pt) * | 1998-08-26 | 2001-05-22 | Du Pont | Processo aperfeiçoado para a decomposição de um hidroperóxido para formar uma mistura que contém um álcool e uma cetona correspondentes |
| FR2802526B1 (fr) * | 1999-12-17 | 2003-04-18 | Rhodia Polyamide Intermediates | Procede de preparation de melanges alcools/cetones |
| DE60023358T2 (de) | 2000-08-18 | 2006-07-13 | Invista Technologies S.A.R.L., Wilmington | Verbesserter hydroperoxid zersetzungskatalysator |
| US6700022B2 (en) * | 2002-06-05 | 2004-03-02 | E. I. Du Pont De Nemours And Company | High yield cyclohexyl hydroperoxide decompostition process |
| US7091365B2 (en) | 2004-03-08 | 2006-08-15 | Abb Lummus Global Inc. | Process for olefin epoxidation and co-production of nylon precursor |
| CN101010273B (zh) * | 2004-08-24 | 2010-06-30 | 因维斯塔技术有限公司 | 减少含有环己烯酮的有机混合物中的环己烯酮含量的方法 |
| EP1805125A1 (en) * | 2004-10-27 | 2007-07-11 | DSMIP Assets B.V. | Process for the preparation of cyclohexanol and cyclohexanone |
| EA011556B1 (ru) * | 2004-12-22 | 2009-04-28 | ДСМ АйПи АССЕТС Б.В. | Способ разложения циклогексилгидропероксида |
| JP2008528528A (ja) * | 2005-01-25 | 2008-07-31 | ディーエスエム アイピー アセッツ ビー．ブイ． | シクロヘキサノンおよびシクロヘキサノールの製造方法 |
| US7592493B2 (en) * | 2007-06-27 | 2009-09-22 | H R D Corporation | High shear process for cyclohexanol production |
| US7491856B2 (en) | 2007-06-27 | 2009-02-17 | H R D Corporation | Method of making alkylene glycols |
| US8304584B2 (en) | 2007-06-27 | 2012-11-06 | H R D Corporation | Method of making alkylene glycols |
| TW200944497A (en) * | 2008-04-17 | 2009-11-01 | China Petrochemical Dev Corp | System and method for producing naphthenone |
| CN101607875B (zh) * | 2008-06-17 | 2012-07-25 | 中国石油化学工业开发股份有限公司 | 制造环烷酮的方法 |
| EA025632B1 (ru) | 2011-12-07 | 2017-01-30 | Кап Iii Б.В. | Способ получения смеси, содержащей циклогексанол и циклогексанон |
| CN103987452B (zh) | 2011-12-07 | 2016-02-24 | Capiii有限公司 | 包含环己醇和环己酮的混合物的制备方法 |
| JP6565926B2 (ja) | 2014-10-31 | 2019-09-04 | 宇部興産株式会社 | ケトン及び／又はアルコールの製造方法及びそのシステム |
| JP6816724B2 (ja) * | 2015-12-07 | 2021-01-27 | 宇部興産株式会社 | ケトン及び／又はアルコールの製造方法及びそのシステム |
| EP3781543B1 (en) * | 2018-04-17 | 2023-09-27 | DSM IP Assets B.V. | Oxidation of alkylated p-hydroquinones in aqueous solutions by oxygen |
| CN110871064B (zh) * | 2018-08-29 | 2022-09-23 | 中国石油化工股份有限公司 | 一种碳材料组合处理液及其制备方法、碳材料及其应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2070977A5 (es) * | 1969-12-12 | 1971-09-17 | Rhone Poulenc Sa | |
| DE2127520A1 (de) * | 1971-06-03 | 1972-12-14 | Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Cycloalkanol- und Cycloalkanon-Gemischen |
| DE2148322B2 (de) * | 1971-09-28 | 1977-02-10 | Davy International Ag, 6000 Frankfurt | Kreislaufverfahren zur entfernung der bei der partiellen oxidation von cycloalkan entstandenen carbonsaeuren und carbonsaeurederivate aus den erhaltenen oxidationsprodukten |
| AT327166B (de) * | 1972-10-21 | 1976-01-26 | Stamicarbon | Verfahren zur herstellung eines gemisches aus cycloalkanon und cycloalkanol mit 5 bis 12 kohlenstoffatomen, insbesondere aus cyclohexanon und cyclohexanol |
| JPS5432416A (en) * | 1977-08-19 | 1979-03-09 | Sumitomo Chem Co Ltd | Treatment of oxidized liquid |
-
1978
- 1978-02-25 NL NL7802125A patent/NL7802125A/xx not_active Application Discontinuation
-
1979
- 1979-02-20 EP EP79200086A patent/EP0004105B1/en not_active Expired
- 1979-02-20 DE DE7979200086T patent/DE2960603D1/de not_active Expired
- 1979-02-21 AR AR275576A patent/AR219789A1/es active
- 1979-02-21 IN IN124/DEL/79A patent/IN150726B/en unknown
- 1979-02-21 CA CA000321994A patent/CA1118453A/en not_active Expired
- 1979-02-23 MX MX797738U patent/MX5676E/es unknown
- 1979-02-23 BR BR7901214A patent/BR7901214A/pt unknown
- 1979-02-23 ES ES478008A patent/ES478008A1/es not_active Expired
- 1979-02-24 PL PL1979213694A patent/PL114149B1/pl unknown
- 1979-02-26 JP JP2178379A patent/JPS54135748A/ja active Granted
- 1979-02-26 US US06/015,433 patent/US4238415A/en not_active Expired - Lifetime
- 1979-02-26 CS CS791292A patent/CS227668B2/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AR219789A1 (es) | 1980-09-15 |
| PL114149B1 (en) | 1981-01-31 |
| EP0004105B1 (en) | 1981-08-12 |
| CS227668B2 (en) | 1984-05-14 |
| BR7901214A (pt) | 1979-10-02 |
| JPS54135748A (en) | 1979-10-22 |
| EP0004105A1 (en) | 1979-09-19 |
| MX5676E (es) | 1983-12-08 |
| NL7802125A (nl) | 1979-08-28 |
| JPS6257607B2 (es) | 1987-12-02 |
| DE2960603D1 (en) | 1981-11-12 |
| US4238415A (en) | 1980-12-09 |
| IN150726B (es) | 1982-11-27 |
| PL213694A1 (pl) | 1979-12-17 |
| CA1118453A (en) | 1982-02-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20000201 |