ES8704190A1 - Procedimiento para la produccion de ligantes, solubles en agua, para lacas cationicas de electroinmersion. - Google Patents
Procedimiento para la produccion de ligantes, solubles en agua, para lacas cationicas de electroinmersion.Info
- Publication number
- ES8704190A1 ES8704190A1 ES555299A ES555299A ES8704190A1 ES 8704190 A1 ES8704190 A1 ES 8704190A1 ES 555299 A ES555299 A ES 555299A ES 555299 A ES555299 A ES 555299A ES 8704190 A1 ES8704190 A1 ES 8704190A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- production
- water
- acid
- dilutable binders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/443—Polyepoxides
- C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
Abstract
METODO DE FABRICACION DE LIGANTES A BASE DE RESINAS EPOXI MODIFICADAS. COMPRENDE LA REACCION DE POLIADICION DE UN COMPUESTOS DIEPOXI O UNA MEZCLA DE ESTE TIPO DE COMPUESTOS, EN UN DISOLVENTE INERTE EN SU CASO EN PRESENCIA DE UN CATALIZADOR, CON UN INICIADOR DE REACCION MONOFUNCIONAL, DE FORMULA R1OH, EN LA QUE R1 PUEDE SER UNO DE VARIOS TIPOS DE RADICALES, A UNA TEMPERATURA COMPRENDIDA ENTRE 100JC Y 195JC; SEGUIDA DE REACCION DE LA RESINA FORMADA CON UNA AMINA O UNA DE SUS SALES, O UNA MEZCLA DE SULFURO/ACIDO O FOSFINA/ACIDO, EN UN DISOLVENTE INERTE, A TEMPERATURAS ENTRE 70JC Y 110JC; Y FINALMENTE, TRATAMIENTO OPCIONAL CON UN POLIOL, POLIACIDO, POLIAMINA, POLISULFURO O POLIFENOL. LA SOLUBILIZACION EN AGUA SE EFECTUA MEDIANTE PROTONIZACION. ESTOS COMPUESTOS TIENEN APLICACIONES PARA LA PRODUCCION DE LACAS DE ELECTROINMERSION CATIONICAS, EMPLEADAS EN IMPRIMACION.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853518732 DE3518732A1 (de) | 1985-05-24 | 1985-05-24 | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8704190A1 true ES8704190A1 (es) | 1987-03-16 |
| ES555299A0 ES555299A0 (es) | 1987-03-16 |
Family
ID=6271566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES555299A Expired ES8704190A1 (es) | 1985-05-24 | 1986-05-23 | Procedimiento para la produccion de ligantes, solubles en agua, para lacas cationicas de electroinmersion. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US4824927A (es) |
| EP (1) | EP0256020B1 (es) |
| JP (1) | JPS62502898A (es) |
| BR (1) | BR8607118A (es) |
| CA (1) | CA1266546A (es) |
| DE (2) | DE3518732A1 (es) |
| ES (1) | ES8704190A1 (es) |
| WO (1) | WO1986007082A1 (es) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3518732A1 (de) * | 1985-05-24 | 1986-11-27 | BASF Lacke + Farben AG, 4400 Münster | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| DE3866456D1 (de) | 1987-07-29 | 1992-01-09 | Basf Lacke & Farben | Kathodisch abscheidbare kunstharze enthaltende waessrige elektrotauchlackbaeder und verfahren zur beschichtung elektrisch leitfaehiger substrate. |
| ZA891937B (en) * | 1988-04-04 | 1990-11-28 | Ppg Industries Inc | Pigment grinding vehicles containing quaternary ammonium and ternary sulfonium groups |
| DE3825562A1 (de) * | 1988-07-28 | 1990-02-01 | Basf Lacke & Farben | Durch protonieren mit saeure wasserverduennbare bindemittel fuer die elektrotauchlackierung zur herstellung dickschichtiger ueberzuege |
| DE3902441A1 (de) * | 1989-01-27 | 1990-08-16 | Basf Lacke & Farben | Hitzehaertbares ueberzugsmittel fuer die kathodische elektrotauchlackierung |
| DE3918511A1 (de) * | 1989-06-07 | 1990-12-13 | Basf Lacke & Farben | Verfahren zur beschichtung elektrisch leitfaehiger substrate, waessriger lack, verfahren zur herstellung eines kationischen, aminmodifizierten epoxidharzes und nach diesem verfahren hergestelltes kationisches, aminmodifiziertes epoxidharz |
| US5693366A (en) * | 1989-06-20 | 1997-12-02 | Nippon Sheet Glass Co., Ltd. | Process for producing plastic lens comprising a primer layer, a hard coat layer and an antireflection coating |
| DE3942766A1 (de) * | 1989-12-23 | 1991-06-27 | Basf Lacke & Farben | Verfahren zum beschichten elektrisch leitfaehiger substrate, waessriger lack, epoxid-aminaddukt und verwendung des epoxid-aminadduktes als reibharz zur herstellung von pigmentpasten |
| JPH0759617B2 (ja) * | 1990-09-10 | 1995-06-28 | 日立化成工業株式会社 | 高分子量エポキシ樹脂の製造方法 |
| JPH0759620B2 (ja) * | 1990-09-12 | 1995-06-28 | 日立化成工業株式会社 | 高分子量エポキシ樹脂の製造方法 |
| US5204385A (en) * | 1990-11-27 | 1993-04-20 | Reichhold Chemicals, Inc. | Water reducible epoxy resin curing agent |
| DE4137639A1 (de) * | 1991-11-15 | 1993-05-19 | Basf Lacke & Farben | Kunstharze |
| DE4224882A1 (de) * | 1992-07-28 | 1994-02-03 | Basf Lacke & Farben | Epoxidharze |
| WO1994009068A1 (en) * | 1992-10-21 | 1994-04-28 | Adhesive Coatings Co. | Novel ionic emulsion polymers and their preparation |
| AU6280594A (en) * | 1992-10-27 | 1994-05-24 | Adhesive Coatings Co. | Novel single package ionic emulsion polymers and their preparation |
| WO1994011449A1 (en) * | 1992-11-16 | 1994-05-26 | Basf Corporation | Composition comprising a polycarbonate-modified epoxide resin for electrodeposition on metal substrates |
| US5565505A (en) * | 1993-06-30 | 1996-10-15 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| US5583167A (en) * | 1993-06-30 | 1996-12-10 | Henkel Corporation | Curing agents for aqueous epoxy resins |
| TW289024B (es) * | 1993-11-02 | 1996-10-21 | Hoechst Ag | |
| JPH09507873A (ja) | 1993-12-27 | 1997-08-12 | ヘンケル コーポレーション | 自己分散型硬化性エポキシ樹脂と、それを伴って製造される分散液、およびそれから製造される塗料 |
| US5604269A (en) * | 1993-12-27 | 1997-02-18 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| US5565506A (en) * | 1994-03-01 | 1996-10-15 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| US5427857A (en) * | 1994-06-28 | 1995-06-27 | E. I. Du Pont De Nemours And Company | Cathodic electrocoating compositions containing branched epoxy amine resins |
| WO1996003452A1 (en) * | 1994-07-25 | 1996-02-08 | Henkel Corporation | Curing agents for aqueous epoxy resins |
| US5508373A (en) * | 1994-08-04 | 1996-04-16 | Henkel Corporation | Curing agents for epoxy resins based on 1,2-diaminocyclohexane |
| US5527839A (en) * | 1994-12-13 | 1996-06-18 | Air Products And Chemicals, Inc. | Self-emulsifying epoxy curing agent based on the reaction product of epoxy resin and polyether polyol |
| US5643976A (en) * | 1994-12-29 | 1997-07-01 | Henkel Corporation | Self-dispersing curable epoxy resin dispersions and coating compositions made therefrom |
| US5750595A (en) * | 1994-12-29 | 1998-05-12 | Henkel Corporation | Self-dispersing curable epoxy resin dispersions and coating compositions made therefrom |
| US5648409A (en) * | 1994-12-29 | 1997-07-15 | Henkel Corporation | Aqueous self-dispersible epoxy resin based on epoxy-amine adducts containing aromatic polyepoxide |
| WO1996020970A1 (en) * | 1994-12-29 | 1996-07-11 | Henkel Corporation | Aqueous self-dispersible epoxy resin based on epoxy-amine adducts |
| DE19541230A1 (de) | 1995-11-06 | 1997-05-07 | Basf Lacke & Farben | Elektrisch abscheidbares Überzugsmittel |
| DE19547786A1 (de) | 1995-12-20 | 1997-06-26 | Basf Lacke & Farben | Aufbau von modifizierten Epoxidharzen für die kathodische Elektrotauchlackierung mit Katalysator-Desaktivierung und Diolmodifizierung |
| DE19618379A1 (de) | 1996-05-08 | 1997-11-13 | Basf Lacke & Farben | Mit Copolymeren des Vinylacetats modifizierte in Wasser dispergierbare Epoxidharze |
| US5719210A (en) * | 1996-11-26 | 1998-02-17 | Henkel Corporation | Self-dispersing curable epoxy resins, dispersions made therewith, and coating compositions made therefrom |
| DE19703869A1 (de) * | 1997-02-03 | 1998-08-06 | Basf Coatings Ag | Wäßrige Bindemitteldispersion für kationische Elektrotauchlacke |
| DE19816626C2 (de) | 1998-04-15 | 2002-07-18 | Basf Coatings Ag | Mittel zum Blockieren von Polyisocyanaten, hiermit blockierte Polyisocyanate und Beschichtungsmittel, welche diese blockierten Polyisocyanate enthalten |
| EP0974625A3 (en) * | 1998-07-22 | 2001-03-21 | Nippon Paint Co., Ltd. | Method of electrolyte bath stabilization |
| DE19930060A1 (de) | 1999-06-30 | 2001-01-11 | Basf Coatings Ag | Elektrotauchlackbad mit wasserlöslichem Polyvinylalkohol(co)polymeren |
| DE10236350A1 (de) | 2002-08-08 | 2004-02-19 | Basf Coatings Ag | Bismutverbindungen enthaltende Elektrotauchlacke (ETL) |
| DE102005023728A1 (de) | 2005-05-23 | 2006-11-30 | Basf Coatings Ag | Lackschichtbildendes Korrosionsschutzmittel und Verfahren zu dessen stromfreier Applikation |
| DE102006053291A1 (de) | 2006-11-13 | 2008-05-15 | Basf Coatings Ag | Lackschichtbildendes Korrosionsschutzmittel mit guter Haftung und Verfahren zu dessen stromfreier Applikation |
| JP5344789B2 (ja) * | 2006-12-28 | 2013-11-20 | 新日鉄住金化学株式会社 | 新規エポキシ樹脂、該エポキシ樹脂を必須成分とするエポキシ樹脂組成物及び該エポキシ樹脂を必須成分とする硬化物 |
| DE102007012406A1 (de) * | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Verfahren zur Korrosionsschutzausrüstung metallischer Substrate |
| DE102007038824A1 (de) | 2007-08-16 | 2009-02-19 | Basf Coatings Ag | Einsatz von Bismutsubnitrat in Elektrotauchlacken |
| DE102008016220A1 (de) | 2008-03-27 | 2009-10-01 | Basf Coatings Ag | Elektrotauchlacke enthaltend Polymethylenharnstoff |
| DE102009007632A1 (de) | 2009-02-05 | 2010-08-12 | Basf Coatings Ag | Beschichtungsmittel für korrosionsstabile Lackierungen |
| DE102010012047A1 (de) | 2010-03-19 | 2011-09-22 | Basf Coatings Gmbh | Verfahren zur Beschichtung eines Metall- oder Kunststoffsubstrats, daraus erhältliche Beschichtung und beschichtetes Substrat |
| WO2014191481A1 (de) | 2013-05-28 | 2014-12-04 | Basf Coatings Gmbh | Verfahren zur tauchlack-beschichtung elektrisch leitfähiger substrate unter nachbehandlung der tauchlack-beschichtung mit einer wässrigen sol-gel- zusammensetzung vor deren aushärtung |
| US10208213B2 (en) | 2013-08-12 | 2019-02-19 | Basf Coatings Gmbh | Dip-coating composition for electroconductive substrates, comprising a sol-gel composition |
| EP3071658B1 (de) | 2013-11-18 | 2017-12-13 | BASF Coatings GmbH | Zweistufiges verfahren zur tauchlack-beschichtung elektrisch leitfähiger substrate unter verwendung einer bi(iii)-haltigen zusammensetzung |
| JP6375385B2 (ja) | 2013-11-18 | 2018-08-15 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 溶解と非溶解両方のビスマスを含む導電性基材のための水性ディップコーティング組成物 |
| CN105874018B (zh) | 2013-11-18 | 2019-03-08 | 巴斯夫涂料有限公司 | 用于浸涂导电基底的包含溶解形式铋的水性涂料组合物 |
| CA2927271A1 (en) | 2013-11-19 | 2015-05-28 | Basf Coatings Gmbh | Aqueous dip-coating composition for electroconductive substrates, comprising aluminum oxide |
| CN105765007A (zh) | 2013-11-19 | 2016-07-13 | 巴斯夫涂料有限公司 | 用于浸涂导电基底的包含氧化镁的水性涂料组合物 |
| JP6231217B2 (ja) | 2013-12-10 | 2017-11-15 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | ビスマスおよびリン含有アミンブロック化化合物を含む導電性基材のための水性ディップコーティング組成物 |
| WO2015090444A1 (de) | 2013-12-20 | 2015-06-25 | Basf Coatings Gmbh | Pigment und füllstoff enthaltende formulierungen |
| US11692105B2 (en) | 2017-10-09 | 2023-07-04 | Basf Coatings Gmbh | Electrocoats containing at least one triazine compound |
| JP7354789B2 (ja) * | 2018-12-10 | 2023-10-03 | Dic株式会社 | エポキシ樹脂用硬化剤これを含む樹脂組成物、及びエポキシ樹脂モルタル |
| WO2020212074A1 (de) | 2019-04-15 | 2020-10-22 | Basf Coatings Gmbh | Wässrige beschichtungszusammensetzung zur tauchlack-beschichtung elektrisch leitfähiger substrate enthaltend bismut sowie lithium |
| MX2022007462A (es) | 2019-12-19 | 2022-06-27 | Basf Coatings Gmbh | Composiciones de material de recubrimiento por electrodeposicion que contienen pigmento negro de humo. |
| CN115003721B (zh) | 2020-01-24 | 2024-11-12 | 巴斯夫涂料有限公司 | 包含含硅烷的交联剂的水性电泳涂料 |
| EP3854831A1 (en) | 2020-01-24 | 2021-07-28 | BASF Coatings GmbH | Compound comprising fully blocked isocyanate and silane groups and its use as crosslinker in electrocoating materials |
| WO2022128359A1 (en) | 2020-12-15 | 2022-06-23 | Basf Coatings Gmbh | Electrodeposition coating material compositions comprising alkoxylated polyethyleneimines |
| CA3257996A1 (en) | 2022-06-09 | 2023-12-14 | Basf Coatings Gmbh | Electrochemically deposited coating material compositions comprising alkoxylated polyethyleneimines |
| JP2025531251A (ja) | 2022-09-15 | 2025-09-19 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 顔料スラリー、及び金属含有触媒を含有する複合粒子を含む電着塗装材料組成物 |
| WO2024056309A1 (en) | 2022-09-15 | 2024-03-21 | Basf Coatings Gmbh | Electrodeposition coating material compositions comprising composite particles containing metal-containing catalyst |
| WO2026052296A1 (en) | 2024-09-05 | 2026-03-12 | Basf Coatings Gmbh | Serial cathodic electrodeposition coating process |
| WO2026052295A1 (en) | 2024-09-05 | 2026-03-12 | Basf Coatings Gmbh | Electrodeposition coating material having good uv stability |
| WO2026052294A1 (en) | 2024-09-05 | 2026-03-12 | Basf Coatings Gmbh | Electrodeposition coating material with improved uv-stability |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3799854A (en) * | 1970-06-19 | 1974-03-26 | Ppg Industries Inc | Method of electrodepositing cationic compositions |
| US3936405A (en) * | 1972-08-16 | 1976-02-03 | Ppg Industries, Inc. | Novel pigment grinding vehicles |
| CA1111598A (en) * | 1976-01-14 | 1981-10-27 | Joseph R. Marchetti | Amine acide salt-containing polymers for cationic electrodeposition |
| US4260720A (en) * | 1979-10-31 | 1981-04-07 | Ppg Industries, Inc. | Novel mercapto chain extended products and their use in cationic electrodeposition |
| GB8315230D0 (en) * | 1983-06-03 | 1983-07-06 | Shell Int Research | Polyglycidyl ethers |
| DE3331903A1 (de) * | 1983-09-03 | 1985-03-21 | Basf Farben + Fasern Ag, 2000 Hamburg | Wasserdispergierbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| DE3331904A1 (de) * | 1983-09-03 | 1985-03-21 | Basf Farben + Fasern Ag, 2000 Hamburg | Wasserdispergierbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| DE3409188A1 (de) * | 1984-03-14 | 1985-09-19 | Basf Farben + Fasern Ag, 2000 Hamburg | Mit alkoholen modifizierte polyepoxide, ihre herstellung und verwendung in haertbaren mischungen |
| DE3518770A1 (de) * | 1985-05-24 | 1986-11-27 | BASF Lacke + Farben AG, 4400 Münster | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
| DE3518732A1 (de) * | 1985-05-24 | 1986-11-27 | BASF Lacke + Farben AG, 4400 Münster | Wasserverduennbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung |
-
1985
- 1985-05-24 DE DE19853518732 patent/DE3518732A1/de not_active Withdrawn
-
1986
- 1986-05-17 US US07/009,336 patent/US4824927A/en not_active Expired - Lifetime
- 1986-05-17 EP EP86903340A patent/EP0256020B1/de not_active Expired - Lifetime
- 1986-05-17 WO PCT/EP1986/000302 patent/WO1986007082A1/de not_active Ceased
- 1986-05-17 DE DE8686903340T patent/DE3675659D1/de not_active Expired - Lifetime
- 1986-05-17 BR BR8607118A patent/BR8607118A/pt not_active IP Right Cessation
- 1986-05-17 JP JP61502862A patent/JPS62502898A/ja active Granted
- 1986-05-23 CA CA000509887A patent/CA1266546A/en not_active Expired - Lifetime
- 1986-05-23 ES ES555299A patent/ES8704190A1/es not_active Expired
-
1989
- 1989-12-20 US US07/453,343 patent/US5003025A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO1986007082A1 (fr) | 1986-12-04 |
| DE3675659D1 (de) | 1990-12-20 |
| EP0256020B1 (de) | 1990-11-14 |
| CA1266546A (en) | 1990-03-06 |
| JPS62502898A (ja) | 1987-11-19 |
| US4824927A (en) | 1989-04-25 |
| EP0256020A1 (de) | 1988-02-24 |
| ES555299A0 (es) | 1987-03-16 |
| JPH0137431B2 (es) | 1989-08-07 |
| US5003025A (en) | 1991-03-26 |
| DE3518732A1 (de) | 1986-11-27 |
| BR8607118A (pt) | 1988-02-09 |
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| Date | Code | Title | Description |
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| FD1A | Patent lapsed |
Effective date: 20070117 |