ES2002014A6 - Un procedimiento para la fabricacion de un copolomero en bloques de una composicion adecuada como dispersante. - Google Patents
Un procedimiento para la fabricacion de un copolomero en bloques de una composicion adecuada como dispersante.Info
- Publication number
- ES2002014A6 ES2002014A6 ES8602276A ES8602276A ES2002014A6 ES 2002014 A6 ES2002014 A6 ES 2002014A6 ES 8602276 A ES8602276 A ES 8602276A ES 8602276 A ES8602276 A ES 8602276A ES 2002014 A6 ES2002014 A6 ES 2002014A6
- Authority
- ES
- Spain
- Prior art keywords
- pigment dispersant
- group transfer
- transfer polymerization
- acrylic pigment
- dispersant made
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002270 dispersing agent Substances 0.000 title abstract 2
- 239000000049 pigment Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title 1
- OTLNPYWUJOZPPA-UHFFFAOYSA-N 4-nitrobenzoic acid Chemical compound OC(=O)C1=CC=C([N+]([O-])=O)C=C1 OTLNPYWUJOZPPA-UHFFFAOYSA-N 0.000 abstract 1
- 229920001400 block copolymer Polymers 0.000 abstract 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0084—Dispersions of dyes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
PROCEDIMIENTO PARA LA FABRICACION DE UN COPOLIMERO EN BLOQUES DE UNA COMPOSICION ADECUADA COMO DISPERSANTE. UN DISPERSANTE DE PIGMENTOS QUE COMPRENDE UN COPOLIMERO AB, DE BLOQUES, PREFERIBLEMENTE DE METACRILATO DE GLICICIDILO, SE PREPARA MEDIANTE POLIMERIZACION POR TRANSFERENCIA DE GRUPOS Y SE LE HACE REACCIONAR CON GRUPOS POLARES, PREFERIBLEMENTE, ACIDO 4-NITROBENZOICO. LOS DISPERSANTES AB ASI OBTENIDOS SON UTILES EN RECRUBRIMIENTOS Y RESINAS DE MOLDEADO, ENTRE OTRAS MUCHAS APLICACIONES POTENCIALES DE PRODUCTOS PREPARADOS POR POLIMERIZACION POR TRANSFERENCIA DE GRUPO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/782,257 US4656226A (en) | 1985-09-30 | 1985-09-30 | Acrylic pigment dispersants made by group transfer polymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2002014A6 true ES2002014A6 (es) | 1988-07-01 |
Family
ID=25125501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8602276A Expired ES2002014A6 (es) | 1985-09-30 | 1986-09-29 | Un procedimiento para la fabricacion de un copolomero en bloques de una composicion adecuada como dispersante. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4656226A (es) |
| EP (1) | EP0218436B1 (es) |
| JP (1) | JPH0692473B2 (es) |
| KR (1) | KR950008518B1 (es) |
| AR (1) | AR242805A1 (es) |
| AT (1) | ATE69057T1 (es) |
| AU (1) | AU584848B2 (es) |
| BR (1) | BR8604644A (es) |
| CA (1) | CA1247272A (es) |
| DE (1) | DE3682251D1 (es) |
| DK (1) | DK463086A (es) |
| ES (1) | ES2002014A6 (es) |
| HK (1) | HK28192A (es) |
| MX (1) | MX164882B (es) |
| NO (1) | NO167926C (es) |
| SG (1) | SG101791G (es) |
| ZA (1) | ZA867454B (es) |
Families Citing this family (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4847328A (en) * | 1986-08-29 | 1989-07-11 | E. I. Du Pont De Nemours And Company | Hybrid acrylic star polymers |
| CA1281449C (en) * | 1986-08-29 | 1991-03-12 | Clyde S. Hutchins | Hybrid acrylic star polymers and preparation |
| US4851477A (en) * | 1986-08-29 | 1989-07-25 | E. I. Du Pont De Nemours And Company | Hybrid acrylic-condensation star polymers by group transfer polymerization |
| US4812517A (en) * | 1987-12-28 | 1989-03-14 | E. I. Du Pont De Nemours And Company | Dispersants resistant to color change |
| US4948546A (en) * | 1988-06-23 | 1990-08-14 | E. I. Du Pont De Nemours And Company | Process for manufacture of polymethyl methacrylate sheet with controlled color |
| US4925764A (en) * | 1988-12-23 | 1990-05-15 | E. I. Du Pont De Nemours & Co. | Positive solid block toner |
| US4925765A (en) * | 1988-12-23 | 1990-05-15 | E. I. Du Pont De Nemours And Company | Negative solid block toner |
| US4985160A (en) * | 1989-02-08 | 1991-01-15 | E. I. Du Pont De Nemours And Company | Branched polymers as fuel oil additives |
| US4978723A (en) * | 1989-03-01 | 1990-12-18 | E. I. Du Pont De Nemours And Company | Phosphonate-capped polymers |
| US4939211A (en) * | 1989-03-01 | 1990-07-03 | E. I. Du Pont De Nemours And Company | Phosphonate-capped polymers |
| US5085698A (en) * | 1990-04-11 | 1992-02-04 | E. I. Du Pont De Nemours And Company | Aqueous pigmented inks for ink jet printers |
| US5424364A (en) * | 1994-05-17 | 1995-06-13 | E. I. Du Pont De Nemours & Company | Comb pigment dispersants |
| US5859113A (en) | 1997-07-17 | 1999-01-12 | E. I. Du Pont De Nemours And Company | Pigment dispersions containing hydroxylated AB-block polymer dispersant |
| US6204319B1 (en) | 1998-10-30 | 2001-03-20 | E.I. Du Pont De Nemours And Company | Aqueous coating compositions |
| PL196869B1 (pl) * | 1998-12-18 | 2008-02-29 | Basf Ag | Sposób wytwarzania produktu reakcji, sposób wytwarzania polimeru, produkt reakcji, polimer, wodna mieszanina zawierająca produkt reakcji i jej zastosowanie, oraz wodna mieszanina zawierająca polimer i jej zastosowanie |
| ES2228157T3 (es) | 1998-12-23 | 2005-04-01 | Basf Coatings Ag | Agente de recubrimiento. |
| KR100642674B1 (ko) | 1998-12-31 | 2006-11-10 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | Atrp중합체를 함유하는 안료 조성물 |
| DE19930066A1 (de) | 1999-06-30 | 2001-01-11 | Basf Coatings Ag | Farb- und/oder effektgebende Mehrschichtlackierung, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19930067A1 (de) | 1999-06-30 | 2001-01-11 | Basf Coatings Ag | Beschichtungsstoff und seine Verwendung zur Herstellung von Füllerschichten und Steinschlagschutzgrundierungen |
| DE19930664A1 (de) | 1999-07-02 | 2001-01-11 | Basf Coatings Ag | Klarlack und seine Verwendung zur Herstellung von Klarlackierungen und farb- und/oder effektgebenden Mehrschichtlackierungen |
| DE19930665A1 (de) | 1999-07-02 | 2001-01-11 | Basf Coatings Ag | Basislack und seine Verwendung zur Herstellung von farb- und/oder effektgebenden Basislackierungen und Mehrschichtlackierung |
| US6413306B1 (en) | 1999-10-07 | 2002-07-02 | E. I. Du Pont De Nemours And Company | Pigment dispersions containing ABC-block polymer dispersant |
| US6316564B1 (en) | 1999-10-07 | 2001-11-13 | E. I. Du Pont De Nemours And Company | Acrylic block copolymer pigment dispersants containing heterocyclic groups |
| US6410619B2 (en) | 1999-11-22 | 2002-06-25 | Bayer Corporation | Method for conditioning organic pigments |
| DE19959923A1 (de) | 1999-12-11 | 2001-06-28 | Basf Coatings Ag | Wäßrige Primärdispersionen und Beschichtungsstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19959927A1 (de) | 1999-12-11 | 2002-02-07 | Basf Coatings Ag | Wäßrige Primärdispersionen und Beschichtungsstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE19961040A1 (de) * | 1999-12-16 | 2001-06-21 | Basf Ag | Thermoplastische Formmassen mit verbessertem Verarbeitungsverhalten auf Basis von Polyarylenethersulfonen und Polyamiden |
| US6590049B1 (en) * | 1999-12-16 | 2003-07-08 | Ppg Industries Ohio, Inc. | Multi-functional initiators for atom transfer radical (Co)polymerization |
| US6441066B1 (en) | 1999-12-16 | 2002-08-27 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants prepared by controlled radical polymerization and having pendent hydrophobic polymeric segments |
| US6336966B1 (en) | 1999-12-16 | 2002-01-08 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants having core and arm star architecture prepared by controlled radical polymerization |
| US6376597B1 (en) | 1999-12-16 | 2002-04-23 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants having pendent hydrophilic polymeric segments prepared by controlled radical polymerization |
| US6294014B1 (en) | 1999-12-16 | 2001-09-25 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants prepared by controlled radical polymerization and having pendent hydrophilic polymeric segments |
| US6462125B1 (en) | 1999-12-16 | 2002-10-08 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments |
| US6326420B1 (en) | 1999-12-16 | 2001-12-04 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants prepared by controlled radical polymerization |
| US6306209B1 (en) | 1999-12-16 | 2001-10-23 | Ppg Industries Ohio, Inc. | Pigment dispersions containing dispersants having pendent hydrophobic polymeric segments prepared by controlled radical polymerization |
| US6495618B1 (en) | 1999-12-17 | 2002-12-17 | E. I. Du Pont De Nemours And Company | Graft copolymer with an amide functional group as a pigment dispersant |
| US6472463B1 (en) | 1999-12-17 | 2002-10-29 | E. I. Du Pont De Nemours And Company | Graft copolymer pigment dispersant |
| CN100549055C (zh) * | 2000-01-11 | 2009-10-14 | 西巴特殊化学品控股有限公司 | 来自原子转移自由基聚合的大分子单体的梳形聚合物 |
| DE10005819A1 (de) | 2000-02-10 | 2001-08-23 | Basf Coatings Ag | Wäßrige Primärdispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10018078A1 (de) * | 2000-04-12 | 2001-11-08 | Basf Coatings Ag | Formmassen und Verfahren zur Herstellung von Formkörpern |
| DE10018601A1 (de) * | 2000-04-14 | 2001-10-25 | Basf Coatings Ag | Wäßrige Primärdispersionen und Beschichtungsstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung |
| CA2339074A1 (en) * | 2000-05-18 | 2001-11-18 | E.I. Du Pont De Nemours And Company | Metallic flake containing coating compositions having improved glamour |
| US6660793B1 (en) | 2000-06-15 | 2003-12-09 | E. I. Du Pont De Nemours And Company | Aqueous coating compositions having improved transparency |
| DE10029695A1 (de) * | 2000-06-16 | 2001-12-20 | Basf Ag | Verfahren zur Herstellung eines polymeren Umsetzungsprodukts |
| DE10126651A1 (de) * | 2001-06-01 | 2002-12-12 | Basf Coatings Ag | Pulverlacksuspensionen (Pulverslurries) und Pulverlacke, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10126650B4 (de) * | 2001-06-01 | 2005-08-18 | Basf Coatings Ag | Funktionale organische Pulver, Verfahren zu ihrer Herstellung und ihre Verwendung |
| TW200407363A (en) * | 2001-11-29 | 2004-05-16 | Ciba Sc Holding Ag | Pigment compositions with modified ATRP copolymer dispersants |
| US7186770B2 (en) * | 2002-02-25 | 2007-03-06 | E. I. Du Pont De Nemours And Company | Unfinished rutile titanium dioxide slurry for paints and paper coatings |
| EP1594924A2 (en) * | 2003-02-20 | 2005-11-16 | Ciba SC Holding AG | Easily dispersible pigment composition |
| CA2520066A1 (en) * | 2003-04-08 | 2004-10-21 | Ciba Specialty Chemicals Holding Inc. | Light stabilising polymer dispersants in pigment dispersions |
| ATE443739T1 (de) | 2004-03-02 | 2009-10-15 | Du Pont | Mehrschichtdekorsicherheitsglas |
| US20050208312A1 (en) * | 2004-03-17 | 2005-09-22 | Isidor Hazan | One-pack primer surfacer composition for SMC automotive body panels |
| US20050282928A1 (en) * | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Ink jet ink |
| US20050282946A1 (en) * | 2004-06-21 | 2005-12-22 | Tyau-Jeen Lin | Titanium dioxide slurries for ink applications |
| US7691937B2 (en) * | 2005-02-04 | 2010-04-06 | Agfa Graphics Nv | Polymeric dispersants containing (meth)acryloyloxybenzoic acid |
| WO2007057326A1 (en) * | 2005-11-17 | 2007-05-24 | Ciba Holding Inc. | Process for the preparation of a dry powder of a polymeric additive |
| DE102006062441A1 (de) | 2006-12-27 | 2008-07-03 | Byk-Chemie Gmbh | Modifizierte Kammcopolymere |
| US9056988B2 (en) * | 2007-02-05 | 2015-06-16 | Ppg Industries Ohio, Inc. | Solar reflective coatings and coating systems |
| US8822025B2 (en) * | 2007-02-05 | 2014-09-02 | Ppg Industries Ohio, Inc. | Coating system exhibiting cool dark color |
| US8129466B2 (en) * | 2007-02-05 | 2012-03-06 | Ppg Industries Ohio, Inc | Pigment dispersant |
| EP2235146B1 (en) * | 2007-12-18 | 2016-04-20 | Basf Se | Biodiesel cold flow improver |
| JP5223082B2 (ja) * | 2008-08-05 | 2013-06-26 | 大日精化工業株式会社 | 顔料分散液、ブロックポリマーおよびその製造方法 |
| EP2411437B9 (de) | 2009-03-25 | 2013-07-31 | BYK-Chemie GmbH | Zusammensetzung umfassend stabile polyolmischungen |
| WO2011085775A1 (de) | 2009-12-22 | 2011-07-21 | Byk-Chemie Gmbh | Zusammensetzung umfassend stabile polyolmischungen |
| US8679617B2 (en) | 2010-11-02 | 2014-03-25 | Prc Desoto International, Inc. | Solar reflective coatings systems |
| KR101414851B1 (ko) * | 2011-06-02 | 2014-07-03 | 주식회사 엘지화학 | 불소계 수지 조성물, 이의 제조 방법 및 이를 포함하는 광전지 모듈 |
| US9057835B2 (en) | 2011-06-06 | 2015-06-16 | Ppg Industries Ohio, Inc. | Coating compositions that transmit infrared radiation and exhibit color stability and related coating systems |
| JP6034007B2 (ja) * | 2011-09-02 | 2016-11-30 | ベーイプシロンカー ヘミー ゲゼルシャフト ミット ベシュレンクター ハフトゥング | アミノ基を含有するジブロック共重合体の調製方法 |
| US9783708B2 (en) | 2012-08-23 | 2017-10-10 | Bando Chemical Industries, Ltd. | Conductive paste |
| EP3013874B1 (de) | 2013-06-24 | 2016-12-14 | BYK-Chemie GmbH | Haftungs-verstärkendes additiv und dieses enthaltende beschichtungszusammensetzung |
| CA3049143C (en) | 2017-01-03 | 2021-06-15 | Byk-Chemie Gmbh | (meth)acrylic copolymers as rheological additives in drilling fluids and drilling fluids comprising such copolymers |
| JP7090399B2 (ja) | 2017-02-21 | 2022-06-24 | 日本ペイント・オートモーティブコーティングス株式会社 | 水性塗料組成物および複層塗膜 |
| US11292906B2 (en) | 2017-10-23 | 2022-04-05 | Basf Se | Aqueous silicone polymer emulsion |
| WO2019092036A1 (de) | 2017-11-07 | 2019-05-16 | Clariant Plastics & Coatings Ltd | Dispergiermittel für pigmente in nicht wässrigen farbmittelpräparationen |
| US11760832B2 (en) | 2020-02-26 | 2023-09-19 | Axalta Coating Systems Ip Co., Llc | Dispersant polymer and composition comprising the same |
| EP4204467A1 (en) | 2020-08-25 | 2023-07-05 | Merck Patent GmbH | Fluorine containing polymers |
| WO2022177010A1 (ja) | 2021-02-22 | 2022-08-25 | 日本ペイント・オートモーティブコーティングス株式会社 | 複層塗膜 |
| US20240336779A1 (en) | 2023-03-30 | 2024-10-10 | Axalta Coating Systems Ip Co., Llc | Dispersant polymer and composition comprising the same |
| WO2025037281A1 (en) | 2023-08-17 | 2025-02-20 | 3M Innovative Properties Company | Conductive composition, electrically debonding adhesive system, and related methods |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1108261A (en) * | 1963-08-01 | 1968-04-03 | Ici Ltd | Novel dispersants for use in organic media |
| US3433753A (en) * | 1963-08-01 | 1969-03-18 | Ici Ltd | Paint composition including a dispersant having a solvatable chain-like component |
| LU60676A1 (es) * | 1970-04-07 | 1972-02-10 | ||
| US4388448A (en) * | 1981-02-23 | 1983-06-14 | E. I. Du Pont De Nemours And Company | Glycidyl methacrylate polymers, their preparation and solvolysis products |
| US4417034A (en) * | 1981-06-30 | 1983-11-22 | E. I. Du Pont De Nemours & Co. | Living polymers and process for their preparation |
| US4508880A (en) * | 1981-06-30 | 1985-04-02 | E. I. Du Pont De Nemours And Company | "Living" polymers and process for their preparation |
| US4414372A (en) * | 1982-06-17 | 1983-11-08 | E. I. Du Pont De Nemours & Co. | Process for preparing living polymers |
| US4588795A (en) * | 1985-03-01 | 1986-05-13 | E. I. Du Pont De Nemours And Company | Oxyanion-catalyzed polymerization |
-
1985
- 1985-09-30 US US06/782,257 patent/US4656226A/en not_active Expired - Lifetime
-
1986
- 1986-09-25 CA CA000519064A patent/CA1247272A/en not_active Expired
- 1986-09-25 BR BR8604644A patent/BR8604644A/pt not_active Application Discontinuation
- 1986-09-29 DE DE8686307448T patent/DE3682251D1/de not_active Expired - Lifetime
- 1986-09-29 JP JP61228530A patent/JPH0692473B2/ja not_active Expired - Lifetime
- 1986-09-29 MX MX3875A patent/MX164882B/es unknown
- 1986-09-29 AR AR86305420A patent/AR242805A1/es active
- 1986-09-29 KR KR1019860008159A patent/KR950008518B1/ko not_active Expired - Lifetime
- 1986-09-29 DK DK463086A patent/DK463086A/da not_active Application Discontinuation
- 1986-09-29 ES ES8602276A patent/ES2002014A6/es not_active Expired
- 1986-09-29 EP EP86307448A patent/EP0218436B1/en not_active Expired - Lifetime
- 1986-09-29 AT AT86307448T patent/ATE69057T1/de not_active IP Right Cessation
- 1986-09-29 NO NO863873A patent/NO167926C/no unknown
- 1986-09-30 AU AU63259/86A patent/AU584848B2/en not_active Ceased
- 1986-09-30 ZA ZA867454A patent/ZA867454B/xx unknown
-
1991
- 1991-12-02 SG SG1017/91A patent/SG101791G/en unknown
-
1992
- 1992-04-16 HK HK281/92A patent/HK28192A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0692473B2 (ja) | 1994-11-16 |
| EP0218436A3 (en) | 1989-02-22 |
| NO167926C (no) | 1991-12-27 |
| SG101791G (en) | 1992-01-17 |
| AU584848B2 (en) | 1989-06-01 |
| HK28192A (en) | 1992-04-24 |
| JPS6281459A (ja) | 1987-04-14 |
| EP0218436B1 (en) | 1991-10-30 |
| CA1247272A (en) | 1988-12-20 |
| EP0218436A2 (en) | 1987-04-15 |
| NO863873L (no) | 1987-03-31 |
| US4656226A (en) | 1987-04-07 |
| AR242805A1 (es) | 1993-05-31 |
| BR8604644A (pt) | 1987-06-09 |
| ZA867454B (en) | 1988-05-25 |
| KR950008518B1 (ko) | 1995-07-31 |
| DE3682251D1 (de) | 1991-12-05 |
| NO863873D0 (no) | 1986-09-29 |
| MX164882B (es) | 1992-09-29 |
| NO167926B (no) | 1991-09-16 |
| ATE69057T1 (de) | 1991-11-15 |
| DK463086D0 (da) | 1986-09-29 |
| KR880004048A (ko) | 1988-06-01 |
| DK463086A (da) | 1987-03-31 |
| AU6325986A (en) | 1987-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SA6 | Expiration date (snapshot 920101) |
Free format text: 2006-09-29 |
|
| FD1A | Patent lapsed |
Effective date: 20100616 |