ES8702929A1 - Procedimiento para la elaboracion de un cloruro de polvinilo apto para el riego y con elevadas proporciones de acrilato. - Google Patents
Procedimiento para la elaboracion de un cloruro de polvinilo apto para el riego y con elevadas proporciones de acrilato.Info
- Publication number
- ES8702929A1 ES8702929A1 ES553398A ES553398A ES8702929A1 ES 8702929 A1 ES8702929 A1 ES 8702929A1 ES 553398 A ES553398 A ES 553398A ES 553398 A ES553398 A ES 553398A ES 8702929 A1 ES8702929 A1 ES 8702929A1
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- addition
- suspension
- polyvinyl chloride
- pourable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 title abstract 2
- 239000004800 polyvinyl chloride Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 5
- 239000002253 acid Substances 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000000344 soap Substances 0.000 abstract 2
- 239000000375 suspending agent Substances 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 125000005396 acrylic acid ester group Chemical group 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 1
- 239000000920 calcium hydroxide Substances 0.000 abstract 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract 1
- 235000011116 calcium hydroxide Nutrition 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 abstract 1
- 229940043264 dodecyl sulfate Drugs 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000001451 organic peroxides Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/91—Suspending agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/911—Emulsifying agents
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Abstract
PROCEDIMIENTO PARA LA ELABORACION DE UN CLORURO DE POLIVINILO APTO PARA EL RIEGO Y CON ELEVADAS PROPORCIONES DE ELASTOMEROS DE ACRILATO. CONSISTE EN POLIMERIZAR POR EMULSIONAMIENTO UN ESTER DEL ACIDO ACRILICO, CUYOS POLIMEROS PRESENTAN UNA TEMPERATURA D EFRAGUADO VIDRIOSO SUPERIOR A C15JC, REALIZANDOSE ESTA: A) EN PRESENCIA DE UNA SAL ALCALINA DE UN ACIDO GRASO COMO EMULSIONANTE CON C 12 A 18 CON UN PH INICIAL SUPERIOR A 9; O B) EN PRESENCIA DE UN SULFATO ALCALINO DE LAURILO COMO EMULSIONANTE, ES DECIR, POR MEDIO DE LA ADICION INTERMITENTE O CONTINUA DEL MOMENTO EMULSIONADO PREVIAMENTE CON UNA SOLUCION ACUOSA DE SULFATO DE LAURILO, DURANTE LA POLIMERIZACION, REALIZANDOSE LA POLIMERIZACION DEL CLORURO DE VINILO EN PRESENCIA DE UNA CELULOSA METILICA COMO MEDIO DE SUSPENSION AÑADIDO DESPUES, NEUTRALIZANDOSE LA PREPARACION DE POLIMERIZACION AL AÑADIR UN ACIDO, Y POR LO TANTO AÑADIENDO UN PEROXIDO ORGANICO COMO INICIADOR EN FORMA DISUELTA O SUSPENDIDA. TIENE APLICACIONES EN UN REACTOR NUCLEAR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853510899 DE3510899A1 (de) | 1985-03-26 | 1985-03-26 | Verfahren zur herstellung eines rieselfaehigen polyvinylchlorids mit hohen anteilen an acrylatelastomeren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8702929A1 true ES8702929A1 (es) | 1987-01-16 |
| ES553398A0 ES553398A0 (es) | 1987-01-16 |
Family
ID=6266354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES553398A Expired ES8702929A1 (es) | 1985-03-26 | 1986-03-25 | Procedimiento para la elaboracion de un cloruro de polvinilo apto para el riego y con elevadas proporciones de acrilato. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4719265A (es) |
| EP (1) | EP0195942A3 (es) |
| JP (1) | JPS61225206A (es) |
| CN (1) | CN86101762A (es) |
| DE (1) | DE3510899A1 (es) |
| ES (1) | ES8702929A1 (es) |
| NO (1) | NO861218L (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3886677D1 (de) * | 1987-10-23 | 1994-02-10 | Hoechst Ag | Verfahren zur Herstellung eines Acrylsäureester-Vinylchlorid-Pfropfpolymerisates. |
| DE3803036A1 (de) * | 1988-02-02 | 1989-08-10 | Wacker Chemie Gmbh | Verfahren zur herstellung eines elastomerhaltigen vinylchloridpfropfcopolymerisats |
| DE4027640A1 (de) * | 1990-08-31 | 1992-03-05 | Huels Chemische Werke Ag | Herstellung eines schlagzaehen polyacrylsaeureester-vinylchlorid- pfropfpolymerisats |
| DE4029471A1 (de) * | 1990-09-17 | 1992-03-19 | Wacker Chemie Gmbh | Verfahren zur herstellung eines feinteiligen vinylchlorid-pfropfcopolymerisats und verwendung fuer den einsatz als viskositaetserniedriger und mattierungsmittel |
| DE4330180C2 (de) * | 1993-08-31 | 1998-02-19 | Buna Sow Leuna Olefinverb Gmbh | Verfahren zur Herstellung von schlagzähen Pfropfcopolymerisaten des Vinylchlorids |
| US5534589A (en) * | 1994-05-04 | 1996-07-09 | Minnesota Mining And Manufacturing Company | Repulpable plastic films |
| CN1053202C (zh) * | 1997-01-06 | 2000-06-07 | 中国石油化工集团公司北京化工研究院 | 高透明耐冲击聚氯乙烯的制造方法 |
| DE102009043379B4 (de) * | 2009-09-29 | 2018-01-04 | Lg Chem. Ltd. | Verfahren zur Herstellung von Vinylchlorid-Pfropfcopolymer-Harz |
| CN103388284A (zh) * | 2012-05-09 | 2013-11-13 | 杨福敬 | 一种水性硬脂酸锌乳液及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3334156A (en) * | 1964-04-22 | 1967-08-01 | Gen Tire & Rubber Co | Graft polymers of vinyl chloride onto rubbery crosslinked acrylate backbones |
| GB1304517A (es) * | 1969-05-19 | 1973-01-24 | ||
| US4011283A (en) * | 1970-02-06 | 1977-03-08 | Bp Chemicals Limited | Polymerization process |
| US4136242A (en) * | 1970-05-04 | 1979-01-23 | Shinetsu Chemical Company | Method for suspension-polymerizing vinyl chloride |
| US3969431A (en) * | 1971-09-20 | 1976-07-13 | Stauffer Chemical Company | Reinforcement of vinyl chloride resins with suspension emulsion interpolymers |
| DE2437044C3 (de) * | 1974-08-01 | 1983-04-14 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polymerisaten und Copolymerisaten des Vinylchlorids durch Suspensionspolymerisation |
| JPS5556108A (en) * | 1978-10-20 | 1980-04-24 | Shin Etsu Chem Co Ltd | Preparation of vinyl chloride polymer |
-
1985
- 1985-03-26 DE DE19853510899 patent/DE3510899A1/de not_active Withdrawn
-
1986
- 1986-02-25 EP EP86102423A patent/EP0195942A3/de not_active Withdrawn
- 1986-03-19 CN CN198686101762A patent/CN86101762A/zh active Pending
- 1986-03-25 ES ES553398A patent/ES8702929A1/es not_active Expired
- 1986-03-25 NO NO861218A patent/NO861218L/no unknown
- 1986-03-26 JP JP61066096A patent/JPS61225206A/ja active Pending
- 1986-03-26 US US06/844,440 patent/US4719265A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0195942A2 (de) | 1986-10-01 |
| JPS61225206A (ja) | 1986-10-07 |
| CN86101762A (zh) | 1986-12-17 |
| EP0195942A3 (de) | 1987-12-02 |
| DE3510899A1 (de) | 1986-10-02 |
| US4719265A (en) | 1988-01-12 |
| ES553398A0 (es) | 1987-01-16 |
| NO861218L (no) | 1986-09-29 |
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