FI112231B - Katalyyttikantaja, menetelmä katalyyttikantajan prekursorigeelin valmistamiseksi - Google Patents

Katalyyttikantaja, menetelmä katalyyttikantajan prekursorigeelin valmistamiseksi Download PDF

Info

Publication number: FI112231B
Authority: FI; Finland
Prior art keywords: silicon; aluminum; water; alcohol; gel
Prior art date: 1993-05-17

Application number

FI955530A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI955530A7 (fi

FI955530A0 (fi

Inventor

Benoit Koch

Andre Rulmont

Fabienne Wijzen

Original Assignee

Solvay

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-05-17

Filing date

1995-11-16

Publication date

2003-11-14

1995-11-16 Application filed by Solvay filed Critical Solvay

1995-11-16 Publication of FI955530A0 publication Critical patent/FI955530A0/fi

1996-01-12 Publication of FI955530A7 publication Critical patent/FI955530A7/fi

2003-11-14 Application granted granted Critical

2003-11-14 Publication of FI112231B publication Critical patent/FI112231B/fi

Links

238000000034 method Methods 0.000 title claims abstract description 71
239000002243 precursor Substances 0.000 title claims description 25
230000003197 catalytic effect Effects 0.000 title description 6
210000000056 organ Anatomy 0.000 title 1
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229910052710 silicon Inorganic materials 0.000 claims abstract description 60
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 55
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 55
229910052782 aluminium Inorganic materials 0.000 claims abstract description 48
239000003054 catalyst Substances 0.000 claims abstract description 42
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-1 silicon alkoxide Chemical class 0.000 claims abstract description 29
239000002253 acid Substances 0.000 claims abstract description 27
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 22
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims abstract description 18
239000003929 acidic solution Substances 0.000 claims abstract description 11
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XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 58
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239000002244 precipitate Substances 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
230000005070 ripening Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
238000010792 warming Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/033—Using Hydrolysis
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Medicinal Chemistry (AREA)
Health & Medical Sciences (AREA)
Polymers & Plastics (AREA)
Dispersion Chemistry (AREA)
Catalysts (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Polymerization Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

FI955530A 1993-05-17 1995-11-16 Katalyyttikantaja, menetelmä katalyyttikantajan prekursorigeelin valmistamiseksi FI112231B (fi)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
BE9300508A BE1007148A3 (fr)	1993-05-17	1993-05-17	Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur.
BE9300508		1993-05-17
EP9401513		1994-05-10
PCT/EP1994/001513 WO1994026790A1 (fr)	1993-05-17	1994-05-10	Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs

Publications (3)

Publication Number	Publication Date
FI955530A0 FI955530A0 (fi)	1995-11-16
FI955530A7 FI955530A7 (fi)	1996-01-12
FI112231B true FI112231B (fi)	2003-11-14

Family

ID=3887055

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
FI955530A FI112231B (fi)	1993-05-17	1995-11-16	Katalyyttikantaja, menetelmä katalyyttikantajan prekursorigeelin valmistamiseksi
FI955531A FI955531A7 (fi)	1993-05-17	1995-11-16	Menetelmä katalyyttikantajan valmistamiseksi, katalyytti olefiinipolymerisointia varten ja menetelmä olefiinien polymerisoimiseksi mainitulla katalyytillä

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
FI955531A FI955531A7 (fi)	1993-05-17	1995-11-16	Menetelmä katalyyttikantajan valmistamiseksi, katalyytti olefiinipolymerisointia varten ja menetelmä olefiinien polymerisoimiseksi mainitulla katalyytillä

Country Status (22)

Country	Link
US (3)	US5849852A (pl)
EP (2)	EP0700403B1 (pl)
JP (2)	JPH09503234A (pl)
KR (2)	KR100319213B1 (pl)
CN (2)	CN1050366C (pl)
AT (2)	ATE157102T1 (pl)
AU (2)	AU677340B2 (pl)
BE (1)	BE1007148A3 (pl)
BR (2)	BR9406407A (pl)
CA (2)	CA2163119A1 (pl)
DE (2)	DE69405099T2 (pl)
DK (2)	DK0700404T3 (pl)
ES (2)	ES2108462T3 (pl)
FI (2)	FI112231B (pl)
MX (1)	MX9403604A (pl)
MY (2)	MY111095A (pl)
NO (2)	NO308218B1 (pl)
NZ (2)	NZ266777A (pl)
PL (2)	PL178487B1 (pl)
RU (2)	RU2117676C1 (pl)
TW (2)	TW341527B (pl)
WO (2)	WO1994026791A1 (pl)

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1993
- 1993-05-17 BE BE9300508A patent/BE1007148A3/fr not_active IP Right Cessation
1994
- 1994-05-10 CN CN94192642A patent/CN1050366C/zh not_active Expired - Fee Related
- 1994-05-10 DE DE69405099T patent/DE69405099T2/de not_active Expired - Fee Related
- 1994-05-10 AU AU69271/94A patent/AU677340B2/en not_active Ceased
- 1994-05-10 CA CA002163119A patent/CA2163119A1/fr not_active Abandoned
- 1994-05-10 RU RU95122689/04A patent/RU2117676C1/ru not_active IP Right Cessation
- 1994-05-10 CA CA002162915A patent/CA2162915A1/fr not_active Abandoned
- 1994-05-10 JP JP6524957A patent/JPH09503234A/ja active Pending
- 1994-05-10 US US08/553,326 patent/US5849852A/en not_active Expired - Fee Related
- 1994-05-10 AT AT94917615T patent/ATE157102T1/de not_active IP Right Cessation
- 1994-05-10 DK DK94917615.0T patent/DK0700404T3/da active
- 1994-05-10 NZ NZ266777A patent/NZ266777A/en unknown
- 1994-05-10 EP EP94916948A patent/EP0700403B1/fr not_active Expired - Lifetime
- 1994-05-10 ES ES94917615T patent/ES2108462T3/es not_active Expired - Lifetime
- 1994-05-10 NZ NZ267088A patent/NZ267088A/en unknown
- 1994-05-10 KR KR1019950705120A patent/KR100319213B1/ko not_active Expired - Fee Related
- 1994-05-10 KR KR1019950705140A patent/KR100327301B1/ko not_active Expired - Fee Related
- 1994-05-10 WO PCT/EP1994/001514 patent/WO1994026791A1/fr not_active Ceased
- 1994-05-10 PL PL94311674A patent/PL178487B1/pl unknown
- 1994-05-10 JP JP6524956A patent/JPH09500663A/ja not_active Ceased
- 1994-05-10 WO PCT/EP1994/001513 patent/WO1994026790A1/fr not_active Ceased
- 1994-05-10 ES ES94916948T patent/ES2108457T3/es not_active Expired - Lifetime
- 1994-05-10 DK DK94916948.6T patent/DK0700403T3/da active
- 1994-05-10 AU AU68435/94A patent/AU696784B2/en not_active Ceased
- 1994-05-10 US US08/553,330 patent/US5834572A/en not_active Expired - Fee Related
- 1994-05-10 DE DE69405100T patent/DE69405100T2/de not_active Expired - Fee Related
- 1994-05-10 PL PL94311673A patent/PL178575B1/pl not_active IP Right Cessation
- 1994-05-10 BR BR9406407A patent/BR9406407A/pt not_active IP Right Cessation
- 1994-05-10 CN CN94192639A patent/CN1048732C/zh not_active Expired - Fee Related
- 1994-05-10 BR BR9406408A patent/BR9406408A/pt not_active IP Right Cessation
- 1994-05-10 AT AT94916948T patent/ATE157101T1/de not_active IP Right Cessation
- 1994-05-10 RU RU95122675/04A patent/RU2117675C1/ru not_active IP Right Cessation
- 1994-05-10 EP EP94917615A patent/EP0700404B1/fr not_active Expired - Lifetime
- 1994-05-11 MY MYPI94001174A patent/MY111095A/en unknown
- 1994-05-11 MY MYPI94001175A patent/MY110978A/en unknown
- 1994-05-16 MX MX9403604A patent/MX9403604A/es not_active IP Right Cessation
- 1994-05-19 TW TW083104551A patent/TW341527B/zh active
- 1994-08-11 TW TW083107350A patent/TW349959B/zh active
1995
- 1995-11-16 FI FI955530A patent/FI112231B/fi not_active IP Right Cessation
- 1995-11-16 NO NO954639A patent/NO308218B1/no unknown
- 1995-11-16 FI FI955531A patent/FI955531A7/fi unknown
- 1995-11-16 NO NO954638A patent/NO308217B1/no not_active IP Right Cessation
1998
- 1998-02-26 US US09/030,821 patent/US6074980A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2162915A1 (fr)	1994-11-24
NZ266777A (en)	1996-08-27
US5834572A (en)	1998-11-10
JPH09503234A (ja)	1997-03-31
MX9403604A (es)	1995-01-31
RU2117675C1 (ru)	1998-08-20
DE69405100T2 (de)	1998-03-12
BE1007148A3 (fr)	1995-04-11
KR960702483A (ko)	1996-04-27
PL311674A1 (en)	1996-03-04
BR9406407A (pt)	1995-12-19
EP0700403B1 (fr)	1997-08-20
CN1126479A (zh)	1996-07-10
DE69405099T2 (de)	1998-03-05
ATE157101T1 (de)	1997-09-15
US6074980A (en)	2000-06-13
DK0700403T3 (da)	1998-04-06
ATE157102T1 (de)	1997-09-15
NO954638L (no)	1996-01-16
NO954638D0 (no)	1995-11-16
PL311673A1 (en)	1996-03-04
NO954639L (no)	1996-01-16
AU6927194A (en)	1994-12-12
DE69405100D1 (de)	1997-09-25
FI955530A7 (fi)	1996-01-12
PL178575B1 (pl)	2000-05-31
ES2108457T3 (es)	1997-12-16
FI955530A0 (fi)	1995-11-16
TW341527B (en)	1998-10-01
EP0700404A1 (fr)	1996-03-13
WO1994026791A1 (fr)	1994-11-24
KR960702482A (ko)	1996-04-27
KR100327301B1 (ko)	2002-07-12
BR9406408A (pt)	1995-12-19
AU677340B2 (en)	1997-04-17
TW349959B (en)	1999-01-11
PL178487B1 (pl)	2000-05-31
US5849852A (en)	1998-12-15
EP0700404B1 (fr)	1997-08-20
ES2108462T3 (es)	1997-12-16
FI955531A0 (fi)	1995-11-16
RU2117676C1 (ru)	1998-08-20
MY110978A (en)	1999-07-31
DE69405099D1 (de)	1997-09-25
CN1050366C (zh)	2000-03-15
AU6843594A (en)	1994-12-12
DK0700404T3 (da)	1998-03-30
JPH09500663A (ja)	1997-01-21
WO1994026790A1 (fr)	1994-11-24
KR100319213B1 (ko)	2002-04-22
MY111095A (en)	1999-08-30
NO308217B1 (no)	2000-08-14
AU696784B2 (en)	1998-09-17
NO308218B1 (no)	2000-08-14
EP0700403A1 (fr)	1996-03-13
FI955531A7 (fi)	1996-01-12
CN1048732C (zh)	2000-01-26
NO954639D0 (no)	1995-11-16
NZ267088A (en)	1996-10-28
CA2163119A1 (fr)	1994-11-24
CN1126480A (zh)	1996-07-10

Legal Events

Date	Code	Title	Description
1997-11-19	GB	Transfer or assigment of application	Owner name: SOLVAY POLYOLEFINS EUROPE-BELGIUM
2005-11-30	MA	Patent expired

Publication	Publication Date	Title
FI112231B (fi)	2003-11-14	Katalyyttikantaja, menetelmä katalyyttikantajan prekursorigeelin valmistamiseksi
US4364842A (en)	1982-12-21	Phosphate supported chromium catalyst
CA1080206A (en)	1980-06-24	Olefin polymerization catalyst
JP3303239B2 (ja)	2002-07-15	担持触媒
US5292701A (en)	1994-03-08	High pore volume and pore diameter aluminum phosphate and method of making the same
CA1165950A (en)	1984-04-17	Phosphate containing support with zerovalent chromium
HUP0203283A2 (hu)	2003-01-28	Polimerizációs katalizátor-rendszerek, és eljárások alkil-lítium kokatalizátorok alkalmazására
RU2262512C2 (ru)	2005-10-20	Хромсодержащий катализатор на основе диоксида кремния, способ его получения и способ получения полиэтилена с использованием данного катализатора
CA2050815C (en)	2003-02-11	Solid component of catalyst for the (co)polymerization of ethylene
US5030431A (en)	1991-07-09	High pore volume and pore diameter aluminum phosphate
JPH0243685B2 (pl)	1990-10-01
NO155140B (no)	1986-11-10	Titan-modifisert silylkromat-katalysator for etylen-polymerisering, samt fremgangsmaate for fremstilling derav.
HUP0102282A2 (hu)	2001-10-28	Katalizátorkészítmény monomerek polimerizálására
US4049896A (en)	1977-09-20	Olefin polymerization catalyst
FI115529B (fi)	2005-05-31	Katalyyttinen järjestelmä olefiinien polymeroimiseksi ja menetelmä ainakin yhden olefiinin polymeroimiseksi tämän katalyyttisen järjestelmän läsnä ollessa
EP0215336A1 (en)	1987-03-25	High pore volume aluminum phosphate
CA1080207A (en)	1980-06-24	Olefin polymerization catalyst
CA2098380A1 (en)	1992-06-20	Method for the preparation of a polymerizing catalyst component, a polymerizing catalyst component prepared by the method and its use
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CA1077462A (en)	1980-05-13	Process for the polymerization of alpha-olefins, catalyst employed in said process and method for the preparation thereof
USRE34911E (en)	1995-04-18	High pore volume and pore diameter aluminum phosphate