ES8704190A1 - Procedimiento para la produccion de ligantes, solubles en agua, para lacas cationicas de electroinmersion. - Google Patents
Procedimiento para la produccion de ligantes, solubles en agua, para lacas cationicas de electroinmersion.Info
- Publication number
- ES8704190A1 ES8704190A1 ES555299A ES555299A ES8704190A1 ES 8704190 A1 ES8704190 A1 ES 8704190A1 ES 555299 A ES555299 A ES 555299A ES 555299 A ES555299 A ES 555299A ES 8704190 A1 ES8704190 A1 ES 8704190A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- production
- water
- acid
- dilutable binders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/443—Polyepoxides
- C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Molecular Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
Abstract
METODO DE FABRICACION DE LIGANTES A BASE DE RESINAS EPOXI MODIFICADAS. COMPRENDE LA REACCION DE POLIADICION DE UN COMPUESTOS DIEPOXI O UNA MEZCLA DE ESTE TIPO DE COMPUESTOS, EN UN DISOLVENTE INERTE EN SU CASO EN PRESENCIA DE UN CATALIZADOR, CON UN INICIADOR DE REACCION MONOFUNCIONAL, DE FORMULA R1OH, EN LA QUE R1 PUEDE SER UNO DE VARIOS TIPOS DE RADICALES, A UNA TEMPERATURA COMPRENDIDA ENTRE 100JC Y 195JC; SEGUIDA DE REACCION DE LA RESINA FORMADA CON UNA AMINA O UNA DE SUS SALES, O UNA MEZCLA DE SULFURO/ACIDO O FOSFINA/ACIDO, EN UN DISOLVENTE INERTE, A TEMPERATURAS ENTRE 70JC Y 110JC; Y FINALMENTE, TRATAMIENTO OPCIONAL CON UN POLIOL, POLIACIDO, POLIAMINA, POLISULFURO O POLIFENOL. LA SOLUBILIZACION EN AGUA SE EFECTUA MEDIANTE PROTONIZACION. ESTOS COMPUESTOS TIENEN APLICACIONES PARA LA PRODUCCION DE LACAS DE ELECTROINMERSION CATIONICAS, EMPLEADAS EN IMPRIMACION.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853518732 DE3518732A1 (de) | 1985-05-24 | 1985-05-24 | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES555299A0 ES555299A0 (es) | 1987-03-16 |
| ES8704190A1 true ES8704190A1 (es) | 1987-03-16 |
Family
ID=6271566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES555299A Expired ES8704190A1 (es) | 1985-05-24 | 1986-05-23 | Procedimiento para la produccion de ligantes, solubles en agua, para lacas cationicas de electroinmersion. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US4824927A (es) |
| EP (1) | EP0256020B1 (es) |
| JP (1) | JPS62502898A (es) |
| BR (1) | BR8607118A (es) |
| CA (1) | CA1266546A (es) |
| DE (2) | DE3518732A1 (es) |
| ES (1) | ES8704190A1 (es) |
| WO (1) | WO1986007082A1 (es) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3518732A1 (de) * | 1985-05-24 | 1986-11-27 | BASF Lacke + Farben AG, 4400 Münster | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| BR8807631A (pt) | 1987-07-29 | 1990-06-26 | Basf Lacke & Farben | Banhos de laca de eletro-imersao aquosos,contendo resinas sinteticas catodicamente precipitaveis e processo para o revestimento de substratos eletricamente condutores |
| ZA891937B (en) * | 1988-04-04 | 1990-11-28 | Ppg Industries Inc | Pigment grinding vehicles containing quaternary ammonium and ternary sulfonium groups |
| DE3825562A1 (de) * | 1988-07-28 | 1990-02-01 | Basf Lacke & Farben | Durch protonieren mit saeure wasserverduennbare bindemittel fuer die elektrotauchlackierung zur herstellung dickschichtiger ueberzuege |
| DE3902441A1 (de) * | 1989-01-27 | 1990-08-16 | Basf Lacke & Farben | Hitzehaertbares ueberzugsmittel fuer die kathodische elektrotauchlackierung |
| DE3918511A1 (de) * | 1989-06-07 | 1990-12-13 | Basf Lacke & Farben | Verfahren zur beschichtung elektrisch leitfaehiger substrate, waessriger lack, verfahren zur herstellung eines kationischen, aminmodifizierten epoxidharzes und nach diesem verfahren hergestelltes kationisches, aminmodifiziertes epoxidharz |
| US5693366A (en) * | 1989-06-20 | 1997-12-02 | Nippon Sheet Glass Co., Ltd. | Process for producing plastic lens comprising a primer layer, a hard coat layer and an antireflection coating |
| DE3942766A1 (de) * | 1989-12-23 | 1991-06-27 | Basf Lacke & Farben | Verfahren zum beschichten elektrisch leitfaehiger substrate, waessriger lack, epoxid-aminaddukt und verwendung des epoxid-aminadduktes als reibharz zur herstellung von pigmentpasten |
| JPH0759620B2 (ja) * | 1990-09-12 | 1995-06-28 | 日立化成工業株式会社 | 高分子量エポキシ樹脂の製造方法 |
| JPH0759617B2 (ja) * | 1990-09-10 | 1995-06-28 | 日立化成工業株式会社 | 高分子量エポキシ樹脂の製造方法 |
| US5204385A (en) * | 1990-11-27 | 1993-04-20 | Reichhold Chemicals, Inc. | Water reducible epoxy resin curing agent |
| DE4137639A1 (de) * | 1991-11-15 | 1993-05-19 | Basf Lacke & Farben | Kunstharze |
| DE4224882A1 (de) * | 1992-07-28 | 1994-02-03 | Basf Lacke & Farben | Epoxidharze |
| DE69332677T2 (de) * | 1992-10-21 | 2003-06-12 | Air Products And Chemicals, Inc. | Ionische emulsionspolymere und ihre herstellung |
| AU6280594A (en) * | 1992-10-27 | 1994-05-24 | Adhesive Coatings Co. | Novel single package ionic emulsion polymers and their preparation |
| WO1994011449A1 (en) * | 1992-11-16 | 1994-05-26 | Basf Corporation | Composition comprising a polycarbonate-modified epoxide resin for electrodeposition on metal substrates |
| US5583167A (en) * | 1993-06-30 | 1996-12-10 | Henkel Corporation | Curing agents for aqueous epoxy resins |
| US5565505A (en) * | 1993-06-30 | 1996-10-15 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| TW289024B (es) * | 1993-11-02 | 1996-10-21 | Hoechst Ag | |
| EP0739367A4 (en) | 1993-12-27 | 1997-12-10 | Henkel Corp | SELF-DISPERSING CURABLE EPOXY RESINS AND COATING COMPOSITIONS |
| US5604269A (en) * | 1993-12-27 | 1997-02-18 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| US5565506A (en) * | 1994-03-01 | 1996-10-15 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| US5427857A (en) * | 1994-06-28 | 1995-06-27 | E. I. Du Pont De Nemours And Company | Cathodic electrocoating compositions containing branched epoxy amine resins |
| AU3862995A (en) * | 1994-07-25 | 1996-02-22 | Henkel Corporation | Curing agents for aqueous epoxy resins |
| US5508373A (en) * | 1994-08-04 | 1996-04-16 | Henkel Corporation | Curing agents for epoxy resins based on 1,2-diaminocyclohexane |
| US5527839A (en) * | 1994-12-13 | 1996-06-18 | Air Products And Chemicals, Inc. | Self-emulsifying epoxy curing agent based on the reaction product of epoxy resin and polyether polyol |
| WO1996020970A1 (en) * | 1994-12-29 | 1996-07-11 | Henkel Corporation | Aqueous self-dispersible epoxy resin based on epoxy-amine adducts |
| US5750595A (en) * | 1994-12-29 | 1998-05-12 | Henkel Corporation | Self-dispersing curable epoxy resin dispersions and coating compositions made therefrom |
| US5648409A (en) * | 1994-12-29 | 1997-07-15 | Henkel Corporation | Aqueous self-dispersible epoxy resin based on epoxy-amine adducts containing aromatic polyepoxide |
| US5643976A (en) * | 1994-12-29 | 1997-07-01 | Henkel Corporation | Self-dispersing curable epoxy resin dispersions and coating compositions made therefrom |
| DE19541230A1 (de) | 1995-11-06 | 1997-05-07 | Basf Lacke & Farben | Elektrisch abscheidbares Überzugsmittel |
| DE19547786A1 (de) | 1995-12-20 | 1997-06-26 | Basf Lacke & Farben | Aufbau von modifizierten Epoxidharzen für die kathodische Elektrotauchlackierung mit Katalysator-Desaktivierung und Diolmodifizierung |
| DE19618379A1 (de) | 1996-05-08 | 1997-11-13 | Basf Lacke & Farben | Mit Copolymeren des Vinylacetats modifizierte in Wasser dispergierbare Epoxidharze |
| US5719210A (en) * | 1996-11-26 | 1998-02-17 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| DE19703869A1 (de) * | 1997-02-03 | 1998-08-06 | Basf Coatings Ag | Wäßrige Bindemitteldispersion für kationische Elektrotauchlacke |
| DE19816626C2 (de) | 1998-04-15 | 2002-07-18 | Basf Coatings Ag | Mittel zum Blockieren von Polyisocyanaten, hiermit blockierte Polyisocyanate und Beschichtungsmittel, welche diese blockierten Polyisocyanate enthalten |
| EP0974625A3 (en) * | 1998-07-22 | 2001-03-21 | Nippon Paint Co., Ltd. | Method of electrolyte bath stabilization |
| DE19930060A1 (de) | 1999-06-30 | 2001-01-11 | Basf Coatings Ag | Elektrotauchlackbad mit wasserlöslichem Polyvinylalkohol(co)polymeren |
| DE10236350A1 (de) | 2002-08-08 | 2004-02-19 | Basf Coatings Ag | Bismutverbindungen enthaltende Elektrotauchlacke (ETL) |
| DE102005023728A1 (de) | 2005-05-23 | 2006-11-30 | Basf Coatings Ag | Lackschichtbildendes Korrosionsschutzmittel und Verfahren zu dessen stromfreier Applikation |
| DE102006053291A1 (de) | 2006-11-13 | 2008-05-15 | Basf Coatings Ag | Lackschichtbildendes Korrosionsschutzmittel mit guter Haftung und Verfahren zu dessen stromfreier Applikation |
| JP5344789B2 (ja) * | 2006-12-28 | 2013-11-20 | 新日鉄住金化学株式会社 | 新規エポキシ樹脂、該エポキシ樹脂を必須成分とするエポキシ樹脂組成物及び該エポキシ樹脂を必須成分とする硬化物 |
| DE102007012406A1 (de) * | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Verfahren zur Korrosionsschutzausrüstung metallischer Substrate |
| DE102007038824A1 (de) | 2007-08-16 | 2009-02-19 | Basf Coatings Ag | Einsatz von Bismutsubnitrat in Elektrotauchlacken |
| DE102008016220A1 (de) | 2008-03-27 | 2009-10-01 | Basf Coatings Ag | Elektrotauchlacke enthaltend Polymethylenharnstoff |
| DE102009007632A1 (de) | 2009-02-05 | 2010-08-12 | Basf Coatings Ag | Beschichtungsmittel für korrosionsstabile Lackierungen |
| DE102010012047A1 (de) | 2010-03-19 | 2011-09-22 | Basf Coatings Gmbh | Verfahren zur Beschichtung eines Metall- oder Kunststoffsubstrats, daraus erhältliche Beschichtung und beschichtetes Substrat |
| CN105408429B (zh) | 2013-05-28 | 2018-10-19 | 巴斯夫涂料有限公司 | 在固化前用水性溶胶-凝胶组合物后处理浸渍漆涂层的浸渍漆涂布导电基材的方法 |
| EP3033396B1 (de) | 2013-08-12 | 2017-11-29 | BASF Coatings GmbH | Beschichtungszusammensetzung zur tauchlack-beschichtung elektrisch leitfähiger substrate enthaltend eine sol-gel-zusammensetzung |
| MX390670B (es) | 2013-11-18 | 2025-03-20 | Basf Coatings Gmbh | Metodo de dos etapas para el recubrimiento por inmersion de sustratos electricamente conductores utilizando una composicion que contiene bi(iii). |
| US10407578B2 (en) | 2013-11-18 | 2019-09-10 | Basf Coatings Gmbh | Aqueous dip-coating composition for electroconductive substrates, comprising both dissolved and undissolved bismuth |
| MX2016006412A (es) | 2013-11-18 | 2016-12-09 | Basf Coatings Gmbh | Composicion acuosa de recubrimiento por inmersion que comprende bismuto disuelto, para sustratos conductores de electricidad. |
| WO2015074679A1 (de) | 2013-11-19 | 2015-05-28 | Basf Coatings Gmbh | Wässrige beschichtungszusammensetzung zur tauchlack-beschichtung elektrisch leitfähiger substrate enthaltend aluminiumoxid |
| JP6285045B2 (ja) | 2013-11-19 | 2018-02-28 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 酸化マグネシウムを含む導電性基材のための水性ディップコーティング組成物 |
| KR20160096688A (ko) | 2013-12-10 | 2016-08-16 | 바스프 코팅스 게엠베하 | 비스무트 및 인-함유 아민-블록화된 화합물을 함유하는, 전기 전도성 기판의 딥 코팅을 위한 수성 코팅 조성물 |
| KR20160099715A (ko) | 2013-12-20 | 2016-08-22 | 바스프 코팅스 게엠베하 | 안료 및 충전제 함유 제형 |
| MX2020004123A (es) | 2017-10-09 | 2020-08-13 | Basf Coatings Gmbh | Materiales de electro-recubrimiento que comprenden al menos un compuesto triazina. |
| JP7354789B2 (ja) * | 2018-12-10 | 2023-10-03 | Dic株式会社 | エポキシ樹脂用硬化剤これを含む樹脂組成物、及びエポキシ樹脂モルタル |
| EP3956406B1 (de) | 2019-04-15 | 2025-08-27 | BASF Coatings GmbH | Wässrige beschichtungszusammensetzung zur tauchlack-beschichtung elektrisch leitfähiger substrate enthaltend bismut sowie lithium |
| WO2021123106A1 (en) | 2019-12-19 | 2021-06-24 | Basf Coatings Gmbh | Lamp black pigment containing electrodeposition coating material compositions |
| WO2021148261A1 (en) | 2020-01-24 | 2021-07-29 | Basf Coatings Gmbh | Aqueous electrocoating materials comprising a silane-containing crosslinker |
| EP3854831A1 (en) | 2020-01-24 | 2021-07-28 | BASF Coatings GmbH | Compound comprising fully blocked isocyanate and silane groups and its use as crosslinker in electrocoating materials |
| WO2022128359A1 (en) | 2020-12-15 | 2022-06-23 | Basf Coatings Gmbh | Electrodeposition coating material compositions comprising alkoxylated polyethyleneimines |
| JP2025518916A (ja) | 2022-06-09 | 2025-06-19 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | アルコキシル化ポリエチレンイミンを含む電着塗料組成物 |
| WO2024056309A1 (en) | 2022-09-15 | 2024-03-21 | Basf Coatings Gmbh | Electrodeposition coating material compositions comprising composite particles containing metal-containing catalyst |
| JP2025531251A (ja) | 2022-09-15 | 2025-09-19 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 顔料スラリー、及び金属含有触媒を含有する複合粒子を含む電着塗装材料組成物 |
| WO2026052294A1 (en) | 2024-09-05 | 2026-03-12 | Basf Coatings Gmbh | Electrodeposition coating material with improved uv-stability |
| WO2026052296A1 (en) | 2024-09-05 | 2026-03-12 | Basf Coatings Gmbh | Serial cathodic electrodeposition coating process |
| WO2026052295A1 (en) | 2024-09-05 | 2026-03-12 | Basf Coatings Gmbh | Electrodeposition coating material having good uv stability |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3799854A (en) * | 1970-06-19 | 1974-03-26 | Ppg Industries Inc | Method of electrodepositing cationic compositions |
| US3936405A (en) * | 1972-08-16 | 1976-02-03 | Ppg Industries, Inc. | Novel pigment grinding vehicles |
| CA1111598A (en) * | 1976-01-14 | 1981-10-27 | Joseph R. Marchetti | Amine acide salt-containing polymers for cationic electrodeposition |
| US4260720A (en) * | 1979-10-31 | 1981-04-07 | Ppg Industries, Inc. | Novel mercapto chain extended products and their use in cationic electrodeposition |
| GB8315230D0 (en) * | 1983-06-03 | 1983-07-06 | Shell Int Research | Polyglycidyl ethers |
| DE3331904A1 (de) * | 1983-09-03 | 1985-03-21 | Basf Farben + Fasern Ag, 2000 Hamburg | Wasserdispergierbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| DE3331903A1 (de) * | 1983-09-03 | 1985-03-21 | Basf Farben + Fasern Ag, 2000 Hamburg | Wasserdispergierbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| DE3409188A1 (de) * | 1984-03-14 | 1985-09-19 | Basf Farben + Fasern Ag, 2000 Hamburg | Mit alkoholen modifizierte polyepoxide, ihre herstellung und verwendung in haertbaren mischungen |
| DE3518732A1 (de) * | 1985-05-24 | 1986-11-27 | BASF Lacke + Farben AG, 4400 Münster | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| DE3518770A1 (de) * | 1985-05-24 | 1986-11-27 | BASF Lacke + Farben AG, 4400 Münster | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
-
1985
- 1985-05-24 DE DE19853518732 patent/DE3518732A1/de not_active Withdrawn
-
1986
- 1986-05-17 BR BR8607118A patent/BR8607118A/pt not_active IP Right Cessation
- 1986-05-17 EP EP86903340A patent/EP0256020B1/de not_active Expired - Lifetime
- 1986-05-17 WO PCT/EP1986/000302 patent/WO1986007082A1/de not_active Ceased
- 1986-05-17 DE DE8686903340T patent/DE3675659D1/de not_active Expired - Lifetime
- 1986-05-17 JP JP61502862A patent/JPS62502898A/ja active Granted
- 1986-05-17 US US07/009,336 patent/US4824927A/en not_active Expired - Lifetime
- 1986-05-23 CA CA000509887A patent/CA1266546A/en not_active Expired - Lifetime
- 1986-05-23 ES ES555299A patent/ES8704190A1/es not_active Expired
-
1989
- 1989-12-20 US US07/453,343 patent/US5003025A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5003025A (en) | 1991-03-26 |
| WO1986007082A1 (fr) | 1986-12-04 |
| EP0256020B1 (de) | 1990-11-14 |
| US4824927A (en) | 1989-04-25 |
| JPS62502898A (ja) | 1987-11-19 |
| DE3675659D1 (de) | 1990-12-20 |
| ES555299A0 (es) | 1987-03-16 |
| CA1266546A (en) | 1990-03-06 |
| EP0256020A1 (de) | 1988-02-24 |
| JPH0137431B2 (es) | 1989-08-07 |
| DE3518732A1 (de) | 1986-11-27 |
| BR8607118A (pt) | 1988-02-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 20070117 |