ES8200323A1 - Procedimiento de preparacion de esteres de derivados de la aletrolona y de acidos ciclopropeno-carboxilicos - Google Patents

Procedimiento de preparacion de esteres de derivados de la aletrolona y de acidos ciclopropeno-carboxilicos

Info

Publication number
ES8200323A1
ES8200323A1 ES490652A ES490652A ES8200323A1 ES 8200323 A1 ES8200323 A1 ES 8200323A1 ES 490652 A ES490652 A ES 490652A ES 490652 A ES490652 A ES 490652A ES 8200323 A1 ES8200323 A1 ES 8200323A1
Authority
ES
Spain
Prior art keywords
carbon atoms
group
alkyl
hydrogen
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES490652A
Other languages
English (en)
Other versions
ES490652A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of ES490652A0 publication Critical patent/ES490652A0/es
Publication of ES8200323A1 publication Critical patent/ES8200323A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/30—Hetero atoms other than halogen
    • C07D333/32—Oxygen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/24—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16—Unsaturated compounds
    • C07C61/35—Unsaturated compounds having unsaturation outside the rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C62/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C62/30—Unsaturated compounds
    • C07C62/38—Unsaturated compounds containing keto groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/58—One oxygen atom, e.g. butenolide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5407—Acyclic saturated phosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Biochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Molecular Biology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Fodder In General (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Pyrrole Compounds (AREA)

Abstract

PROCEDIMIENTO DE PREPARACION DE ESTERES DE DERIVADOS DE LA ALETROLONA Y DE ACIDOS CICLOPROPENO-CARBOXILICOS DE FORMULA GENERAL (I). SE OBTIENE COMPUESTOS DE FORMULA (I), DONDE R1 Y R2, IGUALES O DIFERENTES, REPRESENTAN UN GRUPO CARBOMOILO O GRUPOS R''1 Y R''2, IGUALES O DIFERENTES, REPRESENTAN UN ATOMO DE HIDROGENO, HALOGENO O UN RADICAL ALCOHILO CON 1 A 3 ATOMOS DE CARBONO8 E Y REPRESENTAN DISTINTOS ELEMENTOS Y RADICALES, COMO UN HALOGENO. PARA ELLO SE SOMETE A UN COMPUESTO DE FORMULA (III) DE CONFIGURACION (S), (R) O (RS).
ES490652A 1979-04-26 1980-04-17 Procedimiento de preparacion de esteres de derivados de la aletrolona y de acidos ciclopropeno-carboxilicos Expired ES8200323A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7910651A FR2455025A1 (fr) 1979-04-26 1979-04-26 Esters de derives de l'allethrolone et d'acides cyclopropane carboxyliques, leurs procedes de preparation et les compositions les renfermant

Publications (2)

Publication Number Publication Date
ES490652A0 ES490652A0 (es) 1981-10-16
ES8200323A1 true ES8200323A1 (es) 1981-10-16

Family

ID=9224794

Family Applications (1)

Application Number Title Priority Date Filing Date
ES490652A Expired ES8200323A1 (es) 1979-04-26 1980-04-17 Procedimiento de preparacion de esteres de derivados de la aletrolona y de acidos ciclopropeno-carboxilicos

Country Status (15)

Country Link
US (1) US4356187A (es)
EP (1) EP0018894B1 (es)
JP (1) JPS55153742A (es)
AT (1) ATE697T1 (es)
AU (1) AU5779380A (es)
BR (1) BR8002601A (es)
DD (1) DD152781A5 (es)
DE (1) DE3060198D1 (es)
DK (1) DK177380A (es)
ES (1) ES8200323A1 (es)
FR (1) FR2455025A1 (es)
HU (1) HU184262B (es)
IL (1) IL59798A0 (es)
PT (1) PT71125B (es)
ZA (1) ZA802344B (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2486073A1 (fr) * 1980-07-02 1982-01-08 Roussel Uclaf Nouveaux derives de l'acide cyclopropane carboxylique, leur procede de preparation, et leur application a la lutte contre les parasites
FR2499071A1 (fr) * 1981-02-05 1982-08-06 Roussel Uclaf Nouveaux derives de l'acide cyclopropane carboxylique substitue en 3 par une chaine vinylique, leur procede de preparation et leur application comme agents parfumants
JPS5978141A (ja) * 1982-10-27 1984-05-04 Sumitomo Chem Co Ltd ２−シクロペンテノン誘導体の製造方法
CH655301A5 (de) * 1983-05-26 1986-04-15 Lonza Ag Verfahren zur herstellung von 4-substituierten acetessigsaeurederivaten.
GB8406731D0 (en) * 1984-03-15 1984-04-18 Elliott M Pesticides
JPH06122605A (ja) * 1992-08-25 1994-05-06 Sumitomo Chem Co Ltd 衣料用防虫剤
JPH06239712A (ja) * 1993-02-19 1994-08-30 Sumitomo Chem Co Ltd 土壌害虫防除剤
JPH06345678A (ja) * 1993-06-03 1994-12-20 Sumitomo Chem Co Ltd シクロペンテノール誘導体の製造法
JPH07112947A (ja) * 1993-08-24 1995-05-02 Sumitomo Chem Co Ltd エステル化合物、それを有効成分とする有害生物防除剤、その製造中間体およびその製造法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2717262A (en) * 1949-08-15 1955-09-06 Chemical Elaborations Inc Process of producing chrysanthemic acid esters of cyclopentenyl ketonic alcohols and products
US2768965A (en) * 1952-07-18 1956-10-30 Union Carbide & Carbon Corp Allethrin and related insecticides
US2815362A (en) * 1956-01-03 1957-12-03 Benzol Products Company Processes for making trans chrysanthemic acid and related compounds and products therefrom
US3009946A (en) * 1958-03-10 1961-11-21 Inst Of Insect Control Process for preparing chrysanthemumdicarboxylic acid and esters thereof
CS164804B2 (es) * 1966-07-20 1975-11-28
US3678172A (en) * 1970-02-03 1972-07-18 Tenneco Chem Allethronyl esters of certain cyclopropane-carboxylic acids as insecticides
US3679667A (en) * 1970-03-27 1972-07-25 Procter & Gamble Esters of 3-(2,2-tetramethylene ethenyl)-2,2 - dimethylcyclopropanecarboxylic acid
US3823177A (en) * 1971-06-25 1974-07-09 Procter & Gamble Insecticidal esters of spiro carboxylic acids
JPS50895B2 (es) * 1972-05-31 1975-01-13
FR2355797A1 (fr) * 1975-09-05 1978-01-20 Wellcome Found Procede de preparation de vinylcyclopropanes substitues utilisables dans la preparation d'insecticides
FR2355747A1 (fr) * 1976-06-24 1978-01-20 Finot Jean Dispositif pour l'extraction de produits ensiles dans une capacite de stockage et capacite equipee dudit dispositif
HU176939B (hu) * 1978-02-23 1981-06-28 Chinoin Gyogyszer Es Vegyeszet Sposob poluchenija proizvodnykh slozhnykh efirov krizantemnojj kisloty
HU176938B (hu) 1978-02-23 1981-06-28 Chinoin Gyogyszer Es Vegyeszet Sposob poluchenija novykh slozhnykh ehfirnykh proizvodnykh khrizantemnoj kisloty

Also Published As

Publication number Publication date
PT71125A (fr) 1980-05-01
PT71125B (fr) 1981-09-01
ZA802344B (en) 1981-04-29
FR2455025A1 (fr) 1980-11-21
DE3060198D1 (en) 1982-03-25
US4356187A (en) 1982-10-26
ES490652A0 (es) 1981-10-16
FR2455025B1 (es) 1981-12-24
EP0018894A1 (fr) 1980-11-12
EP0018894B1 (fr) 1982-02-17
ATE697T1 (de) 1982-03-15
BR8002601A (pt) 1980-12-09
HU184262B (en) 1984-07-30
DD152781A5 (de) 1981-12-09
IL59798A0 (en) 1980-06-30
JPS55153742A (en) 1980-11-29
DK177380A (da) 1980-10-27
AU5779380A (en) 1980-10-30

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19971001