ES8602003A1 - Procedimiento de preparacion de derivados de 1,3,4,9-tetra- hidropirano(3,4,b)indol - Google Patents
Procedimiento de preparacion de derivados de 1,3,4,9-tetra- hidropirano(3,4,b)indolInfo
- Publication number
- ES8602003A1 ES8602003A1 ES540920A ES540920A ES8602003A1 ES 8602003 A1 ES8602003 A1 ES 8602003A1 ES 540920 A ES540920 A ES 540920A ES 540920 A ES540920 A ES 540920A ES 8602003 A1 ES8602003 A1 ES 8602003A1
- Authority
- ES
- Spain
- Prior art keywords
- solvent
- pyrano
- prepn
- hydro
- tetra
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 206010061218 Inflammation Diseases 0.000 title 1
- 239000003814 drug Substances 0.000 title 1
- 229940079593 drug Drugs 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 abstract 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Landscapes
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
PROCEDIMIENTO DE PREPARACION DE DERIVADOS DE 1,3,4,9-TETRAHIDROPIRANO3,4,BINDOL. CONSISTE EN HACER REACCIONAR UN DERIVADO DE INDOL DE FORMULA (II) CON UN NITRILO DE FORMULA (III), EFECTUANDOSE ESTA REACCION EN EL SENO DE UN DISOLVENTE COMO TOLUENO, BENCENO O XILENO, EN PRESENCIA DE UN ACIDO COMO BENCENOSULFONICO O TOLUENOSULFONICO, PARA FORMAR EL COMPUESTO INTERMEDIO DE FORMULA (IV), QUE SE SOMETE A UNA HIDROLISIS POSTERIOR UTILIZANDO COMO DISOLVENTE UNA MEZCLA DE AGUA Y DIOXANO O TETRAHIDROFURANO, A LA TEMPERATURA DE EBULLICION Y EN PRESENCIA DE UN ACIDO COMO SULFURICO O FOSFORICO, PARA FORMAR EL DERIVADO DE 1,3,4,9-TETRAHIDROPIRANO3,4,BINDOL DE FORMULA (I) QUE SE AISLA POR DESTILACION DEL DISOLVENTE ORGANICO Y FILTRACION DE LA SUSPENSION ACUOSA RESULTANTE, PURIFICANDOSE POR CRISTALIZACION EN UN DISOLVENTE. TIENEN UTILIDAD TERAPEUTICA POR SU ACTIVIDAD ANTIINFLAMATORIA.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES540920A ES8602003A1 (es) | 1985-03-05 | 1985-03-05 | Procedimiento de preparacion de derivados de 1,3,4,9-tetra- hidropirano(3,4,b)indol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES540920A ES8602003A1 (es) | 1985-03-05 | 1985-03-05 | Procedimiento de preparacion de derivados de 1,3,4,9-tetra- hidropirano(3,4,b)indol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES540920A0 ES540920A0 (es) | 1985-11-16 |
| ES8602003A1 true ES8602003A1 (es) | 1985-11-16 |
Family
ID=8488790
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES540920A Expired ES8602003A1 (es) | 1985-03-05 | 1985-03-05 | Procedimiento de preparacion de derivados de 1,3,4,9-tetra- hidropirano(3,4,b)indol |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES8602003A1 (es) |
-
1985
- 1985-03-05 ES ES540920A patent/ES8602003A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES540920A0 (es) | 1985-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ATE85790T1 (de) | Verfahren und herstellung von adamantan-1derivaten. | |
| ES8201579A1 (es) | Procedimiento para la preparacion de nuevas 8-fenil-purinas | |
| GB978724A (en) | Manufacture of new poly-n-diacetic acid imides | |
| DE3063059D1 (en) | Process for the purification of organic solutions of percarboxylic acids | |
| BR9003011A (pt) | Processo para purificacao de triptofano | |
| ES2043875T3 (es) | Procedimiento de fabricacion en continuo de oximinosilanos. | |
| EP0403252A3 (en) | Process for preparation of epoxy esters and intermediates prepared thereby | |
| ES8602003A1 (es) | Procedimiento de preparacion de derivados de 1,3,4,9-tetra- hidropirano(3,4,b)indol | |
| Zhang et al. | An improved synthesis of (+)-2-tropinone | |
| BR9103308A (pt) | Processo para a producao de compostos de 1-oxa-3,8-diaza-4-oxo-spiro (4,5)decano | |
| AU6473090A (en) | Recovery of acrylic acid and/or ethyl acrylate from black acid | |
| SE8401996L (sv) | Forfarande for framstellning av kinoner | |
| ATE2892T1 (de) | Synthese von 1,4-bis (dicyanomethylen) cyclohexan und dessen verwendung bei der herstellung von 7,7,8,8-tetracyanquinodimethan. | |
| ES483249A1 (es) | Procedimiento para la obtencion de diciclopentilen(2,2'-bis (4-alquil-6-t-butilfenoles). | |
| Sherman et al. | Three 2-fluoroalkyl-5-nitrofurans | |
| Bishop et al. | Ritter reactions. II. Reductive deamidation of N-bridgehead amides. | |
| Daub et al. | Synthesis of 4-(2-hydroxyethylsulfonyl)-1-naphthalenesulfonamide | |
| DE3779426D1 (de) | Parfuemzusammenstellung. | |
| FR2750990B1 (fr) | Procede de preparation de l'enol-lactone de l'acide 2-oxocyclohexylidene acetique et application a la preparation de la 2-coumaranone | |
| GR3002989T3 (en) | Process for the production of n-acylated mercapto-alpha-amino acids | |
| JPS56113785A (en) | 2-azaerythrinan derivative | |
| US3344180A (en) | Novel thiocarboxamide | |
| FR2455584A1 (fr) | Procede pour purifier du caprolactame brut contenant des amides et d'autres sous-produits et caprolactame purifie obtenu | |
| RU95105585A (ru) | Способ получения амидов 3,3-диарилакриловой кислоты | |
| ATE41766T1 (de) | Verfahren zur herstellung von monochlorhydrochinonen. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PC1A | Transfer granted | ||
| FD1A | Patent lapsed |
Effective date: 20050718 |