ES480390A1 - Un procedimiento de preparacion de un copolimero de injerto. - Google Patents
Un procedimiento de preparacion de un copolimero de injerto.Info
- Publication number
- ES480390A1 ES480390A1 ES480390A ES480390A ES480390A1 ES 480390 A1 ES480390 A1 ES 480390A1 ES 480390 A ES480390 A ES 480390A ES 480390 A ES480390 A ES 480390A ES 480390 A1 ES480390 A1 ES 480390A1
- Authority
- ES
- Spain
- Prior art keywords
- ester
- epoxy
- graft copolymer
- electrodeposition
- fatty acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000578 graft copolymer Polymers 0.000 title abstract 2
- 238000004070 electrodeposition Methods 0.000 title 1
- 150000002148 esters Chemical class 0.000 abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 229920000768 polyamine Polymers 0.000 abstract 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 2
- 239000004971 Cross linker Substances 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- 229920003180 amino resin Polymers 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000004965 peroxy acids Chemical group 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D187/00—Coating compositions based on unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
- C09D187/005—Block or graft polymers not provided for in groups C09D101/00 - C09D185/04
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
- C08G81/025—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4488—Cathodic paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Epoxy Resins (AREA)
Abstract
Un procedimiento de preparación de un copolímero de injerto, constituido por una porción de mono-epóxido injertada sobre una porción de esqueleto acrílico-amínico, caracterizado porque la porción de esqueleto acrílico-amínico y la porción de monoepóxido se hacen reaccionar en proporciones que producen un copolímero de injerto donde las respectivas porciones están constituidas esencialmente, sobre el peso del copolímero de injerto, por alrededor de: (a) 25-60% de un copolímero de esqueleto acrílico-amínico que contribuye con: 14,7-35% de un acrilato o metacrilato de amina secundaria, que da 0,08 a 0,2 equivalentes de amina terciaria por 100 g. de copolímero de injeto, 7-17% de acrilato o metacrilato hidroxi- funcional, 3-7,3% de acrilato de etilo o metacrilato de metilo y 0,3-0,7% de mercaptoetanol, que proporciona la funcionalidad hidroxi primaria terminal, polimerizado por un injerto con (b) y (c): (b) 33-60% de un copolímero de epoxi-ácido graso de un polímero de condensación de proporciones equimoleculares de epiclorhidrina y bisfenol A, que ha reaccionado con un ácido graso en una relación molar de resina epoxi a ácido graso de 1/1,4-1,7 y (c) 7-15% de un éster glicidílico de un ácido carboxílico terciario que contiene de 7 a 9 átomos de carbono.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/902,887 US4167499A (en) | 1978-05-09 | 1978-05-09 | Graft copolymer useful in electrodeposition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES480390A1 true ES480390A1 (es) | 1980-08-16 |
Family
ID=25416560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES480390A Expired ES480390A1 (es) | 1978-05-09 | 1979-05-09 | Un procedimiento de preparacion de un copolimero de injerto. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4167499A (es) |
| EP (1) | EP0005136A1 (es) |
| JP (1) | JPS54146890A (es) |
| AT (1) | AT368532B (es) |
| AU (1) | AU524492B2 (es) |
| BE (1) | BE876108A (es) |
| BR (1) | BR7902589A (es) |
| CA (1) | CA1124434A (es) |
| ES (1) | ES480390A1 (es) |
| FR (1) | FR2425460A1 (es) |
| GB (1) | GB2021122A (es) |
| IT (1) | IT1113390B (es) |
| ZA (1) | ZA792215B (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4246089A (en) * | 1979-11-30 | 1981-01-20 | E. I. Du Pont De Nemours And Company | Graft copolymer useful in electrodeposition |
| BR8008248A (pt) * | 1979-12-21 | 1981-07-21 | Du Pont | Processo para producao de uma nova composicao de materia e de uma composicao aquosa de revestimento, e aperfeicoamento em processo para eletrorrevestimento |
| US4335031A (en) * | 1979-12-21 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Electrocoating composition with polyhydroxyamine and polybutadiene |
| US4340523A (en) * | 1979-12-21 | 1982-07-20 | E. I. Dupont De Nemours And Company | Electrocoating composition with polyhydroxyamine and epoxy |
| US4338235A (en) * | 1979-12-21 | 1982-07-06 | E. I. Du Pont De Nemours And Company | Electrocoating composition with polyhydroxyamine and acrylic or methacrylic polymers |
| US4338236A (en) * | 1979-12-21 | 1982-07-06 | E. I. Du Pont De Nemours And Company | Polyhydroxyamine dispersant useful in electrodeposition |
| US4308121A (en) * | 1979-12-21 | 1981-12-29 | E. I. Du Pont De Nemours And Company | Electrocoating process using polyhydroxyamine and second polymers |
| US4337187A (en) * | 1979-12-21 | 1982-06-29 | E. I. Dupont De Nemours And Company | Electrocoating composition with polyhydroxyamine and polyesters or alkyds |
| WO1982000148A1 (en) * | 1980-07-03 | 1982-01-21 | Australia Ltd Dulux | Dispersion process and product |
| US4383058A (en) * | 1980-12-31 | 1983-05-10 | Mobil Oil Corporation | Epoxy-amine copolymer reaction product and aqueous coating compositions thereof |
| US4459393A (en) * | 1981-12-09 | 1984-07-10 | Shell Oil Company | Process for the preparation of self-linking resinous binders and their use in surface coating compositions |
| US4608314A (en) * | 1984-12-04 | 1986-08-26 | Scm Corporation | Acrylic and acrylic/epoxy copolymer compositions as self-curing cathodic electrocoating vehicles |
| AU599453B2 (en) * | 1988-02-01 | 1990-07-19 | Rohm And Haas Company | Carbon michael cure activated by tertiary amines and epoxides |
| DE4206431A1 (de) * | 1992-02-29 | 1993-09-02 | Basf Lacke & Farben | Wasserverduennbare ueberzugsmittel |
| US6020069A (en) * | 1998-06-18 | 2000-02-01 | E. I. Du Pont De Nemours And Company | Cathodic electrocoating composition containing an epoxy resin chain extended with a primary amine |
| US6326059B1 (en) | 2000-08-07 | 2001-12-04 | E.I. Du Pont De Nemours And Company | Two-stage cure coating compositions |
| US7459504B2 (en) * | 2005-04-08 | 2008-12-02 | Ppg Industries Ohio, Inc. | Reaction product of polyamine and acyclic carbonate |
| IT1397539B1 (it) * | 2009-12-21 | 2013-01-16 | Pava Resine S R L | Composizione per la produzione di una vernice protettiva, di un rivestimento resinoso o simile. |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE483424A (es) * | 1942-07-31 | |||
| US3227672A (en) * | 1962-12-12 | 1966-01-04 | Nat Starch Chem Corp | Water soluble cationic copolymers of beta-hydroxyalkyl ethlenically unsaturated ester with vinyl tertiary amine |
| DE1258535B (de) * | 1963-08-22 | 1968-01-11 | Roehm & Haas Gmbh | Additionspolymerisate als Schmieroelzusaetze |
| DE1546840C3 (de) * | 1965-02-27 | 1975-05-22 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Herstellen von Überzügen |
| US3341505A (en) * | 1965-10-01 | 1967-09-12 | Johnson & Johnson | Adhesive compositions comprising amine salts of acrylic polymers |
| DE1546854B2 (de) * | 1965-12-03 | 1976-08-26 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen von ueberzuegen auf elektrisch leitenden koerpern |
| US3471388A (en) * | 1966-02-07 | 1969-10-07 | American Cyanamid Co | Electrodeposition of aqueous coatings containing etherified methylolated melamine |
| US3922212A (en) * | 1967-08-24 | 1975-11-25 | Scm Corp | Cathodic electrodeposition of surface coatings and compositions therefor |
| GB1235293A (en) * | 1967-12-12 | 1971-06-09 | Canadian Ind | Cationic electrodeposition systems |
| US3937679A (en) * | 1968-10-31 | 1976-02-10 | Ppg Industries, Inc. | Electrodepositable compositions |
| US3663389A (en) * | 1970-04-17 | 1972-05-16 | American Cyanamid Co | Method of electrodepositing novel coating |
| US3676384A (en) * | 1970-05-06 | 1972-07-11 | North Dakota State Univ Memori | Copolymers of hydroxyalkyl methacrylates and an acrylate of methacrylate ester reacted with a partially epoxidized drying oil |
| US3853803A (en) * | 1971-01-27 | 1974-12-10 | Ppg Industries Inc | Method of preparing a cationic acrylic electrodepositable interpolymer |
| ZA72788B (en) * | 1971-04-01 | 1972-10-25 | American Cyanamid Co | Process for electrocoating utilizing polymeric fully etherified polymethylol melamines of guanamine cross linkers |
| US3962165A (en) * | 1971-06-29 | 1976-06-08 | Ppg Industries, Inc. | Quaternary ammonium salt-containing resin compositions |
| US4038166A (en) * | 1972-08-04 | 1977-07-26 | Ppg Industries, Inc. | Electrodepositable compositions |
| US3835076A (en) * | 1972-11-30 | 1974-09-10 | Du Pont | Aqueous sealer composition of an epoxy ester resin of a maleinized drying oil fatty acid and an epoxy resin and an acrylic-epoxy ester graft copolymer |
| US3959202A (en) * | 1973-02-12 | 1976-05-25 | American Cyanamid Company | Composition of matter comprising a blend of certain polyether polyols, certain vinyl emulsion polymers and an aminoplast cross-linking agent |
| US4035275A (en) * | 1974-02-04 | 1977-07-12 | Ppg Industries, Inc. | Novel pigment grinding vehicles |
| US3954688A (en) * | 1974-07-30 | 1976-05-04 | E. I. Du Pont De Nemours And Company | Aqueous electrocoating composition of the reaction product of an epoxy ester resin and a maleinized drying oil blended with a cross-linking agent |
| US3954588A (en) * | 1974-10-01 | 1976-05-04 | E. I. Du Pont De Nemours And Company | Electrocoating process for depositing a corrosion retardant layer on a metal substrate and sequentially electrocoating a cationic film-forming polymer coating |
| US3976615A (en) * | 1974-11-13 | 1976-08-24 | Desoto, Inc. | Water dispersible epoxy ether-aminoacrylate polymers |
| US4026855A (en) * | 1974-11-19 | 1977-05-31 | American Cyanamid Company | Composition of matter particularly adaptable for use in electrodepositing films on metal |
| US4033917A (en) * | 1975-05-12 | 1977-07-05 | Desoto, Inc. | Electrodeposition of aqueous dispersions of copolymers of polyethylenically unsaturated epoxy-amine adducts |
| US4066525A (en) * | 1975-12-22 | 1978-01-03 | Scm Corporation | Cathodic electrocoating process |
| US4066523A (en) * | 1976-02-17 | 1978-01-03 | Scm Corporation | Dual cure cathodic electrocoating composition |
| US4035274A (en) * | 1976-05-24 | 1977-07-12 | Scm Corporation | Dual cure cathodic electrocoating |
| BE857754A (fr) * | 1976-08-18 | 1978-02-13 | Celanese Polymer Special Co | Composition de resine pour revetements, notamment par electrodeposition cathodique |
| US4071428A (en) * | 1976-11-24 | 1978-01-31 | Ppg Industries, Inc. | Process for electrodeposition of quaternary ammonium salt group-containing resins |
| US4115227A (en) * | 1976-12-01 | 1978-09-19 | E. I. Du Pont De Nemours And Company | Cathodic electrodeposition of paints |
-
1978
- 1978-05-09 US US05/902,887 patent/US4167499A/en not_active Expired - Lifetime
- 1978-06-01 EP EP78100067A patent/EP0005136A1/en not_active Ceased
-
1979
- 1979-04-27 BR BR7902589A patent/BR7902589A/pt unknown
- 1979-05-07 CA CA327,219A patent/CA1124434A/en not_active Expired
- 1979-05-08 AU AU46840/79A patent/AU524492B2/en not_active Expired - Fee Related
- 1979-05-08 BE BE0/195043A patent/BE876108A/xx unknown
- 1979-05-08 ZA ZA792215A patent/ZA792215B/xx unknown
- 1979-05-08 GB GB7915790A patent/GB2021122A/en not_active Withdrawn
- 1979-05-08 IT IT22462/79A patent/IT1113390B/it active
- 1979-05-08 FR FR7911595A patent/FR2425460A1/fr not_active Withdrawn
- 1979-05-09 ES ES480390A patent/ES480390A1/es not_active Expired
- 1979-05-09 JP JP5682879A patent/JPS54146890A/ja active Pending
- 1979-05-09 AT AT0346179A patent/AT368532B/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BE876108A (fr) | 1979-11-08 |
| ZA792215B (en) | 1980-10-29 |
| EP0005136A1 (en) | 1979-11-14 |
| AU4684079A (en) | 1979-11-15 |
| AT368532B (de) | 1982-10-25 |
| FR2425460A1 (fr) | 1979-12-07 |
| IT7922462A0 (it) | 1979-05-08 |
| US4167499A (en) | 1979-09-11 |
| AU524492B2 (en) | 1982-09-16 |
| IT1113390B (it) | 1986-01-20 |
| JPS54146890A (en) | 1979-11-16 |
| GB2021122A (en) | 1979-11-28 |
| CA1124434A (en) | 1982-05-25 |
| BR7902589A (pt) | 1979-11-20 |
| ATA346179A (de) | 1982-02-15 |
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