ES8301862A1 - Un procedimiento para hidroxilar olefinas. - Google Patents

Un procedimiento para hidroxilar olefinas.

Info

Publication number
ES8301862A1
ES8301862A1 ES507402A ES507402A ES8301862A1 ES 8301862 A1 ES8301862 A1 ES 8301862A1 ES 507402 A ES507402 A ES 507402A ES 507402 A ES507402 A ES 507402A ES 8301862 A1 ES8301862 A1 ES 8301862A1
Authority
ES
Spain
Prior art keywords
halides
olefins
quaternary
alkaline
metal halides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES507402A
Other languages
English (en)
Other versions
ES507402A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/209,789 external-priority patent/US4314088A/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of ES8301862A1 publication Critical patent/ES8301862A1/es
Publication of ES507402A0 publication Critical patent/ES507402A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN PROCEDIMIENTO PARA HIDROXILAR OLEFINAS. CONSISTE EN HACER REACCIONAR POR LO MENOS UN COMPUESTO OLEFINICO QUE TIENE UNA INSATURACION ETILENICA, CON AGUA Y POR LO MENOS UN HIDROPEROXIDO ORGANICO, EN PRESENCIA DE UNA COMPOSICION CATALITICA Y BAJO CONDICIONES ADECUADAS PARA CONVERTIR DICHA INSATURACION ETILENICA EN SU CORRESPONDIENTE DIOL. LA MENCIONADA COMPOSICION CATALITICA COMPRENDE UN COMPUESTO DE OSMIO Y POR LO MENOS UN CATALIZADOR COMPLEMENTARIO, SELECCIONADO ENTRE UN GRUPO DE HALUROS DE METAL ALCALINO, HALUROS DE METAL ALCALINO-TERREO, HALUROS DE HIDROGENO, HALUROS DE HIDROCARBILFOSFONIO CUATERNARIO, HALOGENOS, Y HALUROS DE METALES DE TRANSICION, SELECCIONANDOSE EL METAL DE TRANSICION ENTRE EL GRUPO FORMADO POR FE, CO, NI, CU, V, CR, MN, SC, TI, MO, RU, RH, PD Y W.
ES507402A 1980-11-24 1981-11-24 Un procedimiento para hidroxilar olefinas. Granted ES507402A0 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/209,789 US4314088A (en) 1980-11-24 1980-11-24 Hydroxylation of olefins
US06/310,099 US4393253A (en) 1980-11-24 1981-10-09 Hydroxylation of olefins

Publications (2)

Publication Number Publication Date
ES8301862A1 true ES8301862A1 (es) 1982-12-16
ES507402A0 ES507402A0 (es) 1982-12-16

Family

ID=26904515

Family Applications (1)

Application Number Title Priority Date Filing Date
ES507402A Granted ES507402A0 (es) 1980-11-24 1981-11-24 Un procedimiento para hidroxilar olefinas.

Country Status (9)

Country Link
US (1) US4393253A (es)
EP (1) EP0053023B1 (es)
AU (1) AU542489B2 (es)
BR (1) BR8107610A (es)
CA (1) CA1181098A (es)
DE (1) DE3170031D1 (es)
ES (1) ES507402A0 (es)
MX (1) MX6780E (es)
NO (1) NO813897L (es)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE19054T1 (de) * 1981-10-09 1986-04-15 Exxon Research Engineering Co Verfahren zur hydroxylierung von olefinen mit osmium-halogen-verbindung enthaltendem katalysator.
US4390739A (en) * 1981-10-09 1983-06-28 Exxon Research & Engineering Co. Hydroxylation of olefins
EP0098701A1 (en) * 1982-07-01 1984-01-18 Exxon Research And Engineering Company Process for hydroxylating olefins in the presence of an osmium oxide catalyst and carboxylate salt co-catalyst
US4413151A (en) * 1982-07-14 1983-11-01 Exxon Research & Engineering Co. Process for hydroxylating olefins using a supported osmium catalyst
US4482763A (en) * 1982-07-19 1984-11-13 Exxon Research & Engineering Co. Process for hydroxylating olefins in the presence of an osmium containing catalyst and organic halogenated hydrocarbon co-catalyst
US4486613A (en) * 1982-09-20 1984-12-04 Exxon Research & Engineering Co. Process for hydroxylating olefins using an osmium carbonyl catalyst
GB2129800B (en) * 1982-11-12 1986-04-23 Exxon Research Engineering Co Process for hydroxylating olefins using an osmium oxide catalyst and sodium hydroxide co-catalyst
US4496778A (en) * 1983-10-03 1985-01-29 Exxon Research & Engineering Co. Process for the hydroxylation of olefins using molecular oxygen, an osmium containing catalyst, a copper Co-catalyst, and an aromatic amine based promoter
US4496779A (en) * 1984-04-26 1985-01-29 Exxon Research & Engineering Co. Process for the hydroxylation of olefins using molecular oxygen, an osmium containing catalyst, a copper co-catalyst, and a cycloaliphatic amine based promoter
US5126494A (en) * 1988-01-11 1992-06-30 Massachusetts Institute Of Technology Methods for catalytic asymmetric dihydroxylation of olefins
US5260461A (en) * 1988-01-11 1993-11-09 Massachusetts Institute Of Technology Ligands for ADH: cinchona alkaloids and moderately sized organic substituents linked through a planar aromatic spacer group
US5516929A (en) * 1988-01-11 1996-05-14 Massachusetts Institute Of Technology Method for catalytic asymmetric dihydroxylation of olefins using heterocyclic chiral ligands
US5227543A (en) * 1988-01-11 1993-07-13 Massachusetts Institute Of Technology Facilitation of turnover in the ADH by additives which catalyze the hydrolysis of the OS(VI) glycolate esters
GB9313080D0 (en) * 1993-06-25 1993-08-11 Solvay Interox Ltd Oxidative cleavage of alkenes
US6962636B2 (en) * 1998-09-17 2005-11-08 Urethane Soy Systems Company, Inc. Method of producing a bio-based carpet material
US6180686B1 (en) * 1998-09-17 2001-01-30 Thomas M. Kurth Cellular plastic material
US20020058774A1 (en) 2000-09-06 2002-05-16 Kurth Thomas M. Transesterified polyol having selectable and increased functionality and urethane material products formed using the polyol
US20030191274A1 (en) * 2001-10-10 2003-10-09 Kurth Thomas M. Oxylated vegetable-based polyol having increased functionality and urethane material formed using the polyol
US8575226B2 (en) 1998-09-17 2013-11-05 Rhino Linings Corporation Vegetable oil-based coating and method for application
US6979477B2 (en) 2000-09-06 2005-12-27 Urethane Soy Systems Company Vegetable oil-based coating and method for application
US7063877B2 (en) 1998-09-17 2006-06-20 Urethane Soy Systems Company, Inc. Bio-based carpet material
US7393985B2 (en) * 2004-04-20 2008-07-01 The University Of Hong Kong Supported ruthenium nanoparticle catalyst for cis -dihydroxylation and oxidative cleavage of alkenes
JP2008535789A (ja) 2005-03-03 2008-09-04 サウス ダコタ ソイビーン プロセッサーズ，エルエルシー 酸化プロセスを利用して植物油から得られる新規ポリオール
KR20260021818A (ko) 2018-09-17 2026-02-13 셰브론 필립스 케미컬 컴퍼니 엘피 크롬 촉매의 광 처리, 관련 촉매 제조 시스템 및 중합 공정
US11078143B2 (en) 2019-09-16 2021-08-03 Chevron Phillips Chemical Company, Lp Chromium-catalyzed production of alcohols from hydrocarbons
EP4031279A1 (en) 2019-09-16 2022-07-27 Chevron Phillips Chemical Company Lp Chromium-based catalysts and processes for converting alkanes into higher and lower aliphatic hydrocarbons
EP4210868A1 (en) 2020-09-14 2023-07-19 Chevron Phillips Chemical Company Lp Transition metal-catalyzed production of alcohol and carbonyl compounds from hydrocarbons
US11814343B2 (en) 2021-06-08 2023-11-14 Chevron Phillips Chemical Company Lp Chromium-catalyzed production of alcohols from hydrocarbons in the presence of oxygen
US12134591B2 (en) 2022-10-31 2024-11-05 Chevron Phillips Chemical Company Lp Methanol production from methane utilizing a supported chromium catalyst

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE907774C (de) * 1943-05-15 1954-03-29 Basf Ag Verfahren zur Herstellung von mehrwertigen Alkoholen
US3335174A (en) * 1964-03-30 1967-08-08 Marathon Oil Co Preparation of diols and aliphatic carboxylic acid esters thereof from olefins
US3351635A (en) * 1966-03-14 1967-11-07 Halcon International Inc Epoxidation process
GB1324763A (en) * 1971-03-19 1973-07-25 Continental Oil Co Phase transfer catalysis of heterogeneous reactions by quaternary salts
US4049724A (en) * 1973-11-20 1977-09-20 Atlantic Richfield Company Osmium catalyzed organic hydroperoxide hydroxylation of olefinic compounds
GB1449716A (en) * 1974-08-09 1976-09-15 Fmc Corp Oxidation of olefinic compounds to glycols
DE2639927C3 (de) * 1976-09-04 1980-02-07 Meto International Gmbh, 6932 Hirschhorn Druckvorrichtung, insbesondere für Etikettiergeräte
JPS54145604A (en) * 1978-05-04 1979-11-14 Mitsubishi Chem Ind Ltd Preparation of diols
US4203926A (en) * 1978-12-18 1980-05-20 Gulf Research & Development Company Hydroxidation of gaseous olefins with ethylbenzene hydroperoxide in a heterogeneous liquid system
US4229601A (en) * 1978-12-26 1980-10-21 Gulf Research & Development Company Converting ethylene and propylene to the glycol using t.butyl hydroperoxide in a two-phase liquid reactant
US4314088A (en) * 1980-11-24 1982-02-02 Exxon Research & Engineering Co. Hydroxylation of olefins

Also Published As

Publication number Publication date
AU7776481A (en) 1982-06-03
EP0053023A1 (en) 1982-06-02
DE3170031D1 (en) 1985-05-23
MX6780E (es) 1986-07-14
AU542489B2 (en) 1985-02-21
CA1181098A (en) 1985-01-15
BR8107610A (pt) 1982-08-17
US4393253A (en) 1983-07-12
NO813897L (no) 1982-05-25
EP0053023B1 (en) 1985-04-17
ES507402A0 (es) 1982-12-16

Similar Documents

Publication Publication Date Title
Noujima et al. Selective Deoxygenation of Epoxides to Alkenes with Molecular Hydrogen Using a Hydrotalcite‐Supported Gold Catalyst: A Concerted Effect between Gold Nanoparticles and Basic Sites on a Support
AR000262A1 (es) Procedimiento de conversión de un alcano clorado en un alqueno menos clorado
MY117735A (en) Catalytic compositions comprising higher alcohol synthesis catalysts and processes using them
ES2185084T3 (es) Catalizador de cascara portante con contenido en metales nobles; procedimiento para la fabricacion del mismo y empleo del mismo en la fabricacion de acetato vinilico.
SE8206257D0 (sv) Catalitic system and process for producing mixtures of methanol and higher alcohols
HU9603187D0 (en) Oxidation of steroids having allylic groups
Mijoin et al. Mechanistic considerations on the involvement of dihydrointermediates in the hydrodesulfurization of dibenzothiophene-type compounds over molybdenum sulfide catalysts
ES2005050A6 (es) Un procedimiento mejorado en fase vapor heterogeneo para producir un alcohol, y correspondiente catalizador de hidrogenacion de aldehido.
ES2028860T3 (es) Catalizador para oxido de etileno y procedimiento para la produccion catalitica de oxido de etileno.
ES2124317T3 (es) Polioles con reactividad mejorada.
ES2086049T3 (es) Procedimiento para la obtencion de carbonatos de alquileno.
IL144815A (en) Process for producing carbonyl or hydroxy compound
ES8303269A1 (es) Un procedimiento para la preparacion de una mezcla ludiocarbonada a partir de una mezcla de monoxido de carbono e hidro-geno.
Tatsumi et al. Alcohol synthesis from CO2/H2 on silica-supported molybdenum catalysts.
ES516353A0 (es) "un procedimiento para hidroxilar al menos un compuesto olefinico que posee por lo menos una insaturacion etilenica".
ES2181218T3 (es) Procedimiento de obtencion de oxido de propileno que usa catalizadores de plata soportados sobre compuestos de metal alcalino-terreo y que contienen promotores de wolframio y de potasio.
Yamagata et al. Oxidative coupling of methane over BaO mixed with CaO and MgO
CN1260786A (zh) 链烯烃的环氧化方法
JPS55149133A (en) Recovery of metal from hydrogen desulfurizing catalyst of hydrocarbon
ES8308822A1 (es) Un procedimiento para la preparacion de etilenglicol.
DE3270461D1 (en) Process for hydroxylating olefins using osmium-halogen compound catalysts
ES2042224T3 (es) Procedimiento de produccion de anhidrosorbitoles y de anhidromanitoles a partir de sorbitol y de manitol.
ES398383A1 (es) Procedimiento para descomponer compuestos peroxidos organi-cos en mezcla con otros compuestos.
EP0934114A4 (en) ACTIVATED SILVER CATALYST
GB1435784A (en) Catalyst material for the preparation of saturated ketones from olefins

Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19960603