ES8403443A1 - Procedimiento para preparar derivados de ciclohexeno-1,2-diona 5-aril-sustituidos. - Google Patents
Procedimiento para preparar derivados de ciclohexeno-1,2-diona 5-aril-sustituidos.Info
- Publication number
- ES8403443A1 ES8403443A1 ES519709A ES519709A ES8403443A1 ES 8403443 A1 ES8403443 A1 ES 8403443A1 ES 519709 A ES519709 A ES 519709A ES 519709 A ES519709 A ES 519709A ES 8403443 A1 ES8403443 A1 ES 8403443A1
- Authority
- ES
- Spain
- Prior art keywords
- alkyl
- alkynyl
- alkenyl
- formula
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000002363 herbicidal effect Effects 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- OILAIQUEIWYQPH-UHFFFAOYSA-N cyclohexane-1,2-dione Chemical class O=C1CCCCC1=O OILAIQUEIWYQPH-UHFFFAOYSA-N 0.000 title 1
- 239000004009 herbicide Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- 125000003342 alkenyl group Chemical group 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 125000000304 alkynyl group Chemical group 0.000 abstract 5
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 3
- 125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 2
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 230000008635 plant growth Effects 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 125000003302 alkenyloxy group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 1
- -1 amino, substituted amino Chemical group 0.000 abstract 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 abstract 1
- 125000001589 carboacyl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001767 cationic compounds Chemical group 0.000 abstract 1
- 235000013339 cereals Nutrition 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000003709 fluoroalkyl group Chemical group 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000002466 imines Chemical class 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 150000002892 organic cations Chemical group 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 230000007363 regulatory process Effects 0.000 abstract 1
- 125000005415 substituted alkoxy group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/22—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/455—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation with carboxylic acids or their derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/46—Friedel-Crafts reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
- C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/546—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings polycyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/55—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/575—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
- C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
- C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
- C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
- C07C49/82—Ketones containing a keto group bound to a six-membered aromatic ring containing hydroxy groups
- C07C49/835—Ketones containing a keto group bound to a six-membered aromatic ring containing hydroxy groups having unsaturation outside an aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
PROCEDIMIENTO PARA LA OBTENCION DE DERIVADOS DE CICLOHEXAN-1,3-DIONA 5-ARIL-SUSTITUIDOS, DE FORMULA (I), EN LA QUE W, X, R1, R2 Y R3 PUEDEN SER VARIOS TIPOS DE RADICALES; P VALE 0-4; Y M Y N VALEN 0-3.CONSISTE EN LA REACCION DE UN DERIVADO DE BENZALDEHIDO DE FORMULA (II), EN LA QUE TODOS LOS SIMBOLOS TIENEN EL MISMO SIGNIFICADO QUE EN LA FORMULA (I), CON ACETONA, SEGUIDA DEL TRATAMIENTO CON UN ESTER DE ACIDO MALONICO DE FORMULA CH2(CO2R)2, EN LA QUE R ES ALQUILO C1-6; ACILACION ON UN ANHIDRIDO DE ACIDO DE FORMULA (R3CO)2O O UN HALURO DE ACIDO DE FORMULA R3COHALSIENDO R3 EL MISMO QUE EN LA FORMULA (I); Y, FINALMENTE, REACCION DE UN DERIVADO DE ALCOXIAMINA.ESTOS COMPUESTOS TIENEN APLICACIONES EN AGRICULTURA POR SUS PROPIEDADES HERBICIDAS.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPF269382 | 1982-02-12 | ||
| AUPF468682 | 1982-07-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES519709A0 ES519709A0 (es) | 1984-03-16 |
| ES8403443A1 true ES8403443A1 (es) | 1984-03-16 |
Family
ID=25642526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES519709A Expired ES8403443A1 (es) | 1982-02-12 | 1983-02-11 | Procedimiento para preparar derivados de ciclohexeno-1,2-diona 5-aril-sustituidos. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4952722A (es) |
| EP (1) | EP0086588B1 (es) |
| JP (2) | JPH072700B2 (es) |
| BR (1) | BR8300704A (es) |
| CA (1) | CA1203546A (es) |
| DE (1) | DE3372286D1 (es) |
| DK (1) | DK59483A (es) |
| ES (1) | ES8403443A1 (es) |
| GR (1) | GR78265B (es) |
| HU (1) | HU189228B (es) |
| IE (1) | IE54550B1 (es) |
| NZ (1) | NZ203104A (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ207541A (en) * | 1983-04-07 | 1987-05-29 | Ici Australia Ltd | Cyclohexane-1,3-dione derivatives and herbicidal compositions |
| NZ207780A (en) * | 1983-05-06 | 1988-09-29 | Ici Australia Ltd | 5-substituted cyclohexane-1,3-dione derivatives and herbicidal compositions |
| EP0176294B1 (en) * | 1984-09-24 | 1991-06-05 | Ici Australia Limited | Cyclohexane-1,3-dione derivatives, compositions containing them, processes for preparing them, and their use as herbicides and plant growth regulators |
| EP0177222B1 (en) * | 1984-09-25 | 1990-06-27 | Ici Australia Limited | Cyclohexane-1,3-dione derivatives, compositions containing them, processes for preparing them, and their use as herbicides and plant growth regulators |
| DE3440410A1 (de) * | 1984-11-06 | 1986-05-07 | Basf Ag, 6700 Ludwigshafen | Cyclohexenonderivate, verfahren zu ihrer herstellung sowie ihre verwendung zur bekaempfung unerwuenschten pflanzenwuchses |
| GB8711525D0 (en) * | 1987-05-15 | 1987-06-17 | Shell Int Research | Oximino ether compounds |
| JP2618639B2 (ja) * | 1987-07-03 | 1997-06-11 | 住友化学工業株式会社 | シクロヘキセノン誘導体およびそれを有効成分とする除草剤 |
| GB8722838D0 (en) * | 1987-09-29 | 1987-11-04 | Shell Int Research | Oximino ether compounds |
| US5239110A (en) * | 1992-12-30 | 1993-08-24 | Sterling Winthrop, Inc. | Phenylcyclohexanol derivatives as agents for treating CNS disorders |
| KR0149055B1 (ko) * | 1994-08-18 | 1998-10-15 | 강박광 | 신규한 제초성 시클로헥산-1,3-디온 유도체와 그 제조방법 |
| US6096930A (en) * | 1994-08-18 | 2000-08-01 | Korea Research Institute Of Chemical Technology | Herbicidal cyclohexane-1,3-dione derivatives and their preparation process |
| DE19545212A1 (de) * | 1995-12-05 | 1997-06-12 | Basf Ag | Cyclohexenonoximether-Metallsalze |
| DE10045131A1 (de) * | 2000-09-13 | 2002-03-21 | Basf Ag | Verfahren zur Herstellung eines Cyclohexenonoximether-Lithiumsalzes, damit erhältliche Produkte, deren Verwendung sowie entsprechende Pflanzenschutzmittel |
| US8987445B2 (en) | 2011-03-16 | 2015-03-24 | Mitsubishi Tanabe Pharma Corporation | Sulfonamide compounds having TRPM8 antagonistic activity |
| CN109369450B (zh) * | 2018-10-31 | 2021-07-27 | 江苏省农用激素工程技术研究中心有限公司 | 三甲苯草酮的精制方法 |
| MX2021005571A (es) * | 2018-11-13 | 2021-07-06 | Arysta Lifescience Inc | Proceso de encapsulacion de ciclohexanodionas y producto. |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3950420A (en) * | 1973-08-15 | 1976-04-13 | Nippon Soda Company, Ltd. | Cyclohexane derivatives |
| NZ202284A (en) * | 1981-11-20 | 1986-06-11 | Ici Australia Ltd | 2-(1-(alkoxyimino)alkyl)-3-hydroxy-5-poly(methyl)phenyl-cyclohex-2-en-1-ones and herbicidal compositions |
-
1983
- 1983-01-26 US US06/461,003 patent/US4952722A/en not_active Expired - Fee Related
- 1983-01-27 NZ NZ203104A patent/NZ203104A/en unknown
- 1983-01-31 DE DE8383300491T patent/DE3372286D1/de not_active Expired
- 1983-01-31 EP EP83300491A patent/EP0086588B1/en not_active Expired
- 1983-02-02 GR GR70390A patent/GR78265B/el unknown
- 1983-02-07 IE IE241/83A patent/IE54550B1/en not_active IP Right Cessation
- 1983-02-09 HU HU83441A patent/HU189228B/hu not_active IP Right Cessation
- 1983-02-10 JP JP58019909A patent/JPH072700B2/ja not_active Expired - Lifetime
- 1983-02-10 BR BR8300704A patent/BR8300704A/pt not_active IP Right Cessation
- 1983-02-11 ES ES519709A patent/ES8403443A1/es not_active Expired
- 1983-02-11 CA CA000421422A patent/CA1203546A/en not_active Expired
- 1983-02-11 DK DK59483A patent/DK59483A/da not_active Application Discontinuation
-
1992
- 1992-09-03 JP JP4236134A patent/JPH0672119B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US4952722A (en) | 1990-08-28 |
| JPH0672119B2 (ja) | 1994-09-14 |
| EP0086588A3 (en) | 1983-11-16 |
| NZ203104A (en) | 1986-08-08 |
| HU189228B (en) | 1986-06-30 |
| DE3372286D1 (en) | 1987-08-06 |
| IE54550B1 (en) | 1989-11-08 |
| ES519709A0 (es) | 1984-03-16 |
| IE830241L (en) | 1983-08-12 |
| DK59483D0 (da) | 1983-02-11 |
| JPH072700B2 (ja) | 1995-01-18 |
| GR78265B (es) | 1984-09-26 |
| JPH05331094A (ja) | 1993-12-14 |
| CA1203546A (en) | 1986-04-22 |
| DK59483A (da) | 1983-08-13 |
| EP0086588A2 (en) | 1983-08-24 |
| JPS58159438A (ja) | 1983-09-21 |
| BR8300704A (pt) | 1983-11-16 |
| EP0086588B1 (en) | 1987-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19970612 |