ES8604286A1 - Procedimiento perfeccionado para la obtencion de copolimerosvinilicos en el seno de un compuesto polihidroxilico - Google Patents
Procedimiento perfeccionado para la obtencion de copolimerosvinilicos en el seno de un compuesto polihidroxilicoInfo
- Publication number
- ES8604286A1 ES8604286A1 ES545144A ES545144A ES8604286A1 ES 8604286 A1 ES8604286 A1 ES 8604286A1 ES 545144 A ES545144 A ES 545144A ES 545144 A ES545144 A ES 545144A ES 8604286 A1 ES8604286 A1 ES 8604286A1
- Authority
- ES
- Spain
- Prior art keywords
- initiator
- effected
- styrene
- methyl methacrylate
- acrylonitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006185 dispersion Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title 1
- 229920005862 polyol Polymers 0.000 title 1
- 150000003077 polyols Chemical class 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 125000002348 vinylic group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
- C08G18/638—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the use of compounds having carbon-to-carbon double bonds other than styrene and/or olefinic nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PERFECCIONAMIENTO EN UN PROCEDIMIENTO PARA LA OBTENCION DE COPOLIMEROS VINILICOS EN EL SENO DE UN COMPUESTO POLIHIDROXILICO. CONSISTENTE EN UNA POLIMERIZACION EN EL SENO DE UN COMPUESTO POLIHIDROXILICO DE PESO MOLECULAR COMPRENDIDO ENTRE 2.10 Y 8,5.10 POR REACCION DE UNA MEZCLA DE MONOMEROS QUE CONTIENE 90-20% DE ACRILONITRILO, 80-5% DE ESTIRENO Y DE 70-3% DE UN MONOMERO VINILICO DISTINTO DE LOS ANTERIORES, PREFERENTEMENTE METACRILATO DE METILO, POR TRATAMIENTO TERMICO EN PRESENCIA DE UN INICIADOR DE FORMACION DE RADICALES LIBRES, EN UN GAS INERTE Y A PRESION SUPERIOR A LA ATMOSFERICA, REGULANDOSE SEGUN EL INICIADOR UTILIZADO Y LA VISCOSIDAD QUE SE DESEE OBTENER EN EL PRODUCTO RESULTANTE. SE UTILIZAN PARA LA FABRICACION DE ESPUMAS FLEXIBLES DE POLIURETANO.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES545144A ES8604286A1 (es) | 1985-07-12 | 1985-07-12 | Procedimiento perfeccionado para la obtencion de copolimerosvinilicos en el seno de un compuesto polihidroxilico |
| IT21076/86A IT1196943B (it) | 1985-07-12 | 1986-07-09 | Procedimento migliorato per l'ottenimento di copolimeri vinilici in un composto polidrossilico |
| FR868610308A FR2591603B1 (fr) | 1985-07-12 | 1986-07-10 | Procede pour obtenir des copolymeres vinyliques d'un compose polyhydroxyle. |
| DE19863623448 DE3623448A1 (de) | 1985-07-12 | 1986-07-11 | Verfahren zur gewinnung von vinylcopolymeren in einer polyhydroxylverbindung |
| NL8601822A NL8601822A (nl) | 1985-07-12 | 1986-07-11 | Verbeterde werkwijze voor het verkrijgen van vinylcopolymeren in een polyhydroxylverbinding. |
| GB8617090A GB2179356B (en) | 1985-07-12 | 1986-07-14 | Process for obtaining vinyl copolymers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES545144A ES8604286A1 (es) | 1985-07-12 | 1985-07-12 | Procedimiento perfeccionado para la obtencion de copolimerosvinilicos en el seno de un compuesto polihidroxilico |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES545144A0 ES545144A0 (es) | 1986-01-16 |
| ES8604286A1 true ES8604286A1 (es) | 1986-01-16 |
Family
ID=8489519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES545144A Expired ES8604286A1 (es) | 1985-07-12 | 1985-07-12 | Procedimiento perfeccionado para la obtencion de copolimerosvinilicos en el seno de un compuesto polihidroxilico |
Country Status (6)
| Country | Link |
|---|---|
| DE (1) | DE3623448A1 (es) |
| ES (1) | ES8604286A1 (es) |
| FR (1) | FR2591603B1 (es) |
| GB (1) | GB2179356B (es) |
| IT (1) | IT1196943B (es) |
| NL (1) | NL8601822A (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4804775A (en) * | 1986-09-09 | 1989-02-14 | Pennwalt Corporation | Process for reducing residual monomers in low viscosity polymer-polyols |
| GB9800011D0 (en) * | 1998-01-02 | 1998-03-04 | Exchem Plc | Composition |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2974125A (en) * | 1953-08-24 | 1961-03-07 | Dow Chemical Co | Copolymers of methyl methacrylate possessing good elongation values |
| DE1152536B (de) * | 1962-03-30 | 1963-08-08 | Bayer Ag | Verfahren zur Herstellung Urethangruppen enthaltender Schaumstoffe |
| US3953393A (en) * | 1974-01-07 | 1976-04-27 | Basf Wyandotte Corporation | Low temperature process for the preparation of graft copolymer dispersions |
| CA1092590A (en) * | 1976-06-24 | 1980-12-30 | Naresh R. Shah | Polymer/polyol compositions, processes for making same and processes for making polyurethane products therefrom |
| CA1123536A (en) * | 1976-12-20 | 1982-05-11 | Russell Van Cleve | Polymer/polyols via non-aqueous dispersion stabilizers |
| US4148840A (en) * | 1978-03-29 | 1979-04-10 | Union Carbide Corporation | Polymer/polyol compositions made from preformed polymer/polyols, processes for making same and processes for making polyurethane products therefrom |
| DE2915610A1 (de) * | 1979-04-18 | 1980-10-30 | Bayer Ag | Verfahren zur herstellung von modifizierten polyetherpolyolen und deren verwendung in verfahren zur herstellung von polyurethankunststoffen |
| GB2053933A (en) * | 1979-06-25 | 1981-02-11 | Basf Wyandotte Corp | Process for preparing graft copolymer dispersions and polyurethanes prepared therefrom |
| ES504557A0 (es) * | 1981-08-05 | 1982-06-01 | Alcudia Sa | Procedimiento para la obtencion de copolimeros vinilicos en el seno de un compuesto polihidroxilico |
| US4463107A (en) * | 1982-05-18 | 1984-07-31 | Union Carbide Corporation | Polymer/polyol compositions having improved combustion resistance |
-
1985
- 1985-07-12 ES ES545144A patent/ES8604286A1/es not_active Expired
-
1986
- 1986-07-09 IT IT21076/86A patent/IT1196943B/it active
- 1986-07-10 FR FR868610308A patent/FR2591603B1/fr not_active Expired - Lifetime
- 1986-07-11 NL NL8601822A patent/NL8601822A/nl not_active Application Discontinuation
- 1986-07-11 DE DE19863623448 patent/DE3623448A1/de not_active Ceased
- 1986-07-14 GB GB8617090A patent/GB2179356B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2591603B1 (fr) | 1990-06-29 |
| NL8601822A (nl) | 1987-02-02 |
| GB2179356B (en) | 1989-07-19 |
| FR2591603A1 (fr) | 1987-06-19 |
| IT1196943B (it) | 1988-11-25 |
| ES545144A0 (es) | 1986-01-16 |
| GB8617090D0 (en) | 1986-08-20 |
| DE3623448A1 (de) | 1987-01-22 |
| IT8621076A0 (it) | 1986-07-09 |
| IT8621076A1 (it) | 1988-01-09 |
| GB2179356A (en) | 1987-03-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20051024 |