FI104354B - Biocid komposition samt förfarande för framställning av en produkt innehållande denna - Google Patents
Biocid komposition samt förfarande för framställning av en produkt innehållande denna Download PDFInfo
- Publication number
- FI104354B FI104354B FI900046A FI900046A FI104354B FI 104354 B FI104354 B FI 104354B FI 900046 A FI900046 A FI 900046A FI 900046 A FI900046 A FI 900046A FI 104354 B FI104354 B FI 104354B
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- FI
- Finland
- Prior art keywords
- group
- carrier
- biocidal
- phosphate ester
- carbon atoms
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- 230000003115 biocidal effect Effects 0.000 title claims abstract description 57
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- 238000000034 method Methods 0.000 title claims description 21
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- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 70
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- 125000000217 alkyl group Chemical group 0.000 claims description 11
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- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 3
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- BHZOKUMUHVTPBX-UHFFFAOYSA-M sodium acetic acid acetate Chemical compound [Na+].CC(O)=O.CC([O-])=O BHZOKUMUHVTPBX-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000542 thalamic effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/08—Amines; Quaternary ammonium compounds containing oxygen or sulfur
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0058—Biocides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Saccharide Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- External Artificial Organs (AREA)
- Biological Depolymerization Polymers (AREA)
- Medicinal Preparation (AREA)
- Detergent Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Claims (21)
1. Biocid komposition för inblandning i eller päföring pä ett föremäll eller ett material, kännetecknad av att den innehäller 10 (a) en inert bärare och (b) en biocidiskt effektiv mängd av en fosfatester med den allmänna formeln 0 II HO -P- OR OR' i vilken R och R' är valda ur gruppen bestäende av alkyl-, aryl-, aralkyl- och alka-rylgrupper, och den ena av R eller R' kan vara H, och i vilken minst en fri hydroxyl-15 grupp förekommer, och att fosfatestem är bunden tili bäraren.
2. Biocid komposition enligt patentkrav 1, kännetecknad av att fosfatestem ut-göres av en partiellt neutraliserad syra med den allmänna formeln
0 II Χ+ Ό - P - OR OH 20. vilken X är vald ur gruppen bestäende av organiska joner, grupp IA-metaller, grupp IIA-metaller och övergängsmetaller.
3. Biocid komposition enligt patentkrav 2, kännetecknad av att X+ är ammo-niumjon.
4. Biocid komposition enligt patentkrav 3, kännetecknad av att ammoniumjonen • 25 har den allmänna formeln 19 104354 il r2-n+-h l Ri i vilken Ri är vald ur gruppen bestäende av alkylgrupper med mellan 1 och 18 kol-atomer och hydroxialkylgrupper med mellan 2 och 18 kolatomer, och R2 är en al-kylgrupp med mellan 8 och 18 kolatomer.
5. Biocid komposition enligt patentkrav 1, kännetecknad av att bäraren är ett inert, oorganiskt partikelformigt material valt ur gruppen bestäende av diatomace-jord, attapulgitlera, kolloidal kiselsyra och zeolit.
6. Biocid komposition enligt patentkrav 1, kännetecknad av att bäraren utgöres av en syntetisk eller naturlig polymer vald ur gruppen bestäende av proteiner, poly- 10 sackarider, kolvätepolymerer och derivat därav.
7. Biocid komposition enligt patentkrav 6, kännetecknad av att bäraren är en naturlig polymer vald ur gruppen bestäende av bomull, ull, Iin, kollagen, kitin, kito-san och gelatin.
8. Biocid komposition enligt patentkrav 6, kännetecknad av att bäraren är vald 15 ur gruppen bestäende av polyolefmer, polystyrener, polyaminer, polyakrylater, po- lyamider, polyetrar, polyuretaner och monomerer därav.
9. Biocid komposition enligt patentkrav 1, kännetecknad av att den även inne-häller en buffertsubstans. • ·
10. Förfarande för framställning av en produkt med antimikrobiella egenskaper, 20 kännetecknat av att man ästadkommer en biocid komposition innehällande (a) en inert bärare och (b) en biocidiskt effektiv mängd av en fosfatester med den allmänna formeln 0 • : Il HO -P- OR OR’ i vilken R och R' är valda frän gruppen bestäende av alkyl-, aryl-, aralkyl- och alka-25 rylgrupper, och den ena av R eller R' kan vara H, och i vilken minst en fri hydroxyl-T grupp förekommer, 20 104354 och i vilken fosfatestem är bunden till bäraren, och att man inblandar den biocida kompositionen i eller applicerar den pä produkten som skall framställas.
11. Förfarande enligt patentkrav 10, kännetecknat av att fosfatestem är en delvis 5 neutraliserad syra med den allmänna formeln 0 + II X+ Ό - P - OR OH i vilken X är vald ur gruppen bestäende av organiska joner, gmpp IA-metaller, gmpp IIA-metaller och övergängsmetaller.
12. Förfarande enligt patentkrav 11, kännetecknat av att X är en ammoniumjon. 10
13. Förfarande enligt patentkrav 12, kännetecknat av att ammoniumjonen har den allmänna formeln Rj R, - N+ - H Ri i vilken Rj är vald ur gruppen bestäende av alkylgrupper med mellan 1 och 18 kol-atomer och hydroxialkylgmpper med mellan 1 och 18 kolatomer, och i vilken R2 är . 15 en alkylgrupp med mellan 8 och 18 kolatomer.
14. Förfarande enligt patentkrav 10, kännetecknat av att bäraren utgöres av ett inert, oorganiskt partikelformigt material valt ur gruppen bestäende av diatomace-jord, attapulgitlera, kolloidal kiselsyra och zeolit.
15. Förfarande enligt patentkrav 10, kännetecknat av att bäraren är en syntetisk : 20 eller naturlig polymer vald ur gruppen bestäende av proteiner, polysackarider, koivä- tepolymerer och derivat därav.
16. Förfarande enligt patentkrav 10, kännetecknat av att bäraren är naturlig polymer vald ur gruppen bestäende av bomull, ull, Iin, kollagen, kitin, kitosan och gelatin. 104354
17. Förfarande enligt patentkrav 10, kännetecknat av att bäraren är vald ur grup-pen bestäende av polyolefiner, polystyrener, polyaminer, polyakrylater, polyamider, polyetrar, polyuretaner och monomerer därav. p
18. Förfarande enligt patentkrav 10, kännetecknat av att tili produkten tillsätts en 5 buffertsubstans.
19. Förfarande enligt patentkrav 10, kännetecknat av att man bildar en beläggning av bärar-biocidkompositionen.
20. Förfarande enligt patentkrav 10, kännetecknat av att den biocida fosfatför-eningen mikroinkapslas inom bäraren. 10
21. Förfarande enligt patentkrav 10, kännetecknat av att produkten som skall framställas är en mälarfärg. t • ·
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/190,370 US4908209A (en) | 1983-08-16 | 1988-05-05 | Biocidal delivery system of phosphate ester and method of preparation thereof |
| US19037088 | 1988-05-05 | ||
| US8901955 | 1989-05-04 | ||
| PCT/US1989/001955 WO1989010691A1 (en) | 1988-05-05 | 1989-05-04 | Biocidal delivery system and method of preparation thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI900046A0 FI900046A0 (fi) | 1990-01-04 |
| FI900046L FI900046L (fi) | 1990-01-04 |
| FI104354B true FI104354B (sv) | 2000-01-14 |
Family
ID=22701065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI900046A FI104354B (sv) | 1988-05-05 | 1990-01-04 | Biocid komposition samt förfarande för framställning av en produkt innehållande denna |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4908209A (sv) |
| EP (1) | EP0371103B1 (sv) |
| JP (2) | JPH089524B2 (sv) |
| KR (1) | KR930002951B1 (sv) |
| AT (1) | ATE124840T1 (sv) |
| AU (1) | AU617812B2 (sv) |
| BR (1) | BR8906946A (sv) |
| CA (1) | CA1339603C (sv) |
| DE (1) | DE68923428T2 (sv) |
| DK (1) | DK172750B1 (sv) |
| FI (1) | FI104354B (sv) |
| NO (1) | NO178712C (sv) |
| WO (1) | WO1989010691A1 (sv) |
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| DK0507106T3 (da) * | 1991-03-26 | 1995-08-07 | Sangi Kk | Antivedhæfningsmiddel til vandbårne organismer |
| US5324525A (en) * | 1991-03-26 | 1994-06-28 | Kabushiki Kaisha Sangi | Anti-adhesion agent to water borne organisms |
| AU3969595A (en) * | 1994-11-03 | 1996-05-31 | Micro-Pak, Inc. | Epoxy ester vesicles and paints |
| JPH08133907A (ja) * | 1994-11-10 | 1996-05-28 | Mikado Kako Kk | 持続性害虫忌避性成形体及びその製造方法 |
| US5756145A (en) * | 1995-11-08 | 1998-05-26 | Baylor College Of Medicine | Durable, Resilient and effective antimicrobial coating for medical devices and method of coating therefor |
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-
1988
- 1988-05-05 US US07/190,370 patent/US4908209A/en not_active Expired - Lifetime
-
1989
- 1989-05-04 CA CA000598904A patent/CA1339603C/en not_active Expired - Lifetime
- 1989-05-04 DE DE68923428T patent/DE68923428T2/de not_active Expired - Fee Related
- 1989-05-04 AU AU35588/89A patent/AU617812B2/en not_active Expired
- 1989-05-04 KR KR1019900700007A patent/KR930002951B1/ko not_active Expired - Fee Related
- 1989-05-04 JP JP1505285A patent/JPH089524B2/ja not_active Expired - Fee Related
- 1989-05-04 AT AT89905481T patent/ATE124840T1/de not_active IP Right Cessation
- 1989-05-04 BR BR898906946A patent/BR8906946A/pt unknown
- 1989-05-04 WO PCT/US1989/001955 patent/WO1989010691A1/en not_active Ceased
- 1989-05-04 EP EP89905481A patent/EP0371103B1/en not_active Expired - Lifetime
-
1990
- 1990-01-04 NO NO900028A patent/NO178712C/no unknown
- 1990-01-04 FI FI900046A patent/FI104354B/sv not_active IP Right Cessation
- 1990-01-05 DK DK199000034A patent/DK172750B1/da not_active IP Right Cessation
-
1995
- 1995-06-14 JP JP7147935A patent/JPH0820509A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02504151A (ja) | 1990-11-29 |
| DK172750B1 (da) | 1999-06-28 |
| CA1339603C (en) | 1997-12-30 |
| WO1989010691A1 (en) | 1989-11-16 |
| AU617812B2 (en) | 1991-12-05 |
| NO178712C (no) | 1996-05-22 |
| NO178712B (no) | 1996-02-12 |
| EP0371103A4 (en) | 1992-06-03 |
| FI900046A0 (fi) | 1990-01-04 |
| NO900028D0 (no) | 1990-01-04 |
| KR900701155A (ko) | 1990-12-01 |
| ATE124840T1 (de) | 1995-07-15 |
| BR8906946A (pt) | 1990-08-14 |
| DK3490A (da) | 1990-01-05 |
| JPH089524B2 (ja) | 1996-01-31 |
| EP0371103A1 (en) | 1990-06-06 |
| JPH0820509A (ja) | 1996-01-23 |
| DK3490D0 (da) | 1990-01-05 |
| FI900046L (fi) | 1990-01-04 |
| US4908209A (en) | 1990-03-13 |
| KR930002951B1 (ko) | 1993-04-16 |
| AU3558889A (en) | 1989-11-29 |
| EP0371103B1 (en) | 1995-07-12 |
| NO900028L (no) | 1990-03-02 |
| DE68923428D1 (de) | 1995-08-17 |
| DE68923428T2 (de) | 1996-02-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Patent granted |
Owner name: INTERFACE RESEARCH CORPORATION |
|
| MA | Patent expired |